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Keywords = nonsymmetric system

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30 pages, 10277 KiB  
Article
A Finite Element Formulation for True Coupled Modal Analysis and Nonlinear Seismic Modeling of Dam–Reservoir–Foundation Systems: Application to an Arch Dam and Validation
by André Alegre, Sérgio Oliveira, Jorge Proença, Paulo Mendes and Ezequiel Carvalho
Infrastructures 2025, 10(8), 193; https://doi.org/10.3390/infrastructures10080193 - 22 Jul 2025
Viewed by 294
Abstract
This paper presents a formulation for the dynamic analysis of dam–reservoir–foundation systems, employing a coupled finite element model that integrates displacements and reservoir pressures. An innovative coupled approach, without separating the solid and fluid equations, is proposed to directly solve the single non-symmetrical [...] Read more.
This paper presents a formulation for the dynamic analysis of dam–reservoir–foundation systems, employing a coupled finite element model that integrates displacements and reservoir pressures. An innovative coupled approach, without separating the solid and fluid equations, is proposed to directly solve the single non-symmetrical governing equation for the whole system with non-proportional damping. For the modal analysis, a state–space method is adopted to solve the coupled eigenproblem, and complex eigenvalues and eigenvectors are computed, corresponding to non-stationary vibration modes. For the seismic analysis, a time-stepping method is applied to the coupled dynamic equation, and the stress–transfer method is introduced to simulate the nonlinear behavior, innovatively combining a constitutive joint model and a concrete damage model with softening and two independent scalar damage variables (tension and compression). This formulation is implemented in the computer program DamDySSA5.0, developed by the authors. To validate the formulation, this paper provides the experimental and numerical results in the case of the Cahora Bassa dam, instrumented in 2010 with a continuous vibration monitoring system designed by the authors. The good comparison achieved between the monitoring data and the dam–reservoir–foundation model shows that the formulation is suitable for simulating the modal response (natural frequencies and mode shapes) for different reservoir water levels and the seismic response under low-intensity earthquakes, using accelerograms measured at the dam base as input. Additionally, the dam’s nonlinear seismic response is simulated under an artificial accelerogram of increasing intensity, showing the structural effects due to vertical joint movements (release of arch tensions near the crest) and the concrete damage evolution. Full article
(This article belongs to the Special Issue Advances in Dam Engineering of the 21st Century)
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26 pages, 4845 KiB  
Article
Modeling and Testing of a Phasor Measurement Unit Under Normal and Abnormal Conditions Using Real-Time Simulator
by Obed Muhayimana, Petr Toman, Ali Aljazaeri, Jean Claude Uwamahoro, Abir Lahmer, Mohamed Laamim and Abdelilah Rochd
Energies 2025, 18(14), 3624; https://doi.org/10.3390/en18143624 - 9 Jul 2025
Viewed by 406
Abstract
Abnormal operations, such as faults occurring in an electrical power system (EPS), disrupt its balanced operation, posing potential hazards to human lives and the system’s equipment. Effective monitoring, control, protection, and coordination are essential to mitigate these risks. The complexity of these processes [...] Read more.
Abnormal operations, such as faults occurring in an electrical power system (EPS), disrupt its balanced operation, posing potential hazards to human lives and the system’s equipment. Effective monitoring, control, protection, and coordination are essential to mitigate these risks. The complexity of these processes is further compounded by the presence of intermittent distributed energy resources (DERs) in active distribution networks (ADNs) with bidirectional power flow, which introduces a fast-changing dynamic aspect to the system. The deployment of phasor measurement units (PMUs) within the EPS as highly responsive equipment can play a pivotal role in addressing these challenges, enhancing the system’s resilience and reliability. However, synchrophasor measurement-based studies and analyses of power system phenomena may be hindered by the absence of PMU blocks in certain simulation tools, such as PSCAD, or by the existing PMU block in Matlab/Simulink R2021b, which exhibit technical limitations. These limitations include providing only the positive sequence component of the measurements and lacking information about individual phases, rendering them unsuitable for certain measurements, including unbalanced and non-symmetrical fault operations. This study proposes a new reliable PMU model in Matlab and tests it under normal and abnormal conditions, applying real-time simulation and controller-hardware-in-the-loop (CHIL) techniques. Full article
(This article belongs to the Section A1: Smart Grids and Microgrids)
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36 pages, 544 KiB  
Article
Well-Posedness of Cauchy-Type Problems for Nonlinear Implicit Hilfer Fractional Differential Equations with General Order in Weighted Spaces
by Jakgrit Sompong, Samten Choden, Ekkarath Thailert and Sotiris K. Ntouyas
Symmetry 2025, 17(7), 986; https://doi.org/10.3390/sym17070986 - 22 Jun 2025
Viewed by 312
Abstract
This paper establishes the well-posedness of Cauchy-type problems with non-symmetric initial conditions for nonlinear implicit Hilfer fractional differential equations of general fractional orders in weighted function spaces. Using fixed-point techniques, we first prove the existence of solutions via Schaefer’s fixed-point theorem. The uniqueness [...] Read more.
