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19 pages, 6191 KB  
Article
Effect of Rubber Fiber Content on the Mechanical Properties of Calcareous Sand
by Yuzhu Cheng, Hansheng Geng, Lei Wang, Yang Wang, Guoyue Yang, Yongsheng Xie, Linjian Ma and Chun Li
J. Compos. Sci. 2025, 9(11), 578; https://doi.org/10.3390/jcs9110578 (registering DOI) - 27 Oct 2025
Abstract
The application of rubber in geotechnical engineering has gained widespread popularity due to its potential to enhance the engineering properties of foundation fills while reducing environmental pollution. This study focuses on investigating the influence of the rubber fiber content on the performance of [...] Read more.
The application of rubber in geotechnical engineering has gained widespread popularity due to its potential to enhance the engineering properties of foundation fills while reducing environmental pollution. This study focuses on investigating the influence of the rubber fiber content on the performance of calcareous sand by conducting a series of triaxial tests. The effects of the rubber fiber content and axial pressure on the strength, deformation, permeability, and particle breakage of rubber–calcareous sand were systematically studied. The experimental results reveal that increasing the rubber fiber content reduces the strength of rubber–calcareous sand, but it also inhibits the shear dilation and mitigates the occurrence of rupture surfaces: the sample with a rubber content of more than 10% only has shear-contraction. Both the rubber fiber content and axial stress contribute to the increased impermeability of rubber-modified calcareous sand, although they exhibit different characteristics. The relationship between the rubber fiber content and permeability coefficient is linear, while, under increasing axial stress, the permeability coefficient initially decreases rapidly; when the deviatoric stresses exceeds 1000 kPa, the decreasing rate slows down. Furthermore, rubber fiber significantly reduces particle breakage in calcareous sand. The relationship between the input energy applied to rubber-modified calcareous sand and the relative breakage rate of calcareous sand can be well-fitted with a power function. Samples with a higher rubber fiber content exhibit a lower relative breakage rate of calcareous sand under the same absorbed input energy. Through the research results of this paper, the best rubber ratio can be selected as the road filler in engineering practice to ensure both cost-effectiveness and environmental protection. Full article
(This article belongs to the Special Issue Composite Materials for Civil Engineering Applications)
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17 pages, 2869 KB  
Article
Vehicle Indoor Air Quality Due to External Pollutant Ingress While Driving
by Ho-Hyeong Yang, In-Ji Park, Cha-Ryung Kim, Hyun-Woo Lee and Ho-Hyun Kim
Atmosphere 2025, 16(11), 1238; https://doi.org/10.3390/atmos16111238 - 27 Oct 2025
Abstract
Vehicle indoor air quality (VIAQ) remains poorly standardized despite its growing health relevance. This study developed and applied a real-road test protocol to quantify in-cabin exposure to particulate and gaseous pollutants under different heating, ventilation, and air-conditioning (HVAC) modes: outside air (OA), recirculation [...] Read more.
Vehicle indoor air quality (VIAQ) remains poorly standardized despite its growing health relevance. This study developed and applied a real-road test protocol to quantify in-cabin exposure to particulate and gaseous pollutants under different heating, ventilation, and air-conditioning (HVAC) modes: outside air (OA), recirculation (RC), and automatic (Auto). Concentrations of PM2.5, particle number (PN), NO, and NO2 were simultaneously measured inside and outside passenger vehicles using validated instruments. In-cabin PM2.5 levels were lowest in RC, intermediate in Auto, and highest in OA, showing strong HVAC dependence. Particle number distributions were dominated by submicron particles (<1.0 μm). Under RC, NO gradually increased while NO2 decreased, likely due to NO–NO2 interconversion and activated-carbon filtration. Short-duration, reproducible on-road tests were conducted under standardized vehicle, occupant, and HVAC settings to minimize variability. Although external conditions could not be fully controlled, consistent routes and configurations ensured comparability. The findings highlight HVAC operation as the dominant factor governing short-term VIAQ and provide practical insight toward harmonized test procedures and design improvements for cabin air management. Full article
(This article belongs to the Section Air Quality)
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11 pages, 540 KB  
Perspective
Microplastics, Nanoplastics and Heart Contamination: The Hidden Threat
by Gian Luca Iannuzzi, Michele D’Alto, Giorgio Bosso, Antonio Pio Montella, Veronica D’Oria, Luigi Pellegrino, Giuseppe Boccaforno, Alessandro Masi, Antonio Orlando, Renato Franco, Andrea Ronchi, Carmine Nicastro and Marisa De Feo
J. Clin. Med. 2025, 14(21), 7618; https://doi.org/10.3390/jcm14217618 (registering DOI) - 27 Oct 2025
Abstract
The global spread of micro- and nanoplastics (MNPs) has emerged as an environmental and medical concern, with growing evidence of their role in cardiovascular disease (CVD). These particles, originating from the degradation of larger plastics and consumer products, can be ingested or inhaled, [...] Read more.
