Search Results (52)

Some of the popular and successful atmospheric pressure fuel/air plasma-assisted combustion methods use repetitive ns pulsed discharges and dielectric-barrier discharges. The transient phase in such discharges is dominated by transport under strong space charge from ionization fronts, which is best characterized by the streamer model. The role of the nonthermal plasma in such discharges is to produce radicals, which accelerates the chemical conversion reaction leading to temperature rise and ignition. Therefore, the characterization of the streamer and its energy partitioning is essential to develop a predictive model. We examine the important characteristics of streamers that influence combustion and develop some macroscopic parameters. Our results show that the radicals’ production efficiency at an applied field is nearly independent of time and the radical density generated depends only on the electrical energy density coupled to the plasma. We compare the results of the streamer model to the zero-dimensional uniform field Townsend-like discharge, and our results show a significant difference. The results concerning the influence of energy density and repetition rate on the ignition of a hydrogen/air fuel mixture are presented. Full article

Driven by dual-carbon targets, marine engines are accelerating their transition towards low-carbon and zero-carbon. Ammonium–hydrogen fusion fuel is considered to be one of the most promising fuels for ship decarbonization. Using non-thermal plasma (NTP) catalytic ammonia on-line hydrogen production technology to achieve hydrogen supply is one of the most important means to guarantee the safety and effectiveness of hydrogen energy in the storage and transportation process. However, the efficiency of ammonia catalytic hydrogen production can be influenced to some extent by the presence of several factors, and the reaction mechanism is complex under the conditions of ship engine temperature emissions. This makes it difficult to realize the precise control of plasma catalytic hydrogen production from ammonia technology under temperature emission conditions, thus restricting an improvement in the ammonia conversion rate. In this study, a kinetic model of hydrogen production from ammonia catalyzed by NTP was established. The influencing factors (reaction temperature, pressure, N₂/NH₃ ratio in the feed gas) and mechanism path of hydrogen production from ammonia decomposition were explored. The results show that the increase in reaction temperature will lead to an increase in the ammonia conversion rate, while the ammonia conversion rate will decrease with the increase in reaction pressure and N₂/NH₃ ratio. When the reaction temperature is 300 K, the pressure is 1 bar, the feed gas is 98%N₂/2%NH₃, and the ammonia conversion rate is 16.7%. The reason why the addition of N₂ is conducive to the hydrogen production from NH₃ decomposition is that the reaction N₂(A3) + NH₃ => N₂ + NH₂ + H, triggered by the electron excited-state N₂(A3), is the main reaction for NH₃ decomposition. Full article

Numerical investigations were conducted to analyze the coupling effects of pulsed H₂ jets and nanosecond-pulsed actuation (NS-SDBD) in a supersonic crossflow. The FVM was employed to solve the multi-component 2D URANS equations with the SST k-omega turbulence model, while H₂-air combustion was described using a seven species–seven reactions chain reaction model, and the plasma thermal effect was represented by a phenomenological model. The backward-facing step flows with an inlet Mach number of 2.5 and a pulsed jet frequency of 10 kHz under different actuation conditions were simulated. The combustion enhancement mechanism under an actuation frequency of 20 kHz was analyzed. Research indicates that compression waves induced by NS-SDBD enhance H₂-air mixing and facilitate temperature transport as the flow progresses. This progress is significantly associated with the flow structures generated by pulsed jets. Under this condition, the fuel utilization rate in the flow field increased by 61.2%, the total pressure recovery coefficient increased by 5.34%, and the outlet total temperature slightly increased even with a 50% reduction in fuel flow rate. Comparative analysis of different actuation cases demonstrates that evenly distributed actuation within the jet cycle yields better effects. The innovation of this study lies in proposing and exploring a potential method to address inadequate combustion under high-speed inflow conditions, which couples NS-SDBD with pulsed hydrogen jets. Full article

