Search Results (46)

The Pulse Magneto Oscillation (PMO) solidification homogenization technique has been successfully applied in the continuous casting production of GCr15 bearing steel. To further investigate the effects of PMO technology on the precipitation mechanisms of primary carbides in GCr15 bearing steel, a series of directional solidification experiments were conducted under the influence of PMO. Characterization and analysis of the area proportion, number density, particle-size distribution, elemental distribution, and types of primary carbides in the as-cast bearing steel under various PMO parameters were conducted using Optical Microscopy (OM), Scanning Electron Microscopy (SEM), Electron Probe Microanalysis (EPMA), and Electron Backscatter Diffraction (EBSD). The findings reveal that the predominant carbide species precipitated in GCr15 bearing steel is M₃C type, characterized by a higher Cr content. As the PMO peak current and pulse frequency increase, there is a significant reduction in both the area proportion and number density of primary carbides. Compared to non-PMO conditions, the application of PMO results in a maximum decrease in carbide area proportion by up to 75.6% and a reduction in number density by up to 58.4%, leading to a more dispersed and uniform carbide distribution. Moreover, under the influence of PMO, the local solidification duration of the solution shortens, leading to an increase in the quantity of inclusions such as MnS, which undergo refinement. This facilitates the refinement of primary carbides that utilize inclusions as heterogeneous nucleation sites. Additionally, the reduction in dendritic arm spacing within the solidification structure and the enhancement of solute distribution near the solid–liquid interface, induced by PMO, also create favorable conditions for the reduction in size and quantity of primary carbides. Based on the distinctive characteristics of primary carbides under varying PMO parameters, an innovative dynamic model for the formation of primary carbides during the solidification process of GCr15 bearing steel has been proposed. Full article

Directional solidification technology is the core process for manufacturing single-crystal blades in aero-engines, but transverse grain boundaries caused by the competitive growth of polycrystals severely degrade blade performance. To gain a deeper understanding of polycrystalline competitive growth behavior, this study investigates the competitive growth of polycrystals during directional solidification under natural convection based on the phase field and lattice Boltzmann coupling model. By adjusting the solutal expansion coefficient, grain configuration, and pulling velocity, the influence of the flow field on polycrystalline competitive growth is analyzed. The results indicate that changes in the solutal expansion coefficient affect the dendritic competition process and outcome, particularly for dendrites with larger favorably oriented (FO) angles, which are more likely to be eliminated at higher solutal expansion coefficients. Additionally, grain configurations with greater orientation differences between adjacent dendrites are more sensitive to changes in the solutal expansion coefficient, whereas configurations with smaller orientation differences are less affected. It was also found that as the pulling velocity increases, the primary dendrite arm spacing decreases and the growth direction of the dendrites deflects towards the temperature gradient direction. This leads to a reduction in vortices at the dendrite tips and grain boundaries, thereby decreasing the overall flow field intensity. During dendrite growth, solute is rejected from the solid phase, creating a concentration gradient between the dendrite tips and the liquid region. This induces convection in the liquid phase. The interaction between the flow field and the solute concentration in the liquid phase causes the flow field strength and solute concentration to exhibit periodic fluctuations. Full article

Nickel-based superalloy GH3625 is widely used in extreme environments due to its exceptional high-temperature strength and corrosion resistance; however, optimizing its comprehensive performance through precise microstructural control remains a critical challenge. In this study, the effect of withdrawal rate (10–200 μm/s) on the microstructural evolution, mechanical properties, and corrosion resistance of GH3625 alloy was investigated using a liquid-metal-cooled directional solidification system. The microstructural characteristics, elemental segregation, and phase distributions were systematically analyzed via OM, SEM, and EDS, followed by uniaxial tensile and electrochemical polarization tests. The results show that with increasing withdrawal rate, the solid–liquid interface morphology evolves from cellular to cellular-dendritic and finally to fully dendritic. Correspondingly, the primary dendrite arm spacing decreases from 270.4 μm to 100.2 μm, and the secondary dendrite arm spacing decreases from 66.5 μm to 12.3 μm. The area fraction of the detrimental Laves phase first decreases and then increases, reaching a minimum at 100 μm/s. Correspondingly, the yield strength increases from 282 MPa to 409 MPa, and the corrosion resistance is optimized at 100 μm/s. The microstructure–property relationships are discussed based on second-phase strengthening theory and microstructural refinement. This study provides a theoretical basis and practical process windows for optimizing directional solidification parameters to achieve enhanced mechanical and corrosion performance in GH3625 alloy. Full article

