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28 pages, 9392 KB  
Article
Analysis Method and Experiment on the Influence of Hard Bottom Layer Contour on Agricultural Machinery Motion Position and Posture Changes
by Tuanpeng Tu, Xiwen Luo, Lian Hu, Jie He, Pei Wang, Peikui Huang, Runmao Zhao, Gaolong Chen, Dawen Feng, Mengdong Yue, Zhongxian Man, Xianhao Duan, Xiaobing Deng and Jiajun Mo
Agriculture 2026, 16(2), 170; https://doi.org/10.3390/agriculture16020170 - 9 Jan 2026
Viewed by 254
Abstract
The hard bottom layer in paddy fields significantly impacts the driving stability, operational quality, and efficiency of agricultural machinery. Continuously improving the precision and efficiency of unmanned, precision operations for paddy field machinery is essential for realizing unmanned smart rice farms. Addressing the [...] Read more.
The hard bottom layer in paddy fields significantly impacts the driving stability, operational quality, and efficiency of agricultural machinery. Continuously improving the precision and efficiency of unmanned, precision operations for paddy field machinery is essential for realizing unmanned smart rice farms. Addressing the unclear influence patterns of hard bottom contours on typical scenarios of agricultural machinery motion and posture changes, this paper employs a rice transplanter chassis equipped with GNSS and AHRS. It proposes methods for acquiring motion state information and hard bottom contour data during agricultural operations, establishing motion state expression models for key points on the machinery antenna, bottom of the wheel, and rear axle center. A correlation analysis method between motion state and hard bottom contour parameters was established, revealing the influence mechanisms of typical hard bottom contours on machinery trajectory deviation, attitude response, and wheel trapping. Results indicate that hard bottom contour height and local roughness exert extremely significant effects on agricultural machinery heading deviation and lateral movement. Heading variation positively correlates with ridge height and negatively with wheel diameter. The constructed mathematical model for heading variation based on hard bottom contour height difference and wheel diameter achieves a coefficient of determination R2 of 0.92. The roll attitude variation in agricultural machinery is primarily influenced by the terrain characteristics encountered by rear wheels. A theoretical model was developed for the offset displacement of the antenna position relative to the horizontal plane during roll motion. The accuracy of lateral deviation detection using the posture-corrected rear axle center and bottom of the wheel center improved by 40.7% and 39.0%, respectively, compared to direct measurement using the positioning antenna. During typical vehicle-trapping events, a segmented discrimination function for trapping states is developed when the terrain profile steeply declines within 5 s and roughness increases from 0.008 to 0.012. This method for analyzing how hard bottom terrain contours affect the position and attitude changes in agricultural machinery provides theoretical foundations and technical support for designing wheeled agricultural robots, path-tracking control for unmanned precision operations, and vehicle-trapping early warning systems. It holds significant importance for enhancing the intelligence and operational efficiency of paddy field machinery. Full article
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28 pages, 5376 KB  
Article
Rheological and Thermo-Mechanical Characterisation of Sustainable Polypropylene Composites Reinforced with Micronised Rice Husk
by Inês Santos, Tatiana Zhiltsova, José Martinho Oliveira, Sara P. Magalhães da Silva and Mónica S. A. Oliveira
J. Compos. Sci. 2025, 9(12), 662; https://doi.org/10.3390/jcs9120662 - 2 Dec 2025
Viewed by 542
Abstract
The growing demand for sustainable materials in construction and sanitation has increased interest in natural fibre-reinforced polymer composites. Rice husk, an abundant agricultural by-product, offers a promising alternative as a reinforcing filler in polypropylene (PP) composites. This study aims to assess the suitability [...] Read more.
