Search Results (1,898)

This study conducted laboratory model tests, integrated with Particle Image Velocimetry (PIV) technology, to investigate the evolution of the uplift bearing capacity of an under-reamed anchor group subjected to cyclic loading. The tests considered various working conditions, including different spacing ratios (S/D = 4, 5, 6, where S was the center-to-center spacing and D was the diameter of the under-reamed body), varying cyclic amplitude ratios (λ = 0.3, 0.5, 0.6, 0.7, 0.8) and different cycle times (M = 1, 5, 10, 30). PIV was utilized to observe the displacement field of the surrounding soil, revealing the group effect of the anchors and the variation in their uplift capacity under diverse cyclic amplitudes and cyclic times. The results indicated that the load–displacement curves could be delineated into three distinct stages: elastic, elastoplastic, and plastic. Notably, the group effect primarily initiated during the elastoplastic stage and developed significantly within the plastic stage. The cyclic amplitude ratio was identified as a key factor influencing the uplift capacity. Furthermore, compared to results from single pull-out tests, both the vertical displacement of the surrounding soil and the shear strength of the sidewall adjacent to the under-reamed body decreased following cyclic loading. Finally, the influence of the cyclic times depended on the occurrence of anchor failure; in the absence of failure, the anchor maintained satisfactory performance even after multiple cycles. Full article

Microplastic contamination in food systems has emerged as a growing concern for food safety and public health. The presence of microplastics in raw milk may represent a potential exposure pathway for both animals and humans. This study investigated the occurrence and characteristics of microplastics in raw milk collected from smallholder dairy farms in Northeastern Thailand. Hand-milked raw milk and bulk tank milk samples were obtained from ten farms and analyzed for microplastic contamination. Suspected microplastic particles were identified and quantified using stereomicroscopy and characterized according to their shape, color, and size, while polymer composition was confirmed by Fourier Transform Infrared Spectroscopy. Microplastics were detected in both hand-milked and bulk tank milk samples, with fiber-shaped particles being the most frequently observed. The majority of detected particles were 0.05–0.15 mm in size and predominantly yellow in color. Polymer analysis revealed that Polydimethylsiloxane, followed by a semi-synthetic composite of Elastane and Rayon. These findings demonstrate that microplastics can be present in raw milk produced by smallholder dairy farms, highlighting the need for improved farm management and milk-handling practices to reduce contamination risks. From a One Health perspective, reducing plastic use and enhancing hygiene during milking and milk storage may help protect animal health, food safety, and consumer well-being. Full article

Plastic microbeads, widely incorporated into personal care and cleansing products, have emerged as a pervasive contaminant in freshwater systems, including in North America. Historical estimates indicate that North American consumers alone contributed trillions of microbeads daily to municipal wastewater, with global usage reaching quadrillions per day. Regulatory actions in 2017 in Canada and the USA to ban microbeads in personal care products appear to have greatly reduced microbead contamination levels, including a decrease in microbead proportion from 2 to 5% to 0.003%, and an 86% reduction in PE microbead discharge from wastewater treatment plants. Yet these particles still persist in the environment due to their resistance to degradation and continued release from unregulated sources, including industrial abrasives and certain cleaning agents. Studies across the Great Lakes, one of the world’s largest freshwater systems, have documented widespread microbead contamination in surface waters, sediments, and shorelines, highlighting their persistence and accumulation. This review synthesizes findings from key studies conducted between 2013 and 2017 to establish a pre-ban baseline of microbead distribution in the Great Lakes, and presents new data collected from 2018 to 2021 as a post-ban contamination assessment. The review emphasizes the unique challenges posed by microbeads within the broader context of microplastic pollution. We also hope that this paper underscores the critical role of polymer chemists and engineers in developing innovative materials and removal strategies to mitigate future contamination. Full article