This paper establishes the well-posedness of Cauchy-type problems with non-symmetric initial conditions for nonlinear implicit Hilfer fractional differential equations of general fractional orders in weighted function spaces. Using fixed-point techniques, we first prove the existence of solutions via Schaefer’s fixed-point theorem. The uniqueness and Ulam–Hyers stability are then derived using Banach’s contraction principle. By introducing a novel singular-kernel Gronwall inequality, we extend the analysis to Ulam–Hyers–Rassias stability and continuous dependence on initial data. The theoretical framework is unified for general fractional orders and validated through examples, demonstrating its applicability to implicit systems with memory effects. Key contributions include weighted-space analysis and stability criteria for this class of equations. Full article
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15 pages, 580 KiB  
Article
Impact of Log-Normal Particle Size Distribution in Holby–Morgan Degradation Model on Aging of Pt/C Catalyst in PEMFC
by Victor A. Kovtunenko
Technologies 2025, 13(7), 262; https://doi.org/10.3390/technologies13070262 - 20 Jun 2025
Viewed by 796
Abstract
The Holby–Morgan model of electrochemical degradation in platinum on a carbon catalyst is studied with respect to the impact of particle size distribution on aging in polymer electrolyte membrane fuel cells. The European Union harmonized protocol for testing by non-symmetric square-wave voltage is [...] Read more.
The Holby–Morgan model of electrochemical degradation in platinum on a carbon catalyst is studied with respect to the impact of particle size distribution on aging in polymer electrolyte membrane fuel cells. The European Union harmonized protocol for testing by non-symmetric square-wave voltage is applied for accelerated stress cycling. The log-normal distribution is estimated using finite size groups which are defined by two parameters of the median and standard deviation. In the non-diffusive model, the first integral of the system is obtained which reduces the number of differential equations. Without ion diffusion, it allows to simulate platinum particles shrank through platinum dissolution and growth by platinum ion deposition. Numerical tests of catalyst degradation in the diffusion model demonstrate the following changes in platinum particle size distribution: broadening for small and shrinking for large medians with tailing towards large particles; the possibility of probability decrease as well as increase for each size group; and overall, a drop in the platinum particle size takes place, which is faster for the small median owing to the Gibbs–Thompson effect. Full article
(This article belongs to the Section Environmental Technology)
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10 pages, 372 KiB  
Article
A Randomized Q-OR Krylov Subspace Method for Solving Nonsymmetric Linear Systems
by Gérard Meurant
Mathematics 2025, 13(12), 1953; https://doi.org/10.3390/math13121953 - 12 Jun 2025
Viewed by 360
Abstract
The most popular iterative methods for solving nonsymmetric linear systems are Krylov methods. Recently, an optimal Quasi-ORthogonal (Q-OR) method was introduced, which yields the same residual norms as the Generalized Minimum Residual (GMRES) method, provided GMRES is not stagnating. In this paper, we [...] Read more.
The most popular iterative methods for solving nonsymmetric linear systems are Krylov methods. Recently, an optimal Quasi-ORthogonal (Q-OR) method was introduced, which yields the same residual norms as the Generalized Minimum Residual (GMRES) method, provided GMRES is not stagnating. In this paper, we study how to introduce matrix sketching in this algorithm. It allows us to reduce the dimension of the problem in one of the main steps of the algorithm. Full article
(This article belongs to the Special Issue Numerical Analysis and Scientific Computing for Applied Mathematics)
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25 pages, 1059 KiB  
Article
Enhancing Differential Evolution: A Dual Mutation Strategy with Majority Dimension Voting and New Stopping Criteria
by Anna Maria Gianni, Ioannis G. Tsoulos, Vasileios Charilogis and Glykeria Kyrou
Symmetry 2025, 17(6), 844; https://doi.org/10.3390/sym17060844 - 28 May 2025
Viewed by 496
Abstract
This paper presents an innovative optimization algorithm based on differential evolution that combines advanced mutation techniques with intelligent termination mechanisms. The proposed algorithm is designed to address the main limitations of classical differential evolution, offering improved performance for symmetric or non-symmetric optimization problems. [...] Read more.
