Search Results (1,456)

This paper discusses the integrated technology of CO₂ adsorption and catalysis, which combines adsorption and catalytic conversion, simplifies the traditional process, reduces energy consumption, and improves efficiency. The traditional carbon capture technology has the problems of high energy consumption, equipment corrosion, and absorbent loss, while the integrated technology realizes the adsorption, conversion, and catalyst regeneration of CO₂ in a single reaction system, avoiding complex desorption steps. Through micropore confinement and surface electron transfer mechanism, the technology improves the reactant concentration and mass transfer efficiency, reduces the activation energy, and realizes the low-temperature and high-efficiency conversion of CO₂. In terms of materials, MOF-based composites, alkali metal modified oxides, and carbon-based hybrid materials show excellent performance, helping to efficiently adsorb and transform CO₂. However, the design and engineering of reactors still face challenges, such as the development of new moving bed reactors. This technology provides a new idea for CO₂ capture and resource utilization and has important environmental significance and broad application prospects. Full article

Direct Air Capture (DAC) is gaining worldwide attention as a negative emissions strategy critical to meeting climate targets. Among emerging DAC materials, pyrolysis chars (PCs) and gasification chars (GCs) derived from biomass present a promising pathway due to their tunable porosity, surface chemistry, and low-cost feedstocks. This review critically examines the current state of research on the physicochemical properties of PCs and GCs relevant to CO₂ adsorption, including surface area, pore structure, surface functionality and aromaticity. Comparative analyses show that chemical activation, especially with KOH, can significantly improve CO₂ adsorption capacity, with some PCs achieving more than 308 mg/g (100 kPa CO₂, 25 °C). Additionally, nitrogen and sulfur doping further improves the affinity for CO₂ through increased surface basicity. GCs, although inherently more porous, often require additional modification to achieve a similar adsorption capacity. Importantly, the long-term stability and regeneration potential of these chars remain underexplored, but are essential for practical DAC applications and economic viability. The paper identifies critical research gaps related to material design and techno-economic feasibility. Future directions emphasize the need for integrated multiscale research that bridges material science, process optimization, and real-world DAC deployment. A synthesis of findings and a research outlook are provided to support the advancement of carbon-negative technologies using thermochemically derived biomass chars. Full article

The physicochemical processes that occur during selective transfer in the contact area of a bronze/steel friction pair lubricated with glycerin are experimentally studied by the polarization method to observe how they influence the tribological properties (friction and wear) of the pair. The proposed method allows for the study of tribochemical transformations of glycerin and the friction pair materials during the work process with selective transfer. The analysis of the experimental results allows for the establishment of the conditions for a stable and stationary selective transfer during the operation of the bronze/steel pair, by friction, at which the friction coefficient (COF) values and wear are low. This was achieved by implementing continuous lubrication with fresh glycerin in the contact area, choosing the optimal flow rate, and maintaining an optimal ratio between glycerin and the chemical transformation products, within well-established limits, to avoid undesirable consequences. Acrolein, as a product of chemical transformation (resulting from the catalytic dehydration of glycerin), is the most important for the initiation and stability of the selective transfer, and as the main reaction product, also represents a pathway of regeneration. Thus, it was found that the friction relative moments and the acrolein concentration presented conclusive/specific results at loads of 4–15 MPa and a sliding speed of 0.3 m/s. The optimum lubricant entry speed is 15–30 mg/min, for a minimum COF and reduced wear (about 0.028–0.03 at relatively high operating temperatures (45 and 60 °C)), and at low temperatures (30 °C) the minimum COF is about 0.038, but the lubricant inlet entry speed increases considerably, by around 1000 mg/min. Therefore, this paper aims to demonstrate the possibility of moving to another stage of practical use of a friction pair (with greatly improved tribological properties) that operates with selective transfer, much different from the ones still present, using a lubricant with special properties (glycerin). The research method used (polarization) highlights the physicochemical properties, tribochemical transformations of the lubricant, and the friction pair materials present in the contact area, for the understanding, maintenance, and stability of selective transfer, based on experiments, as a novelty compared to other studies. Full article

