Search Results (716)

The increasing demand for sustainable energy and efficient wastewater treatment has driven interest in single-chamber microbial fuel cells (SCMFCs) as integrated systems for bioelectricity generation and waste remediation. This study evaluates untreated agro-industrial byproduct olive mill wastewater (OMW) as a substrate in SCMFCs. It investigates the performance of activated biochar derived from olive pomace coated on stainless-steel mesh (ACB/SSM) as a low-cost cathode material. A synthetic media was used as a control. Electrochemical performance was assessed using voltage profiles, polarization analysis, power density, chemical oxygen demand (COD%) removal, and coulombic efficiency (CE%). The synthetic media achieved higher peak voltage (0.647 ± 0.026 V) and power density (46.05 mW m⁻²), whereas OMW showed more stable voltage output and lower internal resistance. OMW exhibited superior initial COD removal (74%) and a gradual increase in CE% up to 63% over successive cycles. In contrast, synthetic media exhibited a consistent COD% of 64%; its CE% removal improved to 61%. These results demonstrate that, despite lower peak power, OMW provides a more stable and sustainable substrate for long-term SCMFC operation. The use of waste-derived biochar cathodes further enhances system feasibility by reducing cost and supporting circular economy principles. This study highlights the potential of OMW-based SCMFCs as a practical approach for simultaneous wastewater treatment and renewable energy recovery. Full article

Wind turbine towers rely on welded joints for structural continuity, and the coarse-grained heat-affected zone (CGHAZ) at these joints is the principal site of fatigue damage under service loading. This study characterises the influence of welding heat input on the microstructural constitution, high-cycle fatigue response, and fracture mechanisms of Gleeble-simulated CGHAZs in a Nb-microalloyed wind power steel. Thermal cycles representative of submerged arc welding at 15, 25, 35, and 45 kJ/cm were applied, and the resulting microstructures were examined by optical microscopy, SEM, EBSD, and TEM. Raising the heat input produced systematic microstructural coarsening: the densities of low-angle grain boundaries (LAGBs) and high-angle grain boundaries (HAGBs) fell by approximately 40% and 26%, respectively, while the mean equivalent diameter (MED) and prior austenite grain (PAG) size grew by roughly 64% and 67%. Life partitioning showed that crack nucleation accounted for more than 84% of total fatigue cycles in every condition, identifying it as the life-governing damage stage. Over the 15-to-45 kJ/cm range, the CGHAZ fatigue strength at 2 × 10⁶ cycles deteriorated from 246.9 MPa to 208.5 MPa (a 15.6% reduction), while the mean fatigue striation spacing widened from 0.142 μm to 0.183 μm (an increase of 28.9%). These results demonstrate that judicious heat-input selection is a practical and effective means of preserving CGHAZ fatigue integrity in wind tower steel fabrication, and they address a previously unresolved gap concerning high-cycle fatigue fracture mechanisms in this critical microstructural zone. Full article

This study investigates the growth and evolution of SiO₂-based inclusions in Si-killed steel under stagnant conditions and varying oxygen levels. Deoxidation experiments were conducted in a high-temperature furnace using commercial FeSi, with systematic variations in holding time and total oxygen content. Automated SEM–EDS analysis was employed to quantify inclusion size, number density, and chemical composition. Under stagnant conditions, SiO₂ inclusions were observed to grow and coarsen in the absence of melt agitation, following a t^1/3 scaling law. In high-oxygen melts, rapid inclusion growth was dominated by Stokes collision mechanisms, resulting in the formation of inclusions in the size range of 1–5 μm, which were subsequently removed by flotation. In contrast, low-oxygen melts exhibited slower growth kinetics governed primarily by Brownian motion and Ostwald ripening, producing smaller inclusions with characteristic sizes of 1–2 μm. These results demonstrate that the initial oxygen content plays a decisive role in controlling the dominant growth mechanisms and the extent of inclusion coarsening in non-agitated steel. Full article

