Search Results (19)

The synthesis process employed solid-state reaction methods to produce phosphors with varying CaO contents, specifically at x values of 0, 0.2, 0.4, 0.6, 0.8, and 1.0. As the CaO content (represented by the x value) increases, the crystalline structure of Ca_2+xGa₄O_8+x + 0.01 Bi₂O₃ + 0.07 ZnO compositions underwent notable transformations. X-ray diffraction was used to characterize these structural changes, and we found that CaGa₂O₄, CaO, Ga₂O₃, and Ca₃Ga₄O₉ were clearly identified. The diffraction intensities of CaGa₂O₄ and CaO phases increased and those of Ga₂O₃ and Ca₃Ga₄O₉ decreased with the x value. Our findings revealed that the photoluminescence excitation (PLE) spectra consistently peak around 340 nm across all samples, while the photoluminescence emission (PL) spectra exhibited slight variations within the range of 474–477 nm. Most notably, the intensity of both PLE and PL spectra demonstrated a non-linear relationship with CaO content, initially increasing with higher CaO concentration, reaching maximum intensity at x = 0.4, and subsequently decreasing as the x value continued to rise. This research provides valuable insights into the relationship between composition, crystal structure, and luminescent behavior in Ca_2+xGa₄O_8+x phosphor systems, and the theoretical mechanisms underlying these observed trends were thoroughly discussed. Full article

In this study, Mn²⁺ and Eu²⁺-codoped Sr_3−xBa_xMgSi₂O₈ (x = 0–1.5) phosphors were synthesized at 1400 °C under a reducing atmosphere composed of 5% H₂ and 95% N₂ to produce materials with blue light emission. The resulting powders were characterized using several analytical techniques: X-ray diffraction (XRD) was employed to identify the crystalline phases, scanning electron microscopy (SEM) was used to observe the microstructure, and photoluminescence excitation (PLE) and emission (PL) spectra were measured using a fluorescence spectrophotometer. The results revealed several key findings. XRD analysis showed that the Sr₃MgSi₂O₈ (Sr_3−xBa_xMgSi₂O₈) phase coexisted with secondary phases of Sr₂SiO₄ and Sr₂MgSi₂O₇. SEM observations indicated that the synthesized powders exhibited a distinctive needle-like structure anchored on the surfaces of the particles. The PL and PLE intensities increased sharply as the BaO content increased from x = 0 to x = 0.6, followed by a more gradual increase, reaching a peak at x = 1.2. Additionally, as the value of x increased, the wavelengths corresponding to maximum PL and PLE intensities exhibited a blue shift, moving to shorter wavelengths. Further investigation focused on the excitation behavior by replotting the PLE spectra using energy (eV) as the x-axis. A Gaussian fitting function was applied to deconvolute the excitation bands, enabling an in-depth analysis of how compositional variations influenced the Stokes shift. Full article

Dy³⁺ single-doped and Dy³⁺/Eu³⁺ co-doped ZnO:B₂O₃:WO₃:Nb₂O₅ glass was successfully synthesized using the melt quenching method. The amorphous character of the prepared samples was confirmed by X-ray diffraction (XRD). The glass transition and crystallization temperatures were examined by differential scanning calorimetry (DSC). Raman spectroscopy was applied to investigate the glass microstructure. Physical properties like the density, molar volume, oxygen molar volume and oxygen packing density of the glass were also determined. The photoluminescence excitation (PLE) and emission (PL) spectra of the resultant glass types were measured. The obtained Dy³⁺ single-doped glass was characterized by strong luminescence at 482 and 574 nm, corresponding to the ⁴F_9/2 → ⁶H_15/2 (blue) and ⁴F_9/2 → ⁶H_13/2 (yellow) transitions, respectively, and weak luminescence at 663 nm and 753 nm due to the ⁴F_9/2 → ⁶H_11/2 (red) and ⁴F_9/2 → ⁶H_9/2 + ⁶F_11/2 (red) transitions. The luminescence results indicate that energy transfer from the Dy³⁺ to Eu³⁺ ions occurs in the proposed glass system. The emitted light from the Dy³⁺ single-doped glass was found to be yellow-orange. The Dy³⁺/Eu³⁺ co-doped samples emitted darker orange light. The obtained results show that the investigated types of glass have the potential to be used as orange light-emitting materials. Full article

