Search Results (449)

In the context of global trends in sustainability and the circular economy (CE), this article aims to investigate the potential of microparticles derived from citrus peel waste (grapefruit, key lime, lemon, and orange), constituting approximately 50% of the fruit weight, as eco-friendly bio-fillers in polymer composites, thereby reducing the consumption of petrochemical resins. The composites were fabricated by gravity casting using polyester resin (PR) as the matrix at filler concentrations of 2.5%, 5%, and 10% by weight. Functional properties were assessed using static tensile testing (measuring Peak Load, Peak Stress, and Young’s modulus) and Shore D hardness testing. The incorporation of unprocessed fillers generally decreased tensile strength (Peak Stress REF: 31.48 MPa), attributed to poor interfacial adhesion. The lowest Peak Stress value was recorded for the 2.5O composite (16.04 MPa). The exception was the 10K composite (10 wt.%key limee), which achieved a Peak Load (1.28 kN) nearly identical to the neat resin (1.29 kN), although the Peak Stress remained lower due to the reduced effective cross-sectional area. Stiffness (Young’s modulus REF: 3.26 GPa) increased by more than 10 wt.% for 5G (3.63 GPa), indicating effective reinforcement at this concentration. A key positive finding was a universal increase in Shore D hardness across all biocomposites (REF: 78.4 ShD), with a maximum of 83.8 ShD for 10L (lemon), a typical response to rigid fillers that suggests enhanced surface resistance. The results suggest that citrus peel waste could be considered for non-structural applications where surface durability and efficient waste management are priorities. Full article

This study investigates the influence of cooling rates on the structural evolution and mechanical properties of ultra-high-molecular-weight polyethylene/high-density polyethylene fibers by systematically varying cooling media from ambient air (f1) to room-temperature water (f5). A significant structural inversion was observed between the as-spun and drawn fiber stages: while slow cooling (f1) promotes thermodynamic crystallization to form large, stable grains and maximum initial crystallinity (54%), rapid quenching (f5) effectively “freezes” the molecular chains in a low-crystallinity, highly orientable precursor state by suppressing thermal relaxation. During subsequent hot-drawing, the quenched samples (f5) exhibited a superior response to tensile stress, achieving the highest maximum draw ratio due to reduced crystalline obstacles and enhanced chain mobility. This enables efficient stress-induced crystallization, leading to near-perfect crystal orientation (f_c > 0.95) and a dense microfibrillar framework. Consequently, the fiber performance trends reversed, with f5 achieving peak tensile strength (1.33 GPa) and modulus, whereas f1 remained limited by its rigid thermal history. These findings highlight that rapid quenching is essential for developing high-performance fibers by preserving a precursor structure that maximizes the potential of stress-induced crystallization. Full article

To address the challenge that traditional dam model materials are difficult to simultaneously meet the requirements of microstructural similarity, dynamic damage simulation, and environmental friendliness, a novel microparticle mortar simulated concrete was developed. This new material consists of cement, sand, gypsum, mineral oil, water, and baryte sand. Through systematic material mechanical tests, the effects of each component on the material’s strength, density, and elastic modulus were revealed, and the optimal mix ratio was determined. This enabled precise control of low elastic modulus and had a high density, while the material is environmentally friendly, non-toxic, and compatible with direct contact with natural water. Its mechanical properties are highly similar to those of the prototype concrete. Based on a 1:70 geometric scale, a shaking table model test of the concrete gravity dam-reservoir system was conducted. The dynamic response and damage evolution under empty and full reservoir conditions were compared and analyzed. The study shows that this material can accurately simulate the stress-strain relationship and failure mode of prototype concrete. Under the full reservoir condition, the dam’s fundamental frequency showed only a 2.72% deviation from the numerical simulation, and as the seismic excitation amplitude increased, the changes in the fundamental frequency effectively reflected the accumulation of damage. Under the design seismic motion, the measured accelerations and stress responses for both empty and full reservoir conditions were in good agreement with numerical calculations. Under overload conditions, the acceleration amplification factor at the dam crest decreased with damage accumulation, and the dam neck was identified as the seismic weak zone. As the peak ground acceleration (PGA) increased from 0.15 g to 0.70 g, the fundamental frequency changes effectively reflected the damage accumulation process in the dam, while the hydrodynamic pressure at the dam heel showed a linear increase (457% increase). The experimentally measured hydrodynamic pressure distribution was between the rigid dam and elastic dam hydrodynamic pressures, reflecting the real fluid-structure interaction effect. This study provides a reliable material solution and data support for dam seismic physical model testing. Full article

