Search Results (347)

Lead (Pb) is a highly toxic heavy metal frequently found in industrial wastewater, posing serious risks to both human health and the environment. In this study, a porous geopolymer synthesized from fly ash, metakaolin, and red mud was evaluated for Pb(II) removal via batch adsorption experiments under varying pH, dosage, contact time, temperature, and initial concentration. The synthesized material exhibited a favorable mesoporous structure, with a BET surface area of 42.05 m² g⁻¹ and an average pore width of 6.26 nm, making it suitable for heavy metal uptake. Adsorption kinetics followed the pseudo-second-order model (R² = 0.9993), while the Langmuir isotherm (R² ≈ 0.999) best described the equilibrium data, indicating monolayer chemical adsorption as the dominant mechanism, with a maximum capacity of 74.26 mg g⁻¹ at 318 K. Thermodynamic analyses confirmed that the adsorption was spontaneous (ΔG° < 0), endothermic (ΔH° > 0), and accompanied by increased entropy (ΔS° > 0). Desorption and regeneration tests revealed EDTA to be a more effective agent than HNO₃, maintaining a reuse efficiency of 81.35% after four cycles. These results highlight the potential of waste-derived porous geopolymers as regenerable, low-cost, and efficient adsorbents for lead removal. Full article

New theropod tracks found in the Papo-Seco Formation (lower Barremian, Lusitanian Basin, Portugal) are presented. In 2022, thirteen theropod tracks were identified on the lowermost bed of this formation, preserved as natural cast infillings on the bedding surface. Two different morphotypes of theropod footprints have been identified, which occur at two different levels of this layer. The first morphotype, consisting of smaller footprints with narrow digits, is attributed to theropoda indet; the other morphotype, consisting only of one footprint, is assigned provisionally to the ichnogenus Megalosauripus isp. It is suggested that they were produced by medium-sized theropods, on a carbonate mud substrate, probably in a coastal environment associated with a lagoon. These tracks, and others previously described in the underlying Areia do Mastro Formation, suggest a temporal continuity of the groups of dinosaurs that frequented this area, during the early Barremian. However, the morphotypes now described differ from those of the theropods tracks from the Areia do Mastro Formation, which may indicate a change in faunal types within the theropod group. Full article

The study highlights the morphological features of mud-brick architecture in Syria, based on a descriptive and analytical approach. The research begins with a theoretical introduction about the studied area and mud-brick architecture, then their urban characteristics, including (design, function and classification). After that, the elements of the mud building in Rif Dimashq, such as foundations, walls, ceilings and cladding are studied. The discussion includes the advantages and disadvantages of mud-brick architecture, its future in Syria through presenting experiences and conducting a questionnaire for two different samples of residents and engineers about the research topic. Finally, the results document Syrian mud-brick architecture and identify its basic morphological elements, providing sustainable design ideas based on traditional construction techniques, with guidelines for developing sustainable future housing that is both heritage oriented and modern. Full article

Hydrocarbon exploration and extraction increasingly rely on drilling fluids that guarantee operating safety and efficiency, particularly in ultra-deep, high-temperature, and unconventional reservoirs. Traditional drilling fluids, especially for water-based muds (WBMs), have several problems, including excessive fluid loss, severe swelling in shale and instability in high-pressure/high-temperature (HPHT) conditions. Polymer nanocomposites (PNCs) are new types of drilling fluid additives that combine the vast surface area and reactivity of nanoparticles (NPs) with the structural flexibility and stability of polymers. This combination enhances rheology, reduces filtrate loss, and, most importantly, creates hydrophobic and pore-blocking barriers that prevent shale from swelling. This review highlights important improvements in drilling fluids with PNCs regarding exceptional rheological properties, low fluid loss, and improved suppression of the shale swelling. The particular focus was placed on the specific mechanisms and role that PNCs play in enhancing shale stability, as well as their responsibilities in improving rheology, heat resistance, and salt tolerance. Current advancements, persistent hurdles, and prospective prospects are rigorously evaluated to emphasize the scientific and industrial trajectories for the development of next-generation, high-performance drilling fluids. Moreover, the current challenges and future opportunities of PNCs in drilling fluids are discussed to motivate future contributions and explore new possibilities. Full article

