Search Results (413)

Deep coalbed methane (CBM) has become an important contributor to natural gas production worldwide. Its fluid occurrence characterized by high free gas content and low water saturation suggests substantial gas-driven displacement caused by hydrocarbon generation overpressure. However, the microscopic evolution of this process and the corresponding occurrence remain poorly understood. To address these issues, we combined centrifugation experiments, nuclear magnetic resonance (NMR) monitoring, and theoretical modeling to systematically investigate pore-scale displacement dynamics and the associated fluid distribution. A dynamic evolution model for gas–water displacement in nanopores is developed by incorporating the capillary pressure and disjoining pressure, and validated against the centrifugation experimental data. At the pore scale, gas–water displacement is governed by critical displacement pressure and water film thickness. Water saturation declines sharply once the displacement pressure exceeds a critical threshold, after which it decreases slowly as the water film progressively thins. At the porous media scale, water saturation continuously decreases with increasing displacement pressure. For the high-rank coal samples in this study, the overall water saturation decreases to 49.15% as the displacement pressure increases to 10 MPa. The water film is negligible for pores larger than 20 nm, but significant for pores smaller than 20 nm. This critical pore size is not fixed, but is a dynamic threshold controlled by the disjoining pressure parameter. The occurrence of free gas in deep CBM is governed by the relative matching between hydrocarbon generation overpressure and reservoir pore structure. These findings provide a theoretical basis for resource assessment and efficient development of deep CBM. Full article

Coal gasification fine ash (CGFA) is a carbon–mineral composite solid waste whose valorization is severely hindered by poor interfacial compatibility with organic media due to its highly polar surface. Here, we report a surface alkylation strategy using haloalkanes with variable chain lengths to systematically tune the surface chemistry and thermo-oxidative behavior of CGFA. Comprehensive spectroscopic characterizations (XPS, FTIR, and ¹³C NMR) confirm successful grafting of alkyl chains, which increases aliphatic C-H content from 24.8% to 43.9% while reducing polar carboxyl groups from 7.9% to 1.6%, with the mineral framework remaining intact. Thermogravimetric analysis reveals that alkylation lowers the onset decomposition temperature from 358 °C to 295 °C and enhances the maximum mass-loss rate. Kinetic analysis shows that grafted alkyl chains act as low-energy initiation sites, reducing the initial activation energy to 95 kJ/mol, while the later-stage oxidation becomes diffusion-limited. Notably, long straight-chain alkylation achieves the best performance, whereas branched chains are less effective due to steric hindrance and pore blockage. This work establishes a clear chain-length-dependent structure–thermal response relationship, positioning alkylated CGFA as a designable precursor for functional carbon materials, intelligent char-forming agents, and tunable components for energy or responsive material systems. Full article

Clay minerals in coal play a key role in controlling mineralogical composition, geochemical signatures, and the industrial behavior of coal and its combustion residues. This study investigates the occurrence, provenance, and potential applications of clay minerals in Carboniferous ash-rich coals from the Bogatyr, Lenin, and Saradyr coal mines in northeastern Kazakhstan. A total of 60 coal samples were analyzed using XRD, SEM–EDS/BSE, XRF, and ICP-OES following acid leaching. Based on ash yield, 52 samples were classified as coal (<50% ash), while 8 samples were classified as carbonaceous shale or mudstone (>50% ash). Mineralogical assemblages show clear variability among the studied mines. Saradyr samples are strongly quartz-dominated with lower clay proportions, Bogatyr samples exhibit highly heterogeneous quartz–clay–mica assemblages, whereas Lenin samples are relatively more clay-rich and dominated by kaolinite and illite-group minerals. Across all samples, kaolinite is the dominant clay mineral (16.6–46 wt.%), occurring mainly as authigenic pore- and cell-filling aggregates. Minor phases include illite–muscovite (7.1–29.9 wt.%), illite–smectite (up to 7.6 wt.% in Bogatyr), and smectite–montmorillonite (0.4–0.7 wt.%). Clay minerals occur as discrete particles, coatings, and pore fillings, contributing to ash formation; however, their correlation with ash yield is weak (R = 0.03–0.05), reflecting heterogeneous mineral inputs and diagenetic overprinting. All geochemical data are reported on a high-temperature coal ash (HTA) basis (815 °C). Geochemical indices (CIA, CIW, CIX) and Al₂O₃/TiO₂ ratios (1.8–17.4) indicate variable provenance and moderate to high weathering intensity, reflecting mixed mafic to intermediate source rocks. A total of 23 trace elements were identified. Au occurs at trace levels (up to 0.02 ppm), while selected rare earth elements (REE: Ce, Dy, Eu, La, Nd, Sm, Y, Yb) average 0.2–0.3 ppm, indicating negligible economic recovery potential. REEs show a strong positive correlation with clay minerals (r = 0.93), indicating adsorption and minor structural incorporation. In contrast, Au correlates with As, V, Zn, Cu, Ni, and Nb, suggesting sulfide association. HTA is enriched in SiO₂–Al₂O₃ phases dominated by kaolinite and quartz, indicating strong potential for cement, geopolymer, ceramic, and zeolite applications. Full article

