Search Results (71)

The inherent hydrophobicity of polyolefin separators significantly impedes rapid electrolyte wetting, thereby limiting the electrochemical performance of lithium-ion batteries. Cellulose, as a hydroxyl-rich natural polymer, serves as an ideal material for enhancing the interface properties of separators. However, there is still a lack of systematic understanding regarding how the morphological structures of cellulose (such as granular, fibrous, or network-like forms) influence the coating structure and ion transport mechanisms. Here, three representative cellulose derivatives—microcrystalline cellulose (MCC), cellulose nanofibers (CNF), and bacterial cellulose (BC)—were selected to construct functionalized polypropylene (PP) composite separators through vacuum filtration. Experimental results demonstrate that all three cellulose coatings reduced contact angles from 50.8° to below 10°, significantly enhancing interfacial affinity. Systematic comparison reveals that cellulose configuration decisively influences separator performance: unlike the dense fiber entanglement networks formed by CNF and BC, the unique rigid granular packing structure of MCC maintains hydrophilicity while establishing more permeable ion transport pathways. Among these, MCC@PP exhibited optimal electrochemical performance, with the lithium-ion migration number increasing to 0.41 and a capacity retention rate of 88.04% after 100 cycles at 0.5 A/g. This study elucidates the relationship between cellulose configuration and the modification of separator performance, demonstrating that MCC represents a more efficient, robust, and cost-effective option for separator modification compared to complex fiber networks. Full article

This study investigates the reuse of mechanically recycled polyester–glass thermoset scraps (PS) as fillers in LDPE and HDPE matrices at 10–50 wt.% loading. Composites were produced through mechanical size reduction, single-screw extrusion, and compression molding without compatibilizers, and their mechanical and microstructural properties were systematically evaluated. LDPE composites exhibited a notable stiffness increase, with tensile modulus rising from 318.8 MPa (neat) to 1245.6 MPA (+291%) and tensile strength improving from 9.50 to 11.45 MPa (+20.5%). Flexural performance showed even stronger reinforcement: flexural modulus increased from 0.40 to 3.00 GPa (+650%) and flexural strength from 14.5 to 35.6 MPa (+145%). HDPE composites displayed similar behavior, with flexural modulus increasing from 1.2 to 3.1 GPa (+158%) and strength from 34.1 to 45.5 MPa (+33%). Surface-treated fillers provided additional stiffness gains (+36% in sPL4; +33% in sPH3). Impact strength decreased with loading (LDPE: −51%, HDPE: −61%), though surface treatment partially mitigated this (+14–19% in LDPE; +13% in HDPE). Density increased proportionally (PL: 0.95 → 1.20 g/cm³, PH: 0.99 → 1.23 g/cm³), while moisture uptake remained low (≤0.25%). Optical and SEM analyses indicated increasingly interconnected fiber networks at high loadings, driving stiffness and fracture behavior. Overall, PS-filled polyolefins offer a scalable route for converting thermoset waste into functional semi-structural materials. Full article

Microplastics (MPs) and nanoplastics (NPs) have emerged as pervasive pollutants across different aquatic systems on a global basis, yet integrated assessments linking wastewater, riverine, and marine environments remain scarce. The present study provides the first comprehensive evaluation of MPs in three interconnected aquatic matrices of Northern Greece, namely surface seawater from the Thermaic Gulf, surface freshwater from the Axios River, and influent and effluent wastewaters from the Thessaloniki WWTP (Sindos). During two sampling periods spanning late 2023 and spring 2024, suspected MPs were isolated, morphologically classified by stereomicroscopy, and chemically characterized through pyrolysis–gas chromatography/mass spectrometry (Py–GC/MS). MPs were ubiquitously detected in all substrates, exhibiting distinct spatial and compositional patterns. Seawater samples displayed moderate concentrations (1.5–4.8 items m⁻³) dominated by fibers and fragments, while riverine samples contained slightly higher levels (0.5–2.5 items m⁻³), enriched in fibrous forms and polyolefins (PE, PP). Wastewater influents showed the highest MP abundance (78–200 items L⁻¹; 155.6–392.3 µg L⁻¹), decreasing significantly in effluents (11–44 items L⁻¹; 27.8–74.3 µg L⁻¹), corresponding to a removal efficiency of 81–87.5%, being the first indicative removal efficiencies in a Greek WWTP. Among the different polymers detected, polyethylene, polypropylene, and poly(ethylene terephthalate) were identified as the most prevalent polymers across all matrices. Interestingly, a shift toward smaller size classes (125–500 µm) in effluents indicated in-plant fragmentation processes, while increased concentrations during December coincided with increased rainfall, highlighting the influence of hydrological conditions on MP fluxes. The combined morphological and polymer-specific approach provides a holistic zunderstanding of MP transport from inland to marine systems, establishing essential baseline data for Mediterranean environments and reinforcing the need for integrated monitoring and mitigation strategies. Full article