This study investigates the microstructural evolution and wear behaviour of aluminium 7075-based metal matrix composites (MMCs) reinforced with high-entropy alloy (HEA) particles and fabricated via friction stir processing (FSP). A detailed characterisation of the grain refinement in the 7075 matrix was conducted, revealing significant dynamic recrystallization and grain size reduction induced by the severe plastic deformation inherent to FSP. The interaction between the matrix and HEA particles was analysed, showing strong interfacial bonding, which was further influenced by post-processing heat treatments. These microstructural modifications were correlated with the wear performance of the composites, demonstrating enhanced resistance due to the synergistic effect of precipitates and particle reinforcement. The findings highlight the potential of FSP as a viable route for tailoring surface properties in advanced MMCs for demanding tribological applications. Full article

This study presents the first evaluation of plastic particle contamination along a complete drinking water supply chain within the distribution system of Milan, Northern Italy. Fourteen grab water samples were collected from various points, including groundwater extraction, post-treatment stages, a public fountain, and ten household taps. Plastic particles were identified using µFTIR spectroscopy and characterized by polymer type, shape, size, and color. Overall, low concentrations of plastic particles were detected, ranging from 0.3 ± 0.5 particles/L in the accumulation tank to an average of 1.9 ± 1.4 particles/L in household tap water, with no significant increase observed along the supply chain. The entire data set was dominated by cellulose particles (76%), as plastics accounted for only 8%. Microplastics (1 µm–1 mm) were the most commonly detected (90%), while the remaining 10% were large microplastics (1–5 mm). Qualitatively, polyester fibers were the most prevalent particles identified. However, greater variability and higher concentrations were found in private residence samples, suggesting that internal plumbing systems may be a primary source of contamination. Estimated human exposure through this supply system, based on a current theoretical model, was minimal compared to global benchmarks. These findings highlight the necessity of integrating private distribution infrastructure into future regulatory frameworks to assist stakeholders in making informed decisions to mitigate potential plastic contamination. Full article

Plastic pollution raises concerns for health and the environment. Plastics are not biodegradable but gradually erode to microplastic and nanoplastic particles spreading almost everywhere. Nanoplastics exhibit colloidal behavior. Thereby, their analysis can be accomplished by refractometry, preferably by an on-chip tool. We present a study of such colloids using a microfabricated Fabry–Pérot cavity with curved mirrors, which holds a capillary micro-tube used both for fluid handling and light collimation, resulting in an optically stable microresonator. Despite the numerous scatterers within the sample, the sub-millimeter scale cavity provides the advantages of reduced interaction length while maintaining light confinement. This significantly reduces optical loss and hence keeps resonance modes with quality factors (resonant frequency/bandwidth) above 1100. Therefore, small quantities of colloids can be measured by the interference spectral response through the shift in resonant wavelengths. The particles’ Brownian motion potentially causing perturbations in the spectra can be overcome either by post-measurement cross-correlation analysis or by avoiding it entirely by taking the measurements at once by a wideband source and a spectrum analyzer. The effective refractive index of solutions with solid contents down to 0.34% could be determined with good agreement with theoretical predictions. Even lower detection capabilities might be attained by slightly altering the technique to cause particle aggregation achieved solely by light. Full article

The emulsification of a molten fusible metal alloy in a liquid epoxy matrix with its subsequent curing is a novel way to create a highly concentrated phase-change material. However, numerous challenges have arisen. The high interfacial tension between the molten metal and epoxy resin and the difference in their viscosities hinder the stretching and breaking of metal droplets during stirring. Further, the high density of metal droplets and lack of suitable surfactants lead to their rapid coalescence and sedimentation in the non-cross-linked resin. Finally, the high differences in the thermal expansion coefficients of the metal alloy and cross-linked epoxy polymer may cause cracking of the resulting phase-change material. This work overcomes the above problems by using nanosilica-induced physical gelation to thicken the epoxy medium containing Wood’s metal, stabilize their interfacial boundary, and immobilize the molten metal droplets through the creation of a gel-like network with a yield stress. In turn, the yield stress and the subsequent low-temperature curing with diethylenetriamine prevent delamination and cracking, while the transformation of the epoxy resin as a physical gel into a cross-linked polymer gel ensures form stability. The stabilization mechanism is shown to combine Pickering-like interfacial anchoring of hydrophilic silica at the metal/epoxy boundary with bulk gelation of the epoxy phase, enabling high metal loadings. As a result, epoxy shape-stable phase-change materials containing up to 80 wt% of Wood’s metal were produced. Wood’s metal forms fine dispersed droplets in epoxy medium with an average size of 2–5 µm, which can store thermal energy with an efficiency of up to 120.8 J/cm³. Wood’s metal plasticizes the epoxy matrix and decreases its glass transition temperature because of interactions with the epoxy resin and its hardener. However, the reinforcing effect of the metal particles compensates for this adverse effect, increasing Young’s modulus of the cured phase-change system up to 825 MPa. These form-stable, high-energy-density composites are promising for thermal energy storage in building envelopes, radiation-protective shielding, or industrial heat management systems where leakage-free operation and mechanical integrity are critical. Full article

