Search Results (16)

Kelvin–Helmholtz (K–H) instabilities play an important role in mixing and entrainment processes in stratified and sediment-laden flows, while their development can be affected by particle properties and rheological contrasts. In this study, a two-phase numerical framework is used to investigate the onset and nonlinear evolution of K–H billows in sediment-laden shear layers. The governing equations are solved using a finite-volume approach with second-order TVD discretization, and the effects of the Richardson number ($Ri$), sediment particle size, and viscosity ratio (W) are examined systematically. In addition to concentration, vorticity, and interphase slip-velocity fields, a box-counting dimension (BCD) diagnostic is introduced as a complementary measure to quantify the instability onset time, the effective growth-start time, and the maximum geometrical growth rate of the sediment–water interface. The results show that, within the tested parameter range, coherent instabilities develop for $Ri\lesssim 0.25$. Decreasing $Ri$ leads to earlier BCD-based onset, shorter effective growth intervals, larger BCD growth rates, and stronger vortical structures. Sediment granulometry also affects the instability evolution: fine silt-like particles delay the onset and produce broader, more diffuse vortical structures, whereas fine-sand-like particles promote earlier destabilization and more compact billows. The viscosity ratio W modifies the vortex morphology, with high viscosity contrast reducing peripheral deformation and concentrating vorticity within the core region. These findings complement classical descriptions of stratified shear instabilities by highlighting the additional effects of sediment granulometry and rheological contrast. The proposed BCD-based diagnostic provides a practical quantitative tool for comparing interfacial growth in sediment-laden shear flows relevant to estuarine, coastal, and hydraulic engineering applications. Full article

Semi-open impeller sewage pumps are widely used for transporting solid-laden fluids due to their anti-clogging properties. However, unlike extensive research on clear water conditions, the specific mechanisms governing pressure instabilities under solid–liquid two-phase flows remain underexplored. This study investigates the unsteady flow field and pulsation characteristics of a Model 80WQ4QG pump using unsteady CFD simulations based on the Standard k−ϵ turbulence model and the Eulerian–Eulerian multiphase model. The effects of flow rate, particle size, and volume fraction were systematically analyzed. Results indicate that the blade-passing frequency (95 Hz) dominates the pressure spectra, with the volute tongue and impeller outlet identified as the most sensitive regions. While increased flow rates weaken fluctuations at the volute tongue, the presence of solid particles significantly amplifies them. Specifically, compared to single-phase flow, the pulsation amplitudes at the volute tongue increased by 68.15% with a 3.0 mm particle size and by 97.73% at a 20% volume fraction. Physically, this amplification is attributed to the intensified momentum exchange between phases and the enhanced turbulent flow disturbances induced by particle inertia at the rotor–stator interface. These findings clarify the particle-induced flow instability mechanisms, offering theoretical guidelines for optimizing pump durability in multiphase environments. Full article

The Yellow River, with its extremely high sediment loads, and the Yellow River Estuary (YRE) serve as a vital conduit for material exchange between land and marine environments, where sediment–phosphorus interactions profoundly influence nutrient cycling, ecological health and eutrophication potential. This paper reviews the distribution of phosphorus in overlying water and sediment, the characteristics of phosphorus migration and transformation across the sediment–water interface, and the effecting factors of phosphorus migrate, such as sediment properties and environmental factors in the YRE. Inorganic phosphorus was the dominant form in the overlying water and sediment. Suspended sediment acts as a dynamic reservoir for phosphorus transportation in the YRE. The dynamic estuarine environment promotes sediment deposition, which helps reduce phosphorus levels in the water. Upon entering the Bohai Sea, sediment is transformed into the source of phosphorus. The released phosphorus may increase the nutrient load in shallow Bohai Sea waters. Fine particles demonstrate strong adsorption capacity for reactive phosphorus, acting as the primary carriers for phosphorus migration at the sediment–water interface. The grain size of the suspended sediment in the Yellow River exhibited significant sorting characteristics with varying sediment content, consequently affecting the forms of phosphorus. Likewise, the influence of biogeochemical conditions on the transport and transformation of sediment and phosphorus was further analyzed and the partial least squares-path model of related variables on estuarine phosphorus is constructed to interpret the behavior of sediment and phosphorus in the YRE. Finally, the current situation and indeterminacy of water quality models in the estuary were appraised. The priority of analyzing and revealing the environmental behaviors of phosphorus in a sediment-laden river estuary in the future was further proposed against the present deficiencies. This review holds significant practical importance for enhancing the assessment of ecological environment quality and ecological restoration in the YRE. Full article

