Search Results (22)

Direct ultrafiltration (UF) is anticipated to be a promising technology for rural water supply due to its stable permeate quality and ease of automatic operation & maintenance. However, seasonal high turbidity in the surface water resources caused severe membrane fouling, resulting in the requirement of frequent cleaning of the UF process, and limiting the broad application of the direct UF in treating rural surface water. To address this issue, this study investigated the feasibility and mechanism of in situ aeration in alleviating the UF membrane fouling in treating surface water with high turbidity (200, 500, and 800 NTU). The results indicated that with the weak aeration (0.4 m³/(m²·min)), the concentration of polysaccharides accumulated on the membrane surface was high, and serious membrane fouling was observed. With medium aeration (0.8 and 1.2 m³/(m²·min)), bubble shear force could effectively reduce the foulants accumulated on the membrane surface to alleviate the membrane fouling. During the whole experiment, the optimal group (1.2 m³/(m²·min)) showed a 45% lower TMP compared to the control. However, strong aeration (1.6 m³/(m²·min)) caused floc breakage and was less conducive to the membrane fouling control compared to the medium aeration. Furthermore, under in situ aeration, the contents of polysaccharide accumulated on the membrane surface and deposited in the membrane pores were reduced by 8.85%~49.29%, and the structures of the cake layer turned out to be porous and permeable, implying that in situ aeration could significantly modify the structure and composition of the cake layer, contributing to the UF membrane fouling control in treating the seasonal high-turbidity surface water. These findings will provide novel approaches for the application of UF technology in rural water supply. Full article

Ceramic membranes are applied to remove non-sugar impurities, including proteins, colloids and starch, from glucose–fructose syrup that is dissolved from raw sugar using acid. The performance of ceramic membranes with 0.05 μm pores in clarifying high-fructose syrup was investigated under various operating conditions. The flux decreased rapidly at the start of the experiment and then tended to stabilize at a temperature of 90 °C, a transmembrane pressure of 2.5 bar, and cross-flow velocity of 5 m/s under total reflux operation. Moreover, the steady-state flux was measured at 181.65 Lm⁻² h⁻¹, and the turbidity of glucose–fructose syrup was reduced from 92.15 NTU to 0.70 NTU. Although membrane fouling is inevitable, it can be effectively controlled by developing a practical approach to regenerating membranes. Mathematical model predictions, scanning electron microscopy, energy dispersive X-ray spectroscopy, and Fourier-transform infrared spectroscopy revealed that foulants primarily responsible for fouling are composed of polysaccharides, proteins, sucrose, phenols, and some metal elements, such as calcium, aluminum, and potassium. Due to the removal of suspended colloidal solids, the membrane-filtered glucose–fructose syrup was decolorized using activated carbon; the filtration rate was effectively improved. A linear relationship between volume increase in syrup and time was observed. A decolorization rate of 90% can be obtained by adding 0.6 (w/w) % of activated carbon. The pretreatment of glucose–fructose syrup using a ceramic membrane coupled with activated carbon results in low turbidity and color value. This information is essential for advancing glucose–fructose syrup and crystalline fructose production technology. Full article

Membrane fouling is a non-negligible issue affecting the performance of membrane systems. Particularly, organic fouling is the most persistent and severe form of fouling. The complexation between inorganic and organic matter may exacerbate membrane organic fouling. This mini review systematically analyzes the role of inorganic matter in membrane organic fouling. Inorganic substances, such as metal ions and silica, can interact with organic foulants like humic acids, polysaccharides, and proteins through ionic bonding, hydrogen bonding, coordination, and van der Waals interactions. These interactions facilitate the formation of larger aggregates that exacerbate fouling, especially for reverse osmosis membranes. Molecular simulations using molecular dynamics (MD) and density functional theory (DFT) provide valuable mechanistic insights complementing fouling experiments. Polysaccharide fouling is mainly governed by transparent exopolymer particle (TEP) formations induced by inorganic ion bridging. Inorganic coagulants like aluminum and iron salts mitigate fouling for ultrafiltration but not reverse osmosis membranes. This review summarizes the effects of critical inorganic constituents on fouling by major organic foulants, providing an important reference for membrane fouling modeling and fouling control strategies. Full article

