Search Results (2,582)

Towards achieving carbon neutrality, it is important to produce carbon-free hydrogen from renewables at an acceptable cost. At the same time, power retailers that own renewables must manage their imbalances between planned and actual generation. This paper proposes an economically viable carbon-free hydrogen method for such retailers, utilizing both positive imbalances of renewables and electricity from the market with non-fossil certificates. The proposed method enables geographically flexible hydrogen production through the power grid while utilizing renewable imbalances within actual power business operations. This paper develops solutions to an optimization problem that minimizes the hydrogen variable cost and offsets the imbalances using an electrolyzer and a battery while accounting for imbalance uncertainty. The case study in Tokyo, Japan demonstrates that imbalance compensation reduces the hydrogen variable cost by 30%. The minimum levelized cost of hydrogen (LCOH) is approximately 60 JPY/Nm${}^3$ when the electrolyzer operates at a 40% capacity factor. Furthermore, sensitivity analysis of market prices indicates that the LCOH can decline to 50 JPY/Nm${}^3$ under lower price conditions. The results suggest that market-independent cost components, such as wheeling and renewable energy charges and non-fossil certificates, remain major obstacles to further reducing hydrogen costs. Full article

Substantial advances have been made since the 1970s in reducing the environmental impacts of ammonia production. Renewable-driven electrochemical synthesis offers a promising pathway to decarbonize ammonia production. This review examines an integrated route in which hydrogen is generated photoelectrochemically under concentrated solar irradiation and subsequently used in electrochemical ammonia synthesis. Photoelectrochemical cells are fabricated by electrostatically depositing photosensitive particles onto cathodes to enhance light-driven hydrogen production. Hydrogen production rates and ammonia yield depend strongly on temperature and electrolyte composition. The synthesized hydrogen is fed into a molten salt electrochemical reactor that operates at atmospheric pressure and receives nitrogen from a dedicated supply. This combined solar–electrochemical approach can produce low-carbon ammonia with improved safety and reduced environmental impact, offering a scalable alternative to conventional processes. Full article

The growing demand for sustainable energy carriers has intensified interest in hydrogen production from renewable resources and waste-derived substrates. In this context, microbial electrolysis cells (MECs) have emerged as a promising technology for the simultaneous treatment of organic waste and biohydrogen generation. This review provides an overview of recent advances in MEC systems, focusing on reactor configurations, performance indicators such as hydrogen production rate, coulombic efficiency, and chemical oxygen demand removal. Attention is given to the valorization of real waste streams, including municipal and agro-industrial effluents, highlighting the differences between laboratory- and pilot-scale applications. While numerous studies have demonstrated the technical feasibility of MECs, several bottlenecks still limit their large-scale implementation, including challenges associated with the use of complex substrates. In particular, untreated wastewater often leads to reduced process efficiency due to its variable composition and the occurrence of competing microbial pathways. To overcome these limitations, integrated approaches are also discussed, with emphasis on the coupling of dark fermentation, capable of enhancing substrate biodegradability through the production of volatile fatty acids, with MEC systems. Overall, MEC technology represents a promising pathway for sustainable hydrogen production within circular waste management frameworks, although further advancements are required to enable its practical application. Full article

Sustainable lightweight materials based on renewable resources have attracted increasing attention as alternatives to synthetic materials. However, developing nanocellulose cryogels with adequate structural integrity and efficient retention of phenolic compounds remains challenging, often requiring furanic and dialdehyde-based additives associated with environmental and health concerns. In this context, tannin-containing nanocellulose cryogels were produced using vanillin and hydrogen peroxide as sustainable modification agents. The effects of the additives on the structural, morphological, colorimetric, mechanical, thermal, and leaching properties of the cryogels were investigated. FTIR and colorimetric analyses revealed the presence of phenolics and the effect of hydrogen peroxide. SEM analysis showed that tannin promoted structural densification, whereas peroxide induced fragmentation of the cryogel network and pore reorganization. These changes influenced density and mechanical performance, with nanocellulose-tannin exhibiting the highest compressive strength and elastic modulus. Thermal conductivity values remained within the range reported for highly porous lignocellulosic materials (38.93–43.79 (mW/m·K)). Tannin leaching demonstrated that peroxide significantly improved tannin retention, especially in the system including vanillin which exhibited only 13,61% tannin release. Overall, vanillin and hydrogen peroxide modified the supramolecular organization and functional properties of the cryogels, highlighting their potential as additives in porous materials for thermal insulation and adsorption applications. Full article