Polypropylene (PP) membranes have found diverse applications, such as in wastewater treatment, lithium-ion batteries, and pharmaceuticals, due to their low cost, excellent mechanical properties, thermal stability, and chemical resistance. However, the intrinsic hydrophobicity of PP materials leads to membrane fouling and filtration flux reduction, which greatly hinders the applications of PP membranes. Dielectric barrier discharge (DBD) is an effective technique for surface modification of materials because it generates a large area of low-temperature plasma at atmospheric pressure. In this study, O₂ was added to nanosecond pulsed Ar DBD to increase its reactivity. Electrical and optical diagnostic techniques were used to study the discharge characteristics of the DBD at varying O₂ contents. The uniformity of the discharge was quantitatively analyzed using the observed discharge images. Water contact angle measurements were used to assess the surface hydrophilicity of polypropylene. The surface morphology and chemical composition of the PP materials before and after treatment were analyzed using field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). The results show that the moderate addition of O₂ enhances surface hydrophilicity and the uniformity of the modification. By increasing the O₂ addition from 0% to 0.1%, the average power increased from 4.19 W to 5.79 W, and the energy efficiency increased from 17.78% to 21.51%. The water contact angle of the DBD-treated PP showed a tendency to decrease and then increase with increasing O₂ content, with the optimum O₂ addition determined to be 0.1%. Under this condition, the water contact angle of the PP surface decreased by 31.88°, which is 52.31% lower than the untreated surface. O₂ increases the number of oxygen-containing polar groups (-OH, C=O, and O-C=O) on the surface of the material, and deepens and densifies the grooves on the surface of the PP material, resulting in an increase in the hydrophilicity of the PP surface. Full article

In this manuscript, we report on the synthesis of a polynitrogen material from a potassium azide precursor using nanosecond-pulsed spark discharge plasma in liquid nitrogen. The polynitrogen material was characterized using Raman and Fourier transform infrared (FTIR) spectroscopy and identified as K₂N₆, with planar N₆ rings and K- ions that have P6/mmm symmetry. An analysis of the mechanism behind such a transformation shows the importance of direct plasma–chemical effects in polymerization, while the crystal structure changes are believed to be due to plasma-emitted radiation in the ultraviolet range. Full article

In this study, a single-outer-spiral electrode with inductance of 20 μH is employed to couple the energy input of a bipolar nanosecond pulse for the purpose of generating a large-scale atmospheric pressure plasma jet. When the spiral electrode is wrapped around a plasma jet tube with a length of 35 cm, the electrical field can be optimized, resulting in a stable laminar flow field, and a plasma jet with a length and diameter larger than 14 cm and 1.2 cm can be generated. A comparative study of the bipolar and unipolar pulse excitation voltages is also conducted, showing that the maximum lengths of the plasma jet excited by a bipolar pulse voltage, positive pulse voltage, and negative are 14 cm, 10 cm, and 7 cm, respectively. The temporal and spatially resolved spectra of the plasma jets excited by both bipolar and unipolar pulses are investigated, respectively, and the main physiochemical processes of the active species and the plasma dynamics’ evolution are discussed. Full article

Plasma focus devices represent a class of hot and dense plasma sources that serve a dual role in fundamental plasma research and practical applications. These devices allow the observation of various phenomena, including the z-pinch effect, nuclear fusion reactions, plasma filaments, bursts, shocks, jets, X-rays, neutron pulses, ions, and electron beams. In recent years, considerable efforts have been directed toward miniaturizing plasma focus devices, driven by the pursuit of both basic studies and technological advancements. In this paper, we present the design and construction of a compact, portable pulsed plasma source based on plasma focus technology, operating at the ~2–4 Joule energy range for versatile applications (PF-2J: 120 nF capacitance, 6–9 kV charging voltage, 40 nH inductance, 2.16–4.86 J stored energy, and 10–15 kA maximum current at short circuit). The components of the device, including capacitors, spark gaps, discharge chambers, and power supplies, are transportable within hand luggage. The electrical characteristics of the discharge were thoroughly characterized using voltage and current derivative monitoring techniques. A peak current of 15 kiloamperes was achieved within 110 nanoseconds in a short-circuit configuration at a 9 kV charging voltage. Plasma dynamics were captured through optical refractive diagnostics employing a pulsed Nd-YAG laser with a 170-picosecond pulse duration. Clear evidence of the z-pinch effect was observed during discharges in a deuterium atmosphere at 4 millibars and 6 kilovolts. The measured pinch length and radius were approximately 0.8 mm and less than 100 μm, respectively. Additionally, we explore the potential applications of this compact pulsed plasma source. These include its use as a plasma shock irradiation device for analyzing materials intended for the first wall of nuclear fusion reactors, its capability in material film deposition, and its utility as an educational tool in experimental plasma physics. We also show its potential as a pulsed plasma thruster for nanosatellites, showcasing the advantages of miniaturized plasma focus technology. Full article