This study presents a novel unresolved SPH-DEM coupling framework to investigate the complex interactions between rising gas bubbles and sinking solid particles in multiphase systems. Traditional numerical methods often struggle with large deformations, multiphase interfaces, and computational efficiency when simulating dense particle-laden flows. To address these challenges, the proposed model leverages SPH’s Lagrangian nature to resolve fluid motion and bubble dynamics, while the DEM captures particle–particle and particle–bubble interactions. An unresolved coupling strategy is introduced to bridge the scales between fluid and particle phases, enabling efficient simulations of large-scale systems with discrete bubbles/particles. The model is validated against benchmark cases, including single bubbles rising and single particle’s sedimentation. Simulation studies reveal the effects of particle/bubble number and initial distance on phase interaction patterns and clustering behaviors. Results further illustrate the model’s capability to capture complex phenomena such as particle entrainment by bubble wakes and hindered settling in dense suspensions. The framework offers a robust and efficient tool for optimizing industrial processes like mineral flotation, where bubble–particle dynamics play a critical role. Full article

Nitrile Butadiene Rubber (NBR) is commonly used in ships’ water-lubricated tail bearings. However, sediment in the water significantly affects these bearings’ friction and wear performance. This study investigates NBR test blocks’ friction and wear behavior in conjunction with ZCuSn10Zn2 copper ring friction pairs within a sediment-laden water lubrication environment. Two primary factors were considered: sediment particle concentration and sediment particle size. Friction and wear tests were conducted under pure water and sediment-laden conditions using the ZY-1 ring block friction and wear tester. The friction coefficients, wear quantities, and variations in mass concentrations and sediment particle sizes were measured and compared. The surface morphology of the test blocks was analyzed using a laser confocal microscope. The findings indicate that as sediment concentration increases, the particle size’s impact on NBR’s abrasive wear diminishes. The variation in particle size directly influences the number of particles that penetrate the interface between the friction partners and the nature of three-body wear. Conversely, changes in particle concentration primarily affect the extent of wear; specifically, both the wear volume and the average coefficient of friction of the NBR specimens increase with rising sediment concentration. The wear mechanisms observed on the surface of the NBR test blocks are predominantly characterized by micro-cutting, rolling wear, and the coexistence of both wear modes. This study offers valuable insights for the design and optimization of water-lubricated bearings. Full article

The behavior of colloidal particles near fluid interfaces has attracted significant scientific interest, as particles minimize the contact area between the two fluid phases, stabilizing interfacial systems. This study explores the influence of surface roughness on the properties of particle monolayers at the air–water interface, focusing on colloidal silica particles and fumed silica particles of similar hydrodynamic diameter. This research involves comparing low-surface-area (LSA) and medium-surface-area (MSA) fumed silica particles with spherical colloidal silica particles (250 nm in diameter). Utilizing a Langmuir trough, the interfacial particle networks are compressed and expanded. Analysis of surface pressure isotherms reveals that fumed silica particle monolayers form networks at a lower particle surface coverage compared to spherical particles. The spherical particle monolayer exhibits a higher apparent surface elasticity, indicating greater resistance to the applied compression compared to fumed silica networks. Additionally, monolayers formed by fumed silica particles display hysteresis even after successive compressions and expansions due to irreversible particle interlocking and the formation of multilayered aggregates. These findings provide insights into the impact of surface roughness on the behavior of particle monolayers at fluid interfaces, offering valuable information for designing and optimizing mechanisms involved in emulsion and foam stabilization. Full article

This study investigates the surface modification of hydrophilic silica nanoparticles by non-chemical adsorption of an amphiphilic triblock copolymer, Pluronic F-127, and elucidates its influence on the interfacial dispersion properties. The interaction between Pluronic F-127 and silica nanoparticles drives the formation of copolymer-decorated particles with increased hydrodynamic diameter and reduced effective charge as the copolymer concentration increases, while the opposite effect occurs as the particle concentration increases at a fixed polymer concentration. This indicates that increasing the copolymer concentration leads to an increase in the coating density, whereas increasing the particle concentration leads to a decrease. This is of paramount importance for modulating the reorganization of the Pluronic F-127 shell upon adsorption at fluid–fluid interfaces and, thus, the adsorption of the decorated nanoparticles at the interface and the rheological properties of the obtained layers. In fact, the relationship between copolymer concentration and interfacial tension, as well as the mechanical response of the interface, mirrors the patterns observed in Pluronic F-127 solutions, and only a shift mediated by the Pluronic F-127 concentration is found. This suggests that the presence of particles limits the space available for Pluronic F-127 molecules to reorganize at the interface but does not significantly affect the interfacial behavior of the particle-laden interface. Full article

