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Keywords = modified asphalt mastic

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16 pages, 2504 KiB  
Article
Thermal Field and High-Temperature Performance of Epoxy Resin System Steel Bridge Deck Pavement
by Rui Mao, Xingyu Gu, Jiwang Jiang, Zhu Zhang and Kaiwen Lei
Materials 2025, 18(13), 3109; https://doi.org/10.3390/ma18133109 - 1 Jul 2025
Viewed by 325
Abstract
Epoxy Resin System (ERS) steel bridge pavement, which comprises a resin asphalt (RA) base layer and a modified asphalt wearing course, offers cost efficiency and rapid installation. However, the combined effects of traffic loads and environmental conditions pose significant challenges, requiring greater high-temperature [...] Read more.
Epoxy Resin System (ERS) steel bridge pavement, which comprises a resin asphalt (RA) base layer and a modified asphalt wearing course, offers cost efficiency and rapid installation. However, the combined effects of traffic loads and environmental conditions pose significant challenges, requiring greater high-temperature stability than conventional pavements. The thermal sensitivity of resin materials and the use of conventional asphalt mixtures may weaken deformation resistance under elevated temperature conditions. This study investigates the thermal field distribution and high-temperature performance of ERS pavements under extreme conditions and explores temperature reduction strategies. A three-dimensional thermal field model developed using finite element analysis software analyzes interactions between the steel box girder and pavement layers. Based on simulation results, wheel tracking and dynamic creep tests confirm the superior performance of the RA05 mixture, with dynamic stability reaching 23,318 cycles/mm at 70 °C and a 2.1-fold improvement in rutting resistance in Stone Mastic Asphalt (SMA)-13 + RA05 composites. Model-driven optimization identifies that enhancing internal airflow within the steel box girder is possible without compromising its structural integrity. The cooling effect is particularly significant when the internal airflow aligns with ambient wind speeds (open-girder configuration). Surface peak temperatures can be reduced by up to 20 °C and high-temperature durations can be shortened by 3–7 h. Full article
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21 pages, 5570 KiB  
Article
Influence of Mineral Powder Content and Gradation on the Aging and High-Temperature Rheological Properties of Styrene-Butadiene-Styrene (SBS) Modified Asphalt
by Chengwei Xing, Zhibin Chang, Bohan Zhu, Tian Jin, Qing Ma and Jie Wang
Materials 2025, 18(12), 2785; https://doi.org/10.3390/ma18122785 - 13 Jun 2025
Viewed by 372
Abstract
This paper aims to explore the influences of the content and gradation of mineral powder on the rheological properties of styrene-butadiene-styrene (SBS) modified asphalt mastic at different aging stages and temperatures. In the experiment, SBS modified asphalt mastic samples with different powder-to-binder ratios [...] Read more.
This paper aims to explore the influences of the content and gradation of mineral powder on the rheological properties of styrene-butadiene-styrene (SBS) modified asphalt mastic at different aging stages and temperatures. In the experiment, SBS modified asphalt mastic samples with different powder-to-binder ratios (0.6, 0.8, and 1.0) and different mineral powder gradations (500 mesh passing rates of 76.89% and 100%) were prepared. Following aging periods of 5, 25, and 45 h in the pressure aging vessel (PAV), the asphalt underwent comprehensive rheological characterization using a dynamic shear rheometer (DSR). The research shows that mineral powder can boost mastic’s deformation resistance and elastic effect. When aged by PAV for 45 h, the powder-to-binder ratio increased from 0.6 to 1.0, and its complex modulus increased by nearly 2.5 times at 58 °C. For SBS modified asphalt mastic of PAV 0 h, the powder-to-binder ratio increased from 0.6 to 1.0 and its phase angle was reduced from 59.6 to 53.2, which indicated that the elasticity of mastic was improved. However, this accelerated the degradation rate of SBS, making the aging process more complex. Fine-grained mineral powder is more effective in enhancing mastic’s deformation resistance than coarse-grained mineral powder. The fine-graded mastic had better rutting resistance after 45 h of aging than after 25 h of aging because the mineral powder compensated for the SBS loss-induced elasticity reduction. Smaller mineral powder particles lead to better a mastic anti-aging effect. After 45 h of aging, fine-grained mineral powder offered a better elastic effect. But the ways in which mineral powder and SBS boost mastic elasticity differ greatly. The results of this study provide a reference for optimizing the design of asphalt mixtures. Full article
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12 pages, 2269 KiB  
Article
Investigation of Rutting and Aging Performance of Gap-Graded Rubberized Asphalt Mixtures
by Marek Pszczola and Bohdan Dolzycki
Materials 2025, 18(10), 2263; https://doi.org/10.3390/ma18102263 - 13 May 2025
Viewed by 439
Abstract
Gap-graded asphalt mixtures like stone mastic asphalt (SMA), porous asphalt (PA), and asphalt mixtures for very thin layers (fr. Béton Bitumineuse Très Mince—BBTM) are usually made with the use of SBS (styrene-butadiene-styrene) polymer-modified bitumen. This is a binder that allows one to achieve [...] Read more.