This paper presents an innovative optimization algorithm based on differential evolution that combines advanced mutation techniques with intelligent termination mechanisms. The proposed algorithm is designed to address the main limitations of classical differential evolution, offering improved performance for symmetric or non-symmetric optimization problems. The core scientific contribution of this research focuses on three key aspects. First, we develop a hybrid dual-strategy mutation system where the first strategy emphasizes exploration of the solution space through monitoring of the optimal solution, while the second strategy focuses on exploitation of promising regions using dynamically weighted differential terms. This dual mechanism ensures a balanced approach between discovering new solutions and improving existing ones. Second, the algorithm incorporates a novel majority dimension mechanism that evaluates candidate solutions through dimension-wise comparison with elite references (best sample and worst sample). This mechanism dynamically guides the search process by determining whether to intensify local exploitation or initiate global exploration based on majority voting across all the dimensions. Third, the work presents numerous new termination rules based on the quantitative evaluation of metric value homogeneity. These rules extend beyond traditional convergence checks by incorporating multidimensional criteria that consider both the solution distribution and evolutionary dynamics. This system enables more sophisticated and adaptive decision-making regarding the optimal stopping point of the optimization process. The methodology is validated through extensive experimental procedures covering a wide range of optimization problems. The results demonstrate significant improvements in both solution quality and computational efficiency, particularly for high-dimensional problems with numerous local optima. The research findings highlight the proposed algorithm’s potential as a high-performance tool for solving complex optimization challenges in contemporary scientific and technological contexts. Full article
(This article belongs to the Section Computer)
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28 pages, 17288 KiB  
Article
The Geometrical Relationship Between Ancient Hindu Technical Treatises and the Planning and Organization of Angkor Wat
by Vacharee Svamivastu and Komsan Maleesee
Buildings 2025, 15(8), 1210; https://doi.org/10.3390/buildings15081210 - 8 Apr 2025
Viewed by 1755
Abstract
Angkor Wat is the supreme masterpiece of Khmer architecture, built by King Sūryavarman II during the 12th century A.D. Jane Przyluski hypothesized that Angkor Wat was the tomb of King Sūryavarman II. On the other hand, George Cœdès thought that Angkor Wat complex [...] Read more.
Angkor Wat is the supreme masterpiece of Khmer architecture, built by King Sūryavarman II during the 12th century A.D. Jane Przyluski hypothesized that Angkor Wat was the tomb of King Sūryavarman II. On the other hand, George Cœdès thought that Angkor Wat complex was habitation in the form of a celestial palace. According to Henri Parmentier, though the buildings and constructions in Angkor Wat temple complex are majestic, they are geometrically out of place. The temple complex is non-symmetrical, as the complex’s center is left-aligned. The above controversial opinions inspire a deep examination of the geometric system of the architectural and structural design of Angkor Wat. This research investigates the architectural planning and frame structures of Angkor Wat stone temple complex using a Hindu grid system. The study was based on field survey data of the temple complex and Hindu ancient texts, specifically the Vāstu Śāstra. PhotoModeler Pro5 and Polycam for iOS-4.0.5 were utilized to render three-dimensional (3D) images of the entire temple complex. The analysis finds the geometric code (suitable module) used in the planning of 2.75 m × 2.75 m in the metric system (1 Phyeam 1 Hat 1 Thnob in) the local Cambodian measuring system). The geometric code (2.75 m × 2.75 m) highlights the design diagram and construction of the temple complex. The research also unveiled the use of a center-shifting technique where the vertical axis running through the center is deliberately left-aligned, to avoid numerical fractions occurring in the grid modules. The technique gives rise to the asymmetry of the temple complex. The findings led to understanding the symbolic meaning of spatial organization of the layout and plan of Angkor Wat design, which was meant to be a suitable residence for the god on earth, the king, and his citizens. Moreover, it also means the final abode of King Sūryavarman II after his death, represented by the image of Lord Viṣṇu. Full article
(This article belongs to the Special Issue Creativity in Architecture)
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11 pages, 1700 KiB  
Article
Compact Modeling and Exploration of the Light Metal Insertion Effect for a Voltage-Controlled Spin–Orbit Torque Magnetic Tunnel Junction
by Weixiang Li, Jiaqi Lu, Chengzhi Wang and Dongsheng Wang
Electronics 2025, 14(7), 1272; https://doi.org/10.3390/electronics14071272 - 24 Mar 2025
Viewed by 462
Abstract
Magnetic random-access memory, recognized as a breakthrough in spintronics, demonstrates substantial potential for next-generation nonvolatile memory and logic devices due to its unique magnetization-switching mechanism. However, realizing reliable perpendicular magnetization switching via spin–orbit torque necessitates an externally applied in-plane magnetic bias, a requirement [...] Read more.