Limited recovery of the viscoelastic properties of aged asphalt on RAP surfaces at ambient temperature reduces interface fusion and bonding with new emulsified asphalt, degrading pavement performance and limiting large-scale promotion and high-value applications of the emulsified asphalt cold recycled mixture (EACRM). Therefore, a cold regenerant was independently prepared to rapidly penetrate, soften, and activate aged asphalt at ambient temperature in this paper, and its effects on the volumetric composition, mechanical strength, and pavement performance of EACRM were systematically investigated. The results showed that as the cold regenerant content increased, the air voids, indirect tensile strength (ITS), and high-temperature deformation resistance of EACRM decreased, while the dry–wet ITS ratio, cracking resistance, and fatigue resistance increased. Considering the comprehensive pavement performance requirements of cold recycled pavements, the optimal content of the activated cold regenerant for EACRM was determined to be approximately 0.6%. Full article

Bis(2-ethylhexyl) phosphate (P204) is widely used in extraction processes in the nuclear and rare earth industries. However, its high solubility in water results in high levels of total organic carbon and phosphorus in aqueous environments, and may also lead to radioactive contamination when it is used to combine with radionuclides. In this paper, we characterized a coconut shell activated carbon (CSAC) and a coal-based activated carbon (CBAC) for the adsorption of P204 and then evaluated their adsorption performance through batch and column experiments. The results found that, except for the main carbon matrix, CSAC and CBAC carried rich oxygen-containing functional groups and a small amount of inorganic substances. Both adsorbents had porous structures with pore diameters less than 4 nm. CSAC and CBAC showed good removal performance for P204 under low pH conditions, with removal efficiencies significantly higher than those of commonly used adsorption resins (XAD-4 and IRA900). The adsorption kinetics of P204 conformed to the pseudo-second-order kinetic model, and the adsorption isotherms conformed to the Langmuir model, indicating a monolayer chemical reaction mechanism. Both adsorbents exhibited strong anti-interference capabilities; their adsorption performance for P204 did not change greatly with the ambient temperature or the concentrations of common interfering ions. Column experiments demonstrated that CSAC could effectively fix dissolved P204 with a removal efficiency exceeding 90%. The fixed P204 could be desorbed with acetone. The findings provide an effective method for the recovery of P204 and the regeneration of spent activated carbon, which shows promise for practical applications in the future. Full article

Sporadic Parkinson’s Disease (PD) affects 3% of people over 65 years of age. People are living longer, thanks in large part to improvements in global health technology and health access for non-neurological diseases. Consequently, neurological diseases of senescence, such as PD, are representing an ever-increasing share of global disease burden. There is an intensifying research focus on the processes that underlie these conditions in the hope that neurological decay may be arrested at the earliest time point. The concept of neuronal death linked to ageing- neural senescence- first emerged in the 1800s. By the late 20th century, it was recognized that neurodegeneration was common to all ageing human brains, but in most cases, this process did not lead to clinical disease during life. Conditions such as PD are the result of accelerated neurodegeneration in particular brain foci. In the case of PD, degeneration of the substantia nigra pars compacta (SNpc) is especially implicated. Why neural degeneration accelerates in these particular regions remains a point of contention, though current evidence implicates a complex interplay between a vast array of neuronal cell functions, bioenergetic failure, and a dysfunctional brain immunological response. Their complexity is a considerable barrier to disease modification trials, which seek to intercept these maladaptive cell processes. This paper reviews current evidence in the domain of neurodegeneration in Parkinson’s disease, focusing on alpha-synuclein accumulation and deposition and the role of oxidative stress and inflammation in progressive brain changes. Recent approaches to disease modification are discussed, including the prevention or reversal of alpha-synuclein accumulation and deposition, modification of oxidative stress, alteration of maladaptive innate immune processes and reactive cascades, and regeneration of lost neurons using stem cells and growth factors. The limitations of past research methodologies are interrogated, including the difficulty of recruiting patients in the clinically quiescent prodromal phase of sporadic Parkinson’s disease. Recommendations are provided for future studies seeking to identify novel therapeutics with disease-modifying properties. Full article