This study aims to investigate the tip resistance mechanism of open-ended steel pipe piles under partially plugged conditions by decomposing the load-sharing contribution of the ring zone and the internal soil core. A virtual static loading test was performed using the two-dimensional discrete element method (2D-DEM). Note that the findings of this study were obtained within the range of the 2D-DEM analysis conditions and do not intend to directly reproduce the three-dimensional arching mechanism or to establish equivalence between 2D and 3D responses. Quasi-static conditions were ensured by identifying loading parameters such that the energy residual remained ≤5% during driving, rest, and static loading phases, and the sensitivity criterion |Δq_b|/q_b ≤ 3% was satisfied when the loading rate was halved or doubled. The primary evaluation range of static loading was set to s/D = 0.1 (10% D), corresponding to the displacement criterion for confirming the tip resistance in the Japanese design specifications for highway bridges. For reference, the post-peak mechanism was additionally tracked up to s/D = 0.2 (20% D). Within a fixed evaluation window located immediately beneath the pile tip, high-contact-force (HCF) points were binarized using the threshold τ = μ + σ, and their occupancy ratio φ and normalized force intensity I* were calculated separately for the ring and core regions. A density-based contribution index (“K_{-density share}”) was defined by combining “strength × area” and normalizing by the geometric width. The results suggest that, for the sand conditions and particle-scale ratios examined (D/d_50 = 25–100), the ring zone tends to carry on the order of 85–90% of the tip resistance within the observed cases up to the ultimate state. Even at high plugging ratios (CRs), the internal soil core gradually increases its occupancy and intensity with settlement; however, high-contact-force struts beneath the ring remain active, and it is suggested that the ring-dominant load-transfer mechanism is generally preserved. In the post-peak plastic regime, the K_{-density share} remains around 60%, indicating that the internal core plays a secondary, confining role rather than becoming dominant. These findings suggest that the conventional plug/unplug classification based on PLR can be supplemented by a combined use of plugging ratio CR (a kinematic indicator) and the ring contribution index (K_{-density share}), potentially enabling a continuous interpretation of plugged and unplugged behaviors and contributing to the establishment of a design backbone for tip resistance evaluation. Calibration of design coefficients, scale regression, and mapping to practical indices such as N-values will be addressed in part II of this study. (Note: “Contribution” in this study refers to the HCF-based density contribution index K_{-density share}, not the reaction–force ratio.) Full article

The aim of this research was to examine the possibility of achieving optimum texture and rheological properties of cocoa spreads produced with cocoa shell, xylitol, and stevia as sugar replacers using different vegetable fats (palm and coconut oil). Samples with different proportions of cocoa shell and sweeteners used to completely replace sugar were produced under laboratory conditions, and rheology, texture, colloidal stability, and particle size were determined. The results showed that texture properties (spreadability and firmness) and yield stress directly correlated with the type of fat used in the recipe, with the best values obtained for coconut fat. Cocoa shell addition increases Casson plastic viscosity (from approximately 2 to 7 Pas) but may reduce Casson yield stress if added in a proportion up to 25% (from approximately 26 to 18 Pa for samples produced with a combination of palm and coconut oil). Overall, samples with coconut fat had better texture properties regardless of the cocoa shell and sweetener quantities, and the sample with the lowest content of cocoa shell had the best spreadability. By careful adjustment of ingredients and the right choice of substitute fat, sustainable, nutritionally improved cocoa spreads with satisfactory texture and rheology may be produced. Full article