This paper focuses on determining the propagation velocity of pressure waves in closed hydraulic pipes. It is shown that under transient conditions, the propagation velocity of pressure waves depends, among other things, on temperature, pressure and the substitute bulk modulus. Accurate knowledge of the pressure wave propagation velocity is crucial for predicting pressure amplitudes during transient flows, including the phenomenon of water hammer. Excessive pressure amplitudes in the pipe can lead to critical pipeline damage and increased vibrations. Experimental studies were conducted to determine the pressure wave propagation velocity in flexible steel-braided pipes and in a rigid pipe over a wide range of internal pressures. The results of the analyses presented in the papers may be helpful to scientists and engineers when designing pipelines and selecting the strength parameters of pipes, taking into account the possible maximum values of internal pressure amplitudes. Full article

Pumped-storage power stations (PSPSs) are vital for grid stability, yet pump-turbines (PTs) operating in the S-shaped region often induce severe hydraulic instability. To reveal the mechanism of these self-excited oscillations, this study establishes a nonlinear mathematical model based on rigid water column theory and a cubic polynomial approximation of the PT’s nonlinear characteristics. Both analytical derivations and numerical simulations were conducted. Analytical results indicate that, in the absence of surge tanks, self-excited oscillations occur when the PT’s negative hydraulic impedance modulus exceeds the pipeline impedance. With a single surge tank, the system behaves analogously to the Van der Pol oscillator, exhibiting oscillations that converge to a stable limit cycle governed by system parameters. Numerical simulations for a dual-surge-tank system further reveal that, due to initial negative damping, the PT transitions to alternative stable equilibria. Crucially, the transition direction is governed by the polarity of the initial disturbance: negative perturbations lead to the regular turbine region, while positive ones lead to the reverse pump region. Additionally, pipe friction causes the steady-state discharge to deviate slightly from the theoretical static value, with deviations remaining below 2.96%. This work provides a theoretical basis for stability prediction in PSPSs. Full article

In an effort to reduce global dependence on fossil-based polymers and advance toward a more sustainable materials industry, research over recent decades has increasingly focused on the development of bio-based polymers and broadening their potential applications. Within this context, the present study investigates nanocomposites based on poly(butylene succinate-co-butylene adipate) (PBSA), reinforced with two types of nanofillers: silicon dioxide nanoparticles (SiO₂ NPs) and cellulose nanofibrils (CNFs). The main objective of this work is to examine how the morphology, geometry, and chemical nature of the nanofillers influence the thermal, mechanical, and barrier properties of PBSA, as well as its biodegradability. For each nanofiller, three formulations were prepared, containing 1, 2, and 5 wt% of filler, respectively. Scanning electron microscopy (SEM) analysis confirmed good dispersion and minimal aggregation in the SiO₂-based systems, whereas marked aggregation was observed in the CNF-based samples. Thermal analysis indicated that the intrinsic thermal properties of neat PBSA were largely preserved. Mechanical testing revealed improvements in both the elastic modulus and elongation at break for most nanocomposite samples. In particular, CNFs provided the most consistent reinforcing effect, with enhancements of approximately 40% in the elastic modulus (495.4 vs. 356.4 GPa in neat PBSA) and 52% in elongation at the break (185.1 vs. 122.0% in neat PBSA) with 5 wt% loading. Additionally, the incorporation of nanofillers did not alter the surface hydrophilicity, but it did improve the oxygen barrier performance and enhanced disintegration under composting conditions. Overall, these findings demonstrate the promising potential of PBSA-based nanocomposites for sustainable rigid packaging applications. Full article

