Search Results (92)

Harvesting remains one of the main bottlenecks in microalgae-based technologies. Although microalgae hold great promise for industrial biotechnology, their growth in dilute suspensions makes biomass recovery challenging. Conventional harvesting methods are often energy-intensive and costly, limiting large-scale implementation. This study applies a life cycle assessment (LCA) to evaluate the environmental performance of a laboratory-scale magnetic harvesting process of Chlorella vulgaris (C. vulgaris) using Fe₃O₄ microparticles in combination with polyaluminum chloride (PAC) and polyacrylamide (PAM), followed by magnetic oscillation for particle detachment and subsequent reuse. Electricity consumption was identified as the dominant environmental hotspot across most impact categories, with the detachment step accounting for nearly two-thirds of the total energy demand, a step often overlooked in previous LCA studies. The global warming potential (GWP) is consistent with typical laboratory-scale assessments and is mainly driven by energy inefficiencies associated with small processing volumes. The values obtained and the scale-up literature indicate that further optimization and future industrial-scale production will decrease these values into a realistic and competitive range. Sensitivity analysis showed that replacing grid electricity with photovoltaic power significantly reduces environmental impacts. The use of NaOH as a reagent also contributed substantially to environmental impacts. Reusing magnetic particles (4 cycles) reduced material resource depletion by up to fourfold, which is a very relevant result bearing in mind the principles of sustainability and circularity. Full article

Microplastics, MPs, plastic particles with dimensions between 0.1 and 5 mm, represent an important environmental pollutant. The removal of microplastics from natural and wastewater is a challenging research topic. In this regard, high-performance technical solutions must be identified, which can be based on existing treatment and purification technologies, to ensure their removal at concentration values in accordance with the legislation in force. In this study, the efficiency of removing some fractions of polyurethane microplastics, with dimensions smaller than 500 µm, from aqueous synthetic solutions with a concentration of 0.2 g L⁻¹, i.e., around 175 NTU, was evaluated. In the first stage of the study, the doses of coagulants and flocculants effective for the removal of microplastics were identified through the Jar Test. The variation in turbidity and their removal efficiencies were evaluated in the presence of classic coagulants, such as aluminum sulfate, Al₂(SO₄)₃·18H₂O, SA; iron sulfate (ferrous sulfate), FeSO₄, IS; polyaluminum chloride, [Al₂(OH)_nCl_6−n], PAC; Aloe Vera, AV, a flocculant; and activated carbon, AC, of the Norit GAC 830 W type. Classic coagulants, such as aluminum sulfate, have a good efficiency in removing microplastics, being able to provide a residual turbidity in the range of 6–10 NTU after a retention time of 50–60 min. In the second stage of the study, the removal efficiency of microplastics was tested using a laboratory pilot plant—called in the study the Smart Decantation-Filtration System, SDFS. The efficiency of the decanter was studied using Response Surface Methodology (RSM) to identify mathematical models that characterize the influence of key process variables: flow rate (A), microplastic size (B) and aluminum sulfate concentration (C) on microplastic removal efficiency. Sedimentation in the specially constructed decanter can raise the optimal value of the removal efficiency of polyurethane microplastics to 98.98%, and filtration can ensure an efficiency that reaches over 99.5%. Through this research, we aimed to identify viable solutions that can be applied to remove microplastics, MPs, from natural and wastewater. A novel element is the fact that we chose to study the removal of polyurethane, which is studied little in the literature. We identified the optimal doses of coagulants and flocculants that help sedimentation of MPs. The efficiency of an installation called Smart Decantation-Filtration System, specially designed to ensure increased efficiency in the removal of microplastics, was determined. The results obtained were encouraging. Full article