The self-activated halotungstate Ba₃WO₅Cl₂ was successfully synthesized using a high-temperature solid-state method. X-ray diffraction analysis (XRD) confirmed the formation of a single-phase compound with a monoclinic crystal structure, ensuring the material’s purity and structural integrity. The luminescence properties of Ba₃WO₅Cl₂ were thoroughly investigated using both optical and laser-excitation spectroscopy. The photoluminescent excitation (PLE) and emission (PL) spectra, together with the corresponding decay curves, were recorded across a broad temperature range, from 10 K to 480 K. The charge transfer band (CTB) of the [WO₅Cl] octahedron was clearly identified in both the PL and the PLE spectra under ultraviolet light excitation, indicating efficient energy transfer within the material’s structure. A strong blue emission could be detected around 450 nm, which is characteristic of the material’s luminescent properties. However, this emission exhibited thermal quenching as the temperature increased, a common phenomenon where the luminescence intensity diminishes due to thermal effects. To better understand the thermal quenching behavior, variations in luminescence intensity and decay time were analyzed using a straightforward thermal quenching model. This comprehensive study of Ba₃WO₅Cl₂ luminescent properties not only deepens the understanding of its photophysical behavior but also contributes to the development of novel materials with tailored optical properties for specific technological applications. Full article

High-quality single crystals with empirical composition Y₂.₉₆Sm₀.₀₄Ga₅O₁₂ (YGG: Sm³⁺) were successfully prepared by the optical floating zone method for the first time and compared with related single crystals of Y₂.₉₆Sm₀.₀₄Al₅O₁₂ (YAG: Sm³⁺). With both crystals, XRD showed that Sm³⁺ entered the cubic-phase structure. Optical absorption spectra produced a series of peaks from Sm³⁺ in the 250 nm to 550 nm range, and photoluminescence excitation (PLE) spectra detected at 613 nm showed strong excitation peaks at 407 nm and 468 nm. A strong emission peak at 611 nm (orange-red light) was observed in the photoluminescence (PL) spectra under excitations at both 407 and 468 nm, respectively, but it was much brighter under excitation at 407 nm. Furthermore, with both emission spectra, the peaks from the YGG: Sm³⁺ crystal were significantly more intense than those from the YAG: Sm³⁺ crystal, and both experienced a blue shift. In addition, under excitation at 407 nm, the color purity of the emitted orange-red light of YGG: Sm³⁺ was higher than that of the YAG: Sm³⁺ crystal, and the fluorescence lifetime for the ⁴G_5/2 → ⁶H_7/2 transition of YGG: Sm³⁺ was longer than that of the YAG: Sm³⁺ crystal. The optical properties of the YGG: Sm³⁺ crystal are better than those of the YAG: Sm³⁺ crystal. Full article

Previously, there were almost no relevant studies on developing the optimal Ca_xMg_2-xSi₂O₆:yEu²⁺ phosphor composition for its finest optical properties. This study employs two steps to determine the optimal composition for Ca_xMg_2-xSi₂O₆:yEu²⁺ phosphors. First, CaMgSi₂O₆:yEu²⁺ (y = 0.015, 0.020, 0.025, 0.030, 0.035) was used as the primary composition of specimens synthesised in a reducing atmosphere of 95% N₂ + 5% H₂ to investigate the effect of Eu²⁺ ions on the photoluminescence properties of each variant. The emission intensities of the entire photoluminescence excitation (PLE) and photoluminescence (PL) emission spectra of the CaMgSi₂O₆:yEu²⁺ phosphors initially increased as the concentration of the Eu²⁺ ions increased, peaking at y = 0.025. The cause of the variations across the entire PLE and PL spectra of all five CaMgSi₂O₆:yEu²⁺ phosphors was investigated. Because the CaMgSi₂O₆:0.025Eu²⁺ phosphor had the highest PLE and PL emission intensities, in the next step, Ca_xMg_2-xSi₂O₆:0.025Eu²⁺ (x = 0.5, 0.75, 1.0, 1.25) was used as the primary composition to investigate the effect on the photoluminescence properties when the CaO content varied. We also show that the Ca content has an apparent effect on the photoluminescence properties of Ca_xMg_2-xSi₂O₆:0.025Eu²⁺ phosphors, and the optimal phosphor composition is Ca₀.₇₅Mg₁.₂₅Si₂O₆:0.025Eu²⁺ because it has the largest PLE and PL values. X-ray diffraction (XRD) analyses of Ca_xMg_2-xSi₂O₆:0.025Eu²⁺ phosphors were performed to identify the factors responsible for this outcome. Full article