The separator is a key component of lithium-ion batteries, and its properties play a crucial role in the performance of such batteries. However, the most widely used polyolefin separators are not only made from non-renewable resources such as petroleum, but also have poor wettability to electrolytes, and their low melting points may cause short circuits or even explosions. Therefore, advanced separators that meet the increasing requirements of such batteries are urgently needed. Compared to polyolefin separators, renewable biomass fiber-based separators have better compatibility with electrolytes, higher thermal stability, and are naturally abundant. Their use is not only in line with sustainable development, but it also lowers their material cost. Therefore, biomass fiber-based separators are considered a promising candidate for replacing polyolefin separators for lithium-ion batteries in the future. In this article, studies on the preparation and application of biomass fiber-based separators in lithium-ion batteries in recent years are reviewed, looking forward to their future development, with the aim of providing a reference for researchers. Full article

This study quantifies the mechanical behavior of 10–15 mm thick WPC boards compression-molded from post-consumer bottle-cap polyolefins (PP/HDPE, 70/30 wt%) and pine sawdust (0, 10, 20 wt%). Flexural and tensile strength/modulus are determined and application-oriented acceptability assessed for non-structural temporary concrete formwork under ASTM bending and tension protocols. Mechanical performance was evaluated using three-point and four-point bending tests, as well as axial tension. Flexural strengths averaged 17.31, 16.38, and 8.71 MPa for 0, 10, and 20 wt% sawdust (three-points), and 15.23, 13.18, and 9.20 MPa (four-points), with flexural moduli as high as 1.60 GPa (four-points). Tensile strengths averaged 3.60, 3.79, and 3.44 MPa, with tensile elastic moduli of 0.10, 0.33, and 0.36 GPa, respectively. Stress–strain curves showed a nonlinear elastic-brittle response without a defined yield point, followed by fracture, consistent with porous, non-compatibilized WPCs. Variability increased with the sawdust content, reflecting the distribution of filler and matrix-fiber adhesion. Although the properties are inferior to those of conventional building materials, the results are within the application-oriented ranges for non-structural temporary formwork (as established by the reported ASTM tests). UV durability associated with carbon black-pigmented caps is presented as a literature-supported hypothesis for future accelerated aging, rather than as a measured outcome. Overall, the findings demonstrate a circular-economy pathway that converts post-consumer plastics and sawmill waste into WPC panels for sustainable construction. Full article

Thermoset composites provide excellent strength but pose major recycling challenges due to their crosslinked structure. In this study, epoxy–polyurethane–glass fiber (EPG) wastes were mechanically recycled into low-density polyethylene (LDPE), high-density polyethylene (HDPE), and polyamide-6 (PA6) matrices to produce second-generation thermoplastic composites (STCs). Fillers at 10–50 wt% were processed by single-screw extrusion and compression molding, and the resulting composites were comprehensively characterized. For LDPE, the tensile modulus increased by ~286–589% and tensile strength increased by 40–47% at 20–30 wt% loading, though ductility decreased at higher levels. HDPE composites showed a ~347% rise in modulus and ~24% increase in strength, but performance declined with more than 40 wt% filler. PA6 offered the most balanced outcome, retaining ~70% of its neat tensile strength while achieving an ~300% modulus improvement at 40 wt% loading. Thermal stability was strongly enhanced, with char residue at 700 °C rising from 0.4% to 38.7% in PA6 and from ~2.5% to 33–46% in polyolefins. In contrast, crystallinity decreased (e.g., LDPE 62.2% → 23.7%), and impact strength dropped at a loading above 30 wt%. Overall, the results demonstrate that EPG wastes can be reprocessed into functional composites without compatibilizers, with PA6 providing the most robust property retention at high filler contents. Full article

This study investigates the use of a local fiber, specifically milkweed that grows in Quebec, Canada, for nonwoven building applications. Milkweed is a natural fiber with an ultra-lightweight hollow structure that provides excellent acoustic and thermal insulation properties. To provide three-dimensional stability to nonwovens, milkweed fibers were blended with a low-melt fiber composed of a polyethylene terephthalate core and a polyolefin sheath (LM 2.2), and polylactic acid (PLA) fibers. Several nonwovens with different fiber contents were manufactured using an air-laid Spike process. The nonwovens were compared with a commercially available thermal insulation material made of 100% hemp. The thermal conductivity and thermal resistance were measured at different temperatures. The sound absorption coefficient of the nonwovens was determined both using an impedance tube and the Johnson–Champoux–Allard (JCA) acoustic model. The results showed that all nonwovens exhibit thermal conductivity values below 70 mW/m·K at temperatures ranging from −4 °C to 24 °C, which are lower than many materials commonly used in building applications. A sample presented a thermal resistance that is 8%, 10%, and 45% higher than those of rock wool, polyisocyanurate (PIR), and fiberglass, respectively. Full article

