Search Results (80)

In the energy sector and in other types of industries (cement, iron/steel, chemical and petrochemical), highly roasted coffee ground residue can be used as a source material for producing bioadsorbents suitable for CO₂ capture. In this study, a bioadsorbent was produced in a two-step process involving biowaste carbonization and biocarbon activation within a KOH solution. The physicochemical properties of the bioadsorbent were assessed using LECO, TG, SEM, BET and FT-IR methods. Investigating the CO₂, O₂ and N₂ equilibrium adsorption capacity using an IGA analyzer allowed us to calculate CO₂ selectivity factors. We assessed the influence of exhaust gas carbon dioxide concentration (16%, 30%, 81.5% and 100% vol.) and adsorption step temperature (25 °C, 50 °C and 75 °C) on the CO₂ adsorption capacity of the bioadsorbent. We also investigated its stability and regenerability in multi-step adsorption–desorption using a TG-Vacuum system, simulating the VSA process and applying different pressures in the regeneration step (30, 60 and 100 mbar_abs). The tests conducted assessed the possibility of using a produced bioadsorbent for capturing CO₂ using the VSA technique. Full article

Risk management is crucial in engineering projects, especially in highly complex environments like petrochemical plants producing polyvinyl chloride (PVC). This study proposes a tailored risk management model, using analytic hierarchy process (AHP) and linear regression analysis, alongside MS Excel and IBM SPSS^® version 23, to identify, assess, and prioritize key risks. Surveys and interviews revealed seven management factors (budget, schedule, safety, productivity, contracting, quality, and environment) and 18 critical risks, including design errors and procurement delays. The model quantifies risk impacts, provides a regression equation for risk classification, and supports effective mitigation strategies. Based on this model, decision-making can be facilitated for the implementation of effective mitigation strategies. It also promotes continuous improvement, optimizing economic resources and minimizing environmental impacts, addressing a research gap in Colombia’s petrochemical sector and paving the way for broader industrial applications. Full article

In this study, we selected the production processes and main products of three typical chemical enterprises in Shanghai, namely SH Petrochemical (part of the oil-refining sector), SK Ethylene, and HS Chlor-Alkali, to quantitatively assess the synergistic effects across technology, policy, and emission mechanisms. The localized air pollutant levels and greenhouse gas emissions of the three enterprises were calculated. The synergistic effects between the end-of-pipe emission reductions for air pollutants and greenhouse gas emissions were analyzed using the pollutant reduction synergistic and cross-elasticity coefficients, including technology comparisons (e.g., acrylonitrile gas incineration (AOGI) technology vs. traditional flare). Based on these data, we used the SimaPro software and the CML-IA model to conduct a life cycle environmental impact assessment regarding the production and upstream processes of their unit products. By combining the life cycle method and the scenario simulation method, we predicted the trends in the environmental impacts of the three chemical enterprises after the implementation of low-carbon development policies in the chemical industry in 2030. We also quantified the synergistic effects of localized air pollutant and greenhouse gas (GHG) emission reductions within the low-carbon development scenario by using cross-elasticity coefficients based on life cycle environmental impacts. The research results show that, for every ton of air pollutant reduced through end-of-pipe treatment measures, the HS Chlor-Alkali enterprise would increase its maximum CO₂ emissions, amounting to about 80 tons. For SK Ethylene, the synergistic coefficient for VOC reduction and CO₂ emissions when using AOGI thermal incineration technology is superior to that for traditional flare thermal incineration. The activities of the three enterprises had an impact on several environmental indicators, particularly the fossil fuel resource depletion potential, accounting for 69.48%, 53.94%, and 34.23% of their total environmental impact loads, respectively. The scenario simulations indicate that, in a low-carbon development scenario, the overall environmental impact loads of SH Petrochemical (refining sector), SK Ethylene, and HS Chlor-Alkali would decrease by 3~5%. This result suggests that optimizing the upstream power structure, using “green hydrogen” instead of “grey hydrogen” in hydrogenation units within refining enterprises, and reducing the consumption of electricity and steam in the production processes of ethylene and chlor-alkali are effective measures in reducing carbon emissions in the chemical industry. The quantification of the synergies based on life cycle environmental impacts revealed that there are relatively strong synergies for air pollutant and GHG emission reductions in the oil-refining industry, while the chlor-alkali industry has the weakest synergies. Full article