Gap-graded asphalt mixtures like stone mastic asphalt (SMA), porous asphalt (PA), and asphalt mixtures for very thin layers (fr. Béton Bitumineuse Très Mince—BBTM) are usually made with the use of SBS (styrene-butadiene-styrene) polymer-modified bitumen. This is a binder that allows one to achieve the required parameters, but at the same time, its use increases the costs of making pavement layers. An alternative to polymer-modified bitumen (SBS) is rubber-modified bitumen. The research presented in this publication includes an assessment of the resistance to permanent deformation and susceptibility to aging of SMA and porous asphalt (PA) mixtures containing both SBS polymer-modified bitumen and rubber-modified bitumen, where the modification process was carried out directly in the refinery. The laboratory tests of resistance to deformation were assessed based on the rutting test and on the assessment of the dynamic modulus (SPT). The changes in the tested asphalt mixtures after aging in laboratory conditions were assessed based on the changes in the stiffness modulus (IT-CY) and the changes in the indirect tensile strength (ITS) after the short-term and long-term aging processes. The presented research results clearly show that the use of rubber-modified bitumen produced in industrial conditions (i.e., in a refinery) allows one to obtain gap-graded mixtures that are as resistant to permanent deformation as mixtures containing SBS polymer-modified bitumen. Similar conclusions resulted from the study of susceptibility to aging. Changes after aging for both types of asphalt mixtures were at a similar level. The presented results clearly indicate that, in the case of gap-graded mixtures such as SMA- and PA-type mixtures, they meet the rutting and aging expectations when either expensive modified bitumen or a cheaper, more environmentally friendly alternative (rubber-modified bitumen) is used. Full article
(This article belongs to the Special Issue Innovative Approaches in Asphalt Binder Modification and Performance)
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19 pages, 4587 KiB  
Article
Zinc Oxide as a Filler in a Hot-Mix Asphalt: Impact on Mechanical Properties
by Hugo Alexander Rondón-Quintana, Karem Tatiana Forero-Rubiano, Yohan Sebastián Valderrama-Agudelo, Juan Gabriel Bastidas-Martínez and Carlos Alfonso Zafra-Mejía
Infrastructures 2025, 10(5), 110; https://doi.org/10.3390/infrastructures10050110 - 29 Apr 2025
Viewed by 491
Abstract
Zinc oxide (ZnO) exhibits promising thermochemical properties when used as an asphalt binder modifier. Its micrometric size further enhances its potential as a substitute for natural fillers (NFs) in hot-mix asphalt (HMA). This study evaluates the effect of partially and fully replacing NFs [...] Read more.