This study examined the drilling performance of five polymer composite systems: three natural fiber (jute, flax, hemp) composites with aluminum particle-reinforced epoxy, one glass fiber-reinforced composite with the same matrix, and an unreinforced aluminum particle-filled epoxy (Al–epoxy). Drilling experiments were performed at spindle speeds of 1500 and 3000 rpm with feed rates of 50, 75, and 100 mm/min in order to evaluate the effect of cutting parameters on the drilling performance. Cutting zone temperatures were measured using thermocouples embedded within the drill bit’s cooling channels, while thrust forces were recorded with a dynamometer. Additionally, hole exit damage and inner hole surface roughness were evaluated to assess machining quality. The results showed that increasing spindle speed reduces thrust forces due to thermal softening of the matrix, whereas natural fiber-reinforced composites generally exhibit higher thrust forces and slightly rougher inner hole surfaces compared to synthetic counterparts. During drilling, the measured thrust forces ranged from 320 to 693 N for the glass fiber-reinforced specimen and from 335 to 702 N for the Al–epoxy specimen, while for natural fiber-reinforced composites the thrust force values were 352–679 N for hemp, 241–719 N for jute, and 571–732 N for flax specimens. Synthetic specimens (glass fiber and Al–epoxy) exhibited comparable cutting temperature ranges (288–371 °C and 248–327 °C, respectively), whereas natural fiber-reinforced composites showed higher and broader temperature ranges of 311–389 °C for hemp, 368–374 °C for jute, and 307–379 °C for flax specimens. The overall results indicated that lower forces were generated during the drilling of synthetic glass fiber-reinforced composites, while among natural fiber-reinforced plastics, flax fiber-reinforced composites stood out by exhibiting a balanced machining response. Full article

The accurate simulation of sub-GeV particle detectors is essential for interpreting experimental data and optimizing detector design. This work identifies and addresses several critical aspects in modeling such detectors, taking as a case study the High-Energy Particle Detector (HEPD-02), a space-borne instrument developed within the CSES-02 mission to measure electrons in the ∼3–100 MeV range, protons and light nuclei in the ∼30–200 MeV/n. The HEPD-02 instrument consists of a silicon tracker, plastic and LYSO scintillator calorimeters, and anticoincidence systems, making it a representative example of a complex low-energy particle detector operating in Low Earth Orbit. Key challenges arise from replicating intricate detector geometries derived from CAD models, selecting appropriate hadronic physics lists for low-energy interactions, and accurately describing the detector response—particularly quenching effects in scintillators and digitization in solid-state tracking planes. Particular attention is given to three critical aspects: the precise CAD-level geometry implementation, the impact of hadronic physics models on the detector response, and the parameterization of scintillation quenching. In this study, we present original solutions to these challenges and provide data–MC comparisons using data from HEPD-02 beam tests. Full article

The global proliferation of plastics and their degradation into microplastics (<5 mm) have created a pervasive environmental crisis with severe ecological and human health consequences. Despite the exponential growth in microplastic research over the past decade, standardized protocols are still lacking. The absence of consistent sampling, analysis, and reporting methods limits data comparability, interoperability, and harmonization across studies. This study conducted a systematic bibliographic review of 355 peer-reviewed articles published between 2010 and 2022 that investigated microplastics in freshwater as well as marine water and sediment environments. The goal was to evaluate methodological consistency, sampling instruments, measurement units, reported characteristics, and data-sharing practices to identify pathways toward harmonized and FAIR (Findable, Accessible, Interoperable, and Reusable) microplastic data. Results show that 80.6% of studies focused on marine environments, 18% on freshwater, and 1.4% on both. This highlights persistent data gaps in freshwater systems, which function as key transport pathways for plastics to the ocean. Most studies targeted water (59%) rather than sediment (41%) and were mostly based on single-time sampling, limiting long-term analyses. Surface layers (<1 m) were predominantly sampled, while deeper layers remain understudied. Nets, particularly Manta, neuston, and plankton nets were the dominant tools for water sampling, whereas grabs, corers, and metallic receptacles were used for sediments. However, variations in mesh size and sampling depth introduce substantial biases in particle size recovery and reduce comparability across studies. The most common units were counts/volume for water and counts/g dry weight for sediments, but more than ten unit expressions were identified, complicating conversions. Only 35% of studies reported all four key microplastic characteristics (color, polymer type, shape, and size), and less than 20% made datasets publicly available. To advance harmonization, we recommend the adoption of consistent measurement units, mandatory reporting of key metadata, and wider implementation of open data practices aligned with the FAIR principles. These insights provide a foundation for developing robust monitoring strategies and evidence-based management frameworks. This is especially important for freshwater systems, where data remain scarce, and policy intervention is urgently needed. Full article

