Search Results (41)

The broad use of (stainless steel) SS 316 L bipolar plates (BPs) in proton exchange membrane fuel cells relies (PEMFC) on high conductivity and corrosion resistance. To enhance the properties of stainless steel, this study applies ion implantation and heat treatment to form a non-homogeneous modified layer on SS 316 L. The injection of C and Mo ions on the SS 316 L surface caused irradiation damage, producing holes. But with the heat treatment of the ion-implanted samples, the irradiation-damaged surface will be repaired to a certain extent. The corrosion current density (I_corr) of the 600 °C sample in the kinetic potential test (5.32 × 10⁻⁴ A/cm²) was 54% lower than that of the naked SS 316 L (1.17 × 10⁻³ A/cm²). In the electrostatic potential test, the corrosion current of the 600 °C sample stabilized at a low value (about 0.26 μA/cm²), with the lowest concentration of dissolved metal ions (Fe²⁺ 2.908 mg/L). After anodic electrostatic potential polarization, the interfacial contact resistance (ICR) of (Mo+C)_600-1 was much lower than that of the untreated SS 316 L. Heat treatment experiments show that samples treated at 600 °C for 1 h exhibit significantly higher conductivity and anodic corrosion resistance than naked SS 316 L. This improvement is mainly due to the heat treatment under these conditions, which facilitated the formation of Mo carbides from the implanted C and Mo elements. Ion implantation and heat treatment enhance stainless steel surface conductivity and passive film corrosion resistance. These findings are useful in altering stainless steel BPs. Full article

New energy vehicles have emerged as a prominent focus in the automotive industry. This study develops a comprehensive modeling specification for fuel cell systems in new energy vehicles and establishes a framework for fatigue life analysis in the frequency domain. First, a finite element model of the fuel cell system was created in accordance with established standards, followed by grid convergence analysis and grid quality correction to enhance model accuracy. Next, random vibration analysis was performed to determine the root mean square (RMS) stress distribution of the fixed plate assembly in a random vibration environment, and the results were validated through experimental tests. Finally, Miner’s linear cumulative damage rule and the rainflow distribution model for random processes were applied to predict the fatigue life of the fixed plate assembly and connecting bolts. Critical locations for potential structural fatigue were identified, and the simulation results were corroborated through fatigue testing. The findings validate the accuracy of the proposed fatigue analysis framework and offer valuable insights for the continued development of fuel cell systems. Full article

Traditional computational methods for pressurized water reactors are unable to handle dispersed fuel particles as the double heterogeneity and the direct volumetric homogenization can result in significant errors. In contrast, reactivity-equivalent physical transformation techniques offer high precision for addressing the double heterogeneity introduced by dispersed fuel particles. This approach converts the double heterogeneity problem into a single heterogeneity problem, which is then subsequently investigated by using the conventional pressurized water reactor computational procedure. However, it is currently empirical and takes a lot of time to obtain the right k_∞. In this paper, we train the RPT model by using the existing dataset of plate-dispersed fuel and rod-dispersed fuel by a machine learning method based on a linear regression model, and we then use the new data to make predictions and derive the corresponding similarity ratios. The burnup verification, density verification, fission rate verification, and neutron energy spectrum analysis are calculated through the OpenMC program. For plate-type fuel elements, the method maintains an accuracy within 200 pcm during depletion, with deviations in the ²³⁵U density and ²³⁵U fission rate within 0.1% and neutron energy spectrum errors within 6%. For rod-type fuel elements, the method maintains an accuracy within 100 pcm during depletion, with deviations in ²³⁵U and ²³⁹Pu density within 1.5% and neutron energy spectrum errors within 1%. The numerical validation indicates that the reactivity-equivalent physical transformation method based on the linear regression model not only greatly improves the computational efficiency, but also ensures a very high accuracy to deal with double heterogeneity in nuclear reactors. Full article

Bipolar plates are one of the most important components of proton exchange membrane fuel cells. With the miniaturization of bipolar plate flow channel sizes and the increasing demand for precision, springback has become a key focus of research in the bipolar plate forming process. In this paper, the hydroforming process for 316L stainless steel bipolar plates was studied, and an FEM model was built to examine the stress and strain at various locations on the longitudinal section of the plate. Modeling accuracy was validated by the comparison of experimental profile and thickness distribution. The effects of forming pressure and grain size on springback behavior are discussed. The results show that with increasing forming pressure, the springback value decreases initially, followed by an increase, but then again decreases. When the forming pressure is 80 MPa–100 MPa, the deformation of the lower element of the upper rounded corner is not uniform with more elastic regions, and the springback is positively correlated with forming pressure. The springback distribution pattern on the cross-section of the bipolar plate changes from a normal distribution to a distribution of “M” shape with increased pressure. The larger the grain size, the lower the yield strength elastic proportion, resulting in a decrease in springback of the sheet. The maximum amount of springback of the bipolar plate is 3.1 μm when the grain size is 60.7 μm. The research results provide a reference for improving the forming quality of metal bipolar plates with different flow channel shapes. Full article