Magnetic random-access memory, recognized as a breakthrough in spintronics, demonstrates substantial potential for next-generation nonvolatile memory and logic devices due to its unique magnetization-switching mechanism. However, realizing reliable perpendicular magnetization switching via spin–orbit torque necessitates an externally applied in-plane magnetic bias, a requirement that complicates integration in high-density device architectures. This study proposes a novel device architecture where geometric asymmetry engineering in an interlayer design generates an intrinsic equivalent in-plane magnetic field. By strategically introducing a non-symmetrical spacer between the heavy metal and ferromagnetic layers, we establish deterministic magnetization reversal while eliminating external field dependency. Furthermore, the energy barrier during magnetization switching is dynamically adjusted by applying a voltage across a perpendicular-anisotropy magnetic tunnel junction, leveraging the voltage-controlled magnetic anisotropy effect. We established a physics-driven compact model to assess the design and performance of voltage-controlled spin–orbit torque magnetic tunnel junction (VCSOT-MTJ) devices. Simulations reveal that the introduction of a minimally asymmetric light metal layer effectively resolves the issue of incomplete switching in field-free spin-orbit torque systems. Full article
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21 pages, 10984 KiB  
Article
Lumped Parameter Model for Structural Analysis of Over-Constrained Multi-Legged Parallel Mechanism Supporting System Applied to Cryogenic Devices
by Luca Piacentini, Luca Dassa, Diego Perini, Andris Ratkus, Toms Torims and Stefano Uberti
Machines 2025, 13(2), 129; https://doi.org/10.3390/machines13020129 - 8 Feb 2025
Viewed by 515
Abstract
While the design of a cryostat is being developed, one of the most relevant sub-systems is the internal supporting system that sustains the cooled component. According to the literature, the arrangement and number of supports chosen often result in a multi-leg over-constrained architecture. [...] Read more.
While the design of a cryostat is being developed, one of the most relevant sub-systems is the internal supporting system that sustains the cooled component. According to the literature, the arrangement and number of supports chosen often result in a multi-leg over-constrained architecture. These are usually studied by means of finite element analysis tools alone, which makes studies like the optimization of supporting systems computationally expensive. This paper proposes a more structured and general analytical model compared to the existing models for this application. The proposed lumped parameter model allows designers to study the influence of external loads, pre-load, and cool-down on stress levels and deformation status of the supports of the cryogenic device as well as the consequent misalignment of the cooled component. The general lumped parameter model for n tie-rods of different shapes, dimensions, and materials is proposed. Two particularized models of eight and eleven supports are validated by comparing the results with those from standard finite element analysis software. Results show that the proposed model has a strong agreement with finite element simulations, and the median of relative errors is about 1.4%. This accuracy is obtained for models of randomly arranged supports, which proves the effectiveness of the model in predicting results even for non-symmetrical support configurations. Comparable and accurate results are obtained, which are about 130 times faster than in finite element analysis, thus proving the effective reduction in computational cost. Additionally, the proposed code lets designers change input parameters in a quicker and reliable way. Full article
(This article belongs to the Section Machine Design and Theory)
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30 pages, 651 KiB  
Article
Modified Heisenberg Commutation Relations, Free Schrödinger Equations, Tunnel Effect and Its Connections with the Black–Scholes Equation
by Mauricio Contreras González, Roberto Ortiz Herrera and José González Suárez
Axioms 2025, 14(1), 60; https://doi.org/10.3390/axioms14010060 - 15 Jan 2025
Viewed by 957
Abstract
This paper explores the implications of modifying the canonical Heisenberg commutation relations over two simple systems, such as the free particle and the tunnel effect generated by a step-like potential. The modified commutation relations include position-dependent and momentum-dependent terms analyzed separately. For the [...] Read more.