Humic, protein, and polysaccharide substances have been recognized as significant types of foulants in membrane systems. Despite the remarkable amount of research that has been performed on the interaction of these foulants, particularly humic and polysaccharide substances, with inorganic colloids in RO systems, little attention has been paid to the fouling and cleaning behavior of proteins with inorganic colloids in UF membranes. This research examined the fouling and cleaning behavior of bovine serum albumin (BSA) and sodium alginate (SA) with silicon dioxide (SiO₂) and α-aluminum oxide (Al₂O₃) in individual and combined solutions during dead-end UF filtration. The results showed that the presence of SiO₂ or Al₂O₃ in water alone did not cause significant fouling or a flux decline in the UF system. However, the combination of BSA and SA with inorganics was observed to have a synergistic effect on membrane fouling, in which the combined foulants caused higher irreversibility than individual foulants. Analysis of blocking laws demonstrated that the fouling mechanism shifted from cake filtration to complete pore blocking when the combined organics and inorganics were present in water, which resulted in higher BSA and SA fouling irreversibility. The results suggest that membrane backwash needs to be carefully designed and adjusted for better control of BSA and SA fouling with SiO₂ and Al₂O₃. Full article

Ceramic membrane has emerged as a promising material to address the membrane fouling issue in membrane bioreactors (MBR). In order to optimize the structural property of ceramic membrane, four corundum ceramic membranes with the mean pore size of 0.50, 0.63, 0.80, and 1.02 μm were prepared, which were designated as C5, C7, C13, and C20, respectively. Long-term MBR experiments showed that the C7 membrane with medium pore size experienced the lowest trans-membrane pressure development rate. Both the decrease and increase of membrane pore size would lead to more severe membrane fouling in the MBR. It was also interesting that with the increase of membrane pore size, the relative proportion of cake layer resistance in total fouling resistance was gradually increased. The content of dissolved organic foulants (i.e., protein, polysaccharide and DOC) on the surface of C7 was quantified as the lowest among the different ceramic membranes. Microbial community analysis also revealed the C7 had a lower relative abundance of membrane fouling associated bacteria in its cake layer. The results clearly demonstrated that ceramic membrane fouling in MBR could be effectively alleviated through optimizing the membrane pore size, which was a key structural factor for preparation of ceramic membrane. Full article

The Barka desalination plant, commissioned in 2018, is the largest desalination plant in Oman. It has a capacity of 281 MLD with a reverse osmosis (RO) first-pass recovery rate of 46%. As part of the standard operator practice, a membrane autopsy was conducted to determine the cause of reductions in membrane performance. This study investigated fouled membranes (model No. SW30HRLE-440) from two different locations in the membrane rack. Various analytical methods were used to conduct the membrane autopsy. Field-emission scanning electron microscopy/energy-dispersive X-ray (FESEM/EDS) analyses of membrane samples showed major components of inorganic foulants. Moreover, black and salt-like crystals deposited on the membrane surface revealed significant carbon (C) components and oxygen (O), with a small amount of magnesium (Mg), chloride (Cl), sodium (Na), aluminium (Al), and calcium (Ca), respectively. A Fourier transform infrared (FTIR) analysis revealed the presence of long-chain hydrocarbons, carboxylic acids/esters, carbohydrates/polysaccharides, and inorganic foulants. Thermogravimetric analyses (TGA) of the membranes showed a high initial weight loss due to organic and inorganic fouling. X-ray photoelectron (XPS) analyses further confirmed the presence of inorganic and organic foulants on the membrane surfaces. Bacteria identification results showed the presence of Bacillus cereus and Bacillus marisflavi. This paper offers a detailed analysis of the foulants present on the reverse osmosis membrane surface and sub-surface before and after a cleaning process. Full article

In this study, the water purification effect and membrane fouling mechanism of two powdered activated carbons (L carbon and S carbon) enhancing Polyvinylidene Fluoride (PVDF) ultrafiltration (UF) membranes for surface water treatment were investigated. The results indicated that PAC could effectively enhance membrane filtration performance. With PAC addition, organic removal was greatly enhanced compared with direct UF filtration, especially for small molecules, i.e., the S-UF had an additional 25% removal ratio of micro-molecule organics than the direct UF. The S carbon with the larger particle size and lower specific surface area exhibited superior performance to control membrane fouling, with an operation duration of S-UF double than the direct UF. Therefore, the particle size and pore structure of carbon are the two key parameters that are essential during the PAC-UF process. After filtration, acid and alkaline cleaning of UF was conducted, and it was found that irreversible fouling contributed the most to total filtration resistance, while the unrecoverable irreversible resistance ratio with acid cleaning was greater than that with alkaline cleaning. With PAC, irreversible UF fouling could be relieved, and thus, the running time could be extended. In addition, the membrane foulant elution was analyzed, and it was found to be mainly composed of small and medium molecular organic substances, with 12% to 21% more polysaccharides than proteins. Finally, the hydrophilicity of the elution was examined, and it was observed that alkaline cleaning mainly eluted large, medium, and small molecules of hydrophilic and hydrophobic organic matter, while acid cleaning mainly eluted small molecules of hydrophilic organic matter. Full article