The growing demand for sustainable materials in construction and sanitation has increased interest in natural fibre-reinforced polymer composites. Rice husk, an abundant agricultural by-product, offers a promising alternative as a reinforcing filler in polypropylene (PP) composites. This study aims to assess the suitability of PP composites reinforced with micronised rice husk particles for application in sanitary components. Two formulations containing 20% and 30% rice husk were developed and characterised. Comprehensive analysis included morphological, thermal, rheological, mechanical, hygroscopic, and tribological testing. Results showed that particles incorporation enhanced thermal stability and crystallinity due to a nucleating effect, with the 30% composite showing higher crystallinity. Thermogravimetric analysis showed that although the T5% decreased from 374.1 °C for neat PP to 309.2 °C and 296.2 °C for the 20% and 30% composites, respectively, the DTG peak temperatures increased by 15.9 °C and 17.6 °C, indicating a delayed main decomposition stage of PP matrix and enhanced overall thermal stability. Rheological behaviour revealed increased viscosity and pseudoplasticity at higher particle content Mechanical characterisation showed an increase in Young’s modulus from 1021 MPa for neat PP to 1065 MPa (+4%) and 1125 MPa (+10%) for PP_Rice_20% and PP_Rice_30%, respectively. In contrast, the nominal strain at break dropped sharply from 238% (PP) to 30% (PP_Rice_20%) and 16% (PP_Rice_30%). Shrinkage decreased from 1.31% (PP) to approximately 1.05% in both composites, indicating improved dimensional stability. However, water absorption rose from 0.015% (PP) to 0.111% (PP_Rice_20%) and 0.144% (PP_Rice_30%), accompanied by an increase in surface roughness (Sa from 0.34 µm to 0.78 µm and 1.06 µm, respectively). The composite with 20% rice husk demonstrated better filler dispersion, reduced water uptake, and smoother surfaces, making it more suitable for injection-moulded components intended for use in humid environments. Overall, the study supports the use of agricultural residues in high-performance biocomposites, contributing to circular economy strategies and the development of more sustainable polymer-based materials for technical applications. Full article
(This article belongs to the Special Issue Mechanical Properties of Composite Materials and Joints)
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20 pages, 5882 KB  
Article
Microstructure-Driven Feasibility of Crushed Bamboo Coarse Aggregate for Structural–Insulating Wall Composites
by Aliaksandr Bakatovich, Aleksandr Yagubkin, Nadezhda Bakatovich, Olga Kizinievič, Yahor Trambitski and Jie Wen
Buildings 2025, 15(23), 4295; https://doi.org/10.3390/buildings15234295 - 27 Nov 2025
Viewed by 420
Abstract
This study evaluates crushed bamboo as a coarse aggregate for structural–thermal wall composites, comparing its performance against mixes with wood sawdust and rice husk. Crushed bamboo was used in both smooth and surface-roughened conditions, where particle morphology and surface features were characterized by [...] Read more.
This study evaluates crushed bamboo as a coarse aggregate for structural–thermal wall composites, comparing its performance against mixes with wood sawdust and rice husk. Crushed bamboo was used in both smooth and surface-roughened conditions, where particle morphology and surface features were characterized by SEM and AFM methods. The roughened bamboo aggregate exhibited greater surface roughness, thereby improving interfacial adhesion with cement. Surface roughening increased 28-day compressive strength by ~39–44% relative to smooth particles. Incorporating fine plant-based fillers into cement–bamboo composites increased their compressive strength by ~33–75% and reduced thermal conductivity by ~12–18%, compared with the analogues without fine particles. Water-absorption tests on bamboo aggregate showed rapid uptake in the first 24 h (43–45%) and saturation after 7 days of ~65–70%, values lower than typical wood by-products, thereby helping to limit mix water demand. Findings indicate that crushed, surface-roughened bamboo, especially with fine bio-fillers, can produce sustainable wall materials with a strong balance between strength and insulation. Full article
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18 pages, 4375 KB  
Article
Study on the Changes of Antioxidant System and Respiratory Metabolism in Rice Grains Under Nitrogen-Modified Atmosphere Storage from the Targeted Metabolomics Perspective
by Ming Chen, Xia Ma, Wenhao Li, Feiyan Xue and Chenling Qu
Foods 2025, 14(21), 3643; https://doi.org/10.3390/foods14213643 - 25 Oct 2025
Viewed by 630
Abstract
Nitrogen-modified atmosphere technology, due to its effectiveness in pest control, is widely used in grain storage as an eco-friendly preservation method. This study compared the quality changes in unhulled rough rice (paddy) stored under nitrogen-modified atmosphere and conventional conditions. Fatty acid value (FAV), [...] Read more.
