Search Results (1,797)

The construction industry is responsible for 39% of global CO₂ emissions related to energy use, with cement responsible for 5–8% of it. Limestone calcined clay cement (LC³), a ternary blended binder system, offers a low-carbon alternative by partially substituting clinker with calcined clay and limestone. This study investigated the use of waste clay brick powder (WBP), a waste material, as a source of calcined clay in LC³ formulations, addressing both environmental concerns and SCM scarcity. Two LC³ mixtures containing 15% limestone, 5% gypsum, and either 15% or 30% WBP, corresponding to clinker contents of 65% (LC³-65) or 50% (LC³-50), were evaluated against general purpose (GP) cement mortar. Tests included setting time, flowability, soundness, compressive and flexural strengths, drying shrinkage, isothermal calorimetry, and scanning electron microscopy (SEM). Isothermal calorimetry showed peak heat flow reductions of 26% and 49% for LC³-65 and LC³-50, respectively, indicating a slower reactivity of LC³. The initial and final setting times of the LC³ mixtures were 10–30 min and 30–60 min longer, respectively, due to the slower hydration kinetics caused by the reduced clinker content. Flowability increased in LC³-50, which is attributed to the lower clinker content and higher water availability. At 7 days, LC³-65 retained 98% of the control’s compressive strength, while LC³-50 showed a 47% reduction. At 28 days, the compressive strengths of mixtures LC³-65 and LC³-50 were 7% and 46% lower than the control, with flexural strength reductions being 8% and 40%, respectively. The porosity calculated from the SEM images was found to be 7%, 11%, and 15% in the control, LC³-65, and LC³-50, respectively. Thus, the reduction in strength is attributed to the slower reaction rate and increased porosity associated with the reduced clinker content in LC³ mixtures. However, the results indicate that the performance of LC³-65 was close to that of the control mix, supporting the viability of WBP as a low-carbon partial replacement of clinker in LC³. Full article

Using waste biomass as a raw material for the combined production of electricity and heat offers corresponding energy, economic, environmental and resource efficiency benefits. The study examines both the performance of a system for combined energy production based on the Organic Rankine Cycle (ORC) utilizing wood biomass and the market interest in its deployment within Bulgaria. Its objective is to propose a technically and economically viable solution for the recovery of waste biomass through the combined production of electricity and heat while simultaneously assessing the readiness of industrial and municipal sectors to adopt such systems. The cogeneration plant incorporates an ORC module enhanced with three additional economizers that capture residual heat from flue gases. Operating on 2 t/h of biomass, the system delivers 1156 kW of electric power and 3660 kW of thermal energy, recovering an additional 2664 kW of heat. The overall energy efficiency reaches 85%, with projected annual revenues exceeding EUR 600,000 and a reduction in carbon dioxide emissions of over 5800 t/yr. These indicators can be achieved through optimal installation and operation. When operating at a reduced load, however, the specific fuel consumption increases and the overall efficiency of the installation decreases. The marketing survey results indicate that 75% of respondents express interest in adopting such technologies, contingent upon the availability of financial incentives. The strongest demand is observed for systems with capacities up to 1000 kW. However, significant barriers remain, including high initial investment costs and uneven access to raw materials. The findings confirm that the developed system offers a technologically robust, environmentally efficient and market-relevant solution, aligned with the goals of energy independence, sustainability and the transition to a low-carbon economy. Full article

The southeastern Yunnan region in the southwestern Nanpanjiang Basin is one of the most important manganese enrichment zones in China. Manganese mineralization is mainly confined to marine mud–sand–carbonate interbeds of the Middle Triassic Ladinian Falang Formation (T₂f), which contains several medium to large deposits such as Dounan, Baixian, and Yanzijiao. However, the geological processes that control manganese mineralization in this region remain insufficiently understood. Understanding the tectonic evolution of the basin is therefore essential to unravel the mechanisms of Middle Triassic metallogenesis. This study investigates how rift-related tectonic activity influences manganese ore formation. This study integrates global gravity and magnetic field models (WGM2012, EMAG2v3), audio-frequency magnetotelluric (AMT) profiles, and regional geological data to investigate ore-controlling structures. A distinct gravity low–magnetic high belt is delineated along the basin axis, indicating lithospheric thinning and enhanced mantle-derived heat flow. Structural interpretation reveals a rift system with a checkerboard pattern formed by intersecting NE-trending major faults and NW-trending secondary faults. Four hydrothermal plume centers are identified at these fault intersections. AMT profiles show that manganese ore bodies correspond to stable low-resistivity zones, suggesting fluid-rich, hydrothermally altered horizons. These findings demonstrate a strong spatial coupling between hydrothermal activity and mineralization. This study provides the first identification of the internal rift architecture within the Nanpanjiang Basin. The basin-scale rift–graben system exerts first-order control on sedimentation and manganese metallogenesis, supporting a trinity model of tectonic control, hydrothermal fluid transport, and sedimentary enrichment. These insights not only improve our understanding of rift-related manganese formation in southeastern Yunnan but also offer a methodological framework applicable to similar rift basins worldwide. Full article