Currently, pore fractal characteristics of deep marine–terrestrial transitional coal-measure mudstones in the central Sichuan Basin remain poorly understood. To clarify the pore fractal characteristics and their controlling factors, seven representative deep mudstone samples were collected from the Longtan Formation of Well NT1H in the Suining area, central Sichuan Basin. These samples were subjected to total organic carbon (TOC) content determination, vitrinite reflectance (Ro) measurement, X-ray diffraction (XRD) analysis of whole-rock and clay minerals, and low-pressure nitrogen adsorption (LPN₂A) experiments. Pore fractal dimensions were calculated based on the Frenkel–Halsey–Hill (FHH) theoretical model. The influences of mineral composition, organic geochemical characteristics, and pore structural parameters on pore fractal dimensions were analyzed. The results indicate that shale pores in the study area are predominantly developed as mesopores, exhibiting dual fractal characteristics; fractal dimension D1 (structural fractal dimension at high-pressure segment) ranges from 2.6662 to 2.7366, and fractal dimension D2 (surface fractal dimension at low-pressure segment) ranges from 2.5895 to 2.6363. Mineral composition exerts differential control over pore fractal dimensions. The effects of organic matter content and thermal evolution degree on fractal dimensions exhibit stage-dependent characteristics. Correlations between pore structural parameters and fractal dimensions indicate that small-aperture pores (micropores and mesopores) constitute the primary factor controlling pore heterogeneity in shales. These findings provide a theoretical basis for “reservoir evaluation” and “sweet spot” optimization of deep marine–terrestrial transitional coal-measure shales in central Sichuan Basin. Full article

This study investigates the use of mechanical grinding to activate coal bottom ash (CBA) as a low-carbon supplementary cementitious material. Two CBA powders with different fineness levels (75 μm and 45 μm, denoted as SCBA and GCBA) were used to replace 10–50% of cement in mortar specimens. Performance was evaluated through ISO-standard strength tests and the activity index, while micro-analytical techniques characterized the hydration mechanism. The results show that this grinding treatment significantly enhanced pozzolanic activity; at 28 days, the compressive strength of the mixture with 30% GCBA replacement reached 30.6 MPa, which was 44% higher than that of the corresponding SCBA mixture (21.2 MPa). Microstructural analysis confirmed the consumption of portlandite (CH) and the predominant formation of interwoven C-S-H gels and ettringite (AFt), along with residual quartz, calcite, and mullite. These products refine the pore structure and densify the interfacial transition zone. Economic and environmental analysis reveals that CBA substitution reduces raw material costs by 120 CNY/ton and carbon emissions by approximately 261.3 kg CO₂/t. Based on the balance of mechanical integrity and environmental benefits, mechanical grinding of CBA to 45 μm at a 30% cement replacement level is proposed as a promising approach for producing low-carbon cementitious materials and for future application in green concrete. Full article

Coal liquefaction residues (CLRs), including both indirect (ICLR) and direct (DCLR) variants, represent industrial by-products whose conventional landfill disposal raises environmental concerns. This study comparatively analyzes ICLR and DCLR properties against limestone fine aggregates through physicochemical characterization. Results indicate that ICLR contains predominant SiO₂ crystalline phases (50.05%) with trace Fe-Ti-Al-Mg oxides, demonstrating higher Vickers hardness (615 HV vs. 246 HV for limestone) and elastic modulus (98 GPa vs. 81 GPa for limestone), while its apparent relative density (2.612) closely matches that of limestone (2.783). Conversely, DCLR features abundant carbonaceous components (75.9% C) with olefinic/aromatic structures (asphaltene content 66.2%), exhibiting lower mechanical strength (Vickers hardness 21 HV) but enhanced asphalt affinity, as indicated by strong C=C (1591 cm⁻¹) and aromatic C–H (744 cm⁻¹) absorption peaks in FTIR. Both CLRs share comparable gradation curves and micromorphological characteristics with limestone aggregates, including uniform surface scaly textures. While pore-size distributions differ minimally between CLRs, both present finer porosity than limestone and show no leachate toxicity risks, confirming their viability as sustainable alternatives to asphalt fine aggregates. Full article