The global spread of micro- and nanoplastics (MNPs) has emerged as an environmental and medical concern, with growing evidence of their role in cardiovascular disease (CVD). These particles, originating from the degradation of larger plastics and consumer products, can be ingested or inhaled, cross biological barriers, and accumulate in human tissues, including blood, myocardium, and atherosclerotic plaques. Experimental and clinical studies suggest that MNPs contribute to CVD through multiple mechanisms: activation of systemic inflammation and inflammasomes, oxidative stress, endothelial dysfunction, prothrombotic activity, and direct myocardial injury, ultimately promoting fibrosis and impaired contractility. Epidemiological data further indicate that populations exposed to higher plastic pollution or with pre-existing cardiovascular risk factors may be particularly vulnerable. Taken together, these findings identify MNPs as a potential novel environmental cardiovascular risk factor. Advancing detection methods, mechanistic research, and public health strategies will be essential to mitigate their impact and reduce plastic-related cardiovascular burden. Full article
(This article belongs to the Section Cardiology)
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15 pages, 3730 KB  
Article
Hydroxyl Radical Generation in Heterogeneous Fenton Reaction and Its Interaction with Nanoplastics as Potential Advanced Oxidation Process
by Daryl Rafael Osuna-Laveaga, Alondra Micaela Silva-Téllez, Fernando Enrique Espinola-Portilla, Edgar David Moreno-Medrano and Jorge del Real-Olvera
Processes 2025, 13(11), 3447; https://doi.org/10.3390/pr13113447 - 27 Oct 2025
Abstract
Growing concern over nanoplastics as emerging pollutants calls for effective treatment methods, with advanced oxidation processes (AOPs) showing strong potential for their degradation. This study examines the interaction between polyethylene terephthalate nanoplastics (PET-NPs) and magnetite nanoparticles (MNPs) in a heterogeneous Fenton-like system, focusing [...] Read more.
Growing concern over nanoplastics as emerging pollutants calls for effective treatment methods, with advanced oxidation processes (AOPs) showing strong potential for their degradation. This study examines the interaction between polyethylene terephthalate nanoplastics (PET-NPs) and magnetite nanoparticles (MNPs) in a heterogeneous Fenton-like system, focusing on colloidal behavior, hydroxyl radicals (OH) generation, and potential degradation pathways. Zeta potential (ZP) and particle diameter measurements were used to characterize nanoparticle dispersion and aggregation mechanisms over a pH range of 3–9.5. The results revealed a pronounced pH-dependent stability, with MNPs exhibiting larger hydrodynamic diameters (283 nm) and lower stability at pH 3 (ZP: −9.8 mV) compared with neutral or alkaline conditions (189 nm; ZP: −44 to −42 mV). PET-NPs exhibited minimal agglomeration at a pH of 9.5 (ZP: −25.6 mV). Unlike conventional Fenton systems, OH production peaked at pH 7–9.5 (0.3–0.35 μM), attributed to preserved Fe2+ sites and reduced particle agglomeration. Although PET-NPs resisted oxidative degradation, their aggregation with MNPs enabled magnetic recovery (46% efficiency at pH 3) through charge screening, Fe3+/Fe2+ bridging, and hydrophobic interactions. These findings highlight MNPs’ potential for sustainable nanoplastic separation and emphasize the need for optimized catalysts to enhance OH-driven degradation. Overall, this work advances understanding of nanoplastic–magnetite interactions and offers insights into AOP applications. Full article
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16 pages, 3387 KB  
Article
Enhancement of Arsenic Release from Amorphous Arsenic-Containing Ferric Hydroxides Systems Using Bacterial Reduction: Applicability of Injecting Iron-Reducing Bacteria for Dissolved Arsenic Species and Colloid Phases
by Dayong Luo, Xiaosong Tian and Ruxiang Qin
Minerals 2025, 15(11), 1115; https://doi.org/10.3390/min15111115 - 27 Oct 2025
Abstract
It has been demonstrated that iron-reducing bacteria (IRB) Acidiphilium cryptum JF-5 (Alphaproteobacteria) could release arsenic from secondary iron oxyhydroxides in mine areas. This study used injecting IRB technology to carry out arsenic sequestration experiments aimed at alleviating arsenic pollution. Temperature and acetate were [...] Read more.