Plate fuel elements, known for their compact structure and efficient cooling, are commonly used in the core of nuclear reactors. In these reactors, coolant channels are designed as rectangular narrow slits. Bubble behavior in narrow channels differs significantly from that in conventional channels. This paper investigates the vertical rise of bubbles in narrow slit channels. A gas–liquid two-phase flow experimental rig was constructed using transparent acrylic boards. A high-speed camera captured the bubble formation process during gas injection, and code implemented in Matlab was used to process the images. Numerical simulations were conducted with CFD software under identical conditions and compared with the experimental results, showing a good agreement. The results show that the experimental and simulated bubble movement velocities are in good agreement. In the experiments of this paper, when the width of the narrow gap is below 3 mm, the sidewalls exert a pronounced influence on the dynamics of bubble rise, notably altering both the velocity profile and the trajectory of the bubbles’ ascent. As the gas injection flow rate gradually increases, the bubble rising speed and trajectory change from regular to oscillatory patterns. Full article

Proton Exchange Membrane Fuel Cells (PEMFCs) are promising technology to convert chemical energy from dihydrogen in electrical energy. HT-PEMFCs are working at high temperatures (above 120 °C) and with doped orthophosphoric acid H₃PO₄ PBI membranes. In such devices, bipolar metallic plates are used to provide reactive gas inside the fuel cell and collect the electrical current. The metallic elements used as bipolar plates, end plates, and interconnectors in acid electrolyte and gaseous fuel cells are severely damaged by a combination of oxidation (due in particular to the use of oxygen, whether pure or contained in the air) and corrosion (due in particular to acid effluents from the electrolyte). This degradation rapidly leads to the loss of the electrical conductivity of the metallic elements and today requires the use of very specific alloys, possibly coated with pure gold. The solution investigated in the present study is the use of a protective coating based on single-phase nitrides obtained by reactive magnetron sputtering or reactive HiPIMS (High-Power Impulse Magnetron Sputtering). The influence of the microstructure on the physical–chemical properties was studied. The electrochemical properties were quantified following two approaches. First, the corrosion current of the developed coatings was measured at room temperature and at higher temperatures using the Linear Sweep Voltammetry (LSV) technique. Then, Electrochemical Impedance Spectroscopy (EIS) measurements were performed to better identify and evaluate their corrosion-resistance performances. Full article

This study explores the utilization of cathodic vacuum arc (CVA) technology to address the limitations of magnetron sputtering technology in preparing amorphous carbon (a-C) coatings, such as having a low ionization rate, low deposition rate, and insufficiently dense structure. Specifically, a-C coatings were prepared by the cathodic vacuum arc (CVA)and the filtered cathodic vacuum arc (FCVA) technology,, one with embedded carbon particles and one without, both having closely related carbon structures. Research is currently underway on bipolar plate coatings for fuel cells. The corrosion behavior of the prepared a-C coatings was examined through Tafel polarization analysis under simulated fuel cell operating conditions as well as potentiostatic analysis at 0.6 V under normal conditions and 1.6 V under start–stop conditions for 7200 s. The coatings before and after corrosion are characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy, Raman spectroscopy, and infrared spectroscopy. The results reveal that the incorporation of conductive graphite-like particles in the coatings reduces their contact resistance. However, the gaps between these particles and the coatings act as pathways for corrosive solution, exacerbating the corrosion of the coatings. After corrosion at 0.6 V, both sets of coatings with sp²-hybridized carbon structures are contaminated by elements such as hydrogen and oxygen, leading to an increase in their contact resistance. Under high potential conditions (1.6 V), large corrosion pits and defects appear at the locations of graphite-like carbon particles. Furthermore, both sets of samples exhibit more severe oxygen contamination and a transformation of broken carbon bonds from sp³- to sp²-hybridized forms, irrespective of whether embedded graphite particles are present. Full article

