Search Results (730)

In our study, supercapacitor electrodes were prepared by depositing electroless Ni-B coating on copper plates, followed by nitric acid etching. The composition and the micro- and phase structure of the coatings were investigated by ICP-OES, PFIB-SEM, and XRD techniques. The original pebble-like structure of the coating consists of 0.8–10 µm particles, with an X-ray amorphous phase structure. The surface morphology and porosity of the coating can be tuned simply by changing the etching time. The supercapacitive performance of the electrodes was evaluated by means of cyclic voltammetry, galvanostatic charge–discharge, and electrochemical impedance spectroscopy measurements. The capacitance of the coating was found to vary on the etching time according to a maximum function, allowing for the determination of an optimal duration to obtain a specific capacitance of 157 mF/cm² (at 0.5 A/g). An excellent charge storage retention of 178% was found after 5000 CV cycles at a scan rate of 50 mV/s owing to the evolved electrochemically active network on the surface of the electrode, indicating a long-term stable and reliable electrode. Full article

Dried lemon slices (LSs) have become increasingly popular as a healthful beverage when infused in hot water. This study examined the effects of freeze drying (FD), hot air drying (HAD), heat pump drying (HPD), and far-infrared drying (FID) on the quality of dried LSs and their brewed beverages. The results show that FD-LSs and their corresponding beverages have the most appealing appearance and maximum levels of ascorbic acid (2.47 and 0.80 mg/g, respectively), synephrine (8.15 and 0.94 mg/g, respectively), and the overwhelming majority of natural and available phenolic compounds, as well as the strongest antioxidant activity, although numerous volatile compounds in FD-LSs were in the lowest abundances. HPD-LSs exhibited similar trends to FD-LSs but contained the peak concentrations of limonene (2258.87 μg/g), γ-terpinene (704.19 μg/g), β-pinene (502.92 μg/g), and α-pinene (188.91 μg/g), which were the four most abundant volatile compounds in dried LSs. Additionally, active ingredients in HPD-LSs generally featured relative high levels of available amounts. In contrast, HAD- and FID-LSs typically displayed unfavorable coloration and low retention levels of natural and available active ingredients. Consequently, FD and HPD demonstrate superior suitability for the commercial-scale production of dried LSs. Full article

Optimizing water resource utilization is a critical challenge to meet the dramatic increase in food demand. Therefore, continuous studies to minimize water demand for plants are highly needed. This study aims to employ HYDRUS (2D/3D) software to simulate the effects of continuous and intermittent water flow on soil water distribution under a subsurface point source. The constant parameters included loamy sand soil, a water application time of 30 min, and an emitter discharge of 3.41 L/h. The variable parameters consisted are two pipe depths (25 cm and 35 cm), three ratios of ON:OFF times (1ON:1OFF, 1ON:3OFF, and 1ON:5OFF), and five water application cycles (WF1C, WF2C, WF3C, WF4C, and WF5C, with WF1C as for the continuous water flow). The results revealed that, in 30 min of water application, continuous water flow and ON:OFF ratios of 1ON:1OFF and 1ON:3OFF achieved maximum water retention in the vicinity of the emitter. In 60 min, increasing cycles enhanced retention for 1ON:1OFF and 1ON:3OFF, yet the 1ON:5OFF time ratio achieved the highest water content near the emitter. In 120 min, the 1ON:1OFF ratio showed an insignificant effect with cycle variations, but 1ON:3OFF and 1ON:5OFF exhibited increased retention. Similarly, in 180 min, 1ON:1OFF was unaffected by cycles, whereas 1ON:3OFF and 1ON:5OFF significantly improved retention. After 360 min, all treatments displayed equal water retention relative to the emitter position. Also, the results revealed that increasing water application cycles and ON:OFF time ratios lead to more holding soil water content, especially at soil levels of 20, 30, and 40 cm. These results affirm that positioning the emitters line at 25 cm enhances water retention more effectively than at 35 cm. Ultimately, statistical analysis confirmed that the combination of pipe depth, water application cycles, and ON:OFF ratios significantly affects the retention of soil water content in the vicinity of the emitter. Full article