Addressing the issues of poor thermal resistance in conventional polyolefin separators and the low production efficiency of electrospinning, this study innovatively employed high-efficiency centrifugal spinning technology to fabricate a ternary blended modified fiber membrane composed of polyacrylonitrile (PAN), polystyrene (PS), and polymethyl methacrylate (PMMA). By precisely adjusting the polymer ratio (8:2:2) and fine-tuning the spinning process parameters, a separator with a three-dimensional network structure was successfully produced. The research results indicate that the separator exhibited excellent overall performance, with a porosity of 75.87%, an electrolyte absorption rate of up to 346%, and a thermal shrinkage of less than 3% after 1 h at 150 °C, along with a tensile strength reaching 23.48 MPa. A lithium-ion battery assembled with this separator delivered an initial discharge capacity of 159 mAh/g at a 0.2 C rate and maintained a capacity retention of 98.11% after 25 cycles. Moreover, under current rates of 0.5, 1.0, and 2.0 C, the battery assembled with the ASM-14 configuration achieved high discharge capacities of 148, 136, and 116 mAh/g, respectively. This study offers a novel design strategy for modifying multi-component polymer battery separators. Full article

Ultra-high performance concretes (UHPCs) have been widely used in the construction industry due to their high strength and long-term performance. The purpose of this article is to review the literature on UHPC that contained at least two types of hybrid fiber with different lengths, diameters, and volumetric contents. The results show that the type of fiber, its geometry, including length, diameter, and shape, as well as volumetric content, affect the properties of the concrete, not only in the hardened state, but also in the fresh state. The compressive and flexural strength results increase with higher impact velocity and steel fiber content, with a higher content of shorter fibers contributing to increased strength and energy absorption. Tensile strength increases with the length of the steel fibers and the higher content of polyolefin, polyoxymethylene, and polyester fibers. Investigating new types of fiber, various shape factors, geometries, and anchoring mechanisms of hybrid fibers is essential to improve the workability, adhesion, and strength of the material. Full article

The mechanical recycling of thermoplastics (especially of polyolefins) often results in recyclates with inferior properties compared to their virgin counterparts. This phenomenon is mainly due to the modification of the polymer microstructure induced by the degradation processes undergone by the materials during their service life and reprocessing. In this work, a promising route for obtaining high-melt-strength recycled high-density polyethylene (HDPE) is proposed. In particular, the exploited approach involves the utilization of a commercially available additive (i.e., Nexamite^® R305, Nexam Chemical, Lomma, Sweden), which was demonstrated to be capable of driving thermo-mechanical degradation reactions (experienced by HDPE during mechanical recycling) towards the obtainment of a long-chain branched microstructure, thereby enabling the further processing of the recycled material through technologies dominated by elongational flow. The additive-induced alterations of the polymer microstructure were exploited for the formulation of fibers, and the performed tensile characterization showed that the additive-containing material exhibits strikingly improved ductility (namely, elongation at break of 350% for the fibers stretched at a draw ratio of 60) with respect to pristine recycled HDPE. Overall, the obtained results clearly demonstrated the possibility of attaining an effective upcycling of HDPE, which could be exploited for industrially relevant high-added-value applications, hence paving the way for the achievement of full plastic circularity. Full article

Milkweed (MW) fiber is a natural fiber that provides tremendous thermal insulation properties due to its lightweight hollow structure. This study aimed to investigate the effect of milkweed fiber as a thermal fiber in nonwovens. Milkweed fibers were blended with a low-melt fiber consisting of a polyethylene terephthalate core, a polyolefin sheath (LM 2.2), and polylactic acid (PLA) fiber. Nonwovens with different fiber contents were manufactured using an air-laid Spike process to determine their effect on thermal and mechanical properties. Then, the nonwovens were compared with Thinsulate^® and Primaloft^®, two commercially synthetic insulation products. Structural properties, including mass per unit area, thickness, and porosity and thermal properties were studied. Furthermore, compression and short-term compression recovery were also evaluated. The results revealed that milkweed-based nonwovens that contained 50 wt% or 70 wt% of milkweed presented a lower thermal conductivity than synthetic nonwovens. Milkweed nonwovens of the same thickness provided identical thermal resistance as Thinsulate^® and Primaloft. Sample 3, composed of 50 wt% MW, 20 wt% LM 2.2, and 30 wt% PLA, demonstrated the same thermal insulation as Thinsulate^® with a weight three times lighter. Milkweed nonwovens presented higher moisture regain values than Thinsulate^® and Primaloft^®, without affecting thermal conductivity. Full article