Laser-directed energy deposition (DED) using wire or powder feedstock is a promising way to fabricate prototypes in rapid time, including complex metal parts for advanced engineering applications. In this work, AISI 316L stainless steel—a well-known, weldable alloy model—was used to perform a foundational comparative study of wire-fed (LW-DED) and powder-fed (LP-DED) processes, establishing a baseline before progressing to high-temperature alloys. Hollow cylindrical specimens were fabricated and characterized microstructurally and mechanically. LP-DED produced a refined cellular–dendritic structure with primary dendrite arm spacing of 3.29 ± 0.49 µm and slightly higher average hardness (226 ± 8 HV0.2), accompanied by fine, spherical porosity inherent to the powder feedstock. LW-DED generated coarser epitaxial columnar dendrites (5.15 ± 0.69 µm) and slightly lower hardness (206 ± 10 HV0.2) but achieved nearly full density and high material catching efficiency. The results indicate that both methods yield comparable deposits when parameters are controlled, with LP-DED offering enhanced microstructural refinement and LW-DED providing faster deposition and higher build volume. These findings provide practical guidance for the additive manufacturing of high-performance parts and establish a baseline for the application of DED processes to advanced alloys. Full article

During the vacuum arc remelting (VAR) process, external convective cooling conditions exert a significant influence on both the heat transfer behavior and solidification microstructure of ingots. In this research, Φ 480 mm IN718 alloy VAR ingots were investigated. A heat transfer model for the VAR mold was established based on the equivalent thermal resistance method to analyze the effects of varying external convective cooling conditions on overall heat transfer performance. Industrial-scale VAR experiments were conducted at different cooling water flow velocities (0.48, 0.73 and 1.30 m/s) to assess how external cooling affects molten pool morphology and microstructure evolution. The results indicate that cooling water flow velocity is the primary factor affecting the heat transfer performance of the VAR mold. Increasing the flow velocity significantly enhances radial heat transfer capability while exerting a relatively limited effect on axial heat transfer. Furthermore, as the cooling water flow velocity increases, the molten pool depth decreases markedly, the pool morphology becomes shallower and more symmetric, and the ingot cooling rate is enhanced. Consequently, dendrite coarsening is effectively suppressed, resulting in a significant reduction in secondary dendrite arm spacing. Specifically, when the flow velocity increases from 0.48 to 1.30 m/s, SDAS decreases by 30.4% at the center, 31.0% at R/2, and 26.5% at the edge, and the SDAS-derived equivalent cooling rate (GR) increases from 6.53–18.25 K/min to 19.41–46.01 K/min across the three representative radial locations. A significant enhancement in the metallurgical quality of the VAR ingot is achieved. Full article