Zinc oxide (ZnO) exhibits promising thermochemical properties when used as an asphalt binder modifier. Its micrometric size further enhances its potential as a substitute for natural fillers (NFs) in hot-mix asphalt (HMA). This study evaluates the effect of partially and fully replacing NFs with ZnO on the mechanical performance of HMA, addressing a research gap since the influence of ZnO as a filler in asphalt mixtures has not been previously investigated. NFs were replaced by ZnO at weight-based proportions of ZnO/NF = 25, 50, 75, and 100%. Initially, the morphology of NF and ZnO particles was analyzed using Scanning Electron Microscopy (SEM). Asphalt mastics were then produced with the same ZnO/NF proportions and subjected to conventional characterization tests, including penetration, softening point, and viscosity. In the next phase, HMA samples were designed using the Marshall method, incorporating ZnO at 0, 25, 50, and 100% replacement levels (designated as Control, HMA-25, HMA-50, and HMA-100, respectively). The mechanical performance of these mixtures was assessed through indirect tensile strength (ITS) and Cantabro tests. Based on the initial results, further evaluations were conducted on the Control, HMA-50, and HMA-100 mixtures to determine their resilient modulus, fatigue behavior under stress-controlled conditions, and resistance to permanent deformation (static creep test). The findings indicate that ZnO can replace NF in HMA without compromising Marshall stability or Cantabro strength. Additionally, ZnO-modified HMAs exhibit increases in stiffness under cyclic loading, and improvements in resistance to permanent deformation, fatigue performance, and moisture damage. These enhancements occur despite a 0.5% reduction in binder content compared to the Control HMA and a slight increase in porosity. Full article
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20 pages, 5670 KiB  
Article
Performance Evaluation of Waste Rubber-Modified Asphalt Mixtures: A Comparative Study of Asphalt Concrete and Stone Mastic Asphalt Gradings
by Ivana Ban, Ivana Barišić, Marijana Cuculić and Matija Zvonarić
Infrastructures 2025, 10(5), 107; https://doi.org/10.3390/infrastructures10050107 - 25 Apr 2025
Viewed by 703
Abstract
Crumb rubber (CR) obtained from end-of-life tyres (ELT) has gained significant attention in the sustainable design of asphalt pavements in recent years, showing a promising perspective in the enhancement of pavement performance related to its structural and functional properties. Existing research on CR [...] Read more.
Crumb rubber (CR) obtained from end-of-life tyres (ELT) has gained significant attention in the sustainable design of asphalt pavements in recent years, showing a promising perspective in the enhancement of pavement performance related to its structural and functional properties. Existing research on CR influence on pavement performance mostly focused on peculiarities of asphalt mixture modification procedures—dry and wet processes, CR content in the mixture and CR particle size. In this study, a laboratory-based experimental investigation of CR effect on two different mixture gradations, namely dense-graded and gap-graded mixtures with three different binder contents, was performed. CR was added in mixtures through binder modification, with a constant CR content of 18% by binder weight in all mixtures. Volumetric properties—maximum mixture density, bulk density and void characteristics, alongside mechanical properties determined by the Marshall test method—were determined on unmodified and modified mixtures. The goal was to evaluate the influence of CR modification with respect to three different binder contents. The results showed that gap-graded mixtures are more sensitive to change in CR modified binder content in comparison to dense-graded mixtures in terms of air voids content. Furthermore, the mechanical properties of CR-modified mixtures were slightly enhanced in gap-graded mixtures, showing a promising potential of CR modification for pavement performance. However, the choice of optimal binder content in CR-modified mixtures was shown to be a critical mixture design parameter due to the increased sensitivity of binder content change to the analysed voids properties and permanent deformations. Full article
(This article belongs to the Special Issue Sustainable Road Design and Traffic Management)
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17 pages, 5648 KiB  
Article
Performance Evaluation of Highly Modified Asphalt-Based Binders in High Friction Surface Treatment: Comparative Study with Epoxy-Based System
by Alireza Roshan, Magdy Abdelrahman and Mohyeldin Ragab
Buildings 2025, 15(9), 1425; https://doi.org/10.3390/buildings15091425 - 23 Apr 2025
Cited by 1 | Viewed by 376
Abstract
High Friction Surface Treatments (HFSTs) are frequently used to increase skid resistance and reduce collisions, particularly in crash-prone zones, including horizontal curves and intersections. Epoxy-based binders traditionally have been the sole option for HFSTs, but their drawbacks, such as high costs and compatibility [...] Read more.