This study investigates the separation performance of transformer oil–water mixtures using gravity separation and chemical demulsification. The synthetic emulsion had an initial oil concentration (C₀) of approximately 246,000 mg/L. For gravity separation, the effects of compartment volume ratio, influent flow rate, initial water level, and oil discharge strategy were systematically evaluated. Under optimal conditions (volume ratio 2:1:1, flow rate 0.0055 L/s, initial water level 5 cm), the effluent oil concentration was reduced to as low as 0.020 mg/L, corresponding to a removal efficiency higher than 99.99%. For chemical demulsification, polyaluminum chloride (PAC), polyferric sulfate (PFS), polyacrylamide (PAM), and an organosilicon polyether demulsifier (MCL-D) were tested. The effects of pH, dosage, and temperature on demulsification efficiency (DE) and dehydration rate (DR) were investigated. Under optimal conditions (pH 3–5, dosage 300 mg/L, temperature 50 °C), MCL-D achieved the best performance, with a DE of 95.09% and a DR of 99.50%. Overall, gravity separation is effective for removing free and dispersed oil with low operational cost, whereas chemical demulsification is more suitable for treating stable emulsified oil. The combination of these two methods provides an efficient strategy for the treatment of transformer oil-containing wastewater. Full article

A ternary gel composed of polyvinyl alcohol (PVA), polyethyleneimine (PEI), and polyaluminum chloride (PAC) was prepared to address the limited controllability of gelation and the insufficient high-temperature resistance to re-ignition observed in existing mine fire prevention and extinguishing gels. Based on an orthogonal experimental design, the optimal formulation was identified as 14% PVA, 7% PEI, and 5.5% PAC (by mass), achieving a gelation time of 8.2 min. Microscopic characterization revealed that the gel forms a dense, interconnected three-dimensional network structure capable of effectively encapsulating the coal particles. Fourier transform infrared spectroscopy (FTIR) analysis showed that gel treatment resulted in a 29.8% reduction in the peak area of free hydroxyl groups. Thermogravimetric–differential scanning calorimetry (TG-DSC) analysis indicated that the gel increased the ignition temperature by 33.27 °C and shifted the maximum exothermic peak temperature by 13.28 °C. Fire suppression experiments demonstrate that the gel could continuously lower the temperature of high-temperature coal without re-ignition, demonstrating significantly superior performance compared to traditional sodium silicate gel. This gel achieves highly efficient fire prevention and suppression through the cooperative effects of water retention, oxygen barriers, and chemical passivation, providing a new material for the prevention and control of spontaneous coal combustion in deep mines. Full article

Textile industry wastewater poses a significant environmental challenge due to the presence of persistent dyes. Cationic dyes are characterized by resistance to the conventional coagulation method. The appropriate properties and combination of chemicals guarantee an effective removal process. This study explains the effect of modification of methylene blue solution by the addition of a natural biopolymer—hydrolyzed tannic acid (TA). The study assumed that a combination of tannic acid, methylene blue and polyaluminum chloride would provide a synergistic effect and significantly improve the coagulation and sediment filtration process. Coagulation tests were carried out for a range of methylene blue concentrations. The optimal arrangement of solution components and coagulant doses was selected and tested. Over 95% dye removal efficiency was achieved. The maximum dye removal efficiency was determined to be 5 mg/mg Al at pH = 5.0. Based on the analysis of UV-VIS spectroscopy, FTIR and electrokinetic potential, changes in the solutions of tannin-modified dyes and their effect on the precipitation of flocs and the nature of sorption were determined. The main phenomena affecting the removal mechanism are discussed. The results indicate that tannic acid can serve as a sustainable coagulant aid, supporting the development of technologies for treating cationic-dye-laden wastewater. Full article