This paper explores the implications of modifying the canonical Heisenberg commutation relations over two simple systems, such as the free particle and the tunnel effect generated by a step-like potential. The modified commutation relations include position-dependent and momentum-dependent terms analyzed separately. For the position deformation case, the corresponding free wave functions are sinusoidal functions with a variable wave vector k(x). In the momentum deformation case, the wave function has the usual sinusoidal behavior, but the energy spectrum becomes non-symmetric in terms of momentum. Tunneling probabilities depend on the deformation strength for both cases. Also, surprisingly, the quantum mechanical model generated by these modified commutation relations is related to the Black–Scholes model in finance. In fact, by taking a particular form of a linear position deformation, one can derive a Black–Scholes equation for the wave function when an external electromagnetic potential is acting on the particle. In this way, the Scholes model can be interpreted as a quantum-deformed model. Furthermore, by identifying the position coordinate x in quantum mechanics with the underlying asset S, which in finance satisfies stochastic dynamics, this analogy implies that the Black–Scholes equation becomes a quantum mechanical system defined over a random spatial geometry. If the spatial coordinate oscillates randomly about its mean value, the quantum particle’s mass would correspond to the inverse of the variance of this stochastic coordinate. Further, because this random geometry is nothing more than gravity at the microscopic level, the Black–Scholes equation becomes a possible simple model for understanding quantum gravity. Full article
(This article belongs to the Section Mathematical Physics)
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18 pages, 12435 KiB  
Article
Reasonable Coal Pillar Width and Control Technology for Gob-Side Entry Driving in Deep Irregular Working Face
by Shuaifeng Yin, Xubo Zhao, En Wang, Yitao Yan, Kanglei Han, Jun Ma and Yibo Wang
Processes 2025, 13(1), 127; https://doi.org/10.3390/pr13010127 - 6 Jan 2025
Cited by 3 | Viewed by 802
Abstract
Aiming to address the challenges of determining the coal pillar’s width and managing the significant deformation of the surrounding rock in the deep gob-side entry driving, the limiting equilibrium zone theory, employing the operational area of Dongpang Mine 21110 as the engineering setting, [...] Read more.
Aiming to address the challenges of determining the coal pillar’s width and managing the significant deformation of the surrounding rock in the deep gob-side entry driving, the limiting equilibrium zone theory, employing the operational area of Dongpang Mine 21110 as the engineering setting, states that a coal pillar’s appropriate width in the gob-side entry driving falls between 7.9 and 9.8 m. The pattern of vertical stress distribution and the extent of the plastic zone in the roadway for coal pillar widths of 7.0 m, 8.0 m, 9.0 m, and 10.0 m are analyzed, respectively, investigated using the numerical simulation method of FLAC3D. The acceptable coal pillar width in the deep gob-side entry driving is 8.0 m. Combined with the roadway surrounding rock borehole inspection results, the fracture development condition of the roadway’s full-face surrounding rock is determined, and the asymmetric aberration characteristics, with significant surrounding rock damage depth at the coal pillar flank location, are obtained. Based on the theoretical calculations, an integrated proposal for a “non-symmetrical bolt and cable anchor” coupling support scheme for the surrounding rock in the gob-side entry driving is put forward. This was applied at the Dongpang coal mine site. Engineering practice shows that leaving an 8.0 m coal pillar width and adopting the “non-symmetrical bolt and cable anchor” support system design can control the deformation of the surrounding rock in the track entry at a reasonable range, which ensures the stability of the surrounding rock in the gob-side entry driving. Full article
(This article belongs to the Section Process Control and Monitoring)
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14 pages, 778 KiB  
Article
Particle Size Distribution in Holby–Morgan Degradation Model of Platinum on Carbon Catalyst in Fuel Cell: Normal Distribution
by Victor A. Kovtunenko
Technologies 2024, 12(10), 202; https://doi.org/10.3390/technologies12100202 - 17 Oct 2024
Cited by 1 | Viewed by 2114
Abstract
The influence of particle size distribution in platinum catalysts on the aging of PEM fuel cells described by Holby–Morgan electrochemical degradation model is under investigation. The non-diffusive model simulates mechanisms of particle drop by Pt dissolution and particle growth through Pt ion deposition. [...] Read more.