High Friction Surface Treatments (HFSTs) are frequently used to increase skid resistance and reduce collisions, particularly in crash-prone zones, including horizontal curves and intersections. Epoxy-based binders traditionally have been the sole option for HFSTs, but their drawbacks, such as high costs and compatibility challenges, have led to the search for substitute binders, including asphalt-based options. This study investigates the comparative performance of highly modified asphalt-based binders, including polymer-modified, mastic, and highly modified emulsions, in HFST applications using two aggregate types, Calcined Bauxite (CB) and Rhyolite with different gradations, with an emphasis on their frictional properties, durability, and resistance to polishing. Laboratory evaluations, including the Pendulum Tester (BPT), Dynamic Friction Testing Equipment (DFT), Surface Texture Measurement Apparatus (CTM), and Binder Bond Strength Test (BBS), were carried out to examine the Coefficient of Friction (COF), Mean Profile Depth (MPD), and aggregate bonding and retention. In terms of durability and friction, this study indicated that highly modified asphalt-based binders performed better than PG binders and conventional emulsions. The highest BPT values, both prior to and following polishing, were consistently observed for CB, with the emulsion containing the highest reactive polymer modifier showing the smallest decrease in BPT value (12.86% for CB and 10.34% for Rhyolite). Epoxy showed a greater COF retention over lengthy polishing cycles; however, highly polymer-modified (PM) binders like PG82-22 (PM) performed better than Epoxy under specific conditions. The macrotexture analysis revealed that Epoxy-based samples retained surface texture for further polishing cycles, while Mastic2 and PG82-22 (PM) also showed strong MPD retention. These findings highlight the importance of optimizing aggregate–binder combinations to ensure durable and effective HFST applications. Full article
(This article belongs to the Special Issue New Technologies for Asphalt Pavement Materials and Structures)
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22 pages, 20398 KiB  
Article
Rheological and Microstructural Characterization of Steel Slag Powder-Modified Asphalt Mastics: Insights into High-Temperature Performance Enhancement
by Xiaodong Xie, Jie Gao, Zongjie Yu, Liang Song and Xuzhi Zhu
Materials 2025, 18(6), 1357; https://doi.org/10.3390/ma18061357 - 19 Mar 2025
Viewed by 391
Abstract
This study systematically investigates the rheological modification mechanism of steel slag powder (SSP) as an alternative filler in asphalt mastics, with comparative analysis against conventional limestone powder (LP). Four filler-to-asphalt (F/A) ratios (0.6–1.2) were employed to prepare modified mastics. Comprehensive characterization through laser [...] Read more.
This study systematically investigates the rheological modification mechanism of steel slag powder (SSP) as an alternative filler in asphalt mastics, with comparative analysis against conventional limestone powder (LP). Four filler-to-asphalt (F/A) ratios (0.6–1.2) were employed to prepare modified mastics. Comprehensive characterization through laser diffraction analysis, BET nitrogen adsorption, and scanning electron microscopy (SEM) revealed SSP’s significant microstructural advantages: a 29.2% smaller median particle size (D50) and 7.06% larger specific surface area compared to LP, accompanied by enhanced interparticle connectivity and morphological complexity. Rheological evaluation via dynamic shear rheology (DSR) demonstrated SSP’s superior performance enhancement—particularly at elevated F/A ratios (1.0–1.2), where multiple stress creep recovery (MSCR) tests showed a 6.9–46.06% improvement in non-recoverable creep compliance (Jnr) over LP-modified counterparts. The temperature sweep analysis indicated SSP’s effectiveness in reducing the temperature susceptibility index by 9.37–18.06% relative to LP. Fourier-transform infrared spectroscopy (FTIR) combined with two-dimensional correlation analysis (2D-COS) confirmed the dominance of physical interactions over chemical bonding in the SSP–asphalt interface. The results establish SSP’s dual functionality as both a rheological modifier and sustainable construction material, providing mechanistic insights for optimizing steel slag utilization in pavement engineering. Full article
(This article belongs to the Section Construction and Building Materials)
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14 pages, 4385 KiB  
Article
Mechanistic Fatigue Performance Evaluation of Stone Mastic Asphalt Mixtures: Effect of Asphalt Performance Grade and Elastic Recovery
by Jongsub Lee, Sungjin Lee, Yujoong Hwang, Ohsun Kwon and Gyumin Yeon
Polymers 2024, 16(17), 2414; https://doi.org/10.3390/polym16172414 - 26 Aug 2024
Viewed by 1431
Abstract
This study evaluates the crack performance of stone mastic asphalt (SMA) mixtures according to the performance of a modified asphalt binder, evaluated based on the asphalt performance grade (PG) and the elastic recovery of multiple stress creep and recovery (MSCR) according to AASHTO [...] Read more.