This study addresses the issues of coarse primary austenite dendrites and uneven graphite distribution in hypoeutectic gray cast iron. High-energy mechanical activation technology was used to prepare high-energy activated SiC particles (EASiCp), and the regulatory mechanisms of trace additions (0–0.15 wt.%) on the solidification process and microstructure properties of hypoeutectic gray cast iron were systematically investigated. The results indicate that high-energy activation treatment reduced the average particle size of SiC particles from 26.53 μm to 9.51 μm and increased their specific surface area from 0.35 m²/g to 1.78 m²/g. X-ray diffraction (XRD) analysis revealed that the grain size was refined from 55.5 nm to 17.4 nm, with significant lattice distortion. The absorption rate of EASiCp in the melt stabilized between 68–72%, with particles predominantly dispersed within the grains (78.12%) and at grain boundaries (21.88%) in sizes ranging from 0.3 to 2 μm. The addition of EASiCp enhanced the solidification undercooling from 5.3 °C to 8.4 °C and reduced the latent heat of crystallization from 162.6 J/g to 99.96 J/g due to its endothermic reaction in the melt (SiC + Fe → FeSi + C) and heterogeneous nucleation effects. In terms of microstructure, the addition of 0.15 wt.% EASiCp increased the primary austenite dendrite content by 35.29%, reduced the secondary dendrite arm spacing by 57.98%, shortened the graphite length from 0.46 mm to 0.20 mm, and refined the eutectic colony size from over 500 μm to 180 μm. The final material achieved a tensile strength of 308 MPa, an improvement of 12.82% compared to the unadded group. Mechanistic analysis showed that EASiCp facilitated direct nucleation, reaction-induced “micro-area carbon enrichment,” and a synergistic effect in suppressing grain growth, thereby optimizing the solidification microstructure and enhancing performance. This study provides a new method for the efficient nucleation control of hypoeutectic gray cast iron. Full article

AlMg5Si2Mn alloys are widely used in the field of automotive castings. Since the morphology, size, and distribution of the primary Al dendrite and eutectic Mg₂Si have a decisive influence on the mechanical properties of the alloy, a comprehensive analysis of AlMg5Si2Mn alloys with varying Y contents was conducted using optical microscopy (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The influence of Y on the microstructural evolution and mechanical behavior of the cast hypoeutectic AlMg5Si2Mn alloy was studied. Experimental findings indicate that the addition of Y significantly refines and alters the morphology of both primary Al and eutectic Mg₂Si in AlMg5Si2Mn alloys. Specifically, in the alloy containing 0.45 wt.% Y, the primary Al undergoes a structural transformation from a coarse dendritic morphology to finer ellipsoidal grains, with a minimum secondary dendritic arm spacing (SDAS) of 18.6 ± 1.6 μm. Simultaneously, the eutectic Mg₂Si morphology transitions from a coarse lamellar structure to finer worm-like, coral-like, and fibrous forms, exhibiting a reduced average length and aspect ratio (AR) of 3.1 ± 0.4. Furthermore, the AlMg5Si2Mn alloy leads to significant improvements in mechanical performance, particularly in tensile strength. The measured average ultimate tensile strength, yield strength, and elongation are 243.3 MPa, 199.0 MPa, and 8.5%, respectively, representing increases of 19.16%, 24.6%, and 203.6% compared to the Y-free alloy. The fracture mode of the alloy fracture transitioned from brittle fracture in its unmodified condition to ductile fracture characteristics. Full article

A high-alloy (Cr-Mo-V) cold-work tool steel was manufactured by laser powder-bed fusion (PBF-LB) without preheating and by electron-beam powder-bed fusion (PBF-EB) with the build temperature set at 850 °C. The solidification rates, cooling, and thermal cycles that the material was subjected to during manufacturing were different in the laser powder-bed fusion than electron-beam powder-bed fusion, which resulted in very different microstructures and properties. During the solidification of the PBF-LB steel, a cellular–dendritic structure was formed. The primary cell size was 0.28–0.32 µm, corresponding to a solidification rate of 2.0–2.5 × 10⁶ °C/s. No coarse primary carbides were observed in the microstructure. Further rapid cooling resulted in the formation of a martensitic microstructure with high amounts of retained austenite. The high-retained austenite explained the low hardness of 597 ± 38 HV. Upon solidification of the PBF-EB tool steel, dendrites with well-developed secondary arms and a carbide network in the interdendritic space were formed. Secondary dendrite arm spacing was in the range of 1.49–3.10 µm, which corresponds to solidification rates of 0.5–3.8 × 10⁴ °C/s. Cooling after manufacturing resulted in the formation of a bainite needle-like microstructure within the dendrites with a final hardness of 701 ± 17 HV. These findings provide a background for the selection of a manufacturing method and the development of the post-treatment of a steel to obtain a desirable final microstructure, which ensures that the final tool’s performance is up to specification. Full article