The oxidation of multi-walled carbon nanotubes (MWCNTs) using cold plasma was investigated for their subsequent use as adsorbents for the removal of dyes from aqueous solutions. The properties of MWCNTs after plasma modification and their adsorption capacities were compared with pristine and chemically oxidized nanotubes. The modification process employed a reactor where plasma was generated through dielectric barrier discharges (DBD) powered by high-voltage nanosecond pulses. Various modification conditions were examined, such as processing time and pulse voltage amplitude. The degree of oxidation and the impact on the chemistry and structure of the nanotubes was investigated through various physicochemical and morphological characterization techniques (XPS, BET, TEM, etc.). Maximum oxidation (O/C = 0.09 from O/C = 0.02 for pristine MWCNTs) was achieved after 60 min of nanopulsed-DBD plasma treatment. Subsequently, the modified nanotubes were used as adsorbents for the removal of the dye methylene blue (MB) from water. The adsorption experiments examined the effects of contact time between the adsorbent and MB, as well as the initial dye concentration in water. The plasma-modified nanotubes exhibited high MB removal efficiency, with adsorption capacity proportional to the degree of oxidation. Notably, their adsorption capacity significantly increased compared to both pristine and chemically oxidized MWCNTs (~54% and ~9%, respectively). Finally, the kinetics and mechanism of the adsorption process were studied, with experimental data fitting well to the pseudo-second-order kinetic model and the Langmuir isotherm model. This study underscores the potential of plasma technology as a low-cost and environmentally friendly approach for material modification and water purification. Full article

This work reports on observations of positive and negative nanosecond-pulsed discharge in liquid argon. The structures of both positive and negative discharges, their sizes, and the propagation velocities exhibit remarkable similarity. Similar to the streamers in liquid nitrogen and gases, negative streamers require higher applied voltages (electric fields) and propagate to shorter distances. For both polarities, the spectra are almost identical and appear to be a superposition of strongly broadened atomic lines, with preliminary analysis of broadening indicating densities of about 40% that of liquid. Full article

Non-thermal plasma driven ammonia synthesis has great potential for future industrial applications due to its low theoretical energy requirements. To achieve technological advancement and environmental sustainability, it is crucial to boost the energy yield in plasma-assisted ammonia synthesis. Therefore, optimizing energy transfer and utilization are key strategies for enhancing energy efficiency. In this study, dielectric barrier discharge driven by a nanosecond pulsed power supply is used to enhance plasma-assisted ammonia synthesis by controlling the energy transfer through the addition of noble gases. It was found that the addition of noble gases changed the plasma characteristics, significantly improved the uniformity of the discharge, and achieved a high energy yield for ammonia synthesis. The effects of additive amounts of argon (Ar) and helium (He), as well as the pulse parameters including the pulse voltage, pulse repetition frequency, pulse width, and pulse rise time on the energy yield of ammonia synthesis are discussed. The inclusion of noble gases expanded the pathway for gas-phase reactions, with the active components of critical reactions examined through optical emission spectra. This analysis revealed an increased presence of both N₂⁺ and N₂* particles in the reaction’s rate-limiting step, attributed to the addition of noble gases. Finally, a zero-dimensional (0D) plasma chemical kinetic model was established to investigate the influence of Ar addition on the reaction mechanism of ammonia synthesis. Full article

The efficiency of supersonic combustion is largely dependent on inlet and injection parameters. Additional energy input is required in some off-design conditions, and nanosecond discharge actuation can be a solution. In the present study, a phenomenological model of a nanosecond-pulsed surface dielectric barrier discharge (NS-SDBD) actuator was developed to analyze the combustion enhancement effect for a supersonic combustor with transverse H₂ injection. A seven-reaction H₂–air combustion model was adopted for the numerical simulation. Dynamic mode decomposition (DMD) was employed to acquire temperature perturbation in spatial and temporal domains. The results show that the actuator provides additional temperature-increment and species transportation through compression waves. The combustion enhancement effect is mainly attributed to the flow perturbation in the shear layer, which promotes the turbulent diffusion of fuel. Given the same power input, the combustion efficiency at the shockwave reflection point is increased by 17.5%, and the flame height is increased by 15.4% at its maximum. Full article