Despite the enormous environmental damage caused by plastic waste, it makes up over one-third of globally produced plastics. Polyethylene (PE) wastes have low recycling but high production rates. Towards the construction of ionic solar cells from PE, the present work describes the loading of a bioactive photoacid phycocyanobilin (PCB) dye from the pigment of Spirulina blue–green algae (as a natural resource) on low-density polyethylene (LDPE) plastic film. Dyeing was confirmed by X-ray photoelectron spectroscopy (XPS). Upon excitation of the Soret-band (400 nm), the photoluminescence (PL) spectra of PCB in neat solvents revealed two prominent emission peaks at 450–550 and 600–700 nm. The first band assigned to bilirubin-like (PCB_BR) species predominated the spectral profile in the highly rigid solvent glycerol and upon loading 0.45 % (w/w) of the dye on plastic. The photoluminescence excitation (PLE) spectra of PCB for the second region (Q-band) at 672 nm in the same solvents confirmed the ground state heterogenicity previously associated with the presence of PCB_A (neutral), PCB_B (cationic), and PCB_C (anionic) conformers. Time-resolved photoluminescence (TRPL) measurements induced via excitation of all PCB species at 510 nm in methanol revealed three-lifetime components with τ₁ = ~0.1 ns and τ₂ = ~2 ns associated with PCB_BR species and τ₃ = ~5 ns pertinent to the long-living photoproduct X*. Decay-associated spectra (DAS) analysis of the photoluminescence transient spectra of the final dyed films in the solid-state confirmed the improved generation of the long-living photoproduct as manifested in a significant increase in the PL intensity (~100-fold) and lifetime value (~90 ns) in the Q-region upon loading 6.92 % (w/w) of the dye on plastic. The photoproduct species were presumably assigned to the deprotonated PCB species, suggesting improved ionic mobility. The potential implementation of the PCB-sensitized PE solid wastes for the fabrication of ionic solar cells is discussed. Full article

A novel dual green and red-emitting photoluminescent polymer composite ZnAl₂O₄:Mn-bonded GO/polymethyl methacrylate (PMMA) was synthesized in a single-step reaction by surface-initiated atom transfer radical polymerization (SI-ATRP). The polymer chain was surface-initiated from the ZnAl₂O₄:Mn/GO, and the final products have a homogenous photoluminescent property from ZnAl₂O₄:Mn and better mechanical properties strengthened by graphene oxide (GO). The morphologies of ZnAl₂O₄:Mn/GO and the polymer composites were verified by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). X-ray diffraction analysis (XRD) revealed the two valence states of Mn (Mn²⁺, Mn⁴⁺) existing in the ZnAl₂O₄ host lattice, while Fourier-transform infrared spectroscopy (FTIR) spectra proved the transference of the active group, C-Br, from the initiator to the monomer during the polymerization. Gel permeation chromatography (GPC) shows the narrow dispersity of polymer composites fabricated through SI-ATRP. The SEM and FTIR results show the successful ‘graft’ of the polymer chains from the surface of ZnAl₂O₄:Mn/GO. The dual green and red-emitting polymer composites were synthesized, confirmed by the photoluminescence (PL) and photoluminescence excitation (PLE) results. Full article