It has been demonstrated that iron-reducing bacteria (IRB) Acidiphilium cryptum JF-5 (Alphaproteobacteria) could release arsenic from secondary iron oxyhydroxides in mine areas. This study used injecting IRB technology to carry out arsenic sequestration experiments aimed at alleviating arsenic pollution. Temperature and acetate were found to enhance arsenic release from amorphous arsenic-containing hydroxides. A suitable temperature (35 °C) increased the release of arsenic(III) and arsenic(V) by more than 1.9–2.5 and 1.1–1.3 times, respectively. The addition of acetate increased arsenic(III) and arsenic(V) release by more than 2.8–6.1 and 1.1–1.3 times, respectively, compared to the control group. After injecting IRB into amorphous arsenic-containing hydroxide sediment, arsenic associated with particles/colloid was reductively released with aqueous arsenic(III) and arsenic(V), which account for 4%–334% of aqueous arsenic(III) and 6%–332% of aqueous arsenic(V), respectively. Results from the suspension solid also showed that the average values for the lower and upper sites are 131 mg/L and 118 mg/L, respectively. These suspension solids contain rich iron. The effectiveness of this IRB-assisted arsenic release technology became better under suitable temperature (35 °C) than at low temperature (8 °C) due to biological activity. These results suggest that microbially assisted reduction using iron-reducing bacteria may effectively release arsenic by sequestrating arsenic as aqueous and particle/colloidal phases. Full article
(This article belongs to the Special Issue Arsenic Pollution: Sources, Speciation and Remediation Strategies)
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20 pages, 2836 KB  
Review
Human Body Malodor and Deodorants: The Present and the Future
by Hyun Tae Son, Hyo-Seung Choi, Seung-Sik Cho and Dae-Hun Park
Int. J. Mol. Sci. 2025, 26(21), 10415; https://doi.org/10.3390/ijms262110415 - 27 Oct 2025
Abstract
Human axillary malodor negatively influences impression-related appearance, confidence, and hygiene, and ultimately decreases quality of life. Malodor formation involves three steps: vesiculation of odorless precursors within the human body, influx of these precursors into the intracellular space of bacteria, such as Corynebacterium striatum [...] Read more.
Human axillary malodor negatively influences impression-related appearance, confidence, and hygiene, and ultimately decreases quality of life. Malodor formation involves three steps: vesiculation of odorless precursors within the human body, influx of these precursors into the intracellular space of bacteria, such as Corynebacterium striatum and Staphylococcus hominis, and efflux of malodorous metabolites into the axilla after conversion by axillary malodor-releasing enzymes (AMREs). Malodor deodorants are currently in use, and their formulation strategies, based on the ingredients, can be classified as follows: anti-sweating, antiproliferation of malodor-forming bacteria, masking (neutralizing) effects against malodor, and deodorization. However, current deodorants have several adverse effects. To reduce such effects while enhancing malodor suppression, a strategy targeting the specific step in malodor formation should be developed, such as the use of ABCC11 pump inhibitors, specific bacterial active pump controllers, and AMRE blockers. Full article
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28 pages, 2764 KB  
Review
Cellulose-Based Biopolymers from Banana Pseudostem Waste: Innovations for Sustainable Bioplastics
by Alice Waithaka, Sofia Plakantonaki, Kyriaki Kiskira, Ann W. Mburu, Ioannis Chronis, Georgios Zakynthinos, John Githaiga and Georgios Priniotakis
Waste 2025, 3(4), 37; https://doi.org/10.3390/waste3040037 (registering DOI) - 25 Oct 2025
Viewed by 117
Abstract
Plastic materials are widely used for packaging due to their versatility and availability. Global production, mainly from petrochemicals, is estimated at 380 million tons, increasing annually by 4%. Packaging plastics have the shortest lifespan and contribute significantly to environmental pollution. Current production, use, [...] Read more.