Systematic assessment of heavy metal contamination in agricultural soils is critical for addressing ecological and public health risks in industrial-intensive cities like Lanzhou, with direct implications for achieving UN Sustainable Development Goals (SDGs) 2 (Zero Hunger), 15 (Life on Land), and 3 (Good Health). The present study evaluates farmland soils around six industrial sectors: waste disposal (WDZ), pharmaceutical manufacturing (PMZ), chemical manufacturing (CMZ), petrochemical industry (PIZ), metal smelting (MSZ), mining (MZ) and one sewage-irrigated zone (SIZ) using geo-accumulation index, Nemerow composite pollution index, potential ecological risk index, and health risk models. The following are the major findings: (1) SIZ and PMZ emerged as primary contamination clusters, with Hg (I_geo = 1.89) and Cd (I_geo = 0.61) showing marked accumulation. Chronic wastewater irrigation caused severe Hg contamination (0.97 mg·kg⁻¹) in SIZ, where 100% of the samples reached strong polluted levels according to the Nemerow composite pollution index; (2) Hg and Cd dominated the ecological risks, with 41.32% of the samples exhibiting critical Hg risks (100% in PMZ and SIZ) and 32.63% showing strong Cd risks; and (3) oral ingestion constituted the dominant exposure pathway. Children faced carcinogenic risks (CR = 1.33 × 10⁻⁴) exceeding safety thresholds, while adult risks remained acceptable. Notably, high Hg and Cd levels did not translate to proportionally higher health risks due to differential toxicological parameters. The study recommends prioritizing Hg and Cd control in PMZ and SIZ, with targeted exposure prevention measures for children. Full article

Membrane processes are extensively employed in a range of industrial and food applications. Due to growing environmental concerns and the introduction of regulatory measures, it is imperative to develop innovative membrane materials that can effectively replace petrochemical-based polymers, in line with the principles of a circular economy. The focus of this review is the use of polysaccharides for obtaining films/membranes for food and industrial applications using selected case studies. Besides the polysaccharides extracted from biomass, the valorization of agrifood residues and the use of plants adapted to arid lands (i.e., cactus) to produce polysaccharide films for food packaging is addressed. Moreover, microbial polysaccharides produced using renewable resources present a significant alternative to commercial hydrophilic membranes for gases and ethanol dehydration. To meet industry requirements, the mechanical and barrier properties of the films can be improved by the inclusion of inert impermeable fillers and/or the chemical modification of the polysaccharides. The adsorption of proteins, dyes, and pharmaceutical compounds using a cellulose-based polymer is discussed. Despite their unique characteristics, polysaccharide production costs are still higher than most synthetic polymers. This is a challenge that can be overcome by scaling up the production and by valorizing agro-industrial wastes and by-products to make the application of polysaccharide membranes/films in the food and industry sectors more widespread. Full article

Recently, there has been a growing interest in issues related to mining equipment maintenance, with particular focus on pumping systems’ continuous operation. However, despite wide applications of pump system maintenance in a wide range of industries, such as water and wastewater, aviation, petrochemical, building (HVAC system), and nuclear power plant industries, the literature on maintenance of pump systems operating in the mining industry still needs development. This study aims to review the existing literature to present an up-to-date analysis of maintenance strategies for mining pumps, with a particular focus on proactive maintenance approaches. Key aspects considered include predictive diagnostics and prognosis, health status monitoring, maintenance management, and the integration of intelligent mining systems to enhance operational reliability and efficiency in harsh mining environments. The proposed methodology includes a systematic literature review with the use of the Primo multi-search tool, adhering to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines. The selection criteria focused on English studies published between 2005 and 2024, resulting in 88 highly relevant papers. These papers were categorized into six groups: (a) condition/health status monitoring, (b) dewatering system operation and maintenance, (c) health diagnosis and prognosis, (d) intelligent mining (modern technologies), (e) maintenance management, and (f) operational efficiency and reliability optimization. A notable strength of this study is its use of diverse scientific databases facilitated by the multi-search tool. Additionally, a bibliometric analysis was performed, showcasing the evolution of research on pump maintenance in the mining sector over the past decade and identifying key areas such as predictive diagnostics, dewatering system optimization, and intelligent maintenance management. This study highlights the varied levels of research and practical implementation across industries, emphasizing the mining sector’s unique challenges and opportunities. Significant research gaps were identified, including the need for tailored diagnostic tools, real-time monitoring systems, and cost-effective maintenance strategies specific to harsh mining environments. Future research directions are proposed, focusing on advancing predictive maintenance technologies, integrating intelligent systems, and enhancing operational efficiency and reliability. The study concludes with a detailed discussion of the findings and their implications, offering a roadmap for innovations in pump maintenance within the mining industry. Full article