Understanding the pore structure of high-rank coals is essential in evaluating gas storage and transport. Here, twelve semianthracite samples from the early Permian Shanxi Formation were investigated by proximate analysis, optical microscopy, low-temperature N₂ adsorption, and fractal analysis, coupled with diffusion coefficient modeling. The coals exhibit diverse pore types (plant-cellular, interparticle, and dissolution pores) shaped by coalification and minerals and show Type IV (a) isotherms with H4 hysteresis loops, indicating complex pore networks. Pore-size partitioning reveals that mesopores and macropores dominate total pore volume, whereas mesopores contribute most of the specific surface area. The pore structure exhibits strong fractal characteristics with an average comprehensive fractal dimension (F_c) of 2.628. The calculated gas diffusion coefficient decreases monotonically with increasing pressure from 1 MPa to 5.8 MPa, with a more pronounced decline at low pressure, indicating a clear pressure-dependent attenuation effect. Diffusion capacity is weakly related to average pore diameter but shows positive correlations with total pore volume and, particularly, macropore volume. Multiple linear regression further demonstrates that pore volume structure is the dominant control on diffusion under both low- and high-pressure conditions, with the relative importance ranked as macropores > mesopores > micropores. Macropores provide the main low-resistance transport framework, mesopores serve as transitional pathways linking storage and transport domains, whereas micropores mainly contribute to gas storage and may even suppress apparent diffusion when overly developed. These results reveal a clear functional differentiation of multiscale pore systems and highlight that gas migration in semianthracite is jointly governed by pore size distribution, connectivity, tortuosity, and fractal network topology. Full article

The persistent accumulation of antibiotic pollutants in aquatic environments poses potential threats to ecological safety and human health, highlighting the importance of developing low-cost, high-performance adsorbents for their efficient removal. In this study, a hydrothermal method was employed to prepare highly dispersed coal gangue-based calcium silicate hydrate (CSH) adsorbents. The structural characteristics, adsorption performance, and adsorption mechanisms of the material were systematically investigated. The as-prepared CSH exhibited an interwoven nanorod/nanosheet composite morphology with a more developed pore structure and a higher specific surface area. Kinetic analysis indicated that the adsorption process followed a pseudo-second-order model and involved both Boyd diffusion and intraparticle diffusion, with liquid-film diffusion likely serving as the primary rate-limiting step. Isotherm analysis revealed that the adsorption behavior was well described by the Langmuir model, suggesting monolayer adsorption, with a theoretical adsorption capacity (Q_m) of 129.29 mg/g. Thermodynamic analysis further demonstrated that the adsorption of CIP onto CSH was a spontaneous and endothermic process. Combined characterization results and theoretical calculations suggested that the adsorption of CIP by CSH was mainly governed by surface oxygen containing active sites, accompanied by electrostatic interactions, hydrogen bonding, and possible surface coordination effects. In addition, CSH maintained excellent adsorption performance and structural stability in the presence of coexisting ions, in tap water systems, and after repeated adsorption–desorption cycles. This study not only enables the high-value utilization of coal gangue but also provides new insights into the development of low-cost adsorbent materials for antibiotic removal. Full article

Coal gangue accumulation causes land occupation and environmental risks in mining areas, but its use as a planting substrate offers a pathway for ecological restoration. This study optimized a coal gangue-based planting substrate by integrating phosphogypsum, spent mushroom substrate, biochar, and a water retention agent. Using a three-factor, four-level orthogonal design with a fixed value of 10% phosphogypsum, the study assessed the effects of the coal gangue-to-spent mushroom substrate ratio, biochar, and water retention agent on substrate properties, nutrient availability, plant growth, and Pb leaching. The results showed that the tested formulations maintained substrate pH within a near-neutral range across treatments. The coal gangue-to-spent mushroom substrate ratio was the dominant factor controlling substrate structure, water-holding capacity, nutrient status, and ryegrass growth. Increasing the spent mushroom substrate proportion reduced bulk density and improved field water capacity, pore structure, and nutrient availability. Biochar most effectively reduced Pb leaching, although excessive application inhibited growth, whereas the water retention agent mainly enhanced water retention and plant growth. The optimal formulation was 80% coal gangue, 20% spent mushroom substrate, 1% biochar, 1.5 g kg⁻¹ water retention agent and 10% phosphogypsum, providing a theoretical and practical optimization basis for coal gangue reutilization and ecological restoration in mining areas. Full article