In order to alleviate membrane fouling and improve removal efficiency, a series of pretreatment technologies were applied to the ultrafiltration process. In this study, ClO₂ was used as a pre-oxidation strategy for the ultrafiltration (UF) process. Humic acid (HA), sodium alginate (SA), and bovine serum albumin (BSA) were used as three typical organic model foulants, and the mixture of the three substances was used as a representation of simulated natural water. The dosages of ClO₂ were 0.5, 1, 2, 4, and 8 mg/L, with 90 min pre-oxidation. The results showed that ClO₂ pre-oxidation at low doses (1–2 mg/L) could alleviate the membrane flux decline caused by humus, polysaccharides, and simulated natural water, but had a limited alleviating effect on the irreversible resistance of the membrane. The interfacial free energy analysis showed that the interaction force between the membrane and the simulated natural water was also repulsive after the pre-oxidation, indicating that ClO₂ pre-oxidation was an effective way to alleviate cake layer fouling by reducing the interaction between the foulant and the membrane. In addition, ClO₂ oxidation activated the hidden functional groups in the raw water, resulting in an increase in the fluorescence value of humic analogs, but had a good removal effect on the fluorescence intensity of BSA. Furthermore, the membrane fouling fitting model showed that ClO₂, at a low dose (1 mg/L), could change the mechanism of membrane fouling induced by simulated natural water from standard blocking and cake layer blocking to critical blocking. Overall, ClO₂ pre-oxidation was an efficient pretreatment strategy for UF membrane fouling alleviation, especially for the fouling control of HA and SA at low dosages. Full article

Microfiltration and ultrafiltration for water/wastewater treatment have gained global attention due to their high separation efficiency, while membrane fouling still remains one of their bottlenecks. In such a situation, many researchers attempt to obtain a deep understanding of fouling mechanisms and to develop effective fouling controls. Therefore, this article intends to trigger discussions on the appropriate choice of foulant surrogates and the application of mathematic models to analyze fouling mechanisms in these filtration processes. It has been found that the commonly used foulant surrogate (sodium alginate) cannot ideally represent the organic foulants in practical feed water to explore the fouling mechanisms. More surrogate foulants or extracellular polymeric substance (EPS) extracted from practical source water may be more suitable for use in the studies of membrane fouling problems. On the other hand, the support vector machine (SVM) which focuses on the general trends of filtration data may work as a more powerful simulation tool than traditional empirical models to predict complex filtration behaviors. Careful selection of foulant surrogate substances and the application of accurate mathematical modeling for fouling mechanisms would provide deep insights into the fouling problems. Full article

The characteristics of foulant in the cake layer and bulk suspended solids of a 10 L submerged anaerobic membrane bioreactor (AnMBR) used for treatment of palm oil mill effluent (POME) were investigated in this study. Three different organic loading rates (OLRs) were applied with prolonged sludge retention time throughout a long operation time (270 days). The organic foulant was characterized by biomass concentration and concentration of extracellular polymeric substances (EPS). The thicknesses of the cake layer and foulant were analyzed by confocal laser scanning microscopy and Fourier transform infrared spectroscopy. The membrane morphology and inorganic elements were analyzed by field emission scanning electron microscope coupled with energy dispersive X-ray spectrometer. Roughness of membrane was analyzed by atomic force microscopy. The results showed that the formation and accumulation of protein EPS in the cake layer was the key contributor to most of the fouling. The transmembrane pressure evolution showed that attachment, adsorption, and entrapment of protein EPS occurred in the membrane pores. In addition, the hydrophilic charge of proteins and polysaccharides influenced the adsorption mechanism. The composition of the feed (including hydroxyl group and fatty acid compounds) and microbial metabolic products (protein) significantly affected membrane fouling in the high-rate operation. Full article

Forward osmosis (FO) technology has a broad application prospect in the field of liquid food concentration because of the complete retention of flavor components and bioactive substances. Membrane fouling is the main obstacle affecting the FO performance and concentration efficiency. This work systematically investigated the membrane fouling behavior of the FO process for fruit juice concentration elucidated by the models of resistance-in-series, xDLVO theory and FTIR analysis. The results show that the AL-FS mode was more suitable for concentrating orange juice. Increasing the cross-flow rate and pretreatment of feed solutions can effectively improve the water flux and reduce the fouling resistance. The ATR-FTIR analysis revealed that the fouling layer of orange juice was mainly composed of proteins and polysaccharides, and the pretreatment of microfiltration can greatly reduce the content of the major foulant. There was an attractive interaction between the FO membrane and orange juice foulants; by eliminating those foulants, the microfiltration pretreatment then weakened such an attractive interaction and effectively prevented the fouling layer from growing, leading to a lower process resistance and, finally, resulting in a great improvement of concentration efficiency. Full article