The performance of pH controllers in industrial cooling towers is critical for maintaining optimal operational conditions and ensuring system efficiency. Industries such as the fertilizer, petrochemical, oil refinery, gas production, and power plant sectors rely on cooling towers, where poor pH regulation can lead to corrosion, scaling, and microbial growth. Traditional proportional–integral–derivative (PID) controllers are used for pH neutralization but often struggle with the cooling tower environments’ dynamic and nonlinear nature, resulting in suboptimal performance and increased operational costs. A hybrid particle swarm optimization (PSO) algorithm combined with a multiple adaptive neuro-fuzzy inference system (MANFIS) was developed to address these challenges. The MANFIS leverages fuzzy logic and neural networks to handle nonlinear pH fluctuations, while PSO improves the convergence speed and solution accuracy. This hybrid approach optimized the PID controller parameters for real-time adaptive pH control. The methodology involved collecting open-loop pH data, deriving the system transfer function, designing the PID controller, and implementing the PSO–MANFIS algorithm to fine-tune PID gains. Three tuning methods—MATLAB Tuner, MANFIS, and PSO–MANFIS—were compared. The findings proved that the PSO–MANFIS approach markedly enhanced the closed-loop efficiency by reducing overshoot and enhancing the dynamic response. These findings demonstrate that the PSO–MANFIS approach effectively maintains pH levels within desired limits, reduces energy consumption, and minimizes chemical usage and the risk of mechanical equipment damage. This study provided valuable insights into optimizing pH control strategies in industrial cooling tower systems, offering a practical solution for improving efficiency and reliability. Full article

It has been well known for the past decade that the accumulation of food E-preservatives in the human body has harmful consequences for human health. Furthermore, scientists have realized that despite the convenience offered by petrochemical-derived polymers, a circular economy and sustainability are two current necessities; thus, the use of biodegradable alternative materials is imposed. The food packaging sector is one of the most rapidly changing sectors in the world. In recent years, many studies have focused on the development of active packaging films to replace old non-ecofriendly techniques with novel environmentally friendly methods. In this study, a novel self-healable, biodegradable active packaging film was developed using poly(lactic acid) (PLA) as a biopolymer, which was incorporated with a nanohybrid solid material as a natural preservative. This nanohybrid was derived via the absorption of carvacrol (CV) essential oil in an activated carbon (AC) nanocarrier. A material with a high carvacrol load of 71.3%wt. into AC via a vacuum-assisted adsorption method, functioning as a natural antioxidant and an antibacterial agent. The CV@AC nanohybrid was successfully dispersed in a PLA/triethyl citrate (TEC) matrix via melt extrusion, and a final PLA/TEC/xCV@AC nanocomposite film was developed. The study concluded that x = 10%wt. CV@AC was the optimum nanohybrid amount incorporated in the self-healable PLA/TEC and exhibited 277% higher ultimate strength and 72% higher water barrier compared to the pure PLA/TEC. Moreover, it remained ductile enough to show the slowest CV release rate, highest antioxidant activity, and significant antibacterial activity against Staphylococcus aureus and Salmonella enterica ssp. enterica serovar Typhimurium. This film extended the shelf life of fresh minced pork by four days, according to total viable count measurements, and decreased its lipid oxidation rate. Finally, this novel film preserved the nutritional value of porkby maintaining a higher heme iron content and showed a higher level of sensory characteristics compared to commercial packaging paper. Full article