This study evaluates the crack performance of stone mastic asphalt (SMA) mixtures according to the performance of a modified asphalt binder, evaluated based on the asphalt performance grade (PG) and the elastic recovery of multiple stress creep and recovery (MSCR) according to AASHTO M 320 and T 350. The cracking performance of the mixture was evaluated using the asphalt mixture performance tester (AMPT) according to AASHTO T 378 and T 400 through dynamic modulus and direct tension cyclic fatigue tests. Furthermore, the recently developed viscoelastic continuum damage (VECD) theory was utilized to evaluate the cyclic fatigue index parameter (apparent damage capacity, Sapp) and the permissible heavy vehicle class. For performance evaluation, six modified asphalt mixtures were prepared and tested using SMA aggregate gradation with a nominal maximum aggregate size (NMAS) of 10 mm. The MSCR test results revealed that, of the six asphalt mixtures, the rubber-based PG76-28 exhibited the least initial strain and the highest elastic recovery. The dynamic modulus test results demonstrated that using a rubber-based modifier increased the elastic modulus at high temperatures and decreased it at low temperatures, thereby enhancing resistance to plastic deformation in the summer and reducing low-temperature cracking in the winter. Finally, the correlation between the Sapp performance index and the elastic recovery of modified asphalt and the number of direct tension cyclic loads until failure of the mixture was evaluated as 0.87 and 0.76, respectively. Full article
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14 pages, 5500 KiB  
Article
Laboratory Evaluation of Wear Particle Emissions and Suspended Dust in Tire–Asphalt Concrete Pavement Friction
by Jongsub Lee, Ohsun Kwon, Yujoong Hwang and Gyumin Yeon
Appl. Sci. 2024, 14(14), 6362; https://doi.org/10.3390/app14146362 - 22 Jul 2024
Cited by 2 | Viewed by 1279
Abstract
This study aims to evaluate the tire–road-wear particles (TRWPs) and suspended dust generated based on the nominal maximum aggregate size (NMAS) of the polymer-modified stone mastic asphalt (SMA) mixtures indoors. The SMA mixtures containing styrene butadiene styrene (SBS) polymer and the NMASs of [...] Read more.
This study aims to evaluate the tire–road-wear particles (TRWPs) and suspended dust generated based on the nominal maximum aggregate size (NMAS) of the polymer-modified stone mastic asphalt (SMA) mixtures indoors. The SMA mixtures containing styrene butadiene styrene (SBS) polymer and the NMASs of 19, 13, 10, 8, and 6 mm were used. Dust was generated from the wear of the tires and the pavement inside the indoor chamber by using the laboratory tire–road-wear particle generation and evaluation tester (LTRWP tester) developed by Korea Expressway Corporation (KEC). In this method, a cylindrical asphalt-mixture specimen rotates in the center, and a load is applied using three tires on the sides of the test specimen. During the test, a digital sensor was used to measure the concentration for each particle size. After the test was completed, the dust was collected and weighed. According to the test results, the generated TRWP emissions were reduced by approximately 0.15 g as the NMAS of the SMA mixture decreased by 1 mm. TRWP emissions decreased by 20% when using the 6 mm SMA mixture compared to the 13 mm SMA mixture. For practical application, a predicted equation of TRWP emissions estimation was developed by using the concentration of suspended dust measured by the digital sensor in the LTRWP tester. LTRWP can be used as an indoor test method to evaluate pavement and tire materials to reduce the amount of dust generated from tire and pavement wear. Full article
(This article belongs to the Special Issue Advances in Renewable Asphalt Pavement Materials)
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15 pages, 3836 KiB  
Article
The Effect of the Temperature–Humidity Coupling Cycle on the Performance of Styrene Butadiene Styrene Polymer-Modified Asphalt Mastic
by Chao Ma, Youliang Su, Bo Tan, Yuzhu Fan and Wanzhen Zhang
Appl. Sci. 2024, 14(12), 5047; https://doi.org/10.3390/app14125047 - 10 Jun 2024
Viewed by 1406
Abstract
To study the variation laws and effects of asphalt mastic under the cooperative interaction of different temperatures and humidities, cyclic conditions for different temperature ranges were set to conduct indoor experimental simulations of thermal–humidity coupling cycles. Firstly, the macroscopic performance changes in styrene [...] Read more.