Achieving long-term urban sustainability requires energy subsidy frameworks that evolve with changing technological conditions and system needs. Renewable energy subsidy regimes have played a decisive role in accelerating building-integrated solar photovoltaic deployment, but many were designed for an earlier expansion phase focused mainly on increasing generation capacity and reducing technology costs. As electricity systems move toward an integration phase characterized by higher renewable penetration, flexibility constraints, storage needs, and cross-sectoral coordination, generation-centric subsidy architectures may become increasingly misaligned with system-level requirements. This study conducts a structured comparative analysis of subsidy design in Hong Kong, Chinese Mainland, and Australia, examining legal foundations, target scope, incentive structures, and technology orientation across expansion and integration phases. Despite major differences in governance systems and market organization, the findings show a common pattern: Principal subsidy instruments remain anchored in output-based performance metrics, while storage, hydrogen, and hybrid technologies are generally supported through supplementary rather than core mechanisms. The study argues that this policy layering may limit technological inclusiveness and reduce alignment between subsidy design and evolving system needs. It therefore proposes a system-value-oriented comparative framework for subsidy redesign that recognizes flexibility, reliability, and integrated clean energy performance in the built environment. Full article

Hydrogen is a clean and renewable energy carrier, but its reversible storage near ambient conditions remains a major challenge. Here, density functional theory (DFT) combined with ab initio molecular dynamics (AIMD) is employed to assess the newly predicted 2D orthorhombic diboron dinitride (o-B${}_2$N${}_2$) monolayer, in pristine and Li-functionalized forms, as a hydrogen storage medium. On the pristine surface, H${}_2$ physisorbs with binding energies of −0.158 to −0.174 eV. Li atoms anchor strongly at the hexagonal hollow sites ($E_{\mathrm{bind}}$ from −0.979 to −1.321 eV, strongest at the B-rich H1 site), donate 0.65–0.84 $\left|e\right|$ to the substrate, and render the semiconducting monolayer metallic. A positive cluster formation energy ($+0.171$ eV per Li pair) and a 5 ps AIMD simulation at 400 K confirm that the Li adatoms remain dispersed, without clustering. Each Li${}^{+}$ center polarizes and binds up to five H${}_2$ molecules, with average adsorption energies of −0.207 to −0.336 eV/H${}_2$, within the optimal window for room-temperature reversible storage. The 4Li@o-B${}_2$N${}_2$(20H${}_2$) system attains a theoretical gravimetric capacity of 15.12 wt% and a practical capacity of 10.99 wt% under realistic operating conditions (charging at 30 atm/25 ${}^{\circ }$C; release at 3 atm/100 ${}^{\circ }$C). These results establish Li-functionalized o-B${}_2$N${}_2$ as a promising hydrogen storage material that merits experimental exploration. Full article

This paper addresses the current development status of a innovative direct high-pressure electrolyser (DHPEL, operating up to 700 bar) and its integration into a microgrid system in which solar energy constitutes the primary energy source and a hybrid energy storage system, comprising a battery and hydrogen, is employed. The DHPEL under development enables the direct production and storage of hydrogen at high pressures, thereby obviating the need for intermediate mechanical compression. In combination with standardized pressure vessels (300–350 bar) or the increasingly widespread use of CFRP-based high-pressure storage tanks (up to 700 bar), the DHPEL concept represents a technically and economically attractive option for microgrids with hybrid energy storage. The hybrid storage concept is based on functional differentiation between the storage media: the battery is intended to act predominantly as a buffer or short-term storage unit, and the hydrogen is designated for long-term energy storage. In principle, this configuration facilitates an autonomous energy supply relying exclusively on renewable energy sources; this is achieved by enabling the surplus solar energy generated in summer to be converted into hydrogen and subsequently utilized in winter. A rule-based energy-management algorithm is presented, prioritizing hydrogen production from surplus energy during the summer period and aiming to minimize interaction with the public electricity grid. This is particularly relevant for high-latitude regions, such as Germany, where solar irradiation is significantly lower in winter than in summer. A quasi-optimal sizing of all components in the microgrid, along with a realistic techno-economic assessment of the overall system, is performed using an energy-management model implemented in Simulink and utilised with realistic boundary conditions. A case study utilizing realistic solar generation and empirically derived electrical load profiles demonstrates the technical and economic viability of seasonal energy shifting from summer to winter (resulting in an autarky degree exceeding 1) within an economically acceptable cost range. Full article