The study presents a comprehensive assessment of the combustion efficiency of low-grade coal from the Karazhyra deposit in small- and medium-capacity boiler units of the energy workshops operated by Vostokenergo LLP (East Kazakhstan Region, Kazakhstan). It was found that the average annual thermal energy output amounts to 2,387,348.85 GJ with a coal consumption of 164,328.5 tons. Based on operational data from 2016 to 2017, the average thermal efficiency (boiler efficiency) was 66.03%, with a maximum value of 75% recorded at the Zhezkent energy workshop. The average lower heating value (LHV) of the coal was 19.41 MJ/kg, which is below the design value of 20.52 MJ/kg, indicating the use of coal with reduced energy characteristics and elevated ash content (21.4%). The unburned carbon content in the ash and slag waste (ASW) was determined to be between 14 and 35%, indicating incomplete combustion. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) analyses revealed the presence of microspheres, porous granules, and coal residues, with silicon and aluminum oxides dominating the composition (up to 70.49%). Differences in the pollutant potential of ash from different boiler units were identified. Recommendations were substantiated regarding the adjustment of the air–fuel regime, modernization of combustion control systems, and utilization of ASW. The results may be used to develop measures aimed at improving the energy efficiency and environmental safety of coal-fired boiler plants. Full article

Elodea nuttallii is a significant submerged macrophyte utilized in shrimp and crab aquaculture, yet it exhibits low thermotolerance. This study investigated the physiological responses and transcriptomic characteristics of E. nuttallii under high-temperature stress (HTS). The results indicated that HTS significantly reduced the absolute growth rate (AGR) and photosynthetic efficiency of E. nuttallii while concurrently elevating antioxidant enzyme activities, malondialdehyde (MDA) content, and concentrations of osmotic adjustment compounds. Furthermore, the apical segments of E. nuttallii demonstrated greater sensitivity to HTS compared to the middle segments. Under exposure to 35 °C and 40 °C, antioxidant enzyme activities, MDA content, and osmotic adjustment compound levels were significantly higher in the apical segments than in the middle segments. Transcriptomic analysis revealed 7526 differentially expressed genes (DEGs) in the apical segments at 35 °C, a number substantially exceeding that observed in the middle segments. Enrichment analysis of DEGs revealed significant upregulation of key metabolic regulators under HTS, including carbohydrate metabolism genes (HXK, FRK) and phenylpropanoid biosynthesis enzymes (4CL, COMT). This transcriptional reprogramming demonstrates E. nuttallii’s adaptive strategy of modulating carbon allocation and phenolic compound synthesis to mitigate thermal damage. Our findings not only elucidate novel thermotolerance mechanisms in aquatic plants but also provide candidate genetic targets (HXK, 4CL) for molecular breeding of heat-resilient cultivars through transcriptomic screening. Full article

Under the construction background of carbon peak and carbon neutrality, high-energy-consuming enterprises, represented by the electrolytic aluminum industry, have become important carriers for energy conservation and emission reduction. These enterprises are characterized by significant energy consumption and high carbon emissions, greatly impacting the economic and environmental benefits of regional power grids. Existing research often focuses on grid revenue, leaving high-energy-consuming enterprises in a passive regulatory position. To address this, this paper constructs an economic dispatch strategy for power grids that considers waste heat utilization in high-energy-consuming enterprises. A typical representative, electrolytic aluminum load and its waste heat utilization model, for the entire production process of high-energy-consuming loads, is established. Using a tiered carbon trading calculation formula, a low-carbon production scheme for high-energy-consuming enterprises is developed. On the grid side, considering local load levels, the uncertainty of wind power output, and the energy demands of aluminum production, a robust day-ahead economic dispatch model is established. Case analysis based on the modified IEEE-30 node system demonstrates that the proposed method balances economic efficiency and low-carbon performance while reducing the conservatism of traditional optimization approaches. Full article