As one of the most critical components in lithium-ion batteries (LIBs), commercial polyolefin separators suffer from drawbacks such as poor thermal stability and the inability to inhibit the growth of dendrites, which seriously threaten the safety of LIBs. In this study, we prepared calcium alginate fiber/boron nitride-compliant separators (CA@BN) through paper-making technology and the surface coating method using calcium alginate fiber and boron nitride. The CA@BN had favorable electrolyte wettability, flame retardancy, and thermal dimensional stability of the biomass fiber separator. Meanwhile, the boron nitride coating provided excellent thermal conductivity and mechanical strength for the composite separator, which inhibited the growth of lithium dendrites and enabled lithium-ion symmetric batteries to achieve more than 1000 stable and long cycles at a current density of 0.5 mA cm⁻². The interwoven fiber mesh formed by the boron nitride coating and the calcium alginate provided multiple pathways for ion migration, which enhanced the storage capacity of the electrolyte, improved the interfacial compatibility between the separator and the electrode, widened the window of electrochemical stability, and enhanced ionic migration. This eco-friendly bio-based separator paves a new insight for the design of heat-resistance separators as well as the safe running of LIBs. Full article

The introduction of bio-based matrices in automotive applications would, in principle, increase their sustainability and, in case the use of secondary raw materials is also involved, even result in reduced resource depletion. The bio-based polymer composite matrix that has been mainly brought forward towards industrial application is poly(lactic acid) (PLA), which has often been proposed as the replacement for matrices based on polyolefins in fields such as packaging and short-term commodities since, in general, it matches the needs for conventional thermoplastic production processes. The passage to the automotive sector is not obvious, though: problems affecting durability, the relation with water and the environment, together with the requirement for outstanding mechanical and impact performance appear very stringent. On the other hand, PLA has obtained durable success in additive manufacturing as a competitor for acrylonitrile butadiene styrene (ABS). Also, the perspective for 3D and 4D printing does not appear to be confined to bare prototyping. These contrasting pieces of evidence indicate the necessity to provide more insight into the possible development of PLA use in the automotive industry, also considering the pressure for the combined use of more sustainable reinforcement types in automotive composites, such as natural fibers. Full article

The bond strength of tension lap splices in recycled-coarse-aggregate-reinforced concrete strengthened with hybrid (steel–polyolefin) fibers was experimentally investigated. This study was conducted with the help of twelve lap-spliced beam specimens. The replacement level of coarse natural aggregates with recycled concrete aggregate (RCA) was 100%. The following variables were investigated: various ranges of steel–polyolefin fibers—100–0%, 75–25%, 50–50%, 25–75%, and 0–100%—in which the total volume fraction of fibers ($V_f$) remains constant at 1%; and two lengths of lap splices for rebars of 16 mm diameter ($d_b$): 10 $d_b$ and 15 $d_b$. The test results showed that the best range of steel–polyolefin fibers that gave the highest bond strength was 50–50%. The ductility of the fiber-reinforced recycled-aggregate (FR-RA) concrete was significantly improved for all the cases of various relative ratios of steel and polyolefin fibers. The bond strength was also predicted using three empirical equations proposed by Orangun et al., Darwin et al., and Harajli. This study showed that the Harajli equation gave a more accurate estimation of the bond strength of reinforcing bars embedded in FR-RA concrete than those proposed by Orangun et al. and Darwin et al. Full article

The treatment of waste plastics has gradually become a hot topic in the current scientific community. In response to the needs for high-impact performance R-PP-based composites, carbon fiber (CF)-reinforced polyolefin elastomer (POE)/recycled polypropylene (R-PP) composite (CF/POE/R-PP) was prepared by the mechanical blending method, and its mechanical and thermal properties were systematically studied. It was found that the CF could effectively improve the bending and notch impact strength as well as enhance the thermal stability of POE/R-PP. Furthermore, a stable and dispersed composite interface formed by the combination of maleic anhydride-grafted polypropylene (PP-g-MAH) with the surface of CF and the fusion alkyl chains in R-PP and POE further enhanced the CF’s reinforcing effect. As a result, the addition of 9 wt.% CF successfully improved the heat resistance of the composite material, and the residual carbon content increased by 97.84% after sintering. The composite toughening of POE and CF effectively improved the impact strength of the composite material, with a maximum increase of over 1000%. This study ultimately resulted in a high-impact-resistant composite material. Full article