Green hydrogen is increasingly discussed as an energy carrier that can link electricity, gas, heat, and transport sectors. However, many existing reviews address this topic from separate viewpoints, such as hydrogen production technologies, Artificial Intelligence (AI) applications, or system integration, with less attention to how policy and market conditions affect deployment. This review brings these related aspects together in one structured discussion. The paper first reviews the hydrogen supply chain, including production, storage, transport, and utilization. It then discusses an integrated multi-energy architecture in which hydrogen interacts with electricity, natural gas, heat, and cooling networks. Policy instruments in five major economies, including the European Union, the United States, China, Japan, and India, are compared. The review also summarizes the main barriers to large-scale deployment, including high production costs, limited infrastructure, technological challenges, regulatory uncertainty, and supply-chain constraints. In addition, the current market structure and selected large-scale hydrogen projects planned in the United States are reviewed. The paper also examines the role of artificial intelligence in green hydrogen systems. AI applications are grouped into four main stages of the hydrogen value chain: forecasting renewable energy generation, improving electrolyzer design and operation, optimizing storage and distribution, and supporting system-level techno-economic assessment. Recent Machine Learning (ML) studies are compared based on their methods and their contributions to operation and planning. Overall, this review highlights the role of AI in enabling green hydrogen integration within multi-energy systems. Full article

Green ammonia systems provide an important pathway for converting fluctuating renewable electricity into transportable chemical products. To address the coupled challenges of renewable power variability, heterogeneous electrolyzer dynamics, hydrogen storage constraints, and continuous ammonia synthesis under weak-grid conditions, this paper develops a mixed-integer linear programming scheduling model considering the coordination and start–stop characteristics of ALK–PEM hybrid electrolyzers. The model uses a 15 min resolution over a two-day horizon and integrates renewable power supply, grid electricity purchase, electrolysis, hydrogen storage, and flexible ammonia synthesis in a unified framework. The off, hot-standby, and running states of ALK and PEM electrolyzers are explicitly represented. The case results show that, under the high-renewable-resource scenario, ammonia production reaches 494.93 t, with a curtailment ratio of 3.23% and a grid electricity share of 0.68%, indicating strong renewable-energy conversion capability. Under the low-renewable-resource scenario, ammonia production decreases to 180.09 t and the grid electricity share increases to 40%, showing that the operating priority shifts to maintaining continuous production and safe hydrogen inventory. The ALK hydrogen production share decreases from 93.96% in the high-resource scenario to 75.66% in the low-resource scenario, while the PEM share increases from 6.04% to 24.34%. This indicates that ALK mainly supports large-scale base-load hydrogen production under abundant renewable resources, whereas PEM provides fast compensation and marginal regulation when renewable resources are limited and more volatile. The results demonstrate that ALK base-load production, PEM fast regulation, hydrogen storage buffering, and platform-like flexible ammonia operation jointly provide the main flexibility sources in the studied weak-grid green ammonia system. Full article

In electricity–hydrogen coupling systems (EHCSs), the uncertainty of renewable energy generation (REG) tends to impact electrolyzers (ELs) in the following ways: (1) input powers of ELs are prone to fluctuations; (2) ELs are forced to operate under variable load states. Consequently, both impacts will reduce the service life of ELs. In this paper, considering the start–stop characteristics and combined operation modes of multiple ELs, a two-stage multi-time-scale energy allocation strategy (MSEAS) is proposed to mitigate the impacts of REG uncertainty and optimize the energy allocation for EHCSs. First, five refined operating states of ELs, such as shutdown, cold standby, low-load, variable-load and overload, are formulated as mixed-integer constraints and embedded into the system-level energy optimization model. Second, to mitigate power fluctuations caused by REG, a day-ahead optimization is employed to plan the power allocations of ELs, lithium batteries, fuel cells, and the grid with a 1 h time step; and then an intra-day rolling optimization is employed to adjust the operating states and power outputs of the above units with a 4 h window and 15 min step. Third, by enabling multiple ELs to flexibly operate in a combined mode, power-sharing mode and switching mode, the proposed MSEAS can refine the operation powers of ELs and reduce their start-up frequency. Comparative case studies are conducted in the off-grid and grid-connected operation tests, and the relevant results verify that the proposed MSEAS can effectively prevent the frequent start–stop of ELs, which contributes to extending the service life of ELs and reducing the system operating cost. Full article