The dimensional accuracy and microstructure affect the service performance of parts fabricated by wire arc additive manufacturing (WAAM). Regulating the geometry and microstructure of such parts presents a challenge. The coupling method of an artificial neural network and finite element (FE) is proposed in this research for this purpose. Back-propagating neural networks (BPNN) based on optimization algorithms were established to predict the bead width (BW) and height (BH) of the deposited layers. Then, the bead geometry was modeled based on the predicted dimension, and 3D FE heat transfer simulation was performed to investigate the evolution of temperature and microstructure. The results showed that the errors in BW and BH were less than 6%, and the beetle antenna search BPNN model had the highest prediction accuracy compared to the other models. The simulated melt pool error was less than 5% with the experimental results. The decrease in the ratio of the temperature gradient and solidification rate induced the transition of solidified grains from cellular crystals to columnar dendrites and then to equiaxed dendrites. Accelerating the cooling rate increased the primary dendrite arm spacing and δ-ferrite content. These results indicate that the coupling model provides a pathway for regulating the dimensions and microstructures of manufactured parts. Full article

The solidification of Inconel 718 alloy (IN718) from undercooled liquid is studied. The solidification kinetics is evaluated in melted and undercooled droplets processed using the electromagnetic levitation (EML) technique by the temperature–time profiles and solid/liquid (S/L) interface movement during recalescence. The kinetics is monitored in real time by special pyrometrical measurements and high-speed digital camera. It is shown that the growth velocity of $\gamma$-phase (the primary phase in IN718), the final crystalline microstructure (dendritic and grained), and the mechanical properties (microhardness) are strongly dependent on the initial undercooling $\Delta T$ at which the samples started to solidify with the originating $\gamma$-phase. Particularly, with the increase in undercooling, the secondary dendrite arm spacing decreases from 28 μm to 5 μm. At small and intermediate ranges of undercooling, the solidified droplets have a dendritic crystalline microstructure. At higher undercooling values reached in the experiment, $\Delta T>160$ K (namely, for samples solidified with $\Delta T=170$ K and $\Delta T=263$ K), fine crystalline grains are observed instead of the dendritic structure of solidified drops. Such change in the crystalline morphology is qualitatively consistent with the behavior of crystal growth kinetics which exhibits the change from the power law to linear law at $\Delta T\approx 160$ K in the velocity–undercooling relationship (measured by the advancement of the recalescence front in solidifying droplets). Study of the local mechanical properties shows that the microhardness increases with the increase in the ${\gamma }^{″}$-phase within interdendritic spacing. The obtained data are the basis for testing the theoretical and computational of multicomponent alloy samples. Full article

For Al-Mg-Si alloys, cooling after homogenisation is a crucial step because the precipitation of the equilibrium β-Mg₂Si phase determines the processing capabilities in subsequent steps, as well as the subsequent precipitation age hardening potential, and thus, the final properties. It is therefore important to understand how microstructural variations affect the transformation of β-Mg₂Si during cooling after homogenisation. In the present work, alloys with similar effective solute contents of Mg and Si, but with different microstructures and a different amount of primary Al-Fe-Si phases, were produced. Characterisation of the precipitation reaction was performed using interrupted quench experiments with cooling rates of 1–6 K/min, monitored by light optical microscopy (LOM), scanning electron microscopy (SEM) and conductivity measurements. Precipitation kinetics for β-Mg₂Si was found to increase in microstructures with shorter secondary dendrite arm spacing (DAS). However, despite measuring both a higher density and volume fraction of the primary phases, no effect on the phase transformation from an increased iron content was found in terms of precipitation kinetics or particle count statistics. Furthermore, comparisons with iron-free high-purity-based alloys revealed that the precipitation reaction for β-Mg₂Si was identical in the two different microstructures both in terms of onset temperature and overall kinetics. The present results show that nucleation of β-Mg₂Si is not dependent on the larger constituent phases and indicates that overall transformation kinetics is governed by bulk diffusion rates. Full article