Nitrogen-modified atmosphere technology, due to its effectiveness in pest control, is widely used in grain storage as an eco-friendly preservation method. This study compared the quality changes in unhulled rough rice (paddy) stored under nitrogen-modified atmosphere and conventional conditions. Fatty acid value (FAV), reactive oxygen species (ROS) content, coenzyme levels, antioxidant enzyme activities, and concentrations of central carbon metabolism-related metabolites of paddy were monitored during storage under different storage conditions. The results revealed that compared to conventional storage, nitrogen-modified atmosphere resulted in lower FAV and ROS levels, as well as higher pyridine nucleotides contents and antioxidant enzyme activities, including superoxide dismutase (SOD), peroxidase (POD), catalase (CAT), and glutathione reductase (GR). Metabolomic profiling demonstrated that N2-MAS induced metabolic changes characterized by the down-regulation of 2-hydroxyglutaric acid and the up-regulation of fructose 6-phosphate, glucose 1-phosphate, glycerol 3-phosphate, gluconic acid, fumaric acid, and malic acid, which collectively contribute to reduced oxidative damage and enhanced preservation quality. These findings elucidated the mechanism of N2-MAS-delayed quality deterioration and revealed the regulatory role of the antioxidant system and central carbon metabolism. Full article
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30 pages, 1776 KB  
Article
Connectedness of Agricultural Commodities Under Climate Stress: Evidence from a TVP-VAR Approach
by Nini Johana Marín-Rodríguez, Juan David Gonzalez-Ruiz and Sergio Botero
Sci 2025, 7(3), 123; https://doi.org/10.3390/sci7030123 - 4 Sep 2025
Cited by 1 | Viewed by 1992
Abstract
Agricultural markets are increasingly exposed to global risks as climate change intensifies and macro-financial volatility becomes more prevalent. This study examines the dynamic interconnection between major agricultural commodities—soybeans, corn, wheat, rough rice, and sugar—and key uncertainty indicators, including climate policy uncertainty, global economic [...] Read more.
Agricultural markets are increasingly exposed to global risks as climate change intensifies and macro-financial volatility becomes more prevalent. This study examines the dynamic interconnection between major agricultural commodities—soybeans, corn, wheat, rough rice, and sugar—and key uncertainty indicators, including climate policy uncertainty, global economic policy uncertainty, geopolitical risk, financial market volatility, oil price volatility, and the U.S. Dollar Index. Using a Time-Varying Parameter Vector Autoregressive (TVP-VAR) model with monthly data, we assess both internal spillovers within the commodity system and external spillovers from macro-level uncertainties. On average, the external shock from the VIX to corn reaches 12.4%, and the spillover from RGEPU to wheat exceeds 10%, while internal links like corn to wheat remain below 8%. The results show that external uncertainty consistently dominates the connectedness structure, particularly during periods of geopolitical or financial stress, while internal interactions remain relatively subdued. Unexpectedly, recent global disruptions such as the COVID-19 pandemic and the Russia–Ukraine conflict do not exhibit strong or persistent effects on the connectedness patterns, likely due to model smoothing, stockpiling policies, and supply chain adaptations. These findings highlight the importance of strengthening international macro-financial and climate policy coordination to mitigate the propagation of external shocks. By distinguishing between internal and external connectedness under climate stress, this study contributes new insights into how systemic risks affect agri-food systems and offers a methodological framework for future risk monitoring. Full article
(This article belongs to the Special Issue Advances in Climate Change Adaptation and Mitigation)
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23 pages, 17844 KB  
Article
Evaluation of Surface Properties in Biosilica-Reinforced Biobased Polyester Nanocomposites
by Hifa Salah Adeen Embirsh, Ivana O. Mladenović, Vesna Radojević, Aleksandar Marinković and Marija M. Vuksanović
Appl. Sci. 2025, 15(17), 9244; https://doi.org/10.3390/app15179244 - 22 Aug 2025
Viewed by 3728
Abstract
This study investigates the surface properties of bio-based unsaturated polyester resin (b-UPR) nanocomposites reinforced with biosilica nanoparticles derived from rice husk. The b-UPR matrix was synthesized from recycled polyethylene terephthalate (PET) and renewable monomers, providing a sustainable alternative to conventional polyester resins. Unmodified [...] Read more.