Toughening modification of epoxy resin (EP) matrices is important for advancing high-performance fiber-reinforced composites. A promising strategy involves the use of multi-component additive systems. However, synergistic effects in such additive systems are difficult to achieve for multidimensional performance optimization due to insufficient interfacial interactions and competing toughening mechanisms. Herein, a “hard–soft” biphasic synergistic toughening system was engineered for epoxy resin, composed of furan-ring-grafted polyhedral oligomeric silsesquioxane (FPOSS) and liquid polysulfide rubber. The hybrid toughening agent significantly enhanced the integrated performance of the epoxy system: Young’s modulus, tensile strength, and elongation at break increased by 13%, 56%, and 101%, respectively. These improvements are attributed to the formation of enriched molecular chain entanglement sites and optimized dispersion, facilitated by nucleophilic addition reactions between flexible rubber segments and rigid FPOSS units with the epoxy matrix. The marked enhancement in toughness primarily stems from the synergistic toughening mechanism involving “crazing pinning” and “crazing-shear band”. Concurrently, FPOSS incorporation effectively modulated the curing reaction kinetics, rendering the process more gradual while substantially elevating the glass transition temperature (T_g) of the cured system by 16.82 °C and endowing it with superior thermal degradation stability. This work provides a simple and unique strategy to leverage multi-scale mechanisms for the construction of epoxy-based composites with good toughness and strength, and enhanced heat resistance. Full article

Some expressway emergency lanes adopt simplified pavement structures that fail to meet load-bearing requirements after reconstruction. To address the issue of subgrade reinforcement without excavation, a finite element method was employed to analyze the effects of enlarged-borehole grouting (EBG), considering variations in grouting depth and inter-pile subgrade modulus, on pavement load-bearing capacity. Furthermore, field experiments were conducted to evaluate grouting techniques, including enlarged-borehole micro-expansive cement casting (EB-MECC) and enlarged-borehole steel flower pipe split grouting (EB-SFPSG), and three composite grouting schemes. Results indicated that EBG effectively improved the fatigue cracking life of the semi-rigid base layer. Reinforcement effectiveness was positively correlated with grouting depth and subgrade modulus, with the latter exhibiting a more significant influence. Therefore, a 1.5 m grouting depth combined with splitting or compaction is recommended to enhance subgrade stiffness. Field experiments showed that EB-SFPSG effectively enhanced pile–subgrade interaction and mitigated stress concentration around the pile–pavement interface. Comparison of the three composite grouting schemes revealed that both the scheme employing only EB-SFPSG and the hybrid scheme using EB-SFPSG in the middle row with EB-MECC in the side rows exhibited favorable mechanical performance. The latter, however, was achieved at a lower construction cost. Another hybrid scheme that further replaced the middle row with enlarged-borehole conventional pressure grouting (EB-CPG) provided limited reinforcement and poorer uniformity. Full article