Ultrafiltration is widely employed in treating high-salinity organic wastewater for the purpose of retaining particulates, microbes and macromolecules etc. In general, high-salinity wastewater contains diverse types of saline ions at fairly high concentration, which may significantly change foulant properties and subsequent fouling propensity during ultrafiltration. This study filled a knowledge gap by investigating polysaccharide fouling formation affected by various high saline environments, where 2 mol/L Na⁺ and 0.5–1.0 mol/L Ca²⁺/Al³⁺ were employed and the synergistic influences of Na⁺-Ca²⁺ and Na⁺-Al³⁺ were further unveiled. The results demonstrated that the synergistic influence of Na⁺-Ca²⁺ strikingly enlarged the alginate size due to the bridging effects of Ca²⁺ via binding with carboxyl groups in alginate chains. As compared with pure alginate, the involvement of Na⁺ aggravated alginate fouling formation, while the subsequent addition of Ca²⁺ or Al³⁺ on the basis of Na⁺ mitigated fouling development. The coexistence of Na⁺-Ca²⁺ led to alginate fouling formed mostly in a loose and reversible pattern, accompanied by significant cracks appearing on the cake layer. In contrast, the fouling layer formed by alginate-Na⁺-Al³⁺ seemed to be much denser, leading to severer irreversible fouling formation. Notably, the membrane rejection under various high salinity conditions was seriously weakened. Consequently, the current study offered in-depth insights into the development of polysaccharide-associated fouling during ultrafiltration of high-salinity organic wastewater. Full article

This study aims to investigate the effect of operational conditions on organic fouling occurring in a direct contact membrane distillation (DCMD) system used to treat wastewater. A mixed solution of sodium alginate (SA) and bovine serum albumin (BSA) was used as a feed solution to simulate polysaccharides and proteins, respectively, assumed as the main organic foulants. The permeate flux was observed at two feed temperatures 35 and 50 °C, as well as three feed solution pH 4, 6, and 8. Higher permeate flux was observed for higher feed temperature, which allows higher vapor pressure. At higher pH, a smaller particle size was detected with lower permeate flux. A mathematical model based on mass balance was developed to simulate permeate flux with time by assuming (i) the cake formation controlled by attachment and detachment of foulant materials and (ii) the increase in specific cake resistance, the function of the cake porosity, as the main mechanisms controlling membrane fouling to investigate the fouling mechanism responsible of permeate flux decline. The model fitted well with the experimental data with R² superior to 0.9. High specific cake resistance fostered by small particle size would be responsible for the low permeate flux observed at pH 8. Full article

The presence of multiple contaminant species in surface waters makes surface water treatment difficult to accomplish through a single process. Herein, we evaluated the ability of an integrated adsorption/ultrafiltration (UF) membrane filtration system to simultaneously remove phosphates and dissolved organic matter (DOM). When bare powdered activated carbon (PAC) and PAC impregnated with amorphous ferrihydrite (FHPAC) adsorbents were compared, FHPAC showed a greater adsorption rate and capacity for phosphate. FHPAC had a phosphate adsorption capacity of 2.32 mg PO₄³⁻/g FHPAC, even when DOM was present as a competing adsorbate. In a lab-scale hybrid FHPAC-UF system (i.e. integrated adsorption by FHPAC with UF membrane filtration), irreversible membrane fouling was ca. three times lower than that in a PAC-UF system. When membrane fouling in the PAC-UF system was described with pore blockage models, we found that the main cause of fouling was bacterial deposition on the membrane surface. CLSM analysis determined that the chemical composition of foulants in the PAC-UF system included higher proportions of proteins, nucleic acids, and alpha-polysaccharides than that in the FHPAC-UF system. Overall, FHPAC’s ability to undergo ligand exchanges with DOM helped to reduce the nutrients and bacteria that cause biofouling to accumulate on the membrane surface. Full article

Fouling is a major obstacle in the introduction of membrane processes in new applications in the pulping industry. Due to the complex nature of the feed solutions, complementary analysis methods are usually needed to identify the substances involved. Four different methods were used for the comprehensive analysis of a membrane removed from an ultrafiltration plant treating alkaline bleach plant effluent in a sulfite pulp mill to identify the substances causing fouling. Magnesium was detected both on the membrane surface and in the nonwoven membrane backing and a small amount of polysaccharides was detected after acid hydrolysis of the fouled membrane. This study provides information on foulants, which can be used to improve processing conditions and cleaning protocols and thus the membrane performance in pulp mill separation processes. It also provides an overview of the usefulness of various analytical methods. Full article