Proton exchange membrane fuel cells are a prime choice for substitute electricity producers. Membrane electrode assembly (MEA), bipolar electrodes, and current collectors belong to only a limited number of primary parts of the proton exchange membrane fuel cell (PEMFC). Bipolar plates are among the most famous elements in the fuel cell; they are responsible for the electrochemical reaction, as well as the flow of gases from one bipolar plate to another. A bipolar plate is to be a good electro-conducting, non-corrosive, and a high mechanical strength product. The attainability of the specification is achieved by graphite and metallic materials, each one having its own merits and demerits that are discussed in this article. Likewise, making the second pass for the flow pattern is equally important for the cell to have good performance and efficiency. The emergence of innovative and new bipolar plate designs has caused the achievement of high performance of these plates. The present review article principally focuses on the experimental study of diverse flow fields in the design of PEMFC and on the influence of various geometrical properties on the general operation of fuel cells made of PEMFC, and also on the manufacturing procedure utilized for building contemporary fuel cells. Full article

Quickly sensing humidity changes is required in some fields, such as in fuel cell vehicles. The micro humidity sensor used for the relative humidity (RH) measurement with fast response characteristics, and its numerical model and method are rare. This paper firstly presents a numerical model and method for a parallel plate capacitor and a numerical analysis of its dynamic characteristics. The fabrication of this sensor was carried out based on the numerical results, and, the main characteristics of its moisture-sensitive element are shown. This parallel plate capacitor is made using complementary metal-oxide semiconductor (CMOS)-compatible technology, with a P-type monocrystalline silicon wafer used as the substrate, a thin polyimide film (PI) between the upper grid electrode and the lower parallel plate electrode, and electrodes with a molybdenum–aluminum bilayer structure. The shape of the micro sensor is square with 3 mm on the side of the source field. The humidity sensor has a linearity of 0.9965, hysteresis at 7.408% RH, and a sensitivity of 0.4264 pF/%RH. The sensor displays an average adsorption time of 1 s and a minimum adsorption time of 850 ms when the relative humidity increases from 33.2% RH to 75.8% RH. The sensor demonstrates very good stability during a 240 h test in a 25 °C environment. The numerical model and method provided by this study are very useful for predicting the performance of a parallel plate capacitor. Full article

The thermal properties of bipolar plates, being key elements of polymer electrolyte membrane fuel cells, significantly affect their heat conduction and management. This study employed an innovative approach known as a heat flow loop integral method to experimentally assess the in-plane thermal conductivity of graphite bipolar plates, addressing the constraints of traditional methods that have strict demands for thermal stimulation, boundary or initial conditions, and sample size. This method employs infrared thermal imaging to gather information from the surface temperature field of the sample, which is induced by laser stimulation. An enclosed test loop on the infrared image of the sample’s surface, situated between the heat source and the sample’s boundary, is utilized to calculate the in-plane heat flow density by integrating the temperature at the sampling locations on the loop and the in-plane thermal conductivity can be determined based on Fourier’s law of heat conduction. The numerical simulation analysis of the graphite models and the experimental tests with aluminum have confirmed the precision and practicality of this method. The results of 1060 aluminum and 6061 aluminum samples, each 1 and 2 mm in thickness, show a deviation between the reference and actual measurements of the in-plane thermal conductivity within 4.3% and repeatability within 2.7%. Using the loop integral method, the in-plane thermal conductivities of three graphite bipolar plates with thicknesses of 0.5 mm, 1 mm, and 1.5 mm were tested, resulting in 311.98 W(m·K)⁻¹, 314.41 W(m·K)⁻¹, and 323.48 W(m·K)⁻¹, with repeatabilities of 0.9%, 3.0%, and 2.0%, respectively. A comparison with the reference value from the simulation model for graphite bipolar plates with the same thickness showed a deviation of 4.7%. The test results for three different thicknesses of graphite bipolar plates show a repeatability of 2.6%, indicating the high consistency and reliability of this measurement method. Consequently, as a supplement to existing technology, this method can achieve a rapid and nondestructive measurement of materials such as graphite bipolar plates’ in-plane thermal conductivity. Full article

This study investigated how welding affects the thermal deformation of square cells produced for casks, which are dry storage containers for spent nuclear fuel. We aimed to minimize structural deformation by utilizing STS316L as the material for the square cells. We explored a method of subdividing the square cells and joining them through butt welding. Keeping the upper plate thickness constant, GTA butt welding was conducted while varying the column’s wall thickness, followed by measurement with a laser vision sensor. The heat conduction and thermal strain were then calculated using a finite element analysis (FEM). Both experimental and analytical results confirmed that there was significant thermal deformation in the cases of thick-walled columns due to variations in heat conduction distribution, with the resulting deformation patterns depending on thickness. Full article