Coalbed methane development is constrained by reservoir characteristics including high gas adsorption, high salinity, and high closure pressure, which impose significant limitations on conventional polymer fracturing fluids regarding viscosity enhancement, proppant transport, and fracture maintenance. In this study, a novel polymer fracturing fluid system, Z-H-PAM, was designed and synthesized to achieve strong salt tolerance, low adsorption affinity, and high elasticity to withstand closure pressure. This was accomplished through the molecular integration of a zwitterionic monomer ZM-1 and a hydrophobic associative monomer HM-2, forming a unified structure that combines rigid hydrated segments with a hydrophobic elastic network. The results indicate that ZM-1 provides a stable hydration layer and low adsorption tendency under high-salinity conditions, while HM-2 contributes to a high-storage-modulus, three-dimensional physically cross-linked network via reversible hydrophobic association. Their synergistic interaction enables Z-H-PAM to retain viscoelasticity that is significantly superior to conventional HPAM and to achieve rapid structural recovery in high-mineralization environments. Systematic evaluation shows that this system achieves a static sand-suspension rate exceeding 95% in simulated flowback fluid, produces broken gel residues below 90 mg/L, and results in a core damage rate of only 10.5%. Moreover, it maintains 88.8% of its fracture conductivity under 30 MPa closure pressure. Notably, Z-H-PAM can be prepared directly using high-salinity flowback water, maintaining high elasticity and sand-carrying capacity while enabling fluid recycling and reducing reservoir damage. This work clarifies the multi-scale mechanisms of strongly hydrated and highly elastic polymers in coalbed methane reservoirs, offering a theoretical and technical pathway for developing efficient and low-damage fracturing materials. Full article

Most insects secrete special fluids from their tarsal pads which are essential for the function of their attachment systems. Previous studies investigated several physical and chemical characteristics of this pad fluid in different insect species. However, there is not much known about the mechanical properties of fluid from smooth adhesive pads. In this study, we used the stress–relaxation nanoindentation method to examine the viscoelastic properties of pad fluid from Sungaya aeta. Force–displacement and stress–relaxation curves on single fluid droplets were recorded with an atomic force microscope (AFM) and analyzed using Johnson–Kendall–Roberts (JKR) and generalized Maxwell models for determination of effective elastic modulus (E), work of adhesion (Δγ) and dynamic viscosity (η). In addition, we used white light interferometry (WLI) to measure the maximal height of freshly acquired droplets. Our results revealed three different categories of droplets, which we named “almost inviscid”, “viscous” and “rigid”. They are presumably determined at the moment of secretion and retain their characteristics even for several days. The observed mechanical properties suggest a non-uniform composition of different droplets. These findings provide a basis for advancing our understanding about the requirements for adaptive adhesion-mediating fluids and, hence, aid in advancing technical solutions for soft or liquid temporal adhesives and gripping devices. Full article

Due to their superior tribological properties compared to conventional materials, the use of functionally graded materials (FGMs) has long become indispensable in mechanical engineering. The wide variety of in-depth gradings means that solving contact problems requires specific, complex numerical analysis. In many cases, however, the spatial change in Young’s modulus can be approximated by a power law, which allows closed-form analytical solutions. In the present work, integral equations for solving tangentially loaded power-law graded elastic half-planes are derived by using the Mossakovskii–Jäger procedure. In this way, the application of highly complicated singular integrals arising from a superposition of fundamental solutions is avoided. A distinction is made between different mixed boundary conditions. The easy tractability of the novel equations is substantiated by solving the plane strain fretting contact of a rigid parabolic cylinder and a power-law graded (PLG) elastic half-space. The effect of the type of in-depth grading on the dissipated energy density and the total energy lost per cycle is investigated in detail. A comparison of the total dissipated energy per cycle shows that, for very thin stiff layers on soft substrates, the total dissipated energy exceeds that of a homogeneous material. The same trend is observed for thick layers of a functionally graded material whose Young’s modulus gradually increases with depth, matching that of the underlying substrate at the bonded interface. In addition, a closed-form analytical solution for the total dissipated energy per cycle for plane strain parabolic contact of elastically homogeneous material is presented for the first time. Full article