The dynamic non-equilibrium effect (DNE) describes the non-unique character of saturation–capillary pressure relationships observed under static, steady-state, or monotonic hydrodynamic conditions. Macroscopically, the DNE manifests as variations in soil hydraulic characteristic curves arising from varying hydrodynamic testing conditions and is fundamentally governed by soil matrix particle size distribution. Changes in the DNE across porous media with discrete particle size fractions are investigated via stepwise drying experiments. Through quantification of saturation–capillary pressure hysteresis and DNE metrics, three critical signatures are identified: (1) the temporal lag between peak capillary pressure and minimum water saturation; (2) the pressure gap between transient and equilibrium states; and (3) residual water saturation. In the four experimental sets, with the finest material (Test 1), the peak capillary pressure consistently precedes the minimum water saturation by up to 60 s. Conversely, with the coarsest material (Test 4), peak capillary pressure does not consistently precede minimum saturation, with a maximum lag of only 30 s. The pressure gap between transient and equilibrium states reached 14.04 cm H₂O in the finest sand, compared to only 2.65 cm H₂O in the coarsest sand. Simultaneously, residual water saturation was significantly higher in the finest sand (0.364) than in the coarsest sand (0.086). The results further reveal that the intensity of the DNE scales inversely with particle size and linearly with wetting phase saturation (Sw), exhibiting systematic decay as Sw decreases. Coarse media exhibit negligible hysteresis due to suppressed capillary retention; this is in stark contrast with fine sands, in which the DNE is observed to persist in advanced drying stages. These results establish pore geometry and capillary dominance as fundamental factors controlling non-equilibrium fluid dynamics, providing a mechanistic framework for the refinement of multi-phase flow models in heterogeneous porous systems. Full article

To investigate the remediation efficiency of different plant species on cadmium (Cd)-contaminated soil, this study conducted a pot experiment with two woody species (Populu adenopoda and Salix babylonica) and two herbaceous species (Artemisia argyi and Amaranthus hypochondriacus). Soils were collected from an abandoned coal mine and adjacent pristine natural areas within the dam-adjacent section of the Three Gorges Reservoir Area to establish three soil treatment groups: unpolluted soil (T1, 0.18 mg·kg⁻¹ Cd), a 1:1 mixture of contaminated and unpolluted soil (T2, 0.35 mg·kg⁻¹ Cd), and contaminated coal mine soil (T3, 0.54 mg·kg⁻¹ Cd). This study aimed to investigate the growth status of plants, Cd accumulation and translocation characteristics, and the relationship between them and soil environmental factors. Woody plants exhibited significant advantages in aboveground biomass accumulation. Under T3 treatment, the Cd extraction amount of S. babylonica (224.93 mg) increased by about 36 times compared to T1, and the extraction efficiency (6.42%) was significantly higher than other species. Among the herbaceous species, A. argyi showed the maximum Cd extraction amount (66.26 mg) and extraction efficiency (3.11%) during T2 treatment. While A. hypochondriacus exhibited a trend of increasing extraction amount but decreasing extraction efficiency with increasing concentration. With the exception of S. babylonica under T1 treatment (BCF = 0.78), the bioconcentration factor was greater than 1 in both woody (BCF = 1.39–6.42) and herbaceous species (BCF = 1.39–3.11). However, herbaceous plants demonstrated significantly higher translocation factors (TF = 1.58–3.43) compared to woody species (TF = 0.31–0.87). There was a significant negative correlation between aboveground phosphorus (P) content and root Cd (p < 0.05), while underground nitrogen (N) content was positively correlated to aboveground Cd content (p < 0.05). Soil total N and available P were significantly positively correlated with plant Cd absorption, whereas total potassium (K) showed a negative correlation. This study demonstrated that woody plants can achieve long-term remediation through biomass advantages, while herbaceous plants, with their high transfer efficiency, are suitable for short-term rotation. In the future, it is suggested to conduct a mixed planting model of woody and herbaceous plants to remediate Cd-contaminated soils in the tailing areas of reservoir areas. This would synergistically leverage the dual advantages of root retention and aboveground removal, enhancing remediation efficiency. Concurrent optimization of soil nutrient management would further improve the Cd remediation efficiency of plants. Full article