Coagulation is a core technology for treating micro-polluted water containing algae and phosphorus. The development of a new coagulant is crucial for reducing operational costs in water treatment plants and similar enterprises. However, compared with traditional chemical coagulants, mineral-based materials have received relatively less attention in the development of high-efficiency coagulants, and their application potential remains to be fully explored, while traditional coagulants such as polyaluminum chloride (PAC) still dominate the market. This study investigated the effectiveness of a polysilicate aluminum ferric coagulant (PSAC) derived from volcanic rock. The influence of various parameters during synthesis and application on PSAC performance was examined, including NaOH dosage, polymerization temperature, silicic acid content, aging time, water environment pH, water quality type, and coagulant dosage. Performance was evaluated based on the removal efficiency of turbidity, UV₂₅₄, algae density, and total phosphorus. The results showed that the optimal preparation conditions for PSAC are: NaOH dosage of 8 mL, polymerization temperature of 60 °C, inclusion of silicic acid, aging for 72 h, and a pH range of 7–8. Under these conditions, the coagulant demonstrated high removal efficiency for the targeted pollutants. At a PSAC dosage of 80 mg/L, the removal rates for UV₂₅₄, algae, and total phosphorus were 90.2%, 99.2%, and 96.4%, respectively, with stable coagulation performance observed across different water qualities. Overall, PSAC exhibits good removal efficiency for UV₂₅₄, total phosphorus, and algae, indicating its great potential as a coagulant for water and wastewater treatment. Full article

High-ash coal slime water, characterized by its stable colloidal suspension of fine kaolinite particles, poses a significant challenge in the coal preparation industry because it is hard to achieve efficient solid–liquid separation. While traditional coagulants and flocculants often suffer from limited bridging capabilities and distinct pH sensitivity, novel molecular architectures offer potential solutions. In this study, a star-shaped inorganic–organic hybrid flocculant (Al-PAM) was synthesized via in situ polymerization. Its flocculation performance and interfacial adsorption mechanism on the specifically targeted aluminol basal plane of kaolinite were systematically investigated and compared with Polyaluminum Chloride (PAC), Non-ionic Polyacrylamide (NPAM), and their combination (PAC + NPAM). Settling tests revealed that Al-PAM exhibited superior performance at a significantly lower dosage (10 mg∙L⁻¹) compared to the PAC + NPAM binary reagent system. It achieved a rapid initial settling velocity and reduced the supernatant turbidity to 48.45 NTU, while maintaining a near-neutral pH favorable for water recycling. Furthermore, Quartz Crystal Microbalance with Dissipation (QCM-D) monitoring confirmed that Al-PAM forms a thick, viscoelastic, and irreversible adsorption layer on the Al₂O₃ substrate. The dissipation shifts (ΔD) revealed that the star-shaped architecture promotes distinct bridging and electrostatic adsorption, overcoming the limitation of linear polymers. This work elucidates the specific contribution of the alumina-surface interaction with flocculants and proposes an efficient strategy for treating refractory coal slime water. Full article

To address the feasible issues in water treatment facilities such as low particle removal and overuse of chemical in flocculation–sedimentation treatment of complex sediment-laden particles in snowmelt and high-intensity rainfall water, this research presents a new multi-layered separation tank. Combining a multi-layer structural design and a synergistic enhancement mechanism flocculation–centrifugation, it is possible to engineer the tank to achieve improvement in the coexistence of the sediment and water. This study methodically examines the impact of the agitator speed, agitator height, and the number of blades on the flow field qualities and the effectiveness of the agitator in removing particles in the multi-layer separation tank. Computational fluid dynamics (CFD) simulation validation in comparison with hydro-calculations and laboratory experiments are used in a combined method. The findings show that there is strong agreement between numerical representation and experimental values in determining the optimal conditions of operation and the exact rate of dosage of polyaluminum chloride (PAC) and polyacrylamide (PAM). At these optimized conditions, the system achieves at a 75.25 percent removal rate of particles whose size ranges are 20–50 μm and turbidity of the effluent decreases to 10.6 NTU in 30 min of settling time. The proposed technology is more efficient than conventional coagulation processes in that effluent turbidity is reduced by 22.1% with same dosages of chemical additive indicating a higher performance of the proposed technology. Full article