The present investigation provides a comparative quality evaluation of Grade-60 steel rebars produced by induction furnace (IF)-based industries. In addition to analyzing quality variations in different industrial processes, this study aims to evaluate their compliance with international standards such as ASTM A615/615M. Samples of rebars from six local producers were collected, and their chemical compositions, microstructural features, hardness profiles, and tensile properties, including yield and tensile strengths, were analyzed. A special focus was given to analyzing the case–core microstructure, the presence of martensite rings, and impurity density, which substantially affect strength and ductility. Additionally, the electrochemical investigation was conducted at different temperature ranges, from 50 °C to 100 °C. Potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS) with open-circuit potential (OCP) was used to analyze the corrosion behavior of different samples in seawater. The finding suggests that the majority of rebars achieved the minimum requirements of ASTM 615 for Grade-60, except for some manufacturers, where minor deviation was noticed. However, significant variation in mechanical properties and chemical composition was observed among all six industries (A–F). Manufacturers are consistently exhibiting the highest mechanical properties, with a maximum yield strength of 580 MPa and tensile strength of 760 MPa (12 mm diameter sample). In contrast, various samples from E and F manufacturers recorded the lowest values, such as a minimum yield strength of 365 MPa (Industry F, 16 mm diameter) and a critically low elongation of 9.5% for sample E of 16 mm diameter. Microstructural analysis further confirmed the formation of martensite rim structures in samples of manufacturer A, evidencing the efficient thermomechanical treatment system installation in industries. Full article

Inadequate surface sanitization represents a significant risk to sterility assurance and regulatory compliance. Therefore, an effective cleaning and disinfection program is a critical component of contamination control strategies in pharmaceutical facilities manufacturing sterile medicinal products. This study aimed to standardize a carrier-based methodology for evaluating the efficacy of disinfectants against in-house environmental isolates recovered from a pharmaceutical industry facility. Nine representative strains were selected from five different groups—Gram-positive non-spore-forming bacteria (Micrococcus luteus and Kocuria spp.), Gram-positive spore-forming bacteria (two Bacillus spp. strains), Gram-negative bacteria (Pseudomonas aeruginosa and Acinetobacter haemolyticus), yeasts (Candida parapsilosis and Rhodotorula mucilaginosa), and filamentous fungus (Penicillium spp.)—based on historical environmental monitoring data (2012–2022), and were characterized using matrix-assisted laser desorption/ionization-time-of-flight/mass spectrometry (MALDI-TOF MS) and molecular sequencing (16S rRNA or D2 LSU rDNA). Disinfectant efficacy was assessed on stainless-steel and low-density polyethylene surfaces using NF T 72-281:2014 with adaptations, testing alcohol 70%, sodium hypochlorite 0.5%, quaternary ammonium 0.05%, peracetic acid 0.5%, and accelerated hydrogen peroxide wipes. All agents demonstrated ≥5 log₁₀ reductions against vegetative bacteria and fungi on both surfaces. However, variable sporicidal performance was observed, particularly for one Bacillus cereus group strain (B1342/15), which showed limited viability reduction on stainless steel. These findings highlight inter-strain variability and the greater tolerance of surface-associated spores. The study reinforces the importance of carrier-based testing using in-house isolates to ensure realistic validation of disinfectants and to strengthen microbiological risk management within pharmaceutical contamination control strategies. Full article

Reported herein is tantalum (Ta)-based film, including TaN, TaO_x, composite TaO_xN_γ, multilayered TaN/TaO_x-(5:5) and TaN/TaO_x-(10:10), prepared by atomic layer deposition (ALD) technology via adjusting the sub-cycle of TaN and TaO_x films. The influence of different growth parameters on microstructure, crystal form, chemical bonding state and corrosion resistance of Ta-based films was systematically investigated. Representative results include the following: (1) The surface of the Ta-based films prepared by ALD is continuous, dense and smooth, and the root mean square roughness (Rq) of those are TaN: 0.74 nm, TaO_x: 0.69 nm, TaO_xN_γ: 0.55 nm, TaN/TaO_x-5:5: 0.56 nm and TaN/TaO_x-10:10: 0.77 nm. (2) The TaN film presents a polycrystalline structure with good crystallinity, while the incorporation of oxygen significantly inhibits the crystallinity of the film. (3) Electrochemical tests in 3.5 wt.% NaCl solution and neutral salt spray experiments show that ALD deposition of Ta-based films can significantly improve the corrosion resistance of carbon steel substrates. The order of corrosion resistance of different films is TaO_xN_γ film > TaN/TaO_x multilayer film > TaN film. Among them, the TaO_xN_γ film exhibited the most excellent corrosion resistance, with a charge transfer resistance (R_ct) as high as 24.75 Ω·cm² and a corrosion current density (I_corr) as low as 1.20 × 10⁻⁶ A/cm², and no obvious rusting phenomenon was observed on the surface of that film after the 2 h neutral salt spray test. Full article