Steel is an important product in many engineering sectors; however, steelmaking remains one of the largest ${\mathrm{CO}}_2$ emitters. Therefore, new governmental policies drive the steelmaking industry toward a cleaner and more sustainable operation such as the gas-based direct reduction–electric arc furnace process. To become carbon neutral, utilizing more scrap is one of the feasible solutions to achieve this goal. Addressing knowledge gaps regarding scrap heterogeneity (size, shape, and composition) is essential to evaluate the effects of increased scrap ratios in basic oxygen furnace (BOF) operations. This review systematically examines heat and mass transfer correlations relevant to scrap melting in BOF steelmaking, with a focus on low Prandtl number fluids (thick thermal boundary layer) and dense particulate systems. Notably, a majority of these correlations are designed for fluids with high Prandtl numbers. Even for the ones tailored for low Prandtl, they lack the introduction of the porosity effect which alters the melting behavior in such high temperature systems. The review is divided into two parts. First, it surveys heat transfer correlations for single elements (rods, spheres, and prisms) under natural and forced convection, emphasizing their role in predicting melting rates and estimating maximum shell size. Second, it introduces three numerical modeling approaches, highlighting that the computational fluid dynamics–discrete element method (CFD–DEM) offers flexibility in modeling diverse scrap geometries and contact interactions while being computationally less demanding than particle-resolved direct numerical simulation (PR-DNS). Nevertheless, the review identifies a critical gap: no current CFD–DEM framework simultaneously captures shell formation (particle growth) and non-isotropic scrap melting (particle shrinkage), underscoring the need for improved multiphase models to enhance BOF operation. Full article

Under the dual challenges of global energy crisis and climate change, the building sector, as a major carbon emitter consuming 33% of global primary energy, has seen its energy efficiency optimization become a critical pathway towards achieving carbon neutrality goals. The Window-to-Wall Ratio (WWR), serving as a core parameter in building envelope design, directly influences building energy consumption, with its optimized design playing a decisive role in balancing natural daylighting, ventilation efficiency, and thermal comfort. This study focuses on the traditional One-Seal dwellings (Yikeyin) in Kunming, China, establishing a dynamic wind field-thermal environment coupled analysis framework to investigate the impact mechanism of window dimensions (WWR and aspect ratio) on indoor thermal comfort under natural wind conditions in transitional climate zones. Utilizing the Grasshopper platform integrated with Ladybug, Honeybee, and Butterfly plugins, we developed parametric models incorporating Kunming’s Energy Plus Weather meteorological data. EnergyPlus and OpenFOAM were employed, respectively, for building heat-moisture balance calculations and Computational Fluid Dynamic (CFD) simulations, with particular emphasis on analyzing the effects of varying WWR (0.05–0.20) on temperature-humidity, air velocity, and ventilation efficiency during typical winter and summer weeks. Key findings include, (1) in summer, the baseline scenario with WWR = 0.1 achieves a dynamic thermal-humidity balance (20.89–24.27 °C, 65.35–74.22%) through a “air-permeable but non-ventilative” strategy, though wing rooms show humidity-heat accumulation risks; increasing WWR to 0.15–0.2 enhances ventilation efficiency (2–3 times higher air changes) but causes a 4.5% humidity surge; (2) winter conditions with WWR ≥ 0.15 reduce wing room temperatures to 17.32 °C, approaching cold thresholds, while WWR = 0.05 mitigates heat loss but exacerbates humidity accumulation; (3) a symmetrical layout structurally constrains central ventilation, maintaining main halls air changes below one Air Change per Hour (ACH). The study proposes an optimized WWR range of 0.1–0.15 combined with asymmetric window opening strategies, providing quantitative guidance for validating the scientific value of vernacular architectural wisdom in low-energy design. Full article