Plastic materials are widely used for packaging due to their versatility and availability. Global production, mainly from petrochemicals, is estimated at 380 million tons, increasing annually by 4%. Packaging plastics have the shortest lifespan and contribute significantly to environmental pollution. Current production, use, and disposal of these plastics harm the environment, hu-mans, and ecosystems. Microplastics, (plastics particles ranging from 1 µm to 5 mm) formed through degradation, accumulate in ecosystems and the human body, including the brain. Bioplastics and biodegradable polymers from biological sources are a sustainable alternative; however, most production still relies on food crops, raising concerns about food security and sustainability. Utilizing organic wastes reduces production costs, lessens pressure on food systems, and supports waste management efforts. Cellulose, an abundant natural polymer, offers strong potential due to biodegradability, availability, and mechanical properties. This review explores extracting cellulose from banana pseudostem waste for packaging, high-lighting extraction and conversion methods and characterization via FTIR, TGA, SEM, XRD, and mechanical testing. FTIR confirmed the effective removal of lignin and hemicellulose, XRD revealed increased crystallinity corresponding to Type I cellulose, SEM showed a roughened fiber surface after alkaline treatment, and TGA indicated high thermal stability up to 250 °C. The goal is eco-friendly packaging by promoting agrowaste use. Further research should improve performance and scalability of cellulose-based bioplastics to meet industry needs and compete effectively with conventional plastics. Full article
(This article belongs to the Special Issue Agri-Food Wastes and Biomass Valorization—2nd Edition)
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22 pages, 3242 KB  
Article
Evaluation of the Presence of Microplastics in Wastewater Treatment Plants: Development and Verification of Strategies for Their Quantification and Removal in Aqueous Streams
by Ana Belén Lozano Avilés, Ginés Morales Méndez and Francisco del Cerro Velázquez
Sustainability 2025, 17(21), 9470; https://doi.org/10.3390/su17219470 (registering DOI) - 24 Oct 2025
Viewed by 141
Abstract
Water is an essential resource whose quality is threatened by emerging pollutants, including microplastics (MP), whose persistence, bioaccumulation capacity and ecotoxic potential pose a growing risk to ecosystems and human health. Wastewater treatment plants (WWTPs) have been identified as one of the main [...] Read more.
Water is an essential resource whose quality is threatened by emerging pollutants, including microplastics (MP), whose persistence, bioaccumulation capacity and ecotoxic potential pose a growing risk to ecosystems and human health. Wastewater treatment plants (WWTPs) have been identified as one of the main sources of these pollutants, as conventional treatments are insufficient to remove them completely. In response to this problem and with the aim of finding more efficient and sustainable solutions, a study has been carried out at WWTP with a pilot MP capture plant capable of detecting, quantifying and removing these particles from different wastewater sources with high precision and sustainability. This proposal represents a significant advance in the mitigation of invisible pollution, contributing to the protection of the environment and public health, achieving an efficiency of over 80% in the removal of plastic particles. This system not only addresses the challenge of environmental protection but also represents an unavoidable commitment to a healthier, more equitable, and sustainable development model for current and future generations, directly contributing to strategic action to advance the fulfillment of several Sustainable Development Goals (SDGs) promoted by the UN (SDG 3, SDG 6, SDG 12, SDG 14 and SDG 15). Full article
(This article belongs to the Section Sustainable Water Management)
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20 pages, 1471 KB  
Article
Capacity of Microbial Strains and Communities to Degrade Sewerage Fats, Oils, and Grease Clog Deposits
by Allondra M. Woods, Catherine J. Pettinger, Catherine Harris, Tanya Soule, Garth Farley and Erica L.-W. Majumder
Appl. Microbiol. 2025, 5(4), 116; https://doi.org/10.3390/applmicrobiol5040116 - 24 Oct 2025
Viewed by 95
Abstract
Fats, oils, and grease (FOG) deposits are hardened, sticky, insoluble solids that accumulate in sewage systems globally. These deposits contribute to pipe blockages and sanitary sewer overflows, releasing pathogens and pollutants into the environment, posing significant environmental and public health risks. Current removal [...] Read more.