This study investigated the effects of Auricularia auricula Polysaccharide (AAP) concentrations on the rheological and thermal properties of gluten and its subunit components. We used multiple techniques, including dynamic rheology, differential scanning calorimetry (DSC), Fourier-transform infrared spectroscopy (FT-IR), free thiol group analysis, and scanning electron microscopy (SEM). The results revealed that AAP increased the storage (G′) and loss (G″) modulus of gluten, glutenin, and gliadin, promoting compact elastic protein networks. DSC and free thiol group analysis demonstrated that AAP enhanced thermal stability and disulfide bond cross-linking in gluten and glutenin, but reduced thermostability and inhibited disulfide formation in gliadin. Secondary structure analysis showed 31.93% and 17.72% increases in α-helix and β-sheet content, respectively, in glutenin at 8% AAP, thereby enhancing the orderliness of the gluten structure and improving structural rigidity, while reducing gliadin’s structural order. Microscopy confirmed AAP narrowed gluten matrix pores, forming uniform honeycomb structures (though high concentrations caused disruption). In summary, AAP primarily stabilizes gluten conformation by modulating glutenin structure, thereby enhancing rheological and thermal properties. Full article

This study investigates the mechanical performance of three temperature-resistant 3D-printable polymer composites for turbine impellers used in district heating networks for pressure reduction. Using fused deposition modeling (FDM), tensile strength and deformation of ASA-X CF10, PA6-GF30, and ePAHT-CF15 were evaluated at temperatures representative of real operating conditions (60–130 °C). These polymer composites were systematically tested, with particular emphasis on annealed ePAHT-CF15. Results demonstrated that annealing significantly improved mechanical performance, yielding higher tensile strength, Young’s modulus, and reduced deformation. Structural analyses confirmed that ePAHT-CF15, particularly when annealed at 200 °C, exhibited superior thermal stability and rigidity, making it the optimal material choice for high-temperature turbine impeller applications. These findings support the design of 3D-printed composite impellers for pump-as-turbine applications in district heating systems, where high stiffness and heat resistance are required. Full article

Most polymeric plastics used as food packaging are obtained from petroleum or made with non-biodegradable synthetic molecules, which slowly degrade and leach into the environment, resulting in the accumulation of microplastics along the trophic chains. To mitigate these impacts, biodegradable packaging derived from agro-industrial biomass residues has emerged as a promising alternative. In this study, bio-based methylcellulose films reinforced with cellulose nanocrystals (CNCs) extracted from low-quality coffee beans were developed and fully characterized. The extracted CNCs presented a needle-like morphology, with an average height of 7.27 nm and a length of 221.34 nm, with 65.75% crystallinity, were stable at pH 7–8, and presented thermogravimetric mass loss of 8.0%. Methylcellulose films containing 0.6% w/w of CNC were produced by casting and characterized in terms of thermal, mechanical, and optical properties. Notably, the incorporation of CNCs resulted in significantly more flexible and less rigid films, as evidenced by the higher elongation at break (57.90%) and lower Young’s modulus (0.0015 GPa) compared to neat methylcellulose film. The tensile strength was not affected (p > 0.05). Additionally, the MCNC 0.6% films effectively blocked UV light in the 200–300 nm range without compromising transparency. Altogether, these findings underscore the MCNC 0.6% film as a flexible, biodegradable packaging material suitable for food industry application. Full article

Biocomposite films based on polylactic acid (PLA) reinforced with cellulose nanofibers (CNFs) extracted from Salicornia ramosissima by-products were developed and characterised using solvent casting (SC) and electrospinning (ES) techniques. The primary objective was to assess their suitability as sustainable food packaging materials that are compatible with high-pressure processing (HPP). The SC films exhibited a transparent, homogeneous morphology with superior ductility and water vapour barrier performance, whereas the ES films displayed a fibrous, porous structure with enhanced tensile strength and rigidity. The incorporation of CNFs significantly improved the mechanical properties, particularly the tensile strength and Young’s modulus, with optimal reinforcement achieved at a loading of 0.5%. Thermal and spectroscopic analyses confirmed the effective integration of CNF without compromising the thermal stability of PLA. Pouch-type packages from CNF-reinforced SC films withstood industrial HPP conditions without rupture or leakage, demonstrating their technical feasibility for food packaging applications. This study presents the first demonstration of Salicornia ramosissima by-product valorisation for CNF production and its application in HPP-compatible food packaging, addressing both circular economy goals and emerging food processing technologies. Full article