The effect of sodium thiosulfate (ST) on the photodegradation of azathioprine (AZA) was analyzed by UV-VIS spectroscopy, photoluminescence (PL), FTIR spectroscopy, Raman scattering, X-ray photoelectron (XPS) spectroscopy, thermogravimetry (TG) and mass spectrometry (MS). The PL studies highlighted that as the ST concentration increased from 25 wt.% to 75 wt.% in the AZA:ST mixture, the emission band of AZA gradual downshifted to 553, 542 and 530 nm. The photodegradation process of AZA:ST induced: (i) the emergence of a new band in the 320–400 nm range in the UV-VIS spectra of AZA and (ii) a change in the intensity ratio of the photoluminescence excitation (PLE) bands in the 280–335 and 335–430 nm spectral ranges. These changes suggest the emergence of new compounds during the photo-oxidation reaction of AZA with ST. The invoked photodegradation compounds were confirmed by studies of the Raman scattering, the FTIR spectroscopy and XPS spectroscopy through: (i) the downshift of the IR band of AZA from 1336 cm⁻¹ to 1331 cm⁻¹, attributed to N-C-N deformation in the purine ring; (ii) the change in the intensity ratio of the Raman lines peaking at 1305 cm⁻¹ and 1330 cm⁻¹ from 3.45 to 4.57, as the weight of ST in the AZA:ST mixture mass increased; and (iii) the emergence of a new band in the XPS O1s spectrum peaking at 531 eV, which was associated with the C=O bond. Through correlated studies of TG-MS, the main key fragments of ST-reacted AZA are reported. Full article

New aspects concerning the photodegradation (PD) of ampicillin are reported by photoluminescence (PL), Raman scattering and FTIR spectroscopy. The exposure of ampicillin in the absence (AM) and in the presence of the excipient (AMP) to UV light leads to an intensity diminution of the photoluminescence excitation (PLE) and photoluminescence (PL) spectra and the emergence of a new IR band at 3450 cm⁻¹. The photoluminescence studies demonstrate that the AM PD is amplified in the presence of excipients and an alkaline medium. In this last case, the PD process of AM involves the emergence of new compounds, whose presence is highlighted by: (i) the emergence of the isosbestic point at 300 nm in the UV-VIS spectra; (ii) a change in the ratio between the absorbance of IR bands situated in the spectral ranges 1200–1660 and 3250–3450 cm⁻¹; and (iii) a change in the ratio between the intensities of the Raman lines localized in the spectral ranges 1050–1800 and 2750–3100 cm⁻¹. A chemical mechanism of the PD processes of AM in an alkaline medium is proposed. Full article

This study presented an analysis of the TeO₂/GeO₂ molar ratio in an oxide glass system. A family of melt-quenched glasses with the range of 0–35 mol% of GeO₂ has been characterized by using DSC, Raman, MIR, refractive index, PLE, PL spectra, and time-resolved spectral measurements. The increase in the content of germanium oxide caused an increase in the transition temperature but a decrease in the refractive index. The photoluminescence spectra of europium ions were examined under the excitation of 465 nm, corresponding to ⁷F₀ → ⁵D₂ transition. The PSB (phonon sidebands) analysis was carried out to determine the phonon energy of the glass hosts. It was reported that the red (⁵D₀ → ⁷F₂) to orange (⁵D₀ → ⁷F₁) fluorescence intensity ratio for Eu³⁺ ions decreased from 4.49 (Te0Ge) to 3.33 (Te15Ge) and showed a constant increase from 4.58 (Te20Ge) to 4.88 (Te35Ge). These optical features were explained in structural studies, especially changes in the coordination of ^[4]Ge to ^[6]Ge. The most extended lifetime was reported for the Eu³⁺ doped glass with the highest content of GeO₂. This glass was successfully used for the drawing of optical fiber. Full article

In recent years, the use of quantum dots (Qdots) to obtain biological images has attracted attention due to their excellent luminescent properties and the possibility of their association with contrast agents for magnetic resonance imaging (MRI). In this study, Gd³⁺/ZnO (ZnOGd) were conjugated with Qdots composed of a gadolinium-copper-indium-sulphur core covered with a ZnS shell (GCIS/ZnS Qdots). This conjugation is an innovation that has not yet been described in the literature, and which aims to improve Qdot photoluminescent properties. Structural and morphological Qdots features were obtained by transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and thermogravimetric analyses (TGA). The photoluminescent properties were examined by emission (PL) and excitation (PLE) spectra. A new ZnOGd and GCIS/ZnS (ZnOGd-GCIS/ZnS) nanomaterial was synthesized with tunable optical properties depending on the ratio between the two native Qdots. A hydrophilic or lipophilic coating, using 3-glycidyloxypropyltrimethoxysilane (GPTMS) or hexadecyltrimethoxysilane (HTMS) on the surface of ZnOGd-GCIS/ZnS Qdots, was carried out before assessing their efficiency as magnetic resonance contrast agents. ZnOGd-GCIS/ZnS had excellent luminescence and MRI properties. The new Qdots developed ZnOGd-GCIS/ZnS, mostly constituted of ZnOGd (75%), which had less cytotoxicity when compared to ZnOGd, as well as greater cellular uptake. Full article