This study investigates the surface properties of bio-based unsaturated polyester resin (b-UPR) nanocomposites reinforced with biosilica nanoparticles derived from rice husk. The b-UPR matrix was synthesized from recycled polyethylene terephthalate (PET) and renewable monomers, providing a sustainable alternative to conventional polyester resins. Unmodified and modified biosilica particles with silanes: (3-trimethoxysilylpropyl methacrylate—MEMO, trimethoxyvinylsilane—VYNIL, and 3-aminopropyltrimethoxysilane with biodiesel—AMBD) were incorporated in different amounts to evaluate their influence on the wettability, topography, and viscoelastic behavior of the composites. Contact angle measurements revealed that the addition of modified biosilica significantly improved the hydrophobicity of the b-UPR surface. The greatest increase in the wetting angle, amounting to 79.9% compared to composites with unmodified silica, was observed in the composites containing 5 wt.% SiO2-AMBD. Atomic force microscopy (AFM) analysis indicated enhanced surface roughness and uniform dispersion of the nanoparticles. For the composite containing 1 wt.% of silica particles, the surface roughness increased by 25.5% with the AMBD modification and by 84.2% with the MEMO modification, compared to the unmodified system. Creep testing demonstrated that the reinforced nanocomposites exhibited improved dimensional stability under sustained load compared to the neat resin. These findings confirm that the integration of surface-modified biosilica not only enhances the mechanical properties but also optimizes the surface characteristics of bio-based polyester composites, broadening their potential for high-performance and sustainable applications. Full article
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16 pages, 5911 KB  
Article
Effects of Sand Rollers with Different Grit Sizes on Processing Quality, Gelatinization, and Rheological Properties of Rice
by Yang Zhang, Yuxin Han, Weiwei Cao, Wenchao Liu, Linlin Li, Junliang Chen, Xu Duan, Tongxiang Yang, Xinyu Wei, Peijie Zhang, Mengmeng Yang, Mengyao Guo, Debang Zhang, Huiping Fan, Ke Liu and Guangyue Ren
Processes 2025, 13(2), 564; https://doi.org/10.3390/pr13020564 - 17 Feb 2025
Viewed by 1147
Abstract
The surface roughness of sand rollers directly influences the precision of rice processing. Therefore, the effects of sand rollers with different grit sizes (46#, 36#, and 30#) on rice quality were investigated in this work. The results indicated that the embryo retention ratio [...] Read more.
The surface roughness of sand rollers directly influences the precision of rice processing. Therefore, the effects of sand rollers with different grit sizes (46#, 36#, and 30#) on rice quality were investigated in this work. The results indicated that the embryo retention ratio of polished rice decreased, and the milling degree increased as the grit size of the sand rollers decreased. The milling degree of the polished rice milled with sand rollers 36# and 30# was higher than that of rice milled with sand roller 46#. The rice milled with sand roller 30# showed the lowest content of fat, ash, and total phenolics. The rice milled with sand roller 46# exhibited the highest scavenging of ABTS free radicals (41.55%) and DPPH free radical activity (36.79%). The polished rice milled with sand roller 30# exhibited a higher peak viscosity, trough, breakdown, and final viscosity and a lower setback. The retrogradation rate of rice decreased as the rice was milled by all grit sizes of sand rollers. In conclusion, milling brown rice with sand rollers with different abrasive particle sizes could affect the quality of polished rice. This study provides a reference for the processing techniques of polished rice with different degrees of processing. Full article
(This article belongs to the Section Food Process Engineering)
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22 pages, 3519 KB  
Article
Use of Modified Activated Carbon in Groundwater Remediation for Human Consumption
by Cadme-Arévalo María Lorena, Andrade-Yucailla Verónica Cristina, Geijo López Alda, Villamar-Torres Ronald Oswaldo, Campisi Cadme Raisha Lorena, Arreaga Cadme Thais Sarah, Fernández González Javier, Benavente Herrera José, Sesan Abiodun Aransiola and Naga Raju Maddela
Water 2025, 17(2), 207; https://doi.org/10.3390/w17020207 - 14 Jan 2025
Cited by 2 | Viewed by 2062
Abstract
This study aimed to produce activated carbon from desilicated rice husks using various carbonization and activation methods, including a tube furnace, muffle furnace, and artisanal pyrolysis. The resulting activated carbons were characterized for their adsorptive capacity through the determination of iodine number and [...] Read more.