Leptospirosis is a zoonotic disease caused by pathogenic Leptospira, prevalent in tropical/sub-tropical regions. This study aimed to clarify the prevailing leptospiral species, clinical features, and risk factors of leptospirosis in north-central Bangladesh in 2024. Venous blood and urine samples were collected from 117 patients with clinically suspected leptospirosis. Among these cases, 75 (64%) tested positive for Leptospira infection by IgM ELISA test and/or PCR. By phylogenetic analysis of the 16S rRNA gene, all the samples tested were classified into L. wolffii (pathogenic group P2), showing high sequence identity to those of the type strain Khorat-H2 (97–99%) and L. wolffii reported in Bangladesh previously. Confirmed leptospirosis patients were mostly male (93%), aged 15–60 years (93%), living in rural areas in low socioeconomic conditions. Variable symptoms were presented by patients, with jaundice (84%), nausea/vomiting (84%), and myalgia (67%) being common. Some patients showed severe symptoms involving the nervous system (disorientation and neck stiffness) and the respiratory tract (cough, shortness of breath, and hemoptysis). Major risk factors for leptospirosis were exposures to mud/wet soil, sanding water, heavy rain, working in a paddy field, and cattle. In conclusion, L. wolffii was revealed to be circulating endemically in north-central Bangladesh, since its first detection in 2018, associated with variable and severe clinical symptoms in humans. Full article

The Xujiahe Formation (FM) is a significant source rock layer in the Sichuan Basin. In recent years, a growing number of scholars believe that the shale gas potential of the Xujiahe Formation is equally substantial, with the first member of the formation being the richest resource. The deposition of Member (Mbr) 1 of Xujiahe FM represents the first and most extensive transgression event within the entire Xujiahe Formation. This study investigates the sedimentary environment and organic matter (OM) enrichment mechanisms of the dark mud shales in the Mbr1 of Xujiahe FM on the southeastern margin of the Sichuan Basin, utilizing methods such as elemental geochemistry and organic geochemistry analyses. The results indicate that these dark mud shales possess a relatively high OM abundance, averaging 2.20% and reaching a maximum of 6.22%. The OM is primarily Type II₂ to Type III. Furthermore, the paleoclimate during the Mbr1 period in the study area was warm and humid with lush aquatic vegetation. Intense weathering and ample precipitation transported large amounts of nutrients into the lacustrine/marine basin, promoting the growth and reproduction of algae and terrestrial plants. Correlation analysis between the Total Organic Carbon (TOC) content and various geochemical proxies in the Mbr1 mud shales suggests that OM enrichment in the study area was primarily controlled by the climate and sedimentation rate; substantial OM accumulation occurred only with abundant terrigenous OM input and a relatively high sedimentation rate. Redox conditions, primarily productivity, and terrigenous detrital input acted as secondary factors, collectively modulating OM enrichment. Event-driven transgressions also played an important role in creating conditions favorable for OM preservation. Synthesizing the influence of these multiple factors on OM enrichment, this study proposes two distinct composite models for OM enrichment, dominated by climate and sedimentation rate. Full article

Danube Delta (DD), an ecologically vulnerable site, together with fish populations, which are significant food resources, are largely exposed to heavy metal contamination. This study was developed in the Babina–Cernovca sector of DD in September 2023. Zinc (Zn), and iron (Fe) were identified in water, while copper (Cu), iron (Fe), and manganese (Mn) were in sediments (mud). Proximate composition of the muscle tissues of eight fish species identified in the area was assessed. The muscle was also tested to identify heavy metals contamination. The contamination degree was assessed using bioaccumulation and bioconcentrations factors. The relation between nutritional parameters and metals was tested using bivariate and multivariate analyses. Samples were analyzed by specific laboratory tests, and data were processed using ANOVA, Spearman correlation, Principal Component Analysis (PCA), and hierarchical clustering. S. erythrophthalmus, C. gibelio, and A. alburnus have the highest metal bioaccumulation capacity, exhibiting species-specific accumulation patterns. PCA and clustering analysis reflect the influence of species and environmental factors on heavy metal accumulation in fish tissue. The study integrates the heavy metals content with nutritional parameters in fish muscular tissue, using bivariate and multivariate analysis for assessing fish vulnerability to heavy metals exposure in the Danube River. Full article

Seabed-related issues are common in offshore areas. This poses significant challenges for the design and construction of offshore engineering projects. Under unfavourable seabed soil conditions, foundations may fail to meet the load-bearing capacity requirements, resulting in severe settlement and tilting and, ultimately, the failure of offshore structures. Despite the critical nature of these challenges, a comprehensive literature review for the identification and risk analysis of various unfavourable seabed soil conditions is currently lacking. This paper provides an overview of five key challenges related to seabed soil conditions in China, namely thick, soft mud layers; shallow gas and pockmarks; sand liquefaction; dense sand layers; and boulder stones. The formation mechanisms, distribution areas and engineering characteristics of these conditions are discussed in detail, integrating insights from previous research. Data from site investigations of real-world offshore engineering projects are presented, based on which risk assessment is conducted. This study not only enhances our understanding of the identification, distribution and hazards associated with various unfavourable seabed soil conditions in offshore engineering but also offers guidance on utilizing investigation data for effective risk assessment. Full article