To advance the development of protein-rich plant-based foods, a novel binder system for vegan sausage alternatives without the requirement of heat application was investigated. This enables long-term ripening of plant-based analogs similar to traditional fermented meat or dairy products, allowing for refined flavor and texture development. This was achieved by using a poorly water-soluble calcium source (calcium carbonate) to introduce calcium ions into a low-ester pectin—gluten matrix susceptible to crosslinking via divalent ions. The gelling reaction of pectin–gluten dispersions with Ca²⁺ ions was time-delayed due to the gradual production of lactic acid during fermentation. Firm, sliceable matrices were formed, in which particulate substances such as texturized proteins and solid vegetable fat could be integrated, hence forming an unheated raw-fermented plant-based salami-type sausage model matrix which remained safe for consumption over 21 days of ripening. Gluten as well as pectin had a significant influence on the functional properties of the matrices, especially water holding capacity (increasing with higher pectin or gluten content), hardness (increasing with higher pectin or gluten content), tensile strength (increasing with higher pectin or gluten content) and cohesiveness (decreasing with higher pectin or gluten content). A combination of three simultaneously occurring effects was observed, modulating the properties of the matrices, namely, (a) an increase in gel strength due to increased pectin concentration forming more brittle gels, (b) an increase in gel strength with increasing gluten content forming more elastic gels and (c) interactions of low-ester pectin with the gluten network, with pectin addition causing increased aggregation of gluten, leading to strengthened networks. Full article

The intelligent upgrade of heating systems faces the challenge of accurately identifying high-dimensional pipe-network resistance coefficients; difficulties in accomplishing this can lead to hydraulic imbalance and redundant energy consumption. To address the limitations of traditional Differential Evolution (DE) algorithms under high-dimensional operating conditions, this paper proposes an Improved Differential Evolution Algorithm (SDEIA) incorporating chaotic mapping, adaptive mutation and crossover strategies, and an immune mechanism. Furthermore, a multi-constrained identification model is constructed based on Kirchhoff’s laws. Validation with actual engineering data demonstrates that the proposed method achieves a lower average relative error in resistance coefficients and exhibits a more concentrated error distribution. SDEIA provides a high-precision tool for multi-heat-source networking and dynamic regulation in heating systems, facilitating low-carbon and intelligent upgrades. Full article

Benzoxazine resins are gaining attention for their impressive thermal stability, low water uptake, and strong mechanical properties. In this work, two new bio-based benzoxazine monomers were developed using renewable arbutin: one combined with 3-(2-aminoethylamino) propyltrimethoxysilane (AB), and the other with furfurylamine (AF). Both were synthesized using a simple Mannich-type reaction and verified through FT-IR and ¹H-NMR spectroscopy. By blending these monomers in different ratios, copolymers with adjustable thermal, dielectric, and surface characteristics were produced. Thermal analysis showed that the materials had broad processing windows and cured effectively, while thermogravimetric testing confirmed excellent heat resistance—especially in AF-rich blends, which left behind more char. The structural changes obtained during curing process were monitored using FT-IR, and XPS verified the presence of key elements like carbon, oxygen, nitrogen, and silicon. SEM imaging revealed that AB-based materials had smoother surfaces, while AF-based ones were rougher; the copolymers fell in between. Dielectric testing showed that increasing AF content raised both permittivity and loss, and contact angle measurements confirmed that surfaces ranged from water-repellent (AB) to water-attracting (AF). Overall, these biopolymers (AB/AF copolymers) synthesized from arbutin combine environmental sustainability with customizability, making them strong candidates for use in electronics, protective coatings, and flame-resistant composite materials. Full article

In the context of the growing need to reduce greenhouse gas emissions and to develop sustainable solutions for the construction industry, foamed geopolymers represent a promising alternative to traditional binders and insulation materials. This study investigates the thermal properties of novel low-emission, insulating geopolymer binders made from fly ash with diatomite, chalcedonite, and wood wool aiming to assess their potential for use in thermal insulation systems in energy-efficient buildings. The stability of the foamed geopolymer structure is also assessed. Measurements of thermal conductivity, specific heat, microstructure, density, and compressive strength are presented. The findings indicate that the selected geopolymer formulations exhibit low thermal conductivity, high heat capacity and low density, making them competitive with conventional insulation materials—mainly load-bearing ones such as aerated concrete and wood wool insulation boards. Additionally, incorporating waste-derived materials reduces the production carbon footprint. The best results are represented by the composite incorporating all three additives (diatomite, chalcedonite, and wood wool), which achieved the lowest thermal conductivity (0.10154 W/m·K), relatively low density (415 kg/m³), and high specific heat (1.529 kJ/kg·K). Full article