To enhance the utilization of industrial coal gangue, response surface methodology was used to optimize the concrete mix proportions based on three key factors: the mass ratio of fly ash (FA) to metakaolin (MK) (A), the combined dosage of FA and MK (B), and the water-to-binder ratio (C). A quadratic regression model was established, and the optimal mixture was characterized using FT-IR, XRD, and SEM. The model exhibited high statistical significance (p < 0.001) and an excellent fit (R² > 0.95), confirming its predictive reliability. Single-factor analysis revealed that the order of influence on 28 d compressive strength was C > A > B, indicating that the water-to-binder ratio had the most significant effect on later-age strength. The optimal mix proportions were determined as follows: fly ash-to-MK ratio of 0.65, admixture dosage of 20% by mass of total binder, and C of 0.475. Under these conditions, the measured 28 d compressive strength reached 35.9 MPa, which was within 5% of the model-predicted value, thereby validating the model’s accuracy. Microstructural analysis demonstrated that the appropriate incorporation of FA and MK promoted the formation of C-S-H gel, refined the pore structure, and improved the quality of the interfacial transition zone, which collectively enhanced the mechanical performance. A systematic understanding of the strength and microstructural mechanisms of concrete incorporating coal gangue, fly ash, and metakaolin is currently lacking, which hinders the design of more robust and durable structures. This study addresses this gap by systematically clarifying the individual and combined effects of the key variables on the strength of coal gangue concrete. The findings reveal the underlying mechanisms, providing a scientific basis for the sustainable, large-scale application of coal gangue concrete in construction. Full article

During coalbed methane (CBM) production, coal reservoir pore/fracture structure varies dynamically under the action of fluid–solid coupling. And coal reservoir permeability changes accordingly. In order to factually investigate the dynamic changes in coal reservoir permeability in the CBM well drainage process, a comparative simulation experiment on the difference in coal permeability sensitivity to confining pressure (external pressure) and pore pressure (internal pressure) was carried out in this study. The results show that coal permeability presents a typical negative exponential decline with a decrease in pore pressure. The pore pressure sensitivity experiment can effectively simulate the permeability sensitivity characteristics caused by coal reservoir pressure. Based on the negative exponential function relationship between permeability and effective stress, a new calculating method for the effective stress coefficient was deduced. Namely, its value could be expressed as the quotient of the pore pressure sensitivity curve regression coefficient divided by the confining pressure sensitivity curve regression coefficient. A dynamic theoretical model for coal reservoir permeability characterized by reservoir pressure was systematically constructed based on the unique fluid (gas/liquid)–solid coupling characteristics of coal reservoirs. Furthermore, the general characteristics of the stress sensitivity of coal permeability during coalbed methane (CBM) recovery were analyzed. The dynamic evolution characteristics of coal reservoir permeability in the study area were further examined. Taking the production and drainage data of a typical actual CBM production well as an example, the theories regarding the permeability sensitivity of coal reservoirs to reservoir pressure presented in this paper were validated in practice. This indirectly confirmed the rationality and accuracy of the calculation method for the effective stress coefficient obtained through laboratory-based permeability sensitivity simulation experiments. This research provides robust theoretical support for the systematic monitoring and prediction of fluid production, reservoir pressure, and permeability during the CBM production process, carrying significant practical implications. Full article

To elucidate coalbed methane (CBM) adsorption mechanisms in deep coal reservoirs, the macromolecular structures of coal samples with different coal ranks were characterized using FTIR, XPS, and C NMR, followed by the construction of corresponding molecular models. Grand Canonical Monte Carlo (GCMC) simulations were employed to investigate methane adsorption behavior within the coal matrix at 313.15 K and pressures up to 20 MPa. The results showed that as coal rank increased (R_o,max = 1.63% to 3.18%), the coal macromolecular structure transformed from a side-chain-rich configuration to a highly aromatized and directionally stacked structure. This structural maturation leads to a more compact coal matrix, evidenced by a reduction in free volume from 5108.39 ų to 3999.87 ų and a decline in accessible free volume from 8.23% to 6.26%, thereby restricting the effective space for methane storage. At 20 MPa, although the pore walls of high-rank coal exhibit stronger localized adsorption capacity, the bulk adsorption capacity follows the order: DZ > ZC > SH. This suggests that under deep, high-pressure conditions, the pore-volume compression effect associated with increasing coal rank governs the upper limit of adsorption per unit mass of coal. As pressure increases into the deep reservoir regime, the state of methane in coal micropores gradually shifts from surface adsorption to a high-density, quasi-liquid filling behavior. Consequently, the influence of specific surface area diminishes, while effective free volume emerges as the primary determinant of high-pressure adsorption capacity. The impact of coal rank on deep methane adsorption reflects a competition between enhanced adsorption potential and restricted storage space. The densification-induced compression of effective free volume is identified as the dominant factor limiting the adsorption capacity of deep CBM. This study provides a molecular-scale understanding of deep CBM occurrence mechanisms and establishes a theoretical framework for resource evaluation. Full article