In sorption cooling systems, an important stage of the thermodynamic cycle is the separation of the refrigerant fluid from the absorbent mixture. This process is called “regeneration” or “desorption,” and it is similar to thermal desalination, where water is separated from an aqueous saline solution. However, since sorption systems utilize high salt concentration solutions, conventional desalination techniques such as reverse osmosis are not suitable. In this regard, membrane devices can enhance heat and mass transfer processes in compact sizes. In the present paper, a membrane device with an air gap membrane distillation configuration was evaluated, operating with the H₂O/LiBr + LiCl solution (with a mass ratio of 2:1, LiBr:LiCl), to assess the produced distilled water flux. Among the operating parameters analyzed (solution temperature, cooling water temperature, salt concentration, and membrane pore size), solution temperature had the highest impact on the distilled water flux, while the membrane pore size had the lowest impact. The maximum distilled water flux was 7.63 kg/h·m² with a solution temperature of 95.3 °C, a cooling water temperature of 25.1 °C, a salt concentration of 44.99% w/w, and a membrane pore size of 0.45 μm. On the other hand, the minimum distilled water flux was 0.28 kg/h·m² with a solution temperature of 80.3 °C, a cooling water temperature of 40.1 °C, a salt concentration of 50.05% w/w, and with a membrane pore size of 0.22 μm. Full article

Plant-derived vesicle-like nanoparticles (PDVLNs) are bioactive nanovesicles secreted by plant cells, emerging as a novel therapeutic tool for tissue repair and regeneration due to their low immunogenicity, intrinsic bioactivity, and potential as drug delivery carriers. This review examines PDVLNs’ biogenesis mechanisms, isolation techniques, and compositional diversity, emphasizing their roles in promoting essential regenerative processes—cell proliferation, differentiation, migration, immune modulation, and angiogenesis. We explore their therapeutic applications across multiple tissue types, including skin, bone, neural, liver, gastrointestinal, cardiovascular, and dental tissues, using both natural and engineered PDVLNs in various disease models. Compared to mammalian exosomes, PDVLNs offer advantages such as reduced immune rejection and ethical concerns, enhancing their sustainability and appeal for regenerative medicine. However, challenges in clinical translation, including scalability, standardization, and safety remain. This paper consolidates current knowledge on PDVLNs, highlighting their versatility and providing insights into engineering strategies to optimize efficacy, ultimately outlining future research directions to advance their clinical potential. Plant vesicle-like nanoparticles (PDVLNs) may become a new avenue for the treatment of tissue injury, promoting tissue repair and regeneration through their intrinsic bioactivity or as drug delivery carriers. In addition, PDVLNs can be engineered and modified to achieve better results. Full article

This paper proposes an adaptive human–robot concurrent control scheme that achieves the appropriate gait trajectory for a robotic leg prosthesis to improve the wearer’s comfort in various tasks. To accommodate different wearers, a neuromuscular-force-based impedance method was developed using muscle activation to reshape gait trajectory. To eliminate the use of sensors for torque measurement, a disturbance observer was established to estimate the interaction force between the human residual limb and the prosthetic receptacle. The cost function was combined with the interaction force and tracking errors of the joints. We aim to reduce the cost function by minimally changing the control weight of the gait trajectory generated by the Central Pattern Generator (CPG). The control scheme was primarily based on human-in-the-loop optimization to search for a suitable control weight to regenerate the appropriate gait trajectory. To handle the uncertainties and unknown coupling of the motors, an adaptive law was designed to estimate the unknown parameters of the system. Through a stability analysis, the control framework was verified by semi-globally uniformly ultimately bounded stability. Experimental results are discussed, and the effectiveness of the adaptive control framework is demonstrated. In Case 1, the mean error (MEAN) of the tracking performance was $3.6°$ and $3.3°$, respectively. And the minimized mean square errors (MSEs) of the tracking performance were $2.3°$ and $2.8°$, respectively. In Case 2, the mean error (MEAN) of the tracking performance is $2.7°$ and $3.1°$, respectively. And the minimized mean square errors (MSEs) of the tracking performance are $1.8°$ and $2.4°$, respectively. In Case 3, the mean errors (MEANs) of the tracking performance for subject1 and 2 are $2.4°$, $2.9°$, $3.4°$, and $2.2°$, $2.8°$, $3.1°$, respectively. The minimized mean square errors (MSEs) of the tracking performance for subject1 and 2 were $1.6°$, $2.3°$, $2.6°$, and $1.3°$, $1.7°$, $2.2°$, respectively. Full article