To study the variation laws and effects of asphalt mastic under the cooperative interaction of different temperatures and humidities, cyclic conditions for different temperature ranges were set to conduct indoor experimental simulations of thermal–humidity coupling cycles. Firstly, the macroscopic performance changes in styrene butadiene styrene polymer (SBS)-modified asphalt mastic were evaluated by the penetration test, softening point test, ductility test, Brookfield rotational viscosity test, and double-edge notched tensile (DENT) test; then, the mechanism of performance changes was explored from the perspective of chemical composition by combining this with Fourier transform infrared spectroscopy (FTIR). The research results show that with the increase in thermal–humidity coupling cycles, SBS-modified asphalt mastic exhibited aging phenomena such as hardening and embrittlement, and its macroscopic performance deteriorated; under the same test conditions, the interval with a higher temperature difference had a greater impact on the performance of the mastic; the sulfoxide index (IS=O) of SBS-modified asphalt mastic increases after thermal–humidity coupling cycles, while the isoprene index (IB) decreases. Full article
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14 pages, 4850 KiB  
Article
Evaluation of Rheological Properties of Polymer-Modified Asphalt Binders and Mastics with Organic Additive—Imidazoline
by Marta Mielczarek, Sylwia Fornalczyk and Mieczysław Słowik
Sustainability 2024, 16(4), 1434; https://doi.org/10.3390/su16041434 - 8 Feb 2024
Cited by 1 | Viewed by 1504
Abstract
The article presents the results of testing the asphalt binder modified with SBS copolymer (5%) and its mixture with mineral fillers called asphalt mastics. The aim of the research and analysis was to check the possibility of using an organic additive in the [...] Read more.
The article presents the results of testing the asphalt binder modified with SBS copolymer (5%) and its mixture with mineral fillers called asphalt mastics. The aim of the research and analysis was to check the possibility of using an organic additive in the form of imidazolines and to assess their impact on the viscoelastic properties of the obtained asphalt mastics. The main advantage of using imidazoline is the increased resistance of asphalt mixtures to low-temperature cracking at the top of the road route and reducing its maintenance costs. Based on the examination of the adhesion of the binder with the addition of various imidazolines to the aggregate, a selection was made from six analyzed subtypes. One of them was selected for further research. The tests were carried out in a dynamic shear rheometer in a wide temperature range from −36 °C to 82 °C, determining the most important parameters of the tested materials, i.e., dynamic shear modulus (|G*|), phase angle (δ) and the non-recoverable creep compliance (Jnr). The test results and their analysis confirmed the beneficial effect of imidazoline on the viscoelastic properties of mastics in the low-temperature range, even at the lowest content of 0.2%. Based on the results of the determination of Jnr and |G*|/sinδ in the range of high operating temperatures, no significant deterioration in permanent deformation parameters was observed. Moreover, the use of imidazoline reduces technological temperatures during the production of HMA used in the pavement and, therefore, reduces CO2 emissions into the atmosphere. Full article
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22 pages, 7703 KiB  
Article
Surface Modification of Recycled Polyester Fiber and Performance Evaluation of Its Asphalt Mastic and Mixture
by Lei Xia, Dongwei Cao, Hongliang Zhang, Mingming Zhang, Lingyan Shan, Haiyan Zhang and Taiwei Wang
Sustainability 2024, 16(1), 278; https://doi.org/10.3390/su16010278 - 28 Dec 2023
Cited by 5 | Viewed by 1831
Abstract
The use of recycled polyester fiber (Re-PET) partially addresses the scarcity of non-renewable polyester (PET), but its thermal resistance in asphalt mixtures is relatively low. To enhance the reutilization and thermal resistance of Re-PET, it was modified through in situ growth grafting with [...] Read more.