High-Mn twinning-induced plasticity (TWIP) steels are renowned for their exceptional strength-ductility synergy. However, their practical applications are severely constrained by inadequate yield strength and poor corrosion resistance. In this study, an N-alloyed TWIP steel (Fe-25Mn-12Cr-0.3C-0.3N, wt.%, designated as TWIP-2) was developed, using an N-free counterpart (Fe-25Mn-12Cr-0.3C, TWIP-1) as a reference. Both steels underwent hot forging (HF) followed by solution treatment (ST). The synergistic effects of N alloying and thermomechanical processing on the microstructural evolution, mechanical properties, and corrosion behavior were systematically investigated. Results indicate that all samples retain a single-phase FCC austenitic structure. N alloying increased the yield strength of the hot-forged TWIP steel from 488.1 MPa to 802.9 MPa while maintaining an elongation after fracture around 40%. Solution treatment markedly improved corrosion resistance, changing the corrosion mode from intergranular attack to pitting. The TWIP-2-ST specimen exhibited the lowest corrosion current density of 2.88 × 10⁻⁵ A/cm² and demonstrated the best overall performance. This comprehensive improvement in mechanical and corrosion performance is primarily attributed to the elevated work-hardening capacity, a higher fraction of low-energy grain boundaries, and the beneficial role of interstitial N in suppressing pitting nucleation and propagation. Full article

Grain-oriented (GO) silicon steel cores in low-voltage current transformers suffer magnetic degradation from residual stress and increased dislocation density during slitting and winding. This study addresses the gap in systematic optimization of secondary annealing on assembled toroidal cores using a 3² full-factorial design varying temperature (650, 850, 1050 °C) and holding time (60, 90, 120 min) on M4 grade cores. Results showed temperature is the dominant factor, while holding time exhibits a synergistic non-linear effect. The optimal condition (850 °C, 90 min) reduced specific losses from 0.85 W/kg to 0.43 W/kg (49% reduction). Mechanistic analysis confirmed this improvement is driven by complete primary recrystallization (equiaxed grains ~50–60 µm), dislocation annihilation (~10 HV hardness reduction), and reinforcement of the Goss texture ({110} <001>). SEM, EDS, and ICP-OES demonstrated that the Carlite coating remained dimensionally (1.67–1.83 µm) and chemically stable, with beneficial decarburization. Temperatures above 850 °C caused magnetic deterioration due to excessive grain growth. These results provide a validated, industrial framework for recovering magnetic efficiency in wound toroidal cores without compromising coating integrity. Full article

Industrial areas, which represent a specific type of urbanised area with an extremely high concentration of material reserves, can be considered key anthropogenic raw material reservoirs in the context of urban mining. Industrial areas, characterised by a high material density and a specific composition of structural systems, show extraordinary potential for providing secondary raw materials with high material and energy value. This increases the need for their systematic evaluation. The aim of the present study was to define the role of the selected industrial area as a strategic node for secondary raw material extraction, to identify the structure and quality of “urban deposits” in the selected location of the Ostrava–Karviná region (CZ), and to provide an analytical framework for its integration into circular planning processes. The methodological approach is based on a combination of pre-demolition audit, material flow mapping, spatial analysis, and structural element characterisation. It is becoming apparent that industrial areas have a high material density and contain significant amounts of recyclable metals, reinforced concrete elements, etc. These stocks are often concentrated in structural systems with predictable geometries, such as serial assembly prefabricated and steel frames, allowing for more accurate estimates of recoverable volumes. The results show that the incorporation of industrial areas into the process of urban mining can significantly reduce the consumption of primary raw materials, mitigate the environmental impacts associated with the extraction of raw materials, and, at the same time, promote the regeneration of industrial areas (or brownfields) through the planned decomposition of structures. The inclusion of urban mining in urban development strategies and the regeneration of industrial sites leads to the prediction that urban mining is one of the key elements for achieving a material-efficient and low-carbon urban environment. Full article