The inflammatory-associated corrosion of metallic dental and orthopedic implants causes significant complications, which may result in the implant’s failure. The corrosion resistance can be improved with coatings and surface treatments, but at the same time, it might affect the ability of metallic implants to undergo proper osteointegration. In this work, alginate hydrogels with and without octacalcium phosphate (OCP) were made on 3D-printed (patterned) titanium alloys (Ti Group 2 and Ti-Al-V Group 23) to enhance their anticorrosion properties in simulated normal, inflammatory, and severe inflammatory conditions in vitro. Alginate (Alg) and OCP-laden alginate (Alg/OCP) hydrogels were manufactured on the surface of 3D-printed Ti substrates and were characterized with wettability analysis, XRD, and FTIR. The electrochemical characterization of the samples was carried out with open circuit potential, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS). It was observed that the hydrophilicity of Alg/OCP coatings was higher than that of pure Alg and that OCP phase crystallinity was increased when samples were subjected to simulated biological media. The corrosion resistance of uncoated and coated samples was lower in inflammatory and severe inflammatory environments vs. normal media, but the hydrogel coatings on 3D-printed Ti layers moved the corrosion potential towards more nobler values, reducing the corrosion current density in all simulated solutions. These measurements revealed that OCP particles in the Alg hydrogel matrix noticeably increased the electrical charge transfer resistance at the substrate and coating interface more than with Alg hydrogel alone. Full article

Silica nanoparticles find utility in different roles within the commercial domain. They are either employed in bulk within pharmaceutical formulations or at interfaces in anti-coalescing agents. Thus, studying the particle attributes contributing to the characteristics of silica particle-laden interfaces is of interest. The present work highlights the impact of particle size (i.e., 250 nm vs. 1000 nm) on the rheological properties of interfacial networks formed by hydrophobically modified silica nanoparticles at the air–water interface. The particle surface properties were examined using mobility measurements, Langmuir trough studies, and interfacial rheology techniques. Optical microscopy imaging along with Langmuir trough studies revealed the microstructure associated with various surface pressures and corresponding surface coverages ($\varphi$). The 1000 nm silica particle networks gave rise to a higher surface pressure at the same coverage compared to 250 nm particles on account of the stronger attractive capillary interactions. Interfacial rheological characterization revealed that networks with 1000 nm particles possess higher surface modulus and yield stress in comparison to the network obtained with 250 nm particles at the same surface pressure. These findings highlight the effect of particle size on the rheological characteristics of particle-laden interfaces, which is of importance in determining the stability and flow response of formulations comprising particle-stabilized emulsions and foams. Full article

Hybrid nanoparticles that combine special properties of their different parts have numerous applications in electronics, optics, catalysis, medicine, and many others. Of the currently produced particles, Janus particles and ligand-tethered (hairy) particles are of particular interest both from a practical and purely cognitive point of view. Understanding their behavior at fluid interfaces is important to many fields because particle-laden interfaces are ubiquitous in nature and industry. We provide a review of the literature, focusing on theoretical studies of hybrid particles at fluid–fluid interfaces. Our goal is to give a link between simple phenomenological models and advanced molecular simulations. We analyze the adsorption of individual Janus particles and hairy particles at the interfaces. Then, their interfacial assembly is also discussed. The simple equations for the attachment energy of various Janus particles are presented. We discuss how such parameters as the particle size, the particle shape, the relative sizes of different patches, and the amphiphilicity affect particle adsorption. This is essential for taking advantage of the particle capacity to stabilize interfaces. Representative examples of molecular simulations were presented. We show that the simple models surprisingly well reproduce experimental and simulation data. In the case of hairy particles, we concentrate on the effects of reconfiguration of the polymer brushes at the interface. This review is expected to provide a general perspective on the subject and may be helpful to many researchers and technologists working with particle-laden layers. Full article