Hybrid renewable energy systems (HRES) integrating photovoltaic arrays (PV), wind turbines (WT), and fuel cells (FC) require coordinated maximum power extraction to maintain stable operation under dynamic environmental and load conditions. Conventional MPPT approaches based on independent source-level control often suffer from adverse source interaction, increased steady-state oscillation, degraded DC-link stability, and reduced total extracted power when multiple renewable sources operate simultaneously. To address these limitations, this paper proposes an integrated perturb-and-observe control framework for coordinated power optimization in photovoltaic–wind–fuel-cell hybrid renewable energy systems connected through a shared DC-link structure. Unlike conventional independent MPPT controllers, the proposed strategy evaluates the aggregate power behavior of the integrated system and performs coordinated duty-cycle adaptation to improve renewable-energy utilization while suppressing source conflicts and dynamic coupling effects. The proposed controller is implemented and validated using a real-time digital simulator under a sequential disturbance profile consisting of an irradiance drop at 0.2 s, wind-speed increase at 0.4 s, hydrogen-pressure fluctuation at 0.6 s, and load variation at 0.8 s. Comparative evaluation against conventional perturb-and-observe, incremental conductance, and fuzzy-logic-based MPPT methods demonstrates that the proposed framework achieves a tracking efficiency of $97.8\%$, reduces steady-state tracking error to $2.2\%$, and improves settling time by $42.8\%$ under these dynamic operating conditions. In addition, the proposed controller exhibits lower oscillatory behavior, improved extracted renewable power, and enhanced DC-link stability during simultaneous multi-source disturbances. The results demonstrate that the proposed framework provides an effective real-time coordination strategy for hydrogen-enabled hybrid renewable energy systems operating under dynamically coupled renewable-source conditions. Full article

Hydrogen (H₂) is becoming a meaningful way to store energy for long-term use and support thorough decarbonization in systems that use renewable energy. Underground hydrogen storage (UHS) has strategic benefits over above-ground systems because it can hold large volumes, is contained by geology, and is cheap to operate in cycles. This review compares four key geological formations for underground hydrogen storage (UHS): salt caverns, lined rock caverns, depleted hydrocarbon reservoirs, and saline aquifers. Each system is evaluated based on storage mechanisms, efficiency, safety, technological maturity, and economic feasibility. This review also introduces a unified cross-media evaluation framework, a TRL-risk matrix, a technology development roadmap, and novel insights into AI-based monitoring, offering prescriptive guidance for large-scale UHS implementation. Salt caverns have high injectivity, maintain their purity, and undergo 6 to 12 cycles per year at pressures of 60 to 180 bar; however, they are only found in certain places. Lined rock caverns can be built anywhere, but sealing and economic issues make them difficult to use. Depleted hydrocarbon reservoirs with TWh-scale capacity and already built infrastructure. Saline aquifers, on the other hand, have the most potential in the world but need enhanced management of microbiological responses and cushion gas optimization. A synthesis of current studies highlights key research gaps in cyclic geomechanics, hydrogen–rock–microbe interactions, and liner performance for high-pressure storage. The review concludes with techno-economic and safety considerations and identifies future directions for deploying geological UHS as a critical component of a net-zero hydrogen economy. Full article