As a crucial manifestation of ecosystem water regulation and supply functions, water conservation plays a vital role in regional ecosystem development and sustainable water resource management. This study investigates nine major Chinese river basins (Songliao, Haihe, Huaihe, Yellow, Yangtze, Pearl, Southeast Rivers, Southwest Rivers, and Inland Rivers) through integrated application of the InVEST model and geographical detector model. We systematically examine the spatiotemporal heterogeneity of water conservation capacity and its driving mechanisms from 1990 to 2020. The results reveal a distinct northwest–southeast spatial gradient in water conservation across China, with lower values predominating in northwestern regions. Minimum conservation values were recorded in the Inland River Basin (15.88 mm), Haihe River Basin (42.07 mm), and Yellow River Basin (43.55 mm), while maximum capacities occurred in the Pearl River Basin (483.68 mm) and Southeast Rivers Basin (517.21 mm). Temporal analysis showed interannual fluctuations, peaking in 2020 at 130.98 mm and reaching its lowest point in 2015 at 113.04 mm. Precipitation emerged as the dominant factor governing spatial patterns, with higher rainfall correlating strongly with enhanced conservation capacity. Land cover analysis revealed superior water retention in vegetated areas (forests, grasslands, and cultivated land) compared to urbanized and bare land surfaces. Our findings demonstrate that water conservation dynamics result from synergistic interactions among multiple factors rather than single-variable influences. Accordingly, we propose that future water resource policies adopt an integrated management approach addressing climate patterns, land use optimization, and socioeconomic factors to develop targeted conservation strategies. Full article

Urban pluvial flooding (UPF) is an increasingly critical issue due to rapid urbanization and intensified precipitation driven by climate change that yet remains understudied in the Caribbean. This study analyzes the effects of UPF resulting from the transformation of a natural karstic landscape into an urbanized area considering a sub-watershed in Chetumal, Southern Mexican Caribbean, as a case study. Hydrographic numerical modeling was conducted using the IBER 2.5.1 software and the SCS-CN method to estimate surface runoff for a critical UPF event across three stages: (i) 1928—natural condition; (ii) 1998—semi-urbanized (78% coverage); and (iii) 2015—urbanized (88% coverage). Urbanization led to the orthogonalization of the drainage network, an increase in the sub-watershed area (20%) and mainstream length (33%), flow velocities rising 10–100 times, a 52% reduction in surface roughness, and a 32% decrease in the potential maximum soil retention before runoff occurs. In urbanized scenarios, 53.5% of flooded areas exceeded 0.5 m in depth, compared to 16.8% in non-urbanized conditions. Community-based knowledge supported flood extent estimates with 44.5% of respondents reporting floodwater levels exceeding 0.50 m, primarily in streets. Only 43.1% recalled past flood levels, indicating a loss of societal memory, although risk perception remained high among directly affected residents. The reported UPF effects perceived in the area mainly related to housing damage (30.2%), mobility disruption (25.5%), or health issues (12.9%). Although UPF events are frequent, insufficient drainage infrastructure, altered runoff patterns, and limited access to public shelters and communication increased vulnerability. Full article

The formation of soil cracks in soil slopes can compromise structural integrity. Guar gum, as a natural high-molecular-weight biopolymer, offers environmental and economic advantages in soil stabilizers due to its biodegradability, strong binding properties, and ability to form a three-dimensional network structure. To investigate its improvement effects, outdoor dry shrinkage cracking tests were conducted on silt loam using different guar gum dosages. Image preprocessing was performed using Photoshop software, and Python algorithms combined with the PCAS system were employed to quantitatively analyze the development process of cracks, revealing the evolution patterns of basic crack parameters, fractal dimensions, and probability entropy. The results indicate the following: (1) the addition of guar gum improves the water retention capacity of the soil, with the average moisture content of the samples decreasing as the guar gum content increases; (2) as the guar gum content increased, the total length, total area, and surface crack ratio of the cracks all increased, but the average crack width decreased significantly, with the maximum decrease reaching 9.8%, indicating that guar gum can effectively suppress the expansion of crack width and slow down the infiltration rate of rainwater; (3) the fractal dimension of crack area is less affected by guar gum content, while the fractal dimension of crack length is significantly influenced by guar gum content. Combining both parameters can effectively characterize crack morphology and distribution. The final fractal dimension of crack length generally ranges from 1.2 to 1.3, while the fractal dimension of the crack area remains stable between 1.55 and 1.65; (4) the addition of guar gum has a minor effect on the probability entropy of cracks, with a change of less than 3%, indicating that it does not significantly influence the randomness of cracks. Therefore, this study confirms that guar gum has a significant effect in controlling crack width and optimizing the uniformity of the crack network. Through its mechanisms of binding soil particles and delaying drying shrinkage, it provides an important reference for the ecological protection of cohesive soil slopes. Full article