This study presents a methodology for extracting precise insights on sediment transport in the minor bed of a watercourse using MIKE 21 hydrodynamic modelling software. By integrating geotechnical, geomorphological, and hydrological datasets with a good-resolution Digital Terrain Model (DTM), sediment quantities along a 4.9 km stretch of the Șolea stream—spanning from its source to its confluence with the Vâlsan River (Argeș hydrographic basin)—were determined. A three-month simulation using MIKE 21’s “Mud Transport Module” enabled the comparison of pre- and post-simulation terrain models, yielding detailed information on sediment distribution across the riverbed. These results offer predictive capabilities regarding erosional dynamics and inform mitigation measures to address sedimentary erosion within the study area. The study also presents proposals for land reclamation necessary to prevent the degradation of the riverbed and slopes, such as gabion retaining walls and check dams in the riverbed. Full article

The Niland Moving Mud Spring, located near the southeastern margin of the Salton Sea, represents a rare and evolving geotechnical hazard. Unlike the typically stationary mud pots of the Salton Trough, this spring is a CO₂-driven mud spring that has migrated southwestward since 2016, at times exceeding 3 m per month, posing threats to critical infrastructure including rail lines, highways, and pipelines. Emergency mitigation efforts initiated in 2018, including decompression wells, containment berms, and route realignments, have since slowed and recently almost halted its movement and growth. This study integrates hydrochemical, temperature, stable isotope, and tritium data to propose a refined conceptual model of the Moving Mud Spring’s origin and migration. Temperature data from the Moving Mud Spring (26.5 °C to 28.3 °C) and elevated but non-geothermal total dissolved solids (~18,000 mg/L) suggest a shallow, thermally buffered groundwater source influenced by interaction with saline lacustrine sediments. Stable water isotope data follow an evaporative trajectory consistent with imported Colorado River water, while tritium concentrations (~5 TU) confirm a modern recharge source. These findings rule out deep geothermal or residual floodwater origins from the great “1906 flood”, and instead implicate more recent irrigation seepage or canal leakage as the primary water source. A key external forcing may be the 4.1 m drop in Salton Sea water level between 2003 and 2025, which has modified regional groundwater hydraulic head gradients. This recession likely enhanced lateral groundwater flow from the Moving Mud Spring area, potentially facilitating the migration of upwelling geothermal gases and contributing to spring movement. No faults or structural features reportedly align with the spring’s trajectory, and most major fault systems trend perpendicular to its movement. The hydrologically driven model proposed in this paper, linked to Salton Sea water level decline and correlated with the direction, rate, and timing of the spring’s migration, offers a new empirical explanation for the observed movement of the Niland Moving Mud Spring. Full article

Earthen archaeological sites are particularly vulnerable to rain and winds, whose effects may compromise their integrity. The Huaca Chotuna (HC; 8th–16th Century AD) is an adobe platform in Peru’s semi-arid Lambayeque region, and it is in an area with exposure to rain and winds associated with the El Niño Southern Oscillation (ENSO) events. Here we present the results from an orthophotogrammetric and morphometric study aimed at quantifying the effects of erosion and deposition at the HC. The novelty of our approach consists of merging topographic, hydrological, and wind parameters to recognize the sector of the HC with exposure to potentially damaging natural climatic phenomena. We identify zones affected by erosion and deposition processes. Results of a diffusion model aimed to estimate the HC sectors where these processes will act in the next century are also presented. Gully erosion from rainfall indicates a vertical erosion rate of approximately 0.2 m/century, demonstrating the low preservation potential of the HC. Rainwater also deteriorates adobe bricks and triggers water/mud flows. Conversely, sediment-laden winds contribute to the partial burial of the HC. The findings highlight significant hazards to the HC’s structural integrity, including gravity instability. The interdisciplinary methodology we adopt offers a key framework for assessing and protecting other earthen sites globally against the escalating impacts of climate change. Full article

Overpressure systems in the Qingshankou Formation of the Gulong Sag have a significant impact on unconventional shale oil accumulation, but their distribution and genesis are unknown. This study uses a comparative analysis of three primary pressure prediction methods—the equivalent depth method, the Eaton method, and the Bowers method—to investigate the genetic mechanisms of overpressure and their controlling factors. The study clarifies the link between overpressure and hydrocarbon distribution. The key findings are as follows. (1) The Eaton method is identified as the best approach for estimating current formation pore pressure. The Qingshankou Formation exhibits mild overpressure development, with a maximum pressure coefficient of 1.44. (2) Hydrocarbon-generating overpressure, driven by source rock maturation, is confirmed as the dominant mechanism through integrated acoustic velocity–density cross plots and logging analysis. (3) Tectonic-sedimentary factors, such as burial depth, source rock thickness, sand-mud ratio, and faults, collectively control the spatial variability of overpressure. (4) The distribution of the Gulong shale oil and the Fuyu tight oil is influenced by overpressure, with the northwestern part of the sag and the adjacent sand bodies being the respectively favorable areas. These results lay the groundwork for accurately reconstructing paleopressure and better understanding the hydrocarbon accumulation potential of shale oil and Fuyu tight oil. They also provide guidance on the exploration and development of unconventional resources. Full article