This research determines the contribution of Corporate Social Responsibility (CSR) to reducing financial risks and, consequently, to the sustainable development of companies in different sectors of the economy and at different phases of the economic cycle (using Russia as an example). The informational and empirical base comprises data on the dynamics of stock prices of sectoral indices of the Moscow Exchange’s total return “gross” (in Russian rubles): oil and gas, electricity, telecommunications, metals and mining, finance, consumer sector (retail trade), chemicals and petrochemicals, and transportation, as well as the “Responsibility and Openness” index in 2019 (before the crises), in 2020 (COVID-19 crisis), 2022 (sanction crisis), and 2024 (Russia’s economic growth). Economic–mathematical models, compiled through regression analysis, showed that the contribution of CSR to reducing the financial risks of companies is highly differentiated among economic sectors and phases of the economic cycle. The research presents a new sectoral perspective on counter-cyclical management of the financial risks of companies through CSR, enabling a deeper study of the cause-and-effect relationships of such management for the sustainable development of companies from different economic sectors. This is the theoretical significance of this research, its novelty, and its contribution to the literature. The research has practical significance, revealing previously unknown best practices for the sustainable development of companies from different economic sectors of Russia across different phases of the economic cycle. The systematized experience will be useful for forecasting the financial risks of companies during future economic crises in Russia and improving the practice of planning and organizing the financial risk management of Russian companies through CSR. The authors’ conclusions have managerial significance because they will help enhance the flexibility and efficiency of corporate financial risk management by considering the sectoral specifics and cyclical nature of the economy when implementing CSR. Full article

Heat-intensive industries (e.g., iron and steel, aluminum, cement) and explosive sectors (e.g., oil and gas, chemical, petrochemical) face challenges in achieving Industry 4.0 goals due to the widespread adoption of industrial Internet of Things (IIoT) technologies. Wireless solutions are favored in large facilities to reduce the costs and complexities of extensive wiring. However, conventional wireless devices powered by lithium batteries have limitations, including reduced lifespan in high-temperature environments and incompatibility with explosive atmospheres, leading to high maintenance costs. This paper presents a novel approach for energy-intensive and explosive industries, which represent over 40% of the gross production revenue (GPR) in several countries. The proposed solution uses residual heat to power ATEX-certified IIoT devices, eliminating the need for batteries and maintenance. These devices are designed for condition monitoring and predictive maintenance of rotating machinery, which is common in industrial settings. The study demonstrates the successful application of this technology, highlighting its potential to reduce costs and improve safety and efficiency in challenging industrial environments. Full article

This paper presents a systematic review of the contributions of asset integrity and process safety management for the safe operations and sustainability of onshore petrochemical installations. The review highlights how the two systems work as prerequisites for minimizing industrial accidents and preserving the environment. Their contributions to the management of safety-critical equipment and the integration of the emerging technologies of Industry 4.0 are provided. Based on a systematic review of more than one hundred academic papers and gray literature, the authors highlight considerable gaps associated with the operations of the two systems mostly functioning without integration. The authors propose a new conceptual framework, integrated asset integrity and process safety management (iAIPSM), to address the gaps. This review provides insights to strengthen operational safety, ensure regulatory compliance, and support the advancement of the United Nations Sustainable Development Goals (SDGs) within the sector. Full article

With the rapid advancement of modern industries, pressure vessels and piping have become increasingly integral to sectors such as energy, petrochemicals, and process industries. To grasp the research and application status in the field of pressure vessel and piping safety, 670 publications in the Web of Science core database from 2008 to 2024 were taken as data samples in this paper. The knowledge mapping tools were used to carry out co-occurrence analysis, keyword burst detection, and co-citation analysis. The results show that the research in this field presents a multidisciplinary and cross-disciplinary state, involving multiple disciplines such as Nuclear Science and Technology, Engineering Mechanics, and Energy and Fuels. The “International Journal of Hydrogen Energy”, “International Journal of Pressure Vessels and Piping”, and “Nuclear Engineering and Design” are the primary publication outlets in this domain. The study identifies three major research hotspots: (1) the safety performance of pressure vessels and piping, (2) structural integrity, failure mechanisms, and stress analysis, and (3) numerical simulation and thermal–hydraulic analysis under various operating conditions. The current challenges can be summarized into three aspects: (1) addressing the safety risks brought by new technologies and materials, (2) promoting innovation and the application of detection and monitoring technologies, and (3) strengthening the building capacity for accident prevention and emergency management. Specific to China, the current challenges include the safety and management of aging equipment, the effective detection of circumferential weld cracks, the refinement of risk assessment models, and the advancement of smart technology applications. These findings offer valuable insights for advancing safety practices and guiding future research in this multidisciplinary field. Full article