Understanding the impact of ash on nanopore heterogeneity is crucial for evaluating deep coalbed methane (CBM) reservoirs. This study investigates the Benxi Formation coal Seam 8 in the Nalinhe Block, Ordos Basin. Based on proximate analysis, samples were categorized by ash yield (A_ad%). Pore structures were characterized using low-temperature nitrogen adsorption (<2 nm) and carbon dioxide adsorption (2–100 nm). Fractal theory was employed to quantitatively assess pore heterogeneity across different scales. The results indicate that ash content significantly constrains the development of both micropores (<2 nm) and mesopores (2–100 nm), with the most pronounced effect on micropores in the 0.3–0.6 nm range. Ash, primarily derived from kaolinite, occludes pores, reducing pore volume and specific surface area, thereby diminishing methane adsorption capacity. Notably, pore heterogeneity is found to decrease with increasing pore volume. These findings provide valuable insights for the efficient exploration and development of deep CBM resources in the Nalinhe and Suide blocks. Full article

Coalbed methane (CBM) development is strongly controlled by pore structure evolution in deformed coals and its influence on hydraulic fracturing behavior. To clarify the multifractal characteristics of cross-scale pores and their control on fracturing effectiveness, this study investigated eight different deformation coals from the Ordos Basin using low-temperature CO₂/N₂ adsorption (LT-CO₂A/LT-N₂A) and high-pressure mercury intrusion porosimetry (HMIP). Micropores (<2 nm), mesopores (2–50 nm), and macropores (>50 nm) were systematically characterized, and their pore size distributions (PSDs) were quantitatively analyzed using the Coal Structure Index (CSI) and multifractal theory. The results indicate that the multifractal parameters of macropores are significantly distinct from those of mesopores and micropores, exhibiting lower H (0.824–0.893) and D₁ (0.766–0.853), and higher α₀ (1.422–1.541), ΔD (1.230–1.408), and Δα (1.459–1.642). Macropores controlled by tectonic deformation exhibit stronger heterogeneity compared to mesopores and micropores in local parts of the coal mass; PSD varies significantly with deformation rising, derived from the differential pore structure evolution during brittle–ductile transition and the multi-scale synergistic effects including maturity and composition. Combined with field fracturing curves, the results further indicate that the α₀, ΔD, and Δα of macropores are negatively correlated with breakdown pressure, with correlation coefficients of 0.51, 0.61, and 0.59, respectively, and that strong local heterogeneity of macropores favors fracture initiation and propagation and reduces breakdown pressure. Cataclastic coal is the most favorable for hydraulic fracturing, followed by undeformed coal, whereas granulated coal shows the poorest fracturing performance. Full article

To investigate the synergistic effect of hydraulic fracturing and hot water injection on enhancing methane extraction from low-permeability coalbeds and elucidate the underlying thermal-hydraulic coupling mechanism, methane desorption experiments were conducted in coal samples with varying fracture networks using a self-developed multi-field coupling experimental system. Tests were performed under different injection pressures and temperatures to analyze coal temperature evolution and methane desorption-seepage characteristics. The results demonstrate that hydraulic fracturing significantly improves pore structure and connectivity, thereby optimizing methane desorption behavior. The methane migration in the samples is influenced by water injection, exhibiting an initial promotion followed by inhibition. The combined fracturing-thermal injection approach effectively reduces the dynamic viscosity of water, mitigates the water lock effect, and enhances the desorption capacity. The hydraulic fracturing and the hot water injection complement each other, achieving synergistic production enhancement. The optimal injection pressure and water temperature can be selected according to specific reservoir conditions to balance the production increase and cost efficiency. This laboratory-scale study provides theoretical support for optimizing hydraulic measures and thermal injection techniques in coalbed methane extraction, revealing complementary synergies between these two methods and offering new insights into multi-field coupling enhancement mechanisms with practical application guidelines. Full article