The Mindong–Changchunling region is situated in the central portion of the Songliao Basin, Northeast China. The primary target stratum in this area is the Fuyu Oil Layer of the Lower Cretaceous Quantou 4 Member. This reservoir is predominantly composed of fine sandstone and siltstone, with minor interbedded medium sandstone. Variations in provenance, sedimentation, and diagenesis are identified as the main controlling factors for the distribution of high-quality reservoirs in the Mindong–Changchunling region. The sand body distribution in the Changchunling area is influenced by the eastern near-source provenance. The reservoir properties of these sand bodies are impacted by the poor sorting and high mud content typical of near-source delta sand bodies. Nonetheless, reservoir quality is enhanced by late-stage uplift and surface water dissolution-leaching. In contrast, sand body distribution in the Mindong area is governed by the southwestern far-source provenance. Far-source delta sand bodies are characterized by better sorting but high mud content, with their reservoir properties primarily impaired by carbonate cementation. During the early-middle diagenetic stage, feldspar dissolution by organic acids improves sand body reservoir quality. Due to variations in sedimentation and diagenesis, the following three favorable reservoir zones with distinct genetic types have developed in the Mindong–Changchunling area: the Chang107–Chang104–Chang52 well block, the Fu155–Fu161–Fu157 well block, and the Min103–Min31 well block. Full article

Twenty-nine sediment samples were collected from Hurghada Bay, a highly impacted coastal area along the Northern Red Sea of Egypt, to evaluate environmental quality and human-induced effects on benthic ostracods. As potential bioindicators, benthic ostracods are highly responsive to environmental disturbances, with pollution leading to reduced abundance, lower diversity, and increased opportunistic taxa. To investigate the link between ostracod assemblages and sediment contamination, we measured the concentrations of eight heavy metals (Cu, Cd, Zn, Pb, As, Cr, Ni, and Mn) using inductively coupled plasma–atomic emission spectrometry (ICP-AES). Multivariate statistical analyses identified three distinct ostracod assemblages distributed across three station groups with varying pollution levels. Group I, associated with offshore stations, exhibited low to moderate heavy metal (HM) concentrations and high ostracod abundance and was dominated by Moosella striata, Hiltermannicythere rubrimaris, Ruggieria danielopoli, Neonesidea schulzi, and Paranesidea fracticorallcola, where the water depth and sand content are the main controlling factors. In contrast, Group II, corresponding to stations with the highest HMs and total organic matter (TOM), was dominated by pollution-tolerant species Jugosocythereis borchersi, Cyprideis torosa, Alocopocythere reticulata, and, to a lesser extent, Ghardaglaia triebeli, with reduced ostracod density and diversity. Group III, characterized by stations influenced by the mud-controlling factor, had the lowest HMs and was dominated by pollution-sensitive species Xestoleberis rhomboidei, Paranesidea fortificata, and Loxocorniculum ghardaquensis. These findings highlight the ecological risks posed by HM pollution and emphasize the urgent need for pollution mitigation strategies and continued monitoring to preserve the Red Sea’s benthic biodiversity. Full article

Deep drilling and horizontal wells, as important means of unconventional oil and gas development, face problems with the high energy consumption but low removal efficiency of traditional well washing equipment, the uneven cleaning of horizontal well intervals, and an insufficient degree of automation. This paper proposes a novel hydraulic drive well washing device which consists of two main units. The wellbore cleaning unit comprises a hydraulic drive cutting–flushing module, a well cleaning mode-switching module, and a filter storage module. The unit uses hydraulic and mechanical forces to perform combined cleaning to prevent mud and sand from settling. By controlling the flow direction of the well washing fluid, it can directly switch between normal and reverse washing modes in the downhole area, and at the same time, it can control the working state of corresponding modules. The assembly control unit includes the chain lifting module and the arm assembly module, which can lift and move the device through the chain structure, allow for the rapid assembly of equipment through the use of a mechanical arm, and protect the reliability of equipment through the use of a centering structure. The device converts some of the hydraulic power into mechanical force, effectively improving cleaning and plugging removal efficiency, prolonging the downhole continuous working time of equipment, reducing manual operation requirements, and comprehensively improving cleaning efficiency and energy utilization efficiency. Full article