This study aimed to evaluate the drying kinetics, microstructural features, moisture content, color, pH, aw, texture, acidity, rehydration capacity, and sensorial attributes of strawberry slices processed by different drying methodologies. Strawberry samples were processed by hot air-drying (HA, 60 °C, 0.5 m/s), freeze-drying (FD, 0.055 mbar), and pulsed electric field (PEF)-assisted freeze-drying (PEFFD, 1 kV/cm and 3.2 kJ/kg). PEF pre-treatment significantly increased cell membrane permeability by forming micropores, which led to a significant reduction in the moisture content of up to 8.87% and improved the drying efficiency. Nonetheless, this pre-treatment did not significantly alter the drying rate due to the inherent constraints of the freeze-drying process. PEFFD samples better retained their shape, volume, and visual quality, and exhibited a maximum rehydration capacity of 64.90%. The ascorbic acid retention was found to be higher in the FD and PEFFD when compared to HA. FD and PEFFD samples had an increase in both red and yellow hue. PEF shows promise as a pre-treatment technique, improving both the drying efficiency and strawberry quality. Further studies are needed to assess PEFFD’s industrial scalability and economic feasibility. Full article

Background/Objectives: The industrial extraction and purification processes of Cannabis sativa L. compounds are critical steps in creating formulations with reliable and reproducible therapeutic and sensorial attributes. Methods: For this study, standardized preparations of chemotype I were chemically analyzed, and the sensory attributes were studied to characterize the extraction and purification processes, ensuring the maximum retention of cannabinoids and minimization of other secondary metabolites. The industrial process used deep-cooled ethanol for selective extraction. Results: Taking into consideration that decarboxylation occurs in the process, the cannabinoid profile composition was preserved from the herbal substance to the herbal preparations, with wiped-film distillation under deep vacuum conditions below 0.2 mbar, as a final purification step. The profiles of the terpenes and cannabinoids in crude and purified Full-spectrum Extract Cannabis Oil (FECO) were analyzed at different stages to evaluate compositional changes that occurred throughout processing. Subjective intensity and acceptance ratings were received for taste, color, overall appearance, smell, and mouthfeel of FECO preparations. Conclusions: According to sensory analysis, purified FECO was more accepted than crude FECO, which had a stronger and more polarizing taste, and received higher ratings for color and overall acceptance. In contrast, a full cannabis extract in the market resulted in lower acceptance due to taste imbalance. The purification process effectively removed non-cannabinoids, improving sensory quality while maintaining therapeutic potency. Terpene markers of the flower were remarkably preserved in SOMAÍ’s preparations’ fingerprint, highlighting a major qualitative profile reproducibility and the opportunity for their previous separation and/or controlled reintroduction. The study underscores the importance of monitoring the extraction and purification processes to optimize the cannabinoid content and sensory characteristics in cannabis preparations. Full article

Walnut gluten (WGLU) is a plant-based protein rich in essential amino acids for the human body. Due to its poor water solubility and functional properties, its application in the food industry is limited. For the first time, this study looks into how different durations (0, 30, 60, 90, and 120 s) of atmospheric cold plasma (ACP) treatment affect the structure and functional properties of WGLU. ACP processing destroys the spatial structure of the WGLU and alters its functional properties. The comprehensive performance reached its best after 60 s of ACP treatment, the main manifestations included increased β-sheet content, reduced α-helix content, and unfolding of the tertiary structure, which ultimately improved the stability of emulsification and foam. Meanwhile, the solubility (86.35%), water retention rate (2.15 g/g), oil retention rate (5.31 g/g), emulsification rate (10.59 m²/g), and foaming rate (24.67%) of WGLU reached their maximum values. However, longer treatment times (90 and 120 s) induce WGLU aggregation, followed by decreased functional properties. In summary, the physicochemical and functional properties of WGLU can be significantly enhanced through ACP treatment, enhancing the bioavailability of gluten and providing an effective strategy for its application in food processing. Full article

An integrated process scheme is developed for valorizing filtered liquid digestates (FLD) from an industrial anaerobic digestion (AD) plant treating dairy-processing effluents with relatively low nutrient concentrations. The process scheme involves FLD treatment by nanofiltration (NF) membranes, followed by struvite recovery from the NF-retentate. An NF pilot unit (designed for this purpose) is combined with a state-of-the-art NF/RO process simulator. Validation of simulator results with pilot data enables reliable predictions required for scaling up NF systems. The NF permeate meets the standards for restricted irrigation and/or reuse. Considering the significant nutrient concentrations in the NF retentate (i.e., ~500 mg/L NH4-N, ~230 mg/L PO4-P), struvite recovery/precipitation is investigated, including determination of near-optimal processing conditions. Maximum removal of nutrients, through production of struvite-rich precipitate, is obtained at a molar ratio of NH₄:Mg:PO₄ = 1:1.5:1.5 and pH = 10 in the treated stream, attained through the addition of Κ₂HPO₄, ΜgCl₂·6H₂O, and NaOH. Furthermore, almost complete struvite precipitation is achieved within ~30 min, whereas precipitate/solid drying at modest/ambient temperature is appropriate to avoid struvite degradation. Under the aforementioned conditions, a significant amount of dry precipitate is obtained, i.e., ~12 g dry mass per L of treated retentate, including crystalline struvite. The approach taken and the obtained positive results provide a firm basis for further development of this integrated process scheme towards sustainable large-scale applications. Full article