The pursuit of more efficient transport has led engineers to develop a wide variety of aircraft configurations with the aim of reducing fuel consumption and emissions. However, these innovative designs introduce significant aeroelastic couplings that can potentially lead to structural failure. Consequently, aeroelastic analysis and optimization have become an integral part of modern aircraft design. In addition, aeroelastic testing of scaled models is a critical phase in aircraft development, requiring the accurate prediction of aeroelastic behavior during scaled model construction to reduce costs and mitigate the risks associated with full-scale flight testing. Achieving a high degree of similarity between the stiffness, mass distribution and flow field characteristics of scaled models and their full-scale counterparts is of paramount importance. However, achieving similarity is not always straightforward due to the variety of configurations of modern lightweight aircraft, as identical geometry cannot always be directly scaled down. This configuration diversity has a direct impact on the aeroelastic response, necessitating the use of computational aeroelasticity tools and optimization algorithms. This paper presents the development of an aeroelastic scaling framework using multidisciplinary optimization. Specifically, a parametric Finite Element Model (FEM) of the wing is created, incorporating the parameterization of both thickness and geometry, primarily using shell elements. Aerodynamic loads are calculated using the Doublet Lattice Method (DLM) employing twist and camber correction factors, and aeroelastic coupling is established using infinite plate splines. The aeroelastic model is then integrated within an Ant Colony Optimization (ACO) algorithm to achieve static and dynamic similarity between the scaled model and the reference wing. A notable contribution of this work is the incorporation of internal geometry parameterization into the framework, increasing its versatility and effectiveness. Full article

The interest in wind-assisted ship propulsions (WASPs) is increasing to improve fuel efficiency and to reduce greenhouse gas emissions in ships. A rotor sail, one of the typical WASPs, can provide auxiliary propulsive force by rotating a cylinder-shaped structure based on the Magnus effect. However, due to its huge rotating structure, a meticulous evaluation of the influence on the ship structure and dynamical stability of the rotating structure should be conducted in the design stage. In this respect, an analysis of the rotating structure for a 30 m height and 3 m diameter rotor sail was conducted in this study. First, a 4DOF (four-degree-of-freedom) model was derived to simplify the dynamics of the rotor sail. Using the 4DOF model, natural frequencies for four low-order modes of the rotor sail were calculated, and frequency responses at support points were predicted. Next, a comparison and validation with the finite element model of the rotor sail were carried out. For the 1st and 2nd natural frequencies, a difference of approximately 0.3 Hz was observed between the 4DOF model and the finite element model, confirming the effectiveness of the 4DOF model for low-order modes. In analysis with changes in the bearing supporting stiffnesses, it was verified that lower support bearings have a significant impact on rotor dynamics compared to upper support bearings. Vibration response at the upper support was also confirmed through frequency response analysis caused by imbalance at Thom disk and mid-plate. Additionally, when estimating the eccentricity of the Thom disk as imbalance, a limit of eccentricity error could be set as 24 mm. The presented modeling procedures and analysis results can be references during early design stage of a novel rotor sail structure. Full article

316 L stainless steel is an ideal bipolar plate material for a proton exchange membrane fuel cell (PEMFC). However, the thickening of the passivation film on the stainless steel surface and the dissolution of corrosive ions during operation will affect the durability of the PEMFC. Herein, a heterogeneous layer is prepared on the surface of 316 L stainless steel through dual ion implantation of molybdenum ion and carbon ion combined with heat treatment to promote the corrosion resistance and conductivity of the bipolar plate. The ion implantation technique resulted in a uniform distribution of Mo and C elements on the surface of 316 L stainless steel, with a modified layer depth of about 70–80 nm. The electrical conductivity of the ion implanted samples was significantly improved, and the interfacial contact resistance was reduced from 464.25 mΩ × cm² to 42.49 mΩ × cm². Heat treatment enhances the surface homogenization, repairs the defects of irradiation damage, and improves the corrosion resistance of stainless steel. The corrosion current density of (Mo+C)-600 samples decreased from 1.21 × 10⁻⁸ A/cm² to 2.95 × 10⁻⁹ A/cm² under the long-term corrosion condition of 4 h. These results can provide guidance for the modification of stainless steel bipolar plates. Full article

In this study, the feasibility of commercially pure (CP)-Ti bipolar plates for fuel cells were assessed by designing, manufacturing, and evaluating thin plates fabricated through the laser powder bed fusion (L-PBF) technique. The width, height, and thickness of thin CP-Ti plates were carefully considered in its design to ensure comprehensive evaluation. The maximum displacement was measured through blue light scanning in accordance with the building direction. The finite element model and experimental results showed that the building layer per volume has a linear relationship with the maximum displacement and maximum residual tensile stress along the building direction. Thin plates with a high aspect ratio (198 × 53 × 1.5 mm) had the lowest maximum displacement (0.205 mm) when building in the height direction and had a high correlation coefficient with the finite element model (0.936). Proper aspect ratio design and building strategy enable highly accurate manufacturing of CP-Ti thin plates for fuel cell systems. Full article