This study aimed to produce activated carbon from desilicated rice husks using various carbonization and activation methods, including a tube furnace, muffle furnace, and artisanal pyrolysis. The resulting activated carbons were characterized for their adsorptive capacity through the determination of iodine number and methylene blue adsorption; these are key indicators of specific surface area and adsorbent quality. Advanced characterization techniques were employed, such as scanning electron microscopy (SEM), which revealed a highly porous and irregular surface structure, and energy dispersive X-ray spectroscopy (EDS), confirming the effective removal of impurities and optimization of the elemental composition. Atomic force microscopy (AFM) demonstrated favorable surface roughness for adsorption processes. Among the samples, CaDH162-CADH53 exhibited the highest performance, with an iodine number of 1094.8 mg/g and a yield of 93.5%, signifying a high adsorption capacity. The activation treatments with phosphoric acid and calcium carbonate significantly improved the porous structure, further enhancing the material’s adsorptive properties. In conclusion, the activated carbons produced in this study demonstrated optimal physicochemical properties for water purification and contaminant treatment applications. These findings highlight the potential of using agricultural waste, such as rice husk, as a sustainable and scalable alternative for industrial-scale activated carbon production. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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18 pages, 663 KB  
Article
Comparative Analysis of Physical and Engineering Properties of New Egyptian Paddy Rice (Giza 183) Adapted to Mitigate Effects of Climate Change
by Waleed A. Almasoud, Mahmoud Abdel-Sattar, Doaa A. Abdelbary, Saber Sedeek, Abdulwahed M. Aboukarima, Dalia H. Eshra, Hail Z. Rihan and Mohamed E. Yehia
Agronomy 2024, 14(12), 2785; https://doi.org/10.3390/agronomy14122785 - 23 Nov 2024
Cited by 1 | Viewed by 4189
Abstract
One of the major challenges for crop breeding scientists is climate change. Their task is to develop new crop varieties that can withstand this phenomenon. For this study, a new Egyptian paddy variety called Giza 183, which is designed to adapt to mitigate [...] Read more.
One of the major challenges for crop breeding scientists is climate change. Their task is to develop new crop varieties that can withstand this phenomenon. For this study, a new Egyptian paddy variety called Giza 183, which is designed to adapt to mitigate the effects of climate change, was chosen. We focused on examining the physical and engineering properties of this variety in order to design strategies for storage, handling, transportation, drying, parboiling, and processing equipment in rice mills. The goal was to minimize post-harvest losses during the milling process, thereby maximizing high-quality yields while reducing losses. The physical properties of the rice grains, such as the length, width, and thickness, were measured at an average moisture content of 13.7% ± 0.25% (wet basis). The results reveal that the mean values of length, width, and thickness averaged 7.50 mm, 3.18 mm, and 2.19 mm, respectively. Additionally, the geometric mean diameter, the equivalent mean diameter, surface area, arithmetic mean diameter, and volume were approximately 3.74 mm, 2.38 mm, 37.37 mm2, 4.29 mm, and 28.23 mm3, respectively. The mean of sphericity was 49.9%, and the grain shape (length/width) was 2.19. The true density was measured at 1218.28 kgm−3, while the bulk density was 572.17 kgm−3. The porosity was found to be 53.03%. Furthermore, the milling production rates for brown rice, hull, white rice, and broken rice were determined to be 76.83%, 23.15%, 67.97%, and 17.36%, respectively. The average weight of one thousand grains was 25.49 g. A linear regression model for describing the mass of rough rice grain was investigated. The mass was estimated with the single variable of the grain aspect ratio (width/length) with a determination coefficient of 0.9908. Information gained from the current study will be useful in designing post-harvest processing and storage structures in rice processing industries. Full article
(This article belongs to the Section Agroecology Innovation: Achieving System Resilience)
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20 pages, 1612 KB  
Article
Determination of Optical and Structural Parameters of Thin Films with Differently Rough Boundaries
by Ivan Ohlídal, Jiří Vohánka, Jan Dvořák, Vilma Buršíková and Petr Klapetek
Coatings 2024, 14(11), 1439; https://doi.org/10.3390/coatings14111439 - 12 Nov 2024
Cited by 3 | Viewed by 2184
Abstract
The optical characterization of non-absorbing, homogeneous, isotropic polymer-like thin films with correlated, differently rough boundaries is essential in optimizing their performance in various applications. A central aim of this study is to derive the general formulae necessary for the characterization of such films. [...] Read more.