The influence of SiO₂/TiO₂ nanocomposites (STNCs) content on non-radiative energy transfer (Förster-type) from poly (9,9′-dioctylfluorene-2,7-diyl) (PFO) to poly [2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) using steady-state and time-resolved photoluminescence spectroscopies was investigated at room temperature. The improved energy transfer from PFO to MEH-PPV upon an increment of the STNCs was achieved by examining absorbance, emission (PL) and photoluminescence excitation (PLE) spectra. The shorter values of the quantum yield (φ_DA) and lifetime (τ_DA) of the PFO in the hybrid thin films compared with the pure PFO, indicating efficient energy transfer from PFO to MEH-PPV with the increment of STNCs in the hybrid. The energy transfer parameters can be tuned by increment of the STNCs in the hybrid of PFO/MEH-PPV. The Stern–Volmer value (k_SV), quenching rate value (k_q), Förster radius (R₀), distance between the molecules of PFO and MEH-PPV (R_DA), energy transfer lifetime (τ_ET), energy transfer rate (k_ET), total decay rate of the donor (TDR), critical concentration (A_o), and conjugation length (A_π) were calculated. The gradually increasing donor lifetime and decreasing acceptor lifetime, upon increasing the STNCs content, prove the increase in conjugation length and meanwhile enhance in the energy transfer. Full article

In this work, new evidence for the photodegradation reactions of acetaminophen (AC) is reported by photoluminescence (PL), Raman scattering and FTIR spectroscopy. Under excitation wavelength of 320 nm, AC shows a PL band in the spectral range of 340–550 nm, whose intensity decreases by exposure to UV light. The chemical interaction of AC with the NaOH solutions, having the concentration ranging between 0.001 and 0.3 M, induces a gradual enhancement of the photoluminescence excitation (PLE) and PL spectra, when the exposure time of samples at the UV light increases until 140 min, as a result of the formation of p-aminophenol and sodium acetate. This behavior is not influenced by the excipients or other active compounds in pharmaceutical products as demonstrated by PLE and PL studies. Experimental arguments for the obtaining of p-aminophenol and sodium acetate, when AC has interacted with NaOH, are shown by Raman scattering and FTIR spectroscopy. Full article

Ba_2−xSr_xZnWO₆ double perovskite (DP) oxide compounds (x = 1, 1.25, 1.5, 1.75, 2) were successfully created by means of conventional solid-state techniques. The crystal structures of our series were studied using an X-ray diffractometer. The x = 1 compound has a cubic (Fm-3m) crystal structure, the 1 ≤ x ≤ 2 compounds have tetragonal (I4/m) symmetry, and the phase was transferred to monoclinic (P2₁/n) symmetry for the Sr₂ZnWO₆ (x = 2) compound. Scanning electron microscopy (SEM) was used to investigate the morphology of the series, showing that the samples had crystallized microstructures. Molecular bonds were investigated using Fourier transform infrared and Raman spectroscopies, which confirmed the double perovskite octahedral geometry for the samples in our series. Furthermore, the octahedral W–O₆ anti-symmetric stretching mode was found to occur. The optical properties of the Ba_2−xSr_xZnWO₆ series were studied using Ultraviolet–visible (UV–vis) diffuse reflectance and photoluminescence (PL) spectroscopies. The absorption edge of the samples appeared around the near-violet and visible spectra, between 336–360 nm. The band gap energy was investigated in two ways—using the absorption cutoff and Tauc plots—which increased from 3.52 to 3.7 eV with increasing substitution of Ba²⁺ by Sr²⁺. Furthermore, excitation and emission spectra were collected at room temperature. A broad band at 260–360 nm appeared in the PLE spectra for all samples, and the PL spectra of the samples had a band that spread from 320–450 nm. Full article