Our Sun is the closest X-ray astrophysical source to Earth. As such, it makes for a strong case study to better understand astrophysical processes. Solar flares are particularly interesting as they are linked to coronal mass ejections as well as magnetic field reconnection sites in the solar atmosphere. Flares can therefore provide insightful information on the physical processes at play on their production sites but also on the emission and acceleration of energetic charged particles towards our planet, making it an excellent forecasting tool for space weather. While solar flares are critical to understanding magnetic reconnection and particle acceleration, their hard X-ray polarization—key to distinguishing between competing theoretical models—remains poorly constrained by existing observations. To address this, we present the CUbesat Solar Polarimeter (CUSP), a mission under development to perform solar flare polarimetry in the 25–100 keV energy range. CUSP consists of a 6U-XL platform hosting a dual-phase Compton polarimeter. The polarimeter is made of a central assembly of four 4 × 4 arrays of plastic scintillators, each coupled to multi-anode photomultiplier tubes, surrounded by four strips of eight elongated GAGG scintillator bars coupled to avalanche photodiodes. Both types of sensors from Hamamatsu are, respectively, read out by the MAROC-3A and SKIROC-2A ASICs from Weeroc. In this manuscript, we present the preliminary spectral performances of single plastic and GAGG channels measured in a laboratory using development boards of the ASICs foreseen for the flight model. Full article

Plastic waste is a global issue due to the popularity of the product. Over time, plastic degrades into smaller particles known as microplastics and becomes harder to deal with as it easily disperses and can be missed by physical catches. Conventional degradation involves environmental forces like ultraviolet (UV) light, water, temperature, and physical abrasion. However, there is increasing interest in microbial plastic degradation, which could positively impact the transformation of (micro)plastics in various environmental matrices. Most of the available research has focused on bacterial degradation, but there is mounting evidence on the impact of fungal degradation. This review discusses conventional and bacterial degradation, then discusses the advantages of fungal involvement in the degradation of microplastics. Biodegradation enhanced by fungal enzymes is a valuable tool that could greatly improve the removal of these microplastic pollutants from the environment. Due to some biochemical complexities, fungi are naturally omnipresent in marine and terrestrial environments under all sorts of climates. Fungi could thrive by themselves or in association with other microorganisms, which could also be applied in non-biotic plastic degradation processes as an alternative to other forms of plastic management in the environment. Full article

Silica-rich dust intrusion is a persistent challenge for lubrication systems in agricultural machinery, where abrasive third-body particles can accelerate wear and shorten component service life. Here, molecular dynamics simulations are employed to elucidate how SiO₂ nanoparticle contamination degrades polyalphaolefin (PAO) boundary lubrication at the atomic scale. Two confined sliding models are compared: a pure PAO film and a contaminated PAO film containing 7 wt% SiO₂ nanoparticles between crystalline Fe substrates under a constant normal load and sliding velocity. The contaminated system exhibits a higher steady-state friction force, faster lubricant film disruption and migration, and consistently higher interfacial temperatures, indicating intensified energy dissipation. Substrate analyses reveal deeper and stronger von Mises stress penetration, increased severe plastic shear strain, elevated Fe potential energy associated with defect accumulation, and reduced structural order. Meanwhile, PAO molecules store more intramolecular deformation energy (bond, angle, and dihedral terms), reflecting stress concentration and disturbed shear alignment induced by nanoparticles. These results clarify the multi-pathway mechanisms by which abrasive SiO₂ contaminants transform PAO from a protective boundary film into an agent promoting abrasive wear, providing insights for designing wear-resistant lubricants and improved filtration strategies for particle-laden applications. Full article