This review paper presents a comprehensive synthesis of current scientific knowledge on the integration of low-emission technologies into airport operational models. Attention is also given to the role of artificial intelligence techniques in predicting environmental risks, optimizing energy system design, and enhancing operational safety. The primary objective of the study is to evaluate the synergy between renewable energy sources (solar and wind energy) and emerging propulsion technologies in aviation (hydrogen and electrification) from the perspective of safety and operational stability. The methodology is based on a systematic review of 78 scientific studies identified in the Scopus and Web of Science databases. The analysis identifies critical technical and operational barriers, including electromagnetic interference caused by wind turbines, optical hazards associated with photovoltaic systems, and stability challenges in airport microgrids under peak loads resulting from the charging of electric aircraft. Particular attention is given to the safety of hydrogen infrastructure, where findings from the literature indicate the need to revise separation distances and highlight the potential reduction of airport stand capacity by 5% to 16%. The study synthesizes these findings into a strategic framework for “Smart Green Airports”, proposing solutions such as adaptive infrastructure design, the deployment of predictive models based on artificial intelligence, and the implementation of inherently safe energy storage systems. The paper concludes that achieving airport energy self-sufficiency while maintaining the integrity of flight operations is feasible only through the holistic integration of technical measures, simulation-based planning, and strict compliance with updated safety regulations. Full article

Combining oxygen-enriched combustion CO₂ capture technology and CO₂ hydrogenation with methanol technology, a new power–chemicals cogeneration (PCC) design is proposed for thermal power stations with CO₂ capture and utilization under the power-to-liquid concept. For material integration, CO₂ from an oxygen-enriched thermal power station and H₂ from water electrolysis using renewable power serve as raw materials for the methanol production process. O₂ from water electrolysis using renewable power is supplied to the oxygen-enriched thermal power station; thus, electricity can be saved and investment in an air separation unit can be beneficial. For energy integration, power for gas compression and heat for methanol rectification in the methanol production process are supplied by an oxygen-enriched thermal power station. The energy released from the methanol production process is fully recovered for extra power generation. Energy analysis results show that a high CO₂ capture and utilization ratio, which is defined as the ratio of the captured and utilized CO₂ to the total CO₂ generation, of 78.1% could be achieved. By integrating the system in a 600 MW thermal power station, the net power generation and methanol production of the proposed design reaches 473.1 MW and 56.1 kg/s, respectively. Economic analysis results show that the power cost is estimated to be 62.8 $/MWh, which has great market competitiveness compared to the conventional thermal power station with CO₂ capture. Due to the saved material expense and power and heat expense, the methanol cost is reduced from 1.33 $/kg to 1.20 $/kg. The H₂ expense by water electrolysis using renewable power has a decisive influence on the methanol cost. Full article

To improve the low-carbon economic operation of integrated energy systems under wind power uncertainty, this paper develops an optimal scheduling model for an integrated energy system coupling oxygen-enriched combustion with hydrogen–ammonia–carbon utilization pathways. The proposed framework integrates oxygen-enriched combustion, electrolysis-based hydrogen production, methanation, hydrogen fuel cells, ammonia synthesis, urea synthesis, captured CO₂ utilization, reward–penalty ladder-type carbon trading, and IGDT-based wind power uncertainty scheduling. A deterministic scheduling model is first established to minimize the total operating cost, and Information Gap Decision Theory is then introduced to formulate risk-averse and opportunity-seeking scheduling strategies under wind power uncertainty. Simulation results show that, compared with the post-combustion carbon capture scenario and the conventional coal-fired scenario, the proposed system reduces the total operating cost by 3.37% and 8.03%, respectively, and reduces the wind curtailment cost by 40.2% and 57.0%, respectively. Compared with the post-combustion carbon capture scenario, carbon emissions are reduced by 17.7%. The hydrogen–ammonia–urea chain generates approximately 15.68 × 10⁴ CNY of urea revenue and improves carbon resource utilization. Under an IGDT deviation factor of 0.03, the risk-averse strategy increases the total operating cost by approximately 10.30 × 10⁴ CNY to enhance operational robustness, while the opportunity-seeking strategy reduces the total operating cost by approximately 10.30 × 10⁴ CNY and decreases carbon emissions by 19.6 t. These simulation results verify the effectiveness of the proposed scheduling framework under the designed case study. The proposed framework can improve the low-carbon economy, renewable energy accommodation, carbon resource utilization, and adaptability to wind power uncertainty of the studied integrated energy system. Full article