High-temperature furnaces and coal-fired boilers are widely employed in the petrochemical and metal-smelting sectors. Over time, the deterioration, corrosion, and wear of pipelines can lead to equipment malfunctions and safety incidents. Nevertheless, effective real-time monitoring of equipment conditions remains insufficient, primarily due to the interference caused by flames generated from fuel combustion. To address this issue, in this study, a through-flame infrared imager is developed based on the mid-wave infrared (MWIR) radiation characteristics of the flame. The imager incorporates a narrowband filter that operates within the wavelength range of 3.80 μm to 4.05 μm, which is integrated into conventional thermal imagers to perform flame filtering. This configuration enables the radiation from the background to pass through the flame and reach the detector, thereby allowing the infrared imager to visualize objects obscured by the flame and measure their temperatures directly. Our experimental findings indicate that the imager is capable of through-flame imaging; specifically, when the temperature of the target exceeds 50 °C, the imager can effectively penetrate the outer flame of an alcohol lamp and distinctly capture the target’s outline. Importantly, as the temperature of the target increases, the clarity of the target’s contour in the images improves. The MWIR through-flame imager presents considerable potential for the real-time monitoring and preventive maintenance of high-temperature furnaces and similar equipment, such as detecting the degradation of refractory materials and damage to pipelines. Full article

In the global energy mix by 2040, the growth in demand for oil and gas will be predominantly driven by the petrochemical sector across all regions of the world. The strong performance of this industry is anticipated to necessitate additional volumes of key feedstocks. Therefore, understanding the demand dynamics within the petrochemical sector is crucial for policy makers and industry stakeholders to make informed decisions regarding economic diversification, economic planning, and environmental sustainability. However, there is a notable lack of existing literature that explicitly addresses comprehensive regional and product-level demand modeling for petrochemical feedstocks. In this context, this study aims to estimate the demand for four main petrochemical feedstocks (Naphtha, Ethane, Liquefied Petroleum Gas (LPG), and other petrochemical feedstocks) across eight regions of the world. By estimating a total of 30 equations for price and income elasticities of demand in both the short and long term, the study provides detailed insights into the factors driving demand across different regions. The results demonstrate the robustness of the model, with good econometric properties and significant coefficients. In-sample regional simulations revealed small percentage errors across all regional equations, highlighting the model’s accuracy in tracking historical data. For each of the four feedstocks, an aggregate world equation—in other words, one single econometric world equation for each of the four petrochemical feedstocks’ categories mentioned earlier—was also estimated and compared against the aggregation of the regional simulations, with the latter found to track the history of global petrochemical feedstock demand better in-sample than a single econometric world equation. Overall, the study offers valuable contributions to the existing literature by filling a gap in comprehensive demand modeling for petrochemical feedstocks. It underscores the importance of regional and product-level analyses in understanding global demand patterns and informing strategic decisions in the industry. Full article

The production and use of hydrogen are encouraged by the European Union through Delegated Acts, especially in sectors that are difficult to decarbonize, such as the industrial and transport sectors. This study analyzes the possibility of partial decarbonization of the existing plant in the petrochemical industry, with a partial transition from natural gas to renewable hydrogen, as a precursor to the adoption of the hydrogen economy by 2050. This study was based on the example of a plant from the petrochemical industry, namely an existing fertilizer plant. Namely, in the petrochemical industry, hydrogen is produced by steam-reforming natural gas, which is needed in the process of producing ammonia, one of the basic raw materials for mineral fertilizers. By building an electrolyzer at the location of the existing fertilizer plant, it is possible to obtain renewable hydrogen, which enters the ammonia production process as a raw material. The electricity from which hydrogen is produced in the electrolyzer is provided through Power Purchase Agreement contracts concluded with electricity producers from 12 wind power plants. The results of this study show that the production of renewable hydrogen at the location of the analyzed plant is not profitable, but due to the specificity of the process of such an industry, the high consumption of natural gas, and large savings in CO₂ emissions which can be achieved by the production of renewable hydrogen, investment is needed. With a 370 MW electrolyzer, about 31,000 tons of renewable hydrogen is produced, which represents about 50% of the hydrogen needs of the analyzed plant. By producing renewable hydrogen for part of the needs of the analyzed plant, a saving of about 300,000 tons of CO₂ emissions is achieved in relation to the production of gray hydrogen, which contributes to the partial decarbonization of the analyzed plant. The authors are aware that the current market opportunities do not allow the profitability of the investment without subsidies, but with the advancement of technology and a different price ratio of electricity, natural gas, and CO₂ emissions, they believe that such investments will be profitable even without subsidies. Full article