The use of recycled polyester fiber (Re-PET) partially addresses the scarcity of non-renewable polyester (PET), but its thermal resistance in asphalt mixtures is relatively low. To enhance the reutilization and thermal resistance of Re-PET, it was modified through in situ growth grafting with tetrahedral nanoSiO2. A novel nanoSiO2 hybrid material (SiO2/Re-PET) was successfully prepared, and the effects of the surface modification on the morphology and thermal resistance of the Re-PET were investigated with the examination of its mechanism of modification. The results demonstrated an increase in the surface roughness and specific surface area of SiO2/Re-PET, as well as a higher melting point and structural stability compared to Re-PET. Subsequently, Re-PET and SiO2/Re-PET asphalt mastics under a filler–asphalt ratio of 1.0 were prepared, and their classical and rheological properties were investigated and compared. The results indicated an increase in the softening point and shear strength of SiO2/Re-PET asphalt mastic, as well as a significant improvement in its high-temperature performance. Furthermore, subsequent pavement performance tests revealed a significant improvement in the performance of SiO2/Re-PET asphalt mixtures compared to Re-PET asphalt mixtures. Consequently, the findings of this research promote the recycling of Re-PET, ultimately advocating for the sustainability of pavement construction. Full article
(This article belongs to the Special Issue Sustainable Development of Asphalt Materials and Pavement Engineering)
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20 pages, 3805 KiB  
Article
Investigation of Self-Healing Performance of Asphalt Mastic—From the Perspective of Secondary Aging
by Bo Li, Yu Wang, Peng Xiao, Aihong Kang, Yao Zhang and Zhengguang Wu
Materials 2023, 16(24), 7567; https://doi.org/10.3390/ma16247567 - 8 Dec 2023
Cited by 4 | Viewed by 1460
Abstract
Reclaimed asphalt pavement (RAP) has been widely utilized because it is an environmentally friendly and economical material. The performance of recycled asphalt mixtures will deteriorate gradually with the secondary aging process of asphalt, including the self-healing property. To further understand the self-healing characteristics [...] Read more.
Reclaimed asphalt pavement (RAP) has been widely utilized because it is an environmentally friendly and economical material. The performance of recycled asphalt mixtures will deteriorate gradually with the secondary aging process of asphalt, including the self-healing property. To further understand the self-healing characteristics of asphalt after secondary aging, taking 70# petroleum asphalt, SBS-modified asphalt, and extracted old asphalt mastics as objects, the fatigue self-healing test and fracture self-healing test were conducted to simulate the intermediate-and low-temperature healing behaviors of different asphalt mastics. The impact of healing time, healing temperature, and aging degree of mastics on the healing performance was systematically investigated. The results show that the original unaged asphalt mastics present excellent fatigue healing properties with an index of 0.796 and 0.888 for 70# petroleum and SBS-modified asphalt mastics, respectively. The secondary aging process causes significant impact on the healing properties, leading to a great drop in the corresponding index, which decreased to 47.5% and 72.5% of that of the unaged ones. The fracture healing ability of all mastics was much inferior to the fatigue healing. After secondary aging, the fracture healing index values of 70# petroleum asphalt, SBS-modified asphalt, and extracted old asphalt mastics were all as low as around 0.3, indicating similar performance can be found in the secondary aged SBS-modified asphalt mastics and 70# asphalt mastics. Overall, after secondary aging, the fatigue damage of SBS-modified asphalt mastics can be cured effectively by self-healing, but the fatigue and fracture self-healing properties of 70# asphalt mastics are difficult to recover. These results could provide an innovative view to understand the fatigue and fracture healing characteristics of recycled asphalt pavement after secondary aging. Full article
(This article belongs to the Special Issue Green and Sustainable Infrastructure Construction Materials)
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22 pages, 14567 KiB  
Article
Impact of Rejuvenator-Modified Mastic on Asphalt Mixture Stiffness: Meso-Scale Discrete Element Method Approach
by Gustavo Câmara, Nuno Monteiro Azevedo and Rui Micaelo
Buildings 2023, 13(12), 3023; https://doi.org/10.3390/buildings13123023 - 5 Dec 2023
Cited by 7 | Viewed by 1305
Abstract
Encapsulated rejuvenators embedded in asphalt mixtures are a promising technology to extend the service life of asphalt pavements. However, their effects on the asphalt mixture’s performance still need to be properly understood. A recently developed three-dimensional discrete element method framework enables the evaluation [...] Read more.