This paper provides an overview of modern research on magnetoplasma methods of influencing gas-dynamic and plasma flows. The main physical mechanisms that control the interaction of plasma discharges with gaseous moving media are indicated. The ways of organizing pulsed energy input, characteristic of plasma aerodynamics, are briefly described: linearly stabilized discharge, magnetoplasma compressor, capillary discharge, laser-microwave action, electron beam action, nanosecond surface barrier discharges, pulsed spark discharges, and nanosecond optical discharges. A description of the physical mechanism of heating the gas-plasma flow at high values of electric fields, which are realized in high-current and nanosecond (ultrafast heating) electric discharges, is performed. Methods for magnetoplasma control of the configuration and gas-dynamic characteristics of shock waves arising in front of promising and advanced aircraft (AA) are described. Approaches to the control of quasi-stationary separated flows, laminar–turbulent transitions, and static and dynamic separation of the boundary layer (for large PA angles of attack) are presented. Full article

There are numerous scientific and engineering fields where the surface dielectric barrier discharge driven by nanosecond pulses (NS-SDBD) has important applications. To improve its performance, more research is still needed on the effects of electrical parameters on the NS-SDBD actuator’s discharge characteristics. In this study, a two-dimensional numerical model based on 13 discharge particle chemical processes was constructed using a numerical simulation approach, producing findings for the NS-SDBD actuator’s voltage–current (V-A) characteristics, discharge profile, and spectrum analysis. Additionally, a comprehensive investigation into the trends and underlying mechanisms of the effects of the voltage amplitude, pulse width, rise time, and fall time parameters on the discharge behavior of the NS-SDBD actuator was carried out. The results show that higher voltage amplitudes increase the maximum current and electron density, which enhances the plasma excitation effect. The peak power deposition during the second discharge is also raised by longer pulse widths and rise times, whereas the total power deposition during the second discharge is decreased by longer fall times. Full article

The synthesis of the nanopowders of magnesium oxide and magnesium fluoride during the operation of a repetitive diffuse nanosecond discharge in argon at various pressures was performed. Nanosecond voltage pulses with an amplitude of −70 kV, a rise time of 0.7 ns, and a duration of 0.7 ns were applied across a point-to-plane gap of 2 mm in length. The pulse repetition rate was 60 Hz. The high-voltage pointed electrode was made of magnesium. A diffuse discharge cold plasma was formed under these conditions. Nanoparticles were produced as a result of an explosion of microprotrusions on the surface of the magnesium electrode duo to a high current density. Lines of magnesium atoms and ions were observed in the emission optical spectrum. Under the actions of the gas dynamics processes caused by the plasma channel expansion during the interpulse period, nanoparticles were deposited onto the surface of the grounded plane electrode and the side wall of the gas discharge chamber. The morphology, elemental, and phase composition of the powders were studied using transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDS). Full article

The purpose of this article is to analyze the front door coupling effect that may occur in the projectile receiver due to the discharge pulse radiation in electromagnetic railguns, and to simulate the discharge pulse interference. This phenomenon will have an impact on the launch of the projectile, causing its fuse to be disturbed, ultimately affecting the weapon performance of the electromagnetic railgun. Discharge refers to when the armature carrying the projectile is fired out of the chamber, and the armature connected between the two rails detaches, causing a circuit break in the electrical circuit during the operation of the electromagnetic railgun. The current flowing through the armature is disturbed, causing an instantaneous high voltage to penetrate the air gap between the two rails, generating nanosecond pulse width discharge voltage pulse radiation, with a spectrum of up to tens of megahertz. In this paper, we establish a receiving antenna model on the projectile, which is essentially a horn antenna, receiving electromagnetic pulses from the discharge process, and coupling the pulse interference through its front door. During the analysis and calculation, we established an antenna receiver model located in the C-band with a frequency of 6 GHz for simulation, analyzed and calculated the actual interference loaded on the projectile after front door coupling, and verified the correctness of the simulation settings and results by comparing with the literature. Finally, we found that because the main energy spectrum of the pulse is at MHz level, when the front door of the C-band horn antenna is coupled, the standing wave ratio of the antenna is very large and the gain is very small, so the pulse interference is filtered, which can make the interference finally loaded on the projectile insufficient to affect the normal operation of the projectile. At the same time, it is recommended to add an RF filter to the receiving channel to further enhance anti-interference ability, so as to ultimately enable the electromagnetic railgun to function properly. Full article