Fats, oils, and grease (FOG) deposits are hardened, sticky, insoluble solids that accumulate in sewage systems globally. These deposits contribute to pipe blockages and sanitary sewer overflows, releasing pathogens and pollutants into the environment, posing significant environmental and public health risks. Current removal methods are labor-intensive and costly, emphasizing the need for alternatives. While biological strategies offer a viable alternative, the microbial breakdown of FOG is poorly understood. In this study, we evaluated the potential of individual microbial strains and synthetic microbial communities to biodegrade wastewater-derived FOG deposit samples. These biological agents were applied to a range of FOG samples, and biodegradation was assessed through visual observations such as color change or gas bubbles, particle size, cell counts, pH, weight loss, and changes in fatty acid profile. Results demonstrate that microbial augmentation can enhance FOG degradation, offering an alternative or complementary approach for reducing maintenance burdens and preventing sewer blockages. Full article
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26 pages, 652 KB  
Review
Coagulation–Sedimentation in Water and Wastewater Treatment: Removal of Pesticides, Pharmaceuticals, PFAS, Microplastics, and Natural Organic Matter
by Ewelina Łukasiewicz
Water 2025, 17(21), 3048; https://doi.org/10.3390/w17213048 - 24 Oct 2025
Viewed by 421
Abstract
Coagulation–sedimentation remains a widely used process in drinking and wastewater treatment, yet its performance for emerging contaminants requires further evaluation. This review summarizes recent advances in conventional and novel coagulant systems for the removal of pesticides, pharmaceuticals, per- and polyfluoroalkyl substances (PFAS), natural [...] Read more.
Coagulation–sedimentation remains a widely used process in drinking and wastewater treatment, yet its performance for emerging contaminants requires further evaluation. This review summarizes recent advances in conventional and novel coagulant systems for the removal of pesticides, pharmaceuticals, per- and polyfluoroalkyl substances (PFAS), natural organic matter (NOM), and micro- and nanoplastics (MNPs). The efficiency of conventional aluminum- and iron-based coagulants typically ranges from 30–90% for NOM and pesticides, 10–60% for pharmaceuticals, <20% for PFAS, and up to 95% for microplastics. Modified and hybrid materials, including titanium-based and bio-derived coagulants, demonstrate superior performance through combined mechanisms of charge neutralization, adsorption, and complexation. The zeta potential of particles was identified as a key factor in optimizing MNP removal. The ability of iron and titanium to form complexes with organic ligands significantly influences the removal of organic pollutants and metal–organic interactions in water matrices. While most research remains at the laboratory scale, promising developments in hybrid and electrocoagulation systems indicate potential for field-scale application. The review highlights that coagulation is best applied as a pretreatment step in integrated systems, enhancing subsequent adsorption, oxidation, or membrane processes. Future studies should focus on large-scale validation, energy efficiency, and the recovery of metal oxides (e.g., TiO2) from residual sludge to improve sustainability. Full article
(This article belongs to the Section Wastewater Treatment and Reuse)
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20 pages, 581 KB  
Review
Cellular Impact of Micro(nano)plastics on Human Health: A Review
by Longxiao Liu, Pengcheng Tu, Huixia Niu, Xueqing Li, Xin Gong, Zhijian Chen, Mingluan Xing, Lizhi Wu and Xiaoming Lou
Toxics 2025, 13(11), 913; https://doi.org/10.3390/toxics13110913 (registering DOI) - 23 Oct 2025
Viewed by 252
Abstract
Micro(nano)plastics (MNPs), as a globally emerging environmental pollutant, are now ubiquitous in natural environments and can continuously enter the human body through ingestion, inhalation, and dermal contact. This widespread exposure has raised significant concerns regarding the potential health risks posed by MNPs. Although [...] Read more.