Encapsulated rejuvenators embedded in asphalt mixtures are a promising technology to extend the service life of asphalt pavements. However, their effects on the asphalt mixture’s performance still need to be properly understood. A recently developed three-dimensional discrete element method framework enables the evaluation of non-homogeneous distributions of the rejuvenator, closely resembling real conditions. This includes different scenarios involving capsule content and release efficiency. The presented numerical results show that the rejuvenator-to-mastic ratio and the number of rejuvenator-modified contacts influence the stiffness properties of asphalt mixtures. In cases where a homogeneous rejuvenator distribution is assumed, the three-dimensional DEM model predicts a significant reduction in the asphalt mixture’s stiffness that compromises the pavement’s performance. Simulations show that the diffusion effect needs to be considered for predicting the post-healed behavior of asphalt mixtures. For cases considering more suitable modified mastic amounts (less than 1.20 wt%), the effect on the asphalt mixture’s stiffness modulus is less pronounced, and the phase angle is not significantly affected. Additionally, the presented simulations suggest that the capsule content can be increased up to 0.75 wt%, and capsules with a release rate higher than 48% can be used without compromising the rheological performance of asphalt mixtures, possibly improving their self-healing properties. These numerical insights should be considered in future designs to achieve optimal post-healed behavior. Full article
(This article belongs to the Special Issue Multiphysics Analysis of Construction Materials)
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16 pages, 5562 KiB  
Article
Interfacial Water Stability between Modified Phosphogypsum Asphalt Mortar and Aggregate Based on Molecular Dynamics
by Cancan Liang, Yilang Li, Ponan Feng and Yuanle Li
Polymers 2023, 15(22), 4412; https://doi.org/10.3390/polym15224412 - 15 Nov 2023
Cited by 2 | Viewed by 1251
Abstract
The objective of this study is to unravel the modification mechanism of a coupling agent on the water sensitivity of phosphogypsum asphalt mortar. The adhesion process of phosphogypsum asphalt mastic modified with three kinds of coupling agents (KH-550, KH-570, and CS-101) and raw [...] Read more.
The objective of this study is to unravel the modification mechanism of a coupling agent on the water sensitivity of phosphogypsum asphalt mortar. The adhesion process of phosphogypsum asphalt mastic modified with three kinds of coupling agents (KH-550, KH-570, and CS-101) and raw phosphogypsum to the aggregate minerals was simulated based on the molecular dynamics software, Materials Studio 2020, and the water film layer was considered along the simulation. When the three coupling agents were added, the interfacial adhesion work gradually increased with the increase of modified phosphogypsum dosage, and the trends of each model were relatively similar. With the increase of simulation time, the mean square displacement of water molecules of the three interfacial models showed different trends, and the increasing trend rank was unmodified phosphogypsum > KH-550 > KH-570 > CS-101. The diffusion coefficient of the water molecular layer of asphalt mastic modified with CS-101 coupling agent in phosphogypsum shows a significant decrease with the increase of CS-101-modified phosphogypsum (more than 5% mass ratio to asphalt). Compared to raw phosphogypsum asphalt mortar, the addition of coupling agents can significantly limit the diffusion of water molecules and effectively improve the interfacial adhesion work, in which CS-101 coupling agent has the best effect, followed by KH-570 and KH-550. Full article
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