The influence of particle size distribution in platinum catalysts on the aging of PEM fuel cells described by Holby–Morgan electrochemical degradation model is under investigation. The non-diffusive model simulates mechanisms of particle drop by Pt dissolution and particle growth through Pt ion deposition. Without spatial dependence, the number of differential equations can be reduced using the first integral of the system. For an accelerated stress test, a non-symmetric square-wave potential profile is applied according to the European harmonized protocol. The normal particle size distribution determined by two probability parameters of the expectation and the standard deviation is represented within finite groups. Numerical solution of the nonlinear diffusion equation justifies dispersion for small and narrowing for large distribution means, decrease or increase in amplitude, and movement of Pt particle diameters towards small sizes, which is faster for small particles. Full article
(This article belongs to the Section Environmental Technology)
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33 pages, 31456 KiB  
Article
Modeling and Simulation of an Integrated Synchronous Generator Connected to an Infinite Bus through a Transmission Line in Bond Graph
by Gilberto Gonzalez-Avalos, Gerardo Ayala-Jaimes, Noe Barrera Gallegos and Aaron Padilla Garcia
Symmetry 2024, 16(10), 1335; https://doi.org/10.3390/sym16101335 - 9 Oct 2024
Viewed by 1323
Abstract
Most electrical energy generation systems are based on synchronous generators; as a result, their analysis always provides interesting findings, especially if an approach different to those traditionally studied is used. Therefore, an approach involving the modeling and simulation of a synchronous generator connected [...] Read more.
Most electrical energy generation systems are based on synchronous generators; as a result, their analysis always provides interesting findings, especially if an approach different to those traditionally studied is used. Therefore, an approach involving the modeling and simulation of a synchronous generator connected to an infinite bus through a transmission line in a bond graph is proposed. The behavior of the synchronous generator is analyzed in four case studies of the transmission line: (1) a symmetrical transmission line, where the resistance and inductance of the three phases (a,b,c) are equal, which determine resistances and inductances in coordinates (d,q,0) as individual decoupled elements; (2) a symmetrical transmission line for the resistances and for non-symmetrical inductances in coordinates (a,b,c) that result in resistances that are individual decoupled elements and in a field of inductances in coordinates (d,q,0); (3) a non-symmetrical transmission line for resistances and for symmetrical inductances in coordinates (a,b,c) that produce a field of resistances and inductances as individual elements decoupled in coordinates (d,q,0); and (4) a non-symmetrical transmission line for resistances and inductances in coordinates (a,b,c) that determine resistances and inductance fields in coordinates (d,q,0). A junction structure based on a bond graph model that allows for obtaining the mathematical model of this electrical system is proposed. Due to the characteristics of a bond graph, model reduction can be carried out directly and easily. Therefore, reduced bond graph models for the four transmission line case studies are proposed, where the transmission line is seen as if it were inside the synchronous generator. In order to demonstrate that the models obtained are correct, simulation results using the 20-Sim software are shown. The simulation results determine that for a symmetrical transmission line, currents in the generator in the d and q axes are −25.87 A and 0.1168 A, while in the case of a non-symmetrical transmission line, these currents are −26.14 A and 0.0211 A, showing that for these current magnitudes, the generator is little affected due to the parameters of the generator and the line. However, for a high degree of non-symmetry of the resistances in phases a, b and c, it causes the generator to reach an unstable condition, which is shown in the last simulation of the paper. Full article
(This article belongs to the Section Engineering and Materials)
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25 pages, 7559 KiB  
Article
Impact of Geometrical Misplacement of Heat Exchanger Pipe Parallel Configuration in Energy Piles
by Qusi I. Alqawasmeh, Guillermo A. Narsilio and Nikolas Makasis
Energies 2024, 17(11), 2580; https://doi.org/10.3390/en17112580 - 27 May 2024
Cited by 5 | Viewed by 1493
Abstract
Shallow geothermal or ground source heat pump (GSHP) energy systems offer efficient space heating and cooling, reducing greenhouse gas emissions and electrical consumption. Incorporating ground heat exchangers (GHEs) within pile foundations, as part of these GSHP systems, has gained significant attention as it [...] Read more.