Direct Air Capture (DAC) is emerging as a critical climate change mitigation strategy, offering a pathway to actively remove atmospheric CO₂. This comprehensive review synthesizes advancements in DAC technologies, with a particular emphasis on the pivotal role of nanostructured solid sorbent materials. The work critically evaluates the characteristics, performance, and limitations of key nanomaterial classes, including metal–organic frameworks (MOFs), covalent organic frameworks (COFs), zeolites, amine-functionalized polymers, porous carbons, and layered double hydroxides (LDHs), alongside solid-supported ionic liquids, highlighting their varied CO₂ uptake capacities, regeneration energy requirements, and crucial water sensitivities. Beyond traditional temperature/pressure swing adsorption, the review delves into innovative DAC methodologies such as Moisture Swing Adsorption (MSA), Electro Swing Adsorption (ESA), Passive DAC, and CO₂-Binding Organic Liquids (CO₂ BOLs), detailing their unique mechanisms and potential for reduced energy footprints. Despite significant progress, the widespread deployment of DAC faces formidable challenges, notably high capital and operational costs (currently USD 300–USD 1000/tCO₂), substantial energy demands (1500–2400 kWh/tCO₂), water interference, scalability hurdles, and sorbent degradation. Furthermore, this review comprehensively examines the burgeoning global DAC market, its diverse applications, and the critical socio-economic barriers to adoption, particularly in developing countries. A comparative analysis of DAC within the broader carbon removal landscape (e.g., CCS, BECCS, afforestation) is also provided, alongside an address to the essential, often overlooked, environmental considerations for the sustainable production, regeneration, and disposal of spent nanomaterials, including insights from Life Cycle Assessments. The nuanced techno-economic landscape has been thoroughly summarized, highlighting that commercial viability is a multi-faceted challenge involving material performance, synthesis cost, regeneration energy, scalability, and long-term stability. It has been reiterated that no single ‘best’ material exists, but rather a portfolio of technologies will be necessary, with the ultimate success dependent on system-level integration and the availability of low-carbon energy. The review paper contributes to a holistic understanding of cutting-edge DAC technologies, bridging material science innovations with real-world implementation challenges and opportunities, thereby identifying critical knowledge gaps and pathways toward a net-zero carbon future. Full article

Text-to-music (TTM) models have recently revolutionized the automatic music generation research field, specifically by being able to generate music that sounds more plausible than all previous state-of-the-art models and by lowering the technical proficiency needed to use them. For these reasons, they have readily started to be adopted for commercial uses and music production practices. This widespread diffusion of TTMs poses several concerns regarding copyright violation and rightful attribution, posing the need of serious consideration of them by the audio forensics community. In this paper, we tackle the problem of detection and attribution of TTM-generated data. We propose a dataset, FakeMusicCaps, that contains several versions of the music-caption pairs dataset MusicCaps regenerated via several state-of-the-art TTM techniques. We evaluate the proposed dataset by performing initial experiments regarding the detection and attribution of TTM-generated audio considering both closed-set and open-set classification. Full article

This paper focuses on regeneration projects in ‘first-generation’ seaside resorts in England from the perspective of those leading and managing such projects. There have been numerous recent initiatives intended to revive seaside resorts and enable them to regain competitiveness, but limited analysis of what is necessary for such regeneration projects to be successful. This paper contributes to debates about the role of critical success factors (CSFs) in regeneration by identifying issues that apply to the specific context of seaside resorts. In-depth interviews were undertaken with ten managers responsible for individual projects focusing on the CSFs necessary for regeneration projects to succeed. Four such factors were identified: (1) the need to secure appropriate funding (and associated difficulties); (2) the importance of involving stakeholders (particularly the local authority and local community); (3) the need for a strong business plan (which must evolve as the project progresses); and (4) the importance of considering best practices elsewhere. The importance of each success factor varied by the sector (public/commercial/third) leading the regeneration initiative and varied at different stages of a regeneration project. These findings have practical implications for local authorities, commercial enterprises, and third-sector bodies in seaside destinations. Full article