Rational design of thermotropic liquid crystal (LC)-based sensors utilizing different mesophases holds great promise to open up novel detection modalities for various chemical and biological applications. In this context, we present a dissipative particle dynamics study to explore the unique anchoring behavior of nematic and smectic LCs at amphiphile-laden aqueous-LC interface. By increasing the surface coverage of amphiphiles, two distinct anchoring sequences, a continuous planar-tilted-homeotropic transition and a discontinuous planar-to-homeotropic transition, can be observed for the nematic and smectic LCs, respectively. More importantly, the latter occurs at a much lower surface coverage of amphiphiles, demonstrating an outstanding sensitivity for the smectic-based sensors. The dynamics of reorientation further reveals that the formation of homeotropic smectic anchoring is mainly governed by the synchronous growth of smectic layers through the LCs, which is significantly different from the mechanism of interface-to-bulk ordering propagation in nematic anchoring. Furthermore, the smectic LCs have also been proven to possess a potential selectivity in response to a subtle change in the chain rigidity of amphiphiles. These simulation findings are promising and would be valuable for the development of novel smectic-based sensors. Full article

The assembly of soft colloidal particles at fluid interfaces is reviewed in the present paper, with emphasis on the particular case of microgels formed by cross-linked polymer networks. The dual polymer/colloid character as well as the stimulus responsiveness of microgel particles pose a challenge in their experimental characterization and theoretical description when adsorbed to fluid interfaces. This has led to a controversial and, in some cases, contradictory picture that cannot be rationalized by considering microgels as simple colloids. Therefore, it is necessary to take into consideration the microgel polymer/colloid duality for a physically reliable description of the behavior of the microgel-laden interface. In fact, different aspects related to the above-mentioned duality control the organization of microgels at the fluid interface, and the properties and responsiveness of the obtained microgel-laden interfaces. This works present a critical revision of different physicochemical aspects involving the behavior of individual microgels confined at fluid interfaces, as well as the collective behaviors emerging in dense microgel assemblies. Full article

The use of the Janus motif in colloidal particles, i.e., anisotropic surface properties on opposite faces, has gained significant attention in the bottom-up assembly of novel functional structures, design of active nanomotors, biological sensing and imaging, and polymer blend compatibilization. This review is focused on the behavior of Janus particles in interfacial systems, such as particle-stabilized (i.e., Pickering) emulsions and foams, where stabilization is achieved through the binding of particles to fluid interfaces. In many such applications, the interface could be subjected to deformations, producing compression and shear stresses. Besides the physicochemical properties of the particle, their behavior under flow will also impact the performance of the resulting system. This review article provides a synopsis of interfacial stability and rheology in particle-laden interfaces to highlight the role of the Janus motif, and how particle anisotropy affects interfacial mechanics. Full article

Janus droplets can function as excellent templates for fabricating physically and chemically anisotropic particles. Here, we report new surfactant-laden Janus droplets with curvature controllability and enhanced stability against coalescence, suitable for fabricating shape-anisotropic polymer microparticles. Using a microfluidic flow-focusing device on a glass chip, nanoliter-sized biphasic droplets, comprising an acrylate monomer segment and a silicone-oil (SO) segment containing a surfactant, were produced in a co-flowing aqueous polyvinyl alcohol (PVA) solution. At equilibrium, the droplets formed a Janus geometry based on the minimization of interfacial energy, and each of the two Janus segments were uniform in size with coefficient-of-variation values below 3%. By varying the concentration of the surfactant in the SO phase, the curvature of the interface between the two lobes could be shifted among concave, planar, and convex shapes. In addition, the Janus droplets exhibited significantly improved stability against coalescence compared with previously reported Janus droplets carrying no surfactant that coalesced rapidly. Finally, via off-chip photopolymerization, concave-convex, planar-convex, and biconvex lens-shaped particles were fabricated. Full article

Over the last two decades, understanding of the attachment of colloids to fluid interfaces has attracted the interest of researchers from different fields. This is explained by considering the ubiquity of colloidal and interfacial systems in nature and technology. However, to date, the control and tuning of the assembly of colloids at fluid interfaces remain a challenge. This review discusses some of the most fundamental aspects governing the organization of colloidal objects at fluid interfaces, paying special attention to spherical particles. This requires a description of different physicochemical aspects, from the driving force involved in the assembly to its thermodynamic description, and from the interactions involved in the assembly to the dynamics and rheological behavior of particle-laden interfaces. Full article