Effective treatment of coal slime water is essential for sustainable coal preparation plant operation but hindered by the stable suspension of fine, negatively charged particles. To address this, a novel star-shaped inorganic–organic hybrid polymer (aluminum hydroxide-polyacrylamide, Al-PAM) was synthesized via in situ polymerization. Its performance was systematically compared with well-established coagulants/flocculants—polyaluminum chloride (PAC), non-ionic polyacrylamide (NPAM), and their binary combination through settling tests and quartz crystal microbalance with dissipation monitoring (QCM-D). The results showed a positive correlation between the molecular weight of Al-PAM and its flocculation efficiency. The optimal variant, Al-PAM-442, achieved an exceptionally high initial settling rate (50.4 m/h) and low supernatant turbidity (45.77 NTU) at an ultralow dosage of 6 mg/L. QCM-D analysis elucidated the mechanism: Al-PAM forms a thick, soft, and irreversibly adsorbed hydrated layer on silica, enabling strong electrostatic anchoring and effective polymer bridging. In contrast, PAC adsorption was reversible, while NPAM formed a thin, compact film with poor bridging capacity. Although the combined PAC/NPAM system showed synergistic performance, it required a significantly higher dosage (70 mg/L). This study demonstrates that the star-shaped Al-PAM architecture successfully integrates charge neutralization and bridging into a single molecule, offering a highly efficient and practical solution for industrial coal slurry dewatering. Full article

Coagulation significantly alters molecular characteristics and oxidizability of dissolved organic matters (DOM), while the linkage between DOM molecular characteristics and fragmentation pathways were unclear for the following processes. Here, four typical coagulation processes were employed to improve DOM molecular properties in leachate, and their subsequent impact on oxidizability in ozonation was identified. The results indicate that Polyaluminum chloride (PAC), Polyferric sulfate (PFS), Polyaluminium ferric chloride (PAFC) and Polymerized aluminum ferric silicate (PSAF) can all reduce the COD and TOC levels of the leachate concentrate through coagulation and precipitation, with PAC achieving the highest removal efficiency. PAC-ozonation effectively removes aromatic and unsaturated compounds, significantly improving DOM composition and enhancing conditions for subsequent oxidation. In contrast, PFS shows the poorest removal of aromatics (2.92%) and polycyclic aromatics (9.81%), along with the highest NOSC (−0.5036) and lowest (DBE-O)/C (−0.0051), indicating greater oxidation resistance. Only 11% of COD was further removed by ozonation after PFS treatment, suggesting limited reactivity of the residual DOM. Machine learning analysis of molecular transformation networks further confirmed that PFS treatment produced the fewest conversion pathways following ozonation. This indicates the choice rules and relationship between coagulation and ozonation for landfill leachate. This work provides an effective strategy to enhance leachate treatability and reduce energy and reagent consumption in subsequent processes, thereby contributing to more sustainable and cost-effective landfill leachate management. Full article

Wastewater treatment plants represent an important point source of microplastics (MPs) entering aquatic environments, raising increasing concerns regarding ecosystem integrity and potential risks to human health. Improving the removal efficiency of MPs during wastewater treatment is therefore of both environmental and technological significance. Polyaluminum chloride (PAC), polyferric sulfate (PFS), and polyacrylamide (PAM) were applied to remove MPs by coagulation, with particular emphasis on the effects of PAM type (cationic, anionic, and non-ionic). The optimal removal efficiency achieved by PAC alone for polystyrene was 55.00 ± 3.54% at a dosage of 300 mg L⁻¹, which increased significantly to 87.50 ± 1.87% with the addition of cationic PAM. Similarly, MPs removal by PFS increased from 33.75 ± 1.77% at 160 mg L⁻¹ to 62.50 ± 3.53% when combined with cationic PAM. Overall, PAC-based coagulation exhibited higher MPs removal efficiency than PFS, and cationic PAM outperformed anionic and non-ionic PAM, likely attributable to electrostatic interactions with negatively charged MPs in wastewater systems. In addition, PAC/PAM coagulation enabled effective removal of multiple MPs types while simultaneously enhancing phosphate removal, highlighting its potential for the integrated control of MPs and phosphate pollution in wastewater systems. Full article