The optical characterization of non-absorbing, homogeneous, isotropic polymer-like thin films with correlated, differently rough boundaries is essential in optimizing their performance in various applications. A central aim of this study is to derive the general formulae necessary for the characterization of such films. The applicability of this theory is illustrated through the characterization of a polymer-like thin film deposited by plasma-enhanced chemical vapor deposition onto a silicon substrate with a randomly rough surface, focusing on the analysis of its rough boundaries over a wide range of spatial frequencies. The method is based on processing experimental data obtained using variable-angle spectroscopic ellipsometry and spectroscopic reflectometry. The transition layer is considered at the lower boundary of the polymer-like thin film. The spectral dependencies of the optical constants of the polymer-like thin film and the transition layer are determined using the Campi–Coriasso dispersion model. The reflectance data are processed using a combination of Rayleigh–Rice theory and scalar diffraction theory in the near-infrared and visible spectral ranges, while scalar diffraction theory is used for the processing of reflectance data within the ultraviolet range. Rayleigh–Rice theory alone is sufficient for the processing of the ellipsometric data across the entire spectral range. We accurately determine the thicknesses of the polymer-like thin film and the transition layer, as well as the roughness parameters of both boundaries, with the root mean square (rms) values cross-validated using atomic force microscopy. Notably, the rms values derived from optical measurements and atomic force microscopy show excellent agreement. These findings confirm the reliability of the optical method for the detailed characterization of thin films with differently rough boundaries, supporting the applicability of the proposed method in high-precision film analysis. Full article
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14 pages, 2916 KB  
Article
What Is the Relationship Between Sensory Attributes Identified Using CATA (Check-All-That-Apply) Questionnaire and Consumer Acceptance of Cookies Using Plant-Based Oils?
by Juyoun Lee and Seyoung Ju
Foods 2024, 13(22), 3593; https://doi.org/10.3390/foods13223593 - 10 Nov 2024
Cited by 6 | Viewed by 3268
Abstract
The purpose of this study was to investigate sensory attributes identified using a CATA questionnaire and consumer acceptance of cookies using plant-based oils and to determine which sensory attributes influence and improve purchase intention of cookies using plant-based oils. Frequency analysis, one-way analysis [...] Read more.
The purpose of this study was to investigate sensory attributes identified using a CATA questionnaire and consumer acceptance of cookies using plant-based oils and to determine which sensory attributes influence and improve purchase intention of cookies using plant-based oils. Frequency analysis, one-way analysis of variance, correspondence analysis, Pearson correlation analysis, and multiple factor analysis were used for statistical evaluation. Six cookie samples, five with types of vegetable oil (canola, brown rice, coconut, soybean, olive) and one with butter, were evaluated by 112 consumers. Of the 28 sensory attributes, the 11 sensory terms of milk, savory, sweet aroma/odor, sweet, roasted grain, milk taste/flavor, hardness, “crispy”, “stuffy”, roughness, and “crumble” were significantly different among samples (p < 0.001). In the consumer acceptance and purchase intention tests, participants evaluated 12 attributes, namely, overall liking, appearance, color, aroma/smell, overall taste, savory flavor, flavor, sweet taste, aftertaste, texture, “smooth”, “crispy”, “try again”, recommendations, and familiarity, on a 9-point structured hedonic scale. All attributes except “smooth” were significantly different among the six cookie samples tested (p < 0.001). Samples with coconut oil and butter had the highest consumer acceptance. In particular, in a correspondence analysis, the samples with butter and coconut oil positioned in the positive direction (+) of Dimension (Component) 1 were closely related with mouthfeel, sweet aroma, sweet taste, “crispy”, “try again”, recommendation, familiarity, and overall liking. Our results suggest that cookies with coconut oil could be a substitute for animal-fat-based cookies with butter. We hope that our research will provide fundamental data for the development of vegan bakery products that meet the needs of consumers and food companies. Full article
(This article belongs to the Section Plant Foods)
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20 pages, 10241 KB  
Article
Influence of SiO2 Nanoparticles Extracted from Biomass on the Properties of Electrodeposited Ni Matrix Composite Films on Si(100) Substrate
by Ivana O. Mladenović, Nebojša D. Nikolić, Vladislav Jovanov, Željko M. Radovanović, Marko M. Obradov, Dana G. Vasiljević-Radović and Marija M. Vuksanović
Materials 2024, 17(16), 4138; https://doi.org/10.3390/ma17164138 - 21 Aug 2024
Cited by 3 | Viewed by 1954
Abstract
Lab-made biosilica (SiO2) nanoparticles were obtained from waste biomass (rice husks) and used as eco-friendly fillers in the production of nickel matrix composite films via the co-electrodeposition technique. The produced biosilica nanoparticles were characterized using XRD, FTIR, and FE-SEM/EDS. Amorphous nano-sized [...] Read more.