Micro(nano)plastics (MNPs), as a globally emerging environmental pollutant, are now ubiquitous in natural environments and can continuously enter the human body through ingestion, inhalation, and dermal contact. This widespread exposure has raised significant concerns regarding the potential health risks posed by MNPs. Although epidemiological studies are still in the early stages, accumulating in vitro cellular experiments have provided key evidence suggesting that nano- to micro-sized plastic particles can cross physiological barriers in the human body. These particles enter cells via endocytosis or direct penetration through the cell membrane, triggering toxic effects such as oxidative stress, immune responses, mitochondrial dysfunction, and DNA damage, which can potentially lead to cell apoptosis. These findings highlight that the direct interaction between MNPs and human cells could be a core mechanism underlying their potential health hazards. This review systematically summarizes the toxic effects of MNPs exposure on various human cell types, exploring the underlying molecular mechanisms and providing insights for future research into the toxicological impacts of MNPs and their implications for human health risk assessment. Full article
(This article belongs to the Section Emerging Contaminants)
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26 pages, 1979 KB  
Review
From Single-Sensor Constraints to Multisensor Integration: Advancing Sustainable Complex Ore Sorting
by Sefiu O. Adewuyi, Angelina Anani, Kray Luxbacher and Sehliselo Ndlovu
Minerals 2025, 15(11), 1101; https://doi.org/10.3390/min15111101 - 23 Oct 2025
Viewed by 294
Abstract
Processing complex ore remains a challenge due to energy-intensive grinding and complex beneficiation and pyrometallurgical treatments that consume large amounts of water whilst generating significant waste and polluting the environment. Sensor-based ore sorting, which separates ore particles based on their physical or chemical [...] Read more.
Processing complex ore remains a challenge due to energy-intensive grinding and complex beneficiation and pyrometallurgical treatments that consume large amounts of water whilst generating significant waste and polluting the environment. Sensor-based ore sorting, which separates ore particles based on their physical or chemical properties before downstream processing, is emerging as a transformative technology in mineral processing. However, its application to complex and heterogeneous ores remain limited by the constraints of single-sensor systems. In addition, existing hybrid sensor strategies are fragmented and a consolidated framework for implementation is lacking. This review explores these challenges and underscores the potential of multimodal sensor integration for complex ore pre-concentration. A multi-sensor framework integrating machine learning and computer vision is proposed to overcome limitations in handling complex ores and enhance sorting efficiency. This approach can improve recovery rates, reduce energy and water consumption, and optimize process performance, thereby supporting more sustainable mining practices that contribute to the United Nations Sustainable Development Goals (UNSDGs). This work provides a roadmap for advancing efficient, resilient, and next-generation mineral processing operations. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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18 pages, 4149 KB  
Article
Enhanced Chromite Recovery from Tailings via a Custom-Designed Shaking Table: Optimization and Performance
by Savas Ozun and Ahmet Kerim Guraslan
Minerals 2025, 15(11), 1100; https://doi.org/10.3390/min15111100 - 23 Oct 2025
Viewed by 210
Abstract
Significant chromite losses to tailings in gravity separation plants arise from both suboptimal separator design and inefficient beneficiation processes, posing major challenges to resource utilization, energy efficiency, and environmental sustainability. These losses are particularly critical because the material, already comminuted to liberation size, [...] Read more.
Significant chromite losses to tailings in gravity separation plants arise from both suboptimal separator design and inefficient beneficiation processes, posing major challenges to resource utilization, energy efficiency, and environmental sustainability. These losses are particularly critical because the material, already comminuted to liberation size, is discarded, leading to reduced concentrate yield, wasted energy input, and increased environmental pollution. To address this issue, an industrial-scale custom-designed shaking table was developed and tested to recover marketable-grade chromite concentrate (≥42% Cr2O3) from processing plant tailings containing 3.25%–4.25% Cr2O3, which had accumulated over years of chromite beneficiation. Experimental results showed that, under optimized operating parameters (320 rpm stroke frequency, 13 mm stroke length, 1° deck slope, 1300 g/L pulp density, 800 kg/h feed rate, and 7 tph wash water flow rate), Cr2O3 recovery increased from 8% to 27% for the first and second floor operations and from approximately 17% to 41% for the third and fourth floor operations compared with existing plant performance. The results revealed a strong interdependence between Cr2O3 recovery and concentrate grade, both of which are critical indicators of process efficiency. Intermediate particle sizes (−0.250 + 0.150 mm) provided the most favorable balance, yielding high recovery rates without substantially compromising the concentrated grade. Full article
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15 pages, 746 KB  
Article
Influence of Pristine and Photoaging Polystyrene Microspheres on Sperm Quality and DNA Integrity of the Sand Dollars Scaphechinus mirabilis
by Andrey Alexandrovich Mazur, Sergey Petrovich Kukla, Victor Pavlovich Chelomin, Valentina Vladimirovna Slobodskova and Nadezhda Vladimirovna Dovzhenko
J. Xenobiot. 2025, 15(6), 176; https://doi.org/10.3390/jox15060176 - 23 Oct 2025
Viewed by 207
Abstract
Plastic pollution represents a significant emerging environmental problem. Micro-sized particles of synthetic polymers—microplastics (MPs)—have been identified in all parts of marine ecosystems. In the marine environment, organisms are exposed to MPs, which undergo a constant process of physicochemical and biological degradation. Utilization of [...] Read more.