Shallow geothermal or ground source heat pump (GSHP) energy systems offer efficient space heating and cooling, reducing greenhouse gas emissions and electrical consumption. Incorporating ground heat exchangers (GHEs) within pile foundations, as part of these GSHP systems, has gained significant attention as it can reduce capital costs. The design and optimisation of GHEs connected in parallel within energy piles have been researched widely, considering symmetrical placement, while the potential misplacement due to construction errors and the optimal placement remain mostly unexplored. This study utilises 3D finite element numerical methods, analysing energy piles with diameters from 0.5 m to 1.4 m, equipped with parallelly connected U-tube and W-tube GHEs. The impact of GHE loop placement is analysed, considering the influence of the ground and concrete thermal conductivities, pile length, fluid flow rate, GHE pipe diameter, and pile spacing. Results indicate a marginal impact, less than 3%, on the overall heat transfer when loops deviate from symmetry and less than 5% on the total heat transfer shared by each loop, except for highly non-symmetric configurations. Symmetrical and evenly spaced loop placement generally maintains favourable thermal performance and ease of installation. This study underscores the flexibility in GHE design and construction with a low risk of thermal yield variations due to uncertainties, particularly with a separation-to-shank distance ratio between 0.5 and 1.5 in a symmetrical distribution. Full article
(This article belongs to the Special Issue Energy Geotechnics and Geostructures—2nd Edition)
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19 pages, 1998 KiB  
Article
Non-Symmetrically Fused Bis(arylimino)pyridines with para-Phenyl Substitution: Exploring Their Use as N′,N,N″-Supports in Iron Ethylene Polymerization Catalysis
by Yizhou Wang, Zheng Wang, Qiuyue Zhang, Yanping Ma, Gregory A. Solan, Yang Sun and Wen-Hua Sun
Catalysts 2024, 14(3), 213; https://doi.org/10.3390/catal14030213 - 21 Mar 2024
Cited by 2 | Viewed by 1664
Abstract
Through the implementation of a one-pot strategy, five examples of non-symmetrical [N,N-diaryl-11-phenyl-1,2,3,7,8,9,10-heptahydrocyclohepta[b]quinoline-4,6-diimine]iron(II) chloride complexes (aryl = 2,6-Me2Ph Fe1, 2,6-Et2Ph Fe2, 2,6-i-Pr2Ph Fe3, 2,4,6-Me3Ph Fe4 [...] Read more.
Through the implementation of a one-pot strategy, five examples of non-symmetrical [N,N-diaryl-11-phenyl-1,2,3,7,8,9,10-heptahydrocyclohepta[b]quinoline-4,6-diimine]iron(II) chloride complexes (aryl = 2,6-Me2Ph Fe1, 2,6-Et2Ph Fe2, 2,6-i-Pr2Ph Fe3, 2,4,6-Me3Ph Fe4, and 2,6-Et2-4-MePh Fe5), incorporating fused six- and seven-membered carbocyclic rings and appended with a remote para-phenyl group, were readily prepared. The molecular structures of Fe2 and Fe3 emphasize the variation in fused ring size and the skewed disposition of the para-phenyl group present in the N′,N,N″-ligand support. Upon activation with MAO or MMAO, Fe1Fe5 all showed high catalytic activity for ethylene polymerization, with an exceptional level of 35.92 × 106 g (PE) mol−1 (Fe) h−1 seen for mesityl-substituted Fe4/MMAO operating at 60 °C. All catalysts generated highly linear polyethylene with good control of the polymer molecular weight achievable via straightforward manipulation of run temperature. Typically, low molecular weight polymers with narrow dispersity (Mw/Mn = 1.5) were produced at 80 °C (MMAO: 3.7 kg mol−1 and MAO: 4.9 kg mol−1), while at temperatures between 40 °C and 50 °C, moderate molecular weight polymers were obtained (MMAO: 35.6–51.6 kg mol−1 and MAO: 72.4–95.5 kg mol−1). Moreover, analysis of these polyethylenes by 1H and 13C NMR spectroscopy highlighted the role played by both β-H elimination and chain transfer to aluminum during chain termination, with the highest rate of β-H elimination seen at 60 °C for the MMAO-activated system and 70 °C for the MAO system. Full article
(This article belongs to the Special Issue State of the Art in Molecular Catalysis in Europe)
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