Seismic excitations induce floor accelerations that can damage non-structural components and, in extreme cases, contribute to global structural failure. Although floor acceleration demands have been widely studied, their integration into probabilistic seismic performance and reliability frameworks remains limited within Performance-Based Seismic Design (PBSD). This study addresses this gap by proposing a reliability-based framework that incorporates the stochastic nature of floor accelerations through their probability density functions. Five-story steel and reinforced concrete (RC) buildings, designed according to Mexican codes, were analyzed using nonlinear dynamic simulations in PERFORM 3D under 33 ground motions corresponding to immediate occupancy (IO), life safety (LS), and collapse prevention (CP) levels. Structural reliability was quantified using the probability of failure ($p_f$) and the reliability index (β). Results show that peak accelerations occur at the roof level, with higher demands in the steel structure. For the IO level, β ranged from approximately 2.29 to values above 4.0 in steel buildings, while RC structures reached up to β ≈ 4.97. At LS and CP levels, RC buildings maintained β values generally above 3.0, whereas steel structures showed values as low as β ≈ 1.32. The Kernel distribution best captured response variability, reflecting high dispersion ($C.V.$ > 30%). The proposed framework enhances PBSD by linking acceleration demands with reliability-based decision-making. Full article

The performance requirements of wear-resistant and anti-corrosion coatings for marine equipment continue to increase. Diamond-like carbon (DLC) film has become a preferred protective material due to its high hardness, low friction and chemical inertia. To reveal the tribocorrosion mechanism of Si-doped DLC films in a seawater environment, a Cr-WC-WC/C transition layer and DLC-Si films with different Si contents were prepared by high-power pulsed magnetron sputtering (HiPIMS) technology on 304 stainless steel. The tribocorrosion tests were carried out under open-circuit potential and dynamic polarization conditions in seawater. The results show that Si doping improved the tribocorrosion resistance of the films. The sample with Si content of 9.26 at.% has the lowest self-corrosion current density, the smallest volume loss, complete wear scar morphology and no obvious substrate exposure. The strengthening mechanism is attributed to Si doping, which induces the formation of a SiO_x passivation film and a hydrated silica gel lubrication layer. This establishes a synergistic solid-chemical lubrication system, inhibits sp² cluster growth, prolongs the diffusion path of corrosive media, and mitigates the damaging wear–corrosion synergy. This study confirms that moderate Si doping can significantly improve the wear resistance and corrosion resistance of DLC films in a seawater environment, and provides a theoretical basis for the design and application of carbon-based protective coatings for marine equipment. Full article

This study investigates the enhancement of hydrogen production efficiency in water electrolysis through the application of external magnetic fields. A series of controlled experiments were conducted using four distinct electrode materials—stainless steel (SS), low-carbon steel (LCS), titanium (Ti), and platinum-plated titanium (Ti/Pt)—to identify the optimal configuration for maximizing gas output. The research evaluated the influence of electrolyte concentration (KOH), current density, and magnetic field intensity ranging from 0 to 1800 G. Our findings indicate that the application of a 200 G magnetic field leads to a notable 6% increase in the rate of gas production compared to non-magnetized conditions. Specifically, a magnetic field oriented parallel to the electrode plates outperformed a perpendicular orientation by approximately 5%, a phenomenon attributed to the Lorentz force facilitating ionic mass transfer and gas bubble detachment. Furthermore, the integration of ion-exchange and proton-exchange membranes (MC-3470 and N-117) effectively isolated the anodic and cathodic products, elevating hydrogen purity from 67.4% to approaching 100% without compromising electrolysis efficiency. These results demonstrate that the strategic coupling of moderate magnetic fields with optimized electrode configurations provides a promising pathway for improving the efficiency and cleanliness of hydrogen production, which is essential for its role as a sustainable energy carrier. Full article