Lab-made biosilica (SiO2) nanoparticles were obtained from waste biomass (rice husks) and used as eco-friendly fillers in the production of nickel matrix composite films via the co-electrodeposition technique. The produced biosilica nanoparticles were characterized using XRD, FTIR, and FE-SEM/EDS. Amorphous nano-sized biosilica particles with a high SiO2 content were obtained. Various current regimes of electrodeposition, such as direct current (DC), pulsating current (PC), and reversing current (RC) regimes, were applied for the fabrication of Ni and Ni/SiO2 films from a sulfamate electrolyte. Ni films electrodeposited with or without 1.0 wt.% biosilica nanoparticles in the electrolyte were characterized using FE-SEM/EDS (morphology/elemental analyses, roundness), AFM (roughness), Vickers microindentation (microhardness), and sheet resistance. Due to the incorporation of SiO2 nanoparticles, the Ni/SiO2 films were coarser than those obtained from the pure sulfamate electrolyte. The addition of SiO2 to the sulfamate electrolyte also caused an increase in the roughness and electrical conductivity of the Ni films. The surface roughness values of the Ni/SiO2 films were approximately 44.0%, 48.8%, and 68.3% larger than those obtained for the pure Ni films produced using the DC, PC, and RC regimes, respectively. The microhardness of the Ni and Ni/SiO2 films was assessed using the Chen-Gao (C-G) composite hardness model, and it was shown that the obtained Ni/SiO2 films had a higher hardness than the pure Ni films. Depending on the applied electrodeposition regime, the hardness of the Ni films increased from 29.1% for the Ni/SiO2 films obtained using the PC regime to 95.5% for those obtained using the RC regime, reaching the maximal value of 6.880 GPa for the Ni/SiO2 films produced using the RC regime. Full article
(This article belongs to the Special Issue The Microstructures and Advanced Functional Properties of Thin Films)
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17 pages, 14137 KB  
Article
Effects of Mixed Microcapsules in Different Proportions on Aging Resistance and Self-Healing Properties of Waterborne Coatings for Tilia europaea L
by Lingran Xia, Yan Han, Taiyu Yin, Ye Zhu, Xiaoxing Yan and Jun Li
Coatings 2024, 14(8), 1042; https://doi.org/10.3390/coatings14081042 - 15 Aug 2024
Cited by 5 | Viewed by 1349
Abstract
In order to prolong the effective time of the self-healing properties of waterborne coatings containing shellac microcapsules coated with melamine rice husk powder (MRHP), three kinds of MRHPs with better microscopic morphologies, which contain 2.8% (type A), 5.5% (type B), and 8.0% (type [...] Read more.
In order to prolong the effective time of the self-healing properties of waterborne coatings containing shellac microcapsules coated with melamine rice husk powder (MRHP), three kinds of MRHPs with better microscopic morphologies, which contain 2.8% (type A), 5.5% (type B), and 8.0% (type C) of a rice husk powder (RHP), in shell materials were mixed according to three different proportions, and added to the waterborne coatings based on Tilia europaea L., under the conditions of the most proper addition amount of 6.0% microcapsules. The results indicated that the waterborne coatings containing mixed microcapsules can still maintain the best state in terms of optical properties and mechanical properties, with a chromatism of 1.10, an adhesion of zero, a hardness of 4H, an impact resistance of 7 kg·cm, and an elongation at break of 35.28%, respectively. According to the aging resistance test, the waterborne coating containing microcapsules “type A + type B + type C” demonstrated a longer effective time. After aging for 200 h in the UV climate resistance test chamber, the light loss rate at an incident angle of 60° was 2.91%. Through scratch testing, it is verified that the mixed microcapsules can prolong the self-healing time, reduce the crack size, and achieve a coating self-healing rate of 41.11%. They can also inhibit the crack growth rate to a certain extent. Roughness tests indicated that the surface roughness of the coating with mixed microcapsules increased by 0.038 μm in comparation with the single microcapsule, but the surface can still remain smooth after being covered by the topcoat without the microcapsules. Studying the ratio of mixed microcapsules provides new ideas for the optimization of a wood-based coating self-healing effect. Full article
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15 pages, 4022 KB  
Article
Exploring the Organic Acid Secretion Pathway and Potassium Solubilization Ability of Pantoea vagans ZHS-1 for Enhanced Rice Growth
by Shiqi Tian, Yufeng Xu, Yanglin Zhong, Yaru Qiao, Dongchao Wang, Lei Wu, Xue Yang, Meiying Yang and Zhihai Wu
Plants 2024, 13(14), 1945; https://doi.org/10.3390/plants13141945 - 15 Jul 2024
Cited by 18 | Viewed by 3150
Abstract
Soil potassium deficiency is a common issue limiting agricultural productivity. Potassium-solubilizing bacteria (KSB) show significant potential in mitigating soil potassium deficiency, improving soil quality, and enhancing plant growth. However, different KSB strains exhibit diverse solubilization mechanisms, environmental adaptability, and growth-promoting abilities. In this [...] Read more.