Uniquely rooted in regenerative leadership and complemented by Complexity Leadership Theory (CLT), this conceptual essay offers a theoretical exploration of how educational institutions can act as dynamic systems that catalyze adaptive, community-led responses to anthropocentric socio-environmental crises. Rather than sustaining existing structures, educational leadership for regeneration seeks to restore ecological balance and nurture emergent capacities for long-term resilience. Positioned as key sites of influence, educational institutions are explored as engines of innovation capable of mobilizing students, educators, and communities toward collective environmental action. CLT offers a valuable lens for understanding how leadership emerges from nonlinear, adaptive processes within schools, enabling the development of innovative, collaborative, and responsive strategies required for navigating complexity and leading planetary-positive change. Drawing on a synthesis of the recent global literature, this paper begins by outlining the need to go beyond sustainability in envisioning regenerative futures, followed by an introduction to regenerative principles. It then examines the current and evolving role of educational leadership, the relevance in enabling whole-institution transformation, and how this relates to regenerative practices. The theoretical frameworks of systems thinking and CLT are introduced before noting their application within regenerative educational leadership. The final sections identify implementation challenges and offer practical recommendations, including curriculum innovation, professional development, and youth-led advocacy, before concluding with a call for education as a vehicle for cultivating planetary-conscious citizens and systemic change. This work contributes a timely and theoretically grounded model for reimagining educational leadership in an era of global turbulence. Full article

In 2022, the United Nations Global Biodiversity Framework set forth an ambitious target for “biodiversity-inclusive cities”, recognising the imperative to address biodiversity decline across all sectors, including the built environment. However, the application of this emerging concept remains limited, with few projects directly aligned with the framework’s objectives or timelines necessary for meaningful biodiversity outcomes. To address this limitation this research presents The Paddock, a 27-home regenerative development in southeastern Australia, designed to empower residents in ecological restoration and regeneration efforts. Engagement was initiated through citizen science surveys and a co-design workshop during 2015–2016. As a result, The Paddock seeks to support five focal species’ return via ecosystem-centred design principles. Utilising a mixed-methods approach, the paper documents the design process, ecological decision-making, and the evolving people–nature relationships within the community. Preliminary results indicate the anecdotal return of four targeted species alongside other local fauna. Feedback gathered from residents, combined with insights from the landowner and architect, illustrates that residing in a regenerative environment enhances ecological connections and stewardship tendencies. Ongoing long-term species monitoring will further evaluate the project’s ecological impact. This case study underscores the potential of biodiversity inclusive design (BID) in fostering biodiversity-positive and socially responsive housing developments. Full article

High unemployment rates, inaccessible housing markets, and funding challenges create barriers to finding suitable housing for adults with Autism Spectrum Disorder (ASD) who have less obvious support needs, also known as autistic adults. While public and community housing services in Aotearoa New Zealand (AoNZ) may be an option, a lack of accessible designs leaves families uncertain about future care options. This paper, part of the MBIE-funded Public Housing and Urban Regeneration: Maximising Wellbeing research programme in partnership with registered Community Housing Provider, Te Toi Mahana (TTM), takes an exploratory approach to ask how public and community housing can support and help enable semi-independent living for autistic adults. It investigates how design elements—such as dwelling layouts, material choices, colour schemes, lighting, acoustics, shared and community spaces, and external environments—impact the wellbeing of autistic adults. By extension, insights may also inform private housing design. The study focuses on autistic adults who may be considered ‘mid-to-high’ functioning or those who have been previously diagnosed with Asperger’s Syndrome, whose housing needs are often overlooked. It develops guiding principles and detailed guidance points for public and community housing, informed by the literature, case studies, and data from a photo elicitation study and interviews undertaken with autistic adults in AoNZ. These guiding principles are tested through the speculative redesign of a large TTM site in Newtown, Wellington, AoNZ. Findings should be of interest to government agencies, housing providers, architects, stakeholders, and others involved in shaping the built environment, as well as autistic adults and their supporters, both in AoNZ and internationally. Full article