Electroplating wastewater poses a serious environmental threat due to its high concentrations of heavy metals and persistent organic pollutants. This study evaluated the efficiency of a combined coagulation and activated carbon filtration process for the treatment of real electroplating wastewater containing Ni²⁺, Zn²⁺, Cu²⁺, and Cr⁶⁺ ions. The research was conducted in two stages. In the first stage, laboratory-scale experiments were performed to determine the optimal coagulant type (Fe- and Al-based), dosage, and pH (5.0–10.0) for contaminant removal. In the second stage, the selected operating conditions were applied and validated under real industrial plant conditions at a pilot scale. The laboratory studies demonstrated that the highest Cr removal efficiency was achieved using an iron-based coagulant (PIX), while polyaluminum chloride (PAX) proved most effective for the removal of Ni and Zn. Subsequent filtration through activated carbon further enhanced heavy metal removal, increasing overall efficiencies to above 90%. The reported removal efficiencies represent the overall performance of the integrated treatment process. The results confirm that the integration of chemical coagulation and activated carbon filtration is an effective, environmentally friendly, and economically viable approach for treating real electroplating wastewater, enabling compliance with current environmental standards. Full article

Optimizing coagulant dosages in Drinking Water Treatment Plants (DWTPs) is critical for reducing operational costs, minimizing chemical waste, mitigating environmental impacts, and ensuring consistent water quality, particularly in resource-constrained settings where conventional jar tests are labor-intensive and poorly suited to real-time demands. This study develops and validates a Random Forest (RF) machine learning model to predict optimal dosages of aluminum sulfate, polyaluminum chloride, and a polymer flocculant at the Miguel de la Cuba Ibarra DWTP in Peru, addressing the need for an efficient, real-time decision support system. Using a historical dataset of 2556 jar tests, a univariate RF model was developed to predict settled water turbidity, tailored to the plant’s typical operational range. The model demonstrated robust predictive performance, achieving a coefficient of determination (R²) of 0.92 during training and 0.76 during validation with unseen data, alongside a Root Mean Square Error (RMSE) of 0.11 NTU and a Mean Absolute Percentage Error (MAPE) of 0.11 in the training phase. Integrated into a digital platform, the model generates real-time NTU ppm dosing curves, providing a practical and responsive tool to enhance operational efficiency for DWTP operators. This work offers a scalable, data-driven solution to improve water treatment processes in resource-limited contexts. Full article

To address the inefficiency and data loss issues inherent in manual measurement, this study developed a full-time data extraction model for ultra-fine tailing slurry flocculation using Yolov8n. The performance of five flocculants—cationic polyacrylamide (YPAM), non-ionic polyacrylamide (FPAM), polyaluminum chloride (PAC), polymeric ferric sulfate (PFS), and a commercially used flocculant (KY)—was evaluated based on type, dosage, and pH. The model’s reliability was validated through slurry grayscale and clarification height analysis. Results indicate that the model enables automated data collection under varying lighting and viewing angles. YPAM was identified as the optimal flocculant across different pH conditions, improving the selection efficiency by 83% compared to manual methods. Full article

This paper presents the results of the study of electromagnetic disintegration of sludge in a microwave oven at power levels 180 W, 360 W, 540 W, 720 W and 900 W applied at 30 s intervals from 30 to 300 s, originating from a water treatment process where polyaluminum chloride ([Al₂(OH)_nCl_6-n]_m) as a coagulant was applied. The selected physicochemical parameters of water treatment sludge, including the total solids content (TS), volatile solids content (VS), capillary suction time (CST), settleability, chemical oxygen demand (COD), heavy metals (Cu, Zn, Ni, Pb, Cd, Cr) and macro elements (K, Na, Ca) in the water extract and in the sludge liquid were measured. The results indicated that after 24 h of sedimentation, the sediment volume was within the range of 50–60 mL for almost all the samples, CST decreased to 23.06 and 25.72 s (for 720 and 900 W, respectively) and the COD increased to approximately 140 mg O₂/L when the microwave exposure time was extended at least to 120 s. The degree of disintegration of the water treatment sludge increased to 13.4–14.3% for 540–720 W and 270–300 s irradiation time. Heavy metals are not leached from the sludge after microwave disintegration in concentrations that could pose a threat to the environment. The use of electromagnetic disintegration is the viable option for the treatment of sludge from water treatment process. Full article