Soil potassium deficiency is a common issue limiting agricultural productivity. Potassium-solubilizing bacteria (KSB) show significant potential in mitigating soil potassium deficiency, improving soil quality, and enhancing plant growth. However, different KSB strains exhibit diverse solubilization mechanisms, environmental adaptability, and growth-promoting abilities. In this study, we isolated a multifunctional KSB strain ZHS-1, which also has phosphate-solubilizing and IAA-producing capabilities. 16S rDNA sequencing identified it as Pantoea vagans. Scanning electron microscopy (SEM) showed that strain ZHS-1 severely corroded the smooth, compact surface of potassium feldspar into a rough and loose state. The potassium solubilization reached 20.3 mg/L under conditions where maltose was the carbon source, sodium nitrate was the nitrogen source, and the pH was 7. Organic acid metabolism profiling revealed that strain ZHS-1 primarily utilized the EMP-TCA cycle, supplemented by pathways involving pantothenic acid, glyoxylic acid, and dicarboxylic acids, to produce large amounts of organic acids and energy. This solubilization was achieved through direct solubilization mechanisms. The strain also secreted IAA through a tryptophan-dependent metabolic pathway. When strain ZHS-1 was inoculated into the rhizosphere of rice, it demonstrated significant growth-promoting effects. The rice plants exhibited improved growth and root development, with increased accumulation of potassium and phosphorus. The levels of available phosphorus and potassium in the rhizosphere soil also increased significantly. Additionally, we observed a decrease in the relative abundance of Actinobacteria and Proteobacteria in the rice rhizosphere soil, while the relative abundance of genera associated with acid production and potassium solubilization, such as Gemmatimonadota, Acidobacteria, and Chloroflexi, as well as Cyanobacteria, which are beneficial to plant growth, increased. These findings contribute to a deeper understanding of the potassium solubilization mechanisms of strain ZHS-1 and highlight its potential as a plant growth-promoting rhizobacteria. Full article
(This article belongs to the Special Issue Interactions between Plants and Soil Microorganisms)
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Article
Introducing a Novel Application of Bio-Based Fillers Based on Rice Bran Wax Infused with Green Tea: Transitioning from a Cosmetic Additive to a Multifunctional Pigment for Wood Paints
by Massimo Calovi and Stefano Rossi
Appl. Sci. 2024, 14(13), 5895; https://doi.org/10.3390/app14135895 - 5 Jul 2024
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Abstract
This study aims to assess the functionality of a bio-derived additive, comprising rice bran wax infused with green tea, as an environmentally sustainable and adaptable pigment for wood coatings. Additionally, the effectiveness of the bio-based additive, in conjunction with a specialized UV absorber [...] Read more.
This study aims to assess the functionality of a bio-derived additive, comprising rice bran wax infused with green tea, as an environmentally sustainable and adaptable pigment for wood coatings. Additionally, the effectiveness of the bio-based additive, in conjunction with a specialized UV absorber to enhance color consistency under harsh conditions, was examined. Aesthetic impact was analyzed through evaluations of color, gloss, and surface roughness. Moreover, the stability of the wax-based powder in aggressive environments was characterized by subjecting samples to UV-B and climatic chamber exposure. The barrier properties of the additive were investigated using a water uptake test and contact angle measurements, while liquid resistance tests were conducted to gauge its efficacy. Lastly, the protective role of the bio-based additive was analyzed through scrub tests and surface analysis using scanning electron microscopy. Findings underscored the versatility of the green additive as a multifunctional pigment, offering not only color enhancement but also robust protective capabilities. Its unique combination of color, mattifying effect, barrier enhancement, and protective function position it as an attractive bio-based additive for wood coatings with functional applications. Full article
(This article belongs to the Special Issue Bio-Based Products and Co-products Applications)
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