Using low-pressure cold spray technique, Fe-Al composite coatings with different Al contents were applied to the surface of 45 steel to improve its corrosion resistance in chloride-containing settings. The microstructure, mechanical characteristics, and electrochemical corrosion behavior of the coatings were thoroughly examined in relation to the Al content (2, 4, 6, and 8 wt.%). The findings show that the microhardness of the composite coating decreases monotonically (from 157.98 HV to 99.29 HV) as the Al content rises because of the increased proportion of the soft phase; in contrast, the porosity and corrosion current density show a pattern of first decreasing and then increasing. The coating porosity was reduced to a minimum (1.37%) when the Al concentration reached 6 wt.% because the soft Al particles experienced enough plastic flow to fill the holes in the hard Fe matrix. The 6Al composite coating demonstrated the best electrochemical protection performance in a 3.5 wt.% NaCl solution, with the lowest corrosion current density (2.237 × 10⁻⁴ A/cm²) and the strongest interfacial charge transfer resistance. The synergistic corrosion protection mechanism comprising significantly densified physical shielding and microgalvanic sacrificial anode protection by the active Al phase was clarified in this study. The ideal composition ratio for this system was determined to be 6 wt.% Al by carefully matching the coating’s mechanical load-bearing needs with long-term corrosion prevention goals. Full article

The Axial Flux Permanent Magnet Synchronous Motor (AFPMSM) has gained significant attention as a core power source for next-generation industrial sectors, including electric vehicles, wind turbines, robot joints, and drone propulsion motors, due to its high power density from a short axial length and large radial dimensions. Despite these structural advantages, cogging torque caused by magnetic interaction between the stator teeth and permanent magnets remains a critical drawback, inducing noise and vibration. While conventional Soft Magnetic Composite (SMC) core methods facilitate 3D flux paths, they suffer from low magnetic permeability, insufficient mechanical strength, and manufacturing complexity. To address these issues, this study proposes a stepped structure model utilizing electrical steel sheets to effectively reduce cogging torque. This structure features radial stacking of identical electrical steel sheets with varying widths, where each layer’s center is incrementally shifted in the rotational direction. This configuration achieves an effect analogous to continuous skewing without specialized 3D machining. To validate the proposed design, 3D Finite Element Analysis (FEA) was conducted. Results demonstrate that the peak-to-peak cogging torque was reduced to approximately 86% of the conventional model’s value, while maintaining the back-EMF reduction rate within 5%. By presenting a novel skewing technique, this research provides a practical alternative for high-precision and high-power AFPMSM. Full article

Direct methanol fuel cells (DMFCs) offer significant advantages including high energy density and rapid refueling, making them promising power sources for portable electronic products. However, their practical application, particularly in passive systems, is hindered by critical mass transport limitations: water flooding in the cathode and CO₂ bubble blockage in the anode. Herein, a novel dual-gradient patterned wettability current collector (CC) was designed to alleviate this mass transport impedance. The design uniquely integrates wedge-shaped gradients with surface energy gradients to create a unified, self-driven mechanism for efficient water and CO₂ bubble transport at both electrodes. A mathematical model was developed to quantitatively evaluate the effects of the dual-gradient structure. The results confirm that water removal is enhanced when the cathode current collector features a hydrophobic periphery with a dual-gradient patterned wettability interior on the gas-diffusion-layer side and a fully hydrophilic air-side surface, whereas an inverted pattern facilitates anode CO₂ removal. Optimal fabrication parameters on 316 L stainless steel were established by investigating laser scanning conditions and low-surface-energy agent concentrations. The experimental results show that the passive DMFCs incorporating the optimized current collectors delivered marked performance improvements. At 1 mol·L⁻¹ methanol, the novel anode and cathode current collectors increased peak power density by 15.6% and 14.5%, respectively. Electrochemical impedance spectroscopy revealed a 31.4% and 31.9% reduction in mass transfer resistance of the cell with novel anode and cathode current collectors, respectively, confirming improved gas–liquid self-driven efficiency. Furthermore, the new cells exhibited substantially enhanced long-term stability over 18 h of continuous discharge, attributed to the robust wettability achieved via laser–silane modification. Overall, these findings suggest that the proposed dual-gradient wettability design is a promising method for improving internal mass transport, potentially supporting the development of more robust passive DMFCs. Full article