Volatile fatty acids (VFA) are valuable intermediates with growing demand in chemical, pharmaceutical, and environmental applications. Their sustainable production from organic waste is increasingly explored in the context of circular economy and biorefinery models. This study investigates the co-fermentation of waste-activated sludge (WAS) and the organic fraction of municipal solid waste (OFMSW) as a strategy for integrated VFA and biogas production. Semi-continuous experiments were carried out to assess the effect of the substrates ratio (WAS:OFMSW = 90:10 and 30:70), hydraulic retention time (HRT), and pH control (5, 9, no control) on VFA yield and composition. Results showed that higher OFMSW content and alkaline conditions favoured VFA production, with a maximum yield of 144.9 mgHAc·gVS⁻¹ at pH 9 and 70:30 ratio. Acetate dominated, while butyrate production peaked at 114.1 mgHBu·gVS⁻¹ under high sludge conditions. However, the addition of alkali required for pH control may lead to excessive accumulation of alkaline-earth metal ions, which can disrupt biological processes due to their potential toxicity. Anaerobic digestion of fermentation residues enhanced biomethane yields significantly (0.27 NL·gVS⁻¹ vs. 0.05 NL·gVS⁻¹ from raw sludge). The proposed process demonstrates potential for converting wastewater treatment plants into biorefineries, maximising resource recovery while reducing environmental impact. Full article

Effective sustainable fish farming necessitates enhanced models that incorporate environmental variability and contemporary monitoring methods. This research presents an innovative framework for assessing and modeling the environmental carrying capacity based on phosphorus (ECCp) in tropical and neotropical lakes and reservoirs. The model evaluates phosphorus waste from tilapia farming (Oreochromis niloticus) under diverse climatic conditions and production scenarios in cage systems. Using bioenergetic modeling and Monte Carlo simulations, we estimated phosphorus retention in fish and maximum production limits across different temperatures (21 °C, 25 °C, 29 °C) and dietary phosphorus concentrations (0.8%, 1.2%, 2.1%) in Brazil’s Chavantes reservoir. Results indicated that phosphorus retention diminished with higher dietary phosphorus and increased temperatures, ranging from 51% (0.8% P) to 20% (2.1% P). Phosphorus discharge ranged from 3.3 to 20.5 kg/ton of fish produced. The ECCp model forecasted an allowable production of roughly 40 tons per year at full operational capacity, reflecting a 41% increase compared to current regulations. The model’s accuracy (96%) surpassed that of traditional regulatory frameworks, which rely on static parameters, emphasizing the shortcomings of existing practices. The findings promote enhanced modeling strategies, sophisticated monitoring, adaptive management, and revised public policies to mitigate phosphorus emissions and support sustainable aquaculture in tropical and neotropical regions. Full article

The influence of structural water in alumina (Al₂O₃) and silica (SiO₂) coated titanium dioxide (TiO₂) pigments on the photodegradation behavior of polypropylene (PP) composites was investigated. Four commercial rutile TiO₂ pigments with varying surface inorganic coatings were incorporated into PP plaques and subjected to accelerated UV weathering to simulate outdoor exposure. Photodegradation was assessed through gloss retention measurements, the carbonyl index (CI), and stress at break retention, while pigment morphology and composition were analyzed using transmission electron microscopy (TEM) and energy-dispersive X-ray spectroscopy (EDS). Surface charge and water content were determined through the zeta potential (ζ), Karl Fischer titration, thermogravimetric analysis (TGA), and Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS). The results showed that low-alumina coating alone led to the lowest photodegradation resistance, the highest CI, and the lowest stress at break retention. In contrast, increasing alumina content enhanced photostability, reaching its maximum for combined alumina–silica coatings, which mitigated electron–hole pair migration. PP composites with high alumina–silica-coated TiO₂ exhibited higher gloss retention (36%) compared to low-alumina samples (21%). Furthermore, statistical analysis using ANOVA revealed significant differences in coating content and ζ potential among the pigment grades. These findings provide novel insights into oxide-water interactions and the impact of structural water on the photodegradation of polymer composites. Full article