Over recent decades, phase-change materials (PCMs) have gained prominence as latent-heat thermal energy storage systems in building envelopes because of their high energy density. However, only PCMs that complete a full daily charge–discharge cycle can deliver meaningful energy and carbon-emission savings. This simulation study introduces a methodology that simultaneously optimizes PCM integration for storage efficiency, indoor thermal comfort, and energy savings. Two new indicators are proposed: overall storage efficiency (EC_n), which consolidates heating and cooling-efficiency ratios into a single value, and the performance factor (PF), which quantifies the PCM’s effectiveness in maintaining thermal comfort. Using EnergyPlus v8.9 coupled with DesignBuilder, a residential ASHRAE 90.1 mid-rise apartment was modeled in six warm-temperate (Cfb) European cities for the summer period from June 1 to August 31. Four paraffin PCMs (RT-22/25/28/31 HC, 20 mm thickness) were tested under natural and controlled ventilation strategies, with windows opening 50% when outdoor air was at least 2 °C cooler than indoors. Simulation outputs were validated against experimental cubicle data, yielding a mean absolute indoor temperature error ≤ 4.5%, well within the ±5% tolerance commonly accepted for building thermal simulations. The optimum configuration—RT-25 HC with temperature-controlled ventilation—achieved PF = 1.0 (100% comfort compliance) in all six cities and delivered summer cooling-energy savings of up to 3376 kWh in Paris, the highest among the locations studied. Carbon-emission reductions reached 2254 kg CO₂-e year⁻¹, and static payback periods remained below the assumed 50-year building life at a per kg PCM cost of USD 1. The EC_n–PF framework, therefore, provides a transparent basis for selecting cost-effective, energy-efficient, and low-carbon PCM solutions in warm-temperate buildings. Full article

Rammed earth (RE), a traditional material aligned with circular economy (CE) principles, has been gaining renewed interest in contemporary construction due to its low environmental impact and compatibility with sustainable building strategies. Though not a modern invention, it is being reintroduced in response to the increasingly strict European Union (EU) regulations on carbon footprint, life cycle performance, and thermal efficiency. RE walls offer multiple benefits, including humidity regulation, thermal mass, plasticity, and structural strength. This study also draws attention to their often-overlooked ability to mitigate indoor overheating. To preserve these advantages while enhancing thermal performance, this study explores insulation strategies that maintain the vapor-permeable nature of RE walls. A parametric analysis using Delphin 6.1 software was conducted to simulate heat and moisture transfer in two main configurations: (a) a ventilated system insulated with mineral wool (MW), wood wool (WW), hemp shives (HS), and cellulose fiber (CF), protected by a jute mat wind barrier and finished with wooden cladding; (b) a closed system using MW and WW panels finished with lime plaster. In both cases, clay plaster was applied on the interior side. The results reveal distinct hygrothermal behavior among the insulation types and confirm the potential of natural, low-processed materials to support thermal comfort, moisture buffering, and the alignment with CE objectives in energy-efficient construction. Full article

Sustainable building design is significantly impacted by the local climate response knowledge ingrained in traditional architecture. However, its integration and dissemination with contemporary green technologies are limited by the absence of a comprehensive quantitative analysis of the regulation of its humid and temperature environment. The Ganzhou Wei family compound from China’s wind–heat environmental regulation systems are examined in this study. We statistically evaluate the synergy between spatial morphology, material qualities, and microclimate using field data with Thsware and Ecotect software in a multiscale simulation framework. The findings indicate that the compound’s special design greatly controls the thermal and wind conditions. Cold alleyways and courtyards work together to maximize thermal environment regulation and encourage natural ventilation. According to quantitative studies, courtyards with particular depths (1–4 m) and height-to-width ratios (e.g., 1:1) reduce wind speed loss. A cool alley (5:1 height–width ratio) creates a dynamic wind–speed–temperature–humidity balance by lowering summer daytime temperatures by 2.5 °C. It also serves as a “cold source area” that moderates temperatures in the surrounding area by up to 2.1 °C. This study suggests a quantitative correlation model based on “spatial morphology–material performance–microclimate response,” which offers a technical route for historic building conservation renovation and green renewal, as well as a scientific foundation for traditional buildings to maintain thermal comfort under low energy consumption. Although based on a specific geographical case, the innovative analytical methods and strategies of this study are of great theoretical and practical significance for promoting the modernization and transformation of traditional architecture, low-carbon city construction, and sustainable building design. Full article