Plastic pollution represents a significant emerging environmental problem. Micro-sized particles of synthetic polymers—microplastics (MPs)—have been identified in all parts of marine ecosystems. In the marine environment, organisms are exposed to MPs, which undergo a constant process of physicochemical and biological degradation. Utilization of UV irradiation as the optimal exposure factor in the simulation of fundamental natural conditions is a widely accepted approach. This enables the study of the harmful effects of such particles when interacting with aquatic organisms. This study aimed to investigate the effect of pristine and photoaging primary polystyrene microspheres (µPS) at three concentrations on the viability and DNA integrity of the sperm of the sand dollars Scaphechinus mirabilis. The results of the investigation demonstrated that IR spectroscopy revealed structural changes in polystyrene, confirming the oxidative degradation of the polymer under UV irradiation. The study demonstrated that artificially aged µPS exhibited a more pronounced effect than pristine particles, as evidenced by reduced sperm viability and increased DNA damage. Thus, the resazurin test showed that after exposure to UV-irradiated µPS, sperm viability decreased to 83–85% at concentrations of 10 and 100 particles and to 70% at a concentration of 1000. In addition, the Comet assay showed that the particles increased the percentage of DNA in the tail from 20% to 30% in a dose-dependent manner. The findings substantiate and augment the existing body of experimental data of the toxicity of aged plastic fragments, thereby underscoring the need for further study into the toxicity of aged MPs on marine invertebrates. Full article
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28 pages, 5659 KB  
Article
Airborne Microplastics: Source Implications from Particulate Matter Composition
by Hiroyuki Sasaki, Tsukasa Takahashi, Mari Futami, Tomomi Endo, Mizuho Hirano, Yuka Kotake and Kim-Oanh Pham
Atmosphere 2025, 16(11), 1222; https://doi.org/10.3390/atmos16111222 - 22 Oct 2025
Viewed by 202
Abstract
Microplastics (MPs) are emerging pollutants detected in diverse environments and human tissues. Among them, airborne MPs (AMPs) remain poorly characterized due to limited data and methodological inconsistencies. Although regarded as analogous to particulate matter (PM), detailed comparisons with its components are scarce. To [...] Read more.
Microplastics (MPs) are emerging pollutants detected in diverse environments and human tissues. Among them, airborne MPs (AMPs) remain poorly characterized due to limited data and methodological inconsistencies. Although regarded as analogous to particulate matter (PM), detailed comparisons with its components are scarce. To address this gap, this study implemented a unified and seasonal protocol for simultaneous measurement of AMPs and PM across three sites in Japan. AMPs were identified using micro-Raman spectroscopy, enabling polymer- and morphology-resolved analysis. A total of 106 AMPs were identified across all sites and seasons. Polyethylene (PE) was consistently dominant, followed by polyethylene terephthalate (PET) and polyamide (PA). Site-specific variation was evident, with certain polymers being relatively more abundant depending on the local environment. Feret diameter analysis showed a modal range of 4–6 μm, with fragments predominating over granular and fibrous particles. Significant correlations between AMP concentrations and PM components were determined, including syringaldehyde (SYAL), tungsten (W), cobalt (Co), and chromium (Cr), suggesting links to local sources, while indicating that AMP dynamics are not always aligned with PM behavior. This study provides one of the first integrated datasets of AMPs and PM components, offering insights into their occurrence, sources, and atmospheric relevance. Full article
(This article belongs to the Special Issue Micro- and Nanoplastics in the Atmosphere)
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