Improving the high-temperature stress rupture properties of Inconel 718 (IN718) alloys is crucial for enhancing aircraft engine performance. By using the laser powder bed fusion (LPBF) technique, IN718 alloys were crafted at varying volumetric energy densities (VED) in this study. The dendrite growth mode, reinforcing phase distribution and high temperature stress rupture properties of various VED samples were investigated. The results showed that the stress rupture life and the uniform elongation of the samples both first increased and then decreased with the increase in VED. When the VED was 60 J/mm³, the maximum rupture life and elongation of the sample were 43 h and 3.8%, respectively. As the VED increased, the angle of dislocation in the dendrite decreased while the spacing between primary dendrite arms increased, resulting in an increase in the size and volume fraction of the Laves phase. Following a heat treatment, the δ phase would nucleate preferentially around the dissolved Laves phase causing an increase in the volume fraction of the δ phase with the increase in VED. The creep voids readily formed around the δ phase are distributed along the grain boundaries, while the inhomogeneous δ phase and fine grains facilitated crack initiation and propagation. Furthermore, a significant quantity of the δ phase consumed the Nb element, thereby hindering adequate precipitation in the γ″ phase and causing cracks. Full article

The study focuses on investigating the relationship between the ultrasonic effect and microstructure of ultrasonic-assisted gas tungsten arc welding (UA-GTAW) Inconel690 alloy joints. The influence of ultrasonic vibrations on Inconel690 plates was examined, while also clarifying the distribution pattern of the ultrasonic effect across the plate. Furthermore, actual welding experiments were performed by varying the distance between the ultrasonic horn and the welding torch. The results revealed that there were changes in both grain growth direction within the weld zone and refinement effects achieved under different distances. The optimal refinement of primary and secondary dendrite arm spacing was observed at distances of 60 mm and 180 mm between the welding torch and ultrasonic horn. The hardness of weld zone reached 235HV₁ when the distance between ultrasonic horn and welding torch is 180 mm. Full article

In this paper, the effects and the mechanisms of melt superheating treatment (MST) on a directionally solidified alloy were investigated. The mass loss rate of the superalloy becomes severe as the MST temperature rises. The chromium, tantalum, and hafnium are the primary evaporation elements during MST. As the MST temperature increases from 1500 to 1600 °C, the secondary dendrite arm spacing is reduced by 13.3%, and the average size of γ′ particles are reduced by 11.5% and 18.2% in the dendrite core and inter-dendritic area, respectively. The content of oxygen and nitrogen gradually reduces with the increase in the MST temperature. However, the sulfur content is not significantly affected by the MST temperature. The essential cause of γ′ phases transition is supposed to be the MST-induced changes in solute distribution and the decomposition of atomic clusters. In addition, the nitrides and Ti (N, C)-type carbides are continuously dispersed as the MST temperature increases, which promotes the removal of nitrogen impurities. Full article

Some unavoidable factors in the operating environment could damage single-crystal components of nickel-based single-crystal superalloys. This work prepared an epitaxial growth NiCoCrAlYTa repaired coating without the columnar-to-equiaxed transition (CET) phenomenon on a nickel-based single-crystal superalloy by electron beam cladding. The microstructure of two cross-sections and two surfaces at different depths were characterized. Moreover, the formation mechanism of coating dendrite was revealed by studying the relationship between coating dendrite size, growth direction, and solidification rate. The microstructure evolution and crystal growth orientation of the coating were investigated. The microstructural investigation of the sample revealed that the dendrites’ orientations on the coating’s horizontal section were different, and its characteristics were highly visible on the surface of the coating. The crystal growth orientations of the coating on the vertical cross-section parallel/perpendicular to the scanning direction of the electron beam were also different. Moreover, the average primary dendrite arm spacing (PDAS) of the columnar dendrite in the different areas of the coating was different and increased from 2 μm to 4 μm. The oxidation resistance of the coating at 1000 °C was about three times higher than that of the substrate. Full article