Search Results (11,634)

Glass fiber (GF) reinforced unsaturated polyester resin (UP) composites are used in cured-in-place pipe (CIPP) rehabilitation technology of drainage systems due to their low cost and excellent force chemical properties. However, the weak interfacial compatibility between GF and the polymer matrix limits the stress transfer efficiency. Herein, a strategy of a polyhydric boehmite (AlOOH) layer coated on GF (GF-AlOOH) was developed for improving the mechanical properties of UP composites, and the enhancement effects of the coating process were analyzed. The AlOOH-modified GFs significantly improved the flexural and tensile strengths of the modified composites by 41.21% and 21.05%, respectively. Moreover, the enhancement mechanism was explored by analyzing the surface chemical structure of GF-AlOOHs. The nano-AlOOH was grafted on the GF surface by O=Al–OH. Meanwhile, the increase in the mechanical properties of UP/GF-AlOOH was mainly attributed to the combined effect of mechanical interlocking interaction, covalent bonding and hydrogen bonding, which improved the interfacial adhesion between GF and UP. In summary, this work provides effective guidance for achieving high-quality interfaces in GF composites and offers important insights into designing durable and cost-effective materials for CIPP rehabilitation and broader infrastructure applications. Full article

Chloride-ion (Cl⁻)-induced corrosion of steel bars is a major threat to the durability of marine concrete structures. To address this, a type of calcined CaFeAl-layered double oxide (LDO-CFA) with different calcination temperatures was used to enhanced the Cl⁻ adsorption, compressive strength, and corrosion resistance of sulphate-resistant Portland cement (SRPC)-based materials. Experimental results demonstrated that LDO-CFA exhibited high Cl⁻ adsorption capacity in both CPSs and cement-based materials. Specifically, LDO-750-CFA reached 1.98 mmol/g in CPSs—60.1% higher than LDHs-CFA—and followed the Langmuir model, indicating monolayer adsorption. It also reduced the free Cl⁻ content of SRPC paste to 0.255–0.293% after 28 days, confirming its sustained adsorption over extended curing. Furthermore, LDO-CFA positively influenced the compressive strength at all curing ages. At an optimal dosage of 0.8 wt.%, LDO-750-CFA paste significantly improved the compressive strength, increasing it by 22.1% at 7 days and 15.6% at 28 days compared to the control. Electrochemical analysis confirmed the superior corrosion resistance of the LDO-750-CFA system. The property enhancement originated from LDO-750-CFA’s synergistic effects, which included pore refinement, increased tortuosity, Cl⁻ adsorption by structural memory, a PVP-induced passive film, and PVP-improved dispersion. Overall, this work provides a framework for developing LDO-750-CFA-based composites, paving the way for more durable marine concrete. Full article

Zr is a common element in titanium alloys to enhance their mechanical properties; however, its role in combustion remains unknown. This study aimed to elucidate the effects of Zr on the ignition conditions and flame propagation of Ti_100−xZr_x alloys via promoted ignition-combustion (PIC) tests. Results indicated that increasing Zr content (from 30 at% to 70 at%) decreased the critical oxygen pressure, ignition temperature, and burning velocity of Ti_100−xZr_x alloys. The reduction in ignition conditions was attributed to a decrease in ignition activation energy (from 108.37 kJ/mol to 94.26 kJ/mol) and an increase in combustion heat (from 986.34 kJ/mol to 1049.84 kJ/mol) with Zr addition. Additionally, microstructural analysis indicated that the suppression of flame propagation was attributed to Zr promoting the formation of a dense oxide layer. This hindered oxygen diffusion, thereby suppressing the heat release of oxidation reactions in the oxide zone and the peritectic reaction in the melting zone. These findings provided new insights into optimizing the composition of burn-resistant titanium alloys to inhibit combustion kinetics. Full article

In this work, we investigated the use of a piezoelectric flexible device for energy harvesting. The main goal of the study was to fill the nanostructured pores of anodic aluminum oxide (AAO) films with piezoelectric polymer (PVDF-TrFE) via a modified conventional screen printing technique using blade printing. In this way, it is possible to obtain a composite from nanostructured thin films of polymer nanorods that shows improved charge generation ability compared to other non-nanostructured composites or pure (non-composite) aluminum with similar dimensions. This behavior is due to the effect of the highly developed surface of the material used to fill in the AAO nanopore template and its ability to withstand the application of higher mechanical loads to the structured piezoelectric material during deformation. The contact blade print filling technique can produce nanostructured piezoelectric polymer films with precise geometric parameters in terms of thickness and nanorod diameters, at around 200 nm, and a length of 12 μm. At a low frequency of 17 Hz, the highest root-mean-square (RMS) voltage generated using the nanostructured AAO/PVDF-TrFE sample with aluminum electrodes was around 395 mV. At high frequencies above 1700 Hz, the highest RMS voltage generated using the nanostructured AAO/PVDF-TrFE sample with gold electrodes was around 680 mV. The RMS voltage generated using a uniform (non-nanostructured) layer of PVDF-TrFE was 15% lower across the whole frequency range. Full article

This study proposes a composite acoustic porous duct metamaterial muffler composed of a perforated tortuous channel and an externally wrapped porous layer, integrating both structural resonance and material damping effects. Theoretical models for the perforated plate, tortuous channel, and porous material were established, and analytical formulas for the total acoustic impedance and transmission loss of the composite structure were derived. Finite element simulations verified the accuracy of the models. A systematic parametric study was then performed on the effects of porous material type, thickness, and width on acoustic performance, showing that polyester fiber achieves the best results at a thickness of 30 mm and a width of 5 mm. Further analysis of periodic distribution modes revealed that axial periodic arrangement significantly enhances the peak noise attenuation, radial periodic arrangement broadens the effective bandwidth, and multi-frequency parallel configurations further expand the operating range. Considering practical duct conditions, a single-layer multi-cell array was constructed, and its modal excitation mechanism was clarified. By employing the Particle Swarm Optimization (PSO) algorithm for multi-parameter optimization, the average transmission loss was improved from 26.493 dB to 29.686 dB, corresponding to an increase of approximately 12.05%. Finally, physical samples were fabricated via 3D printing, and four-sensor impedance tube experiments confirmed good agreement among theoretical, numerical, and experimental results. The composite structure exhibited an average experimental transmission loss of 24.599 dB, outperforming the configuration without porous material. Overall, this work highlights substantial scientific and practical advances in sound energy dissipation mechanisms, structural optimization design, and engineering applicability, providing an effective approach for broadband and high-efficiency duct noise reduction. Full article

Carbon Capture and Storage (CCS) is a key technology for achieving carbon neutrality goals. Relevant foreign research began in the 1970s, but overall it remains in the exploration and demonstration stage. Clarifying the geological parameters and characteristics of reservoir–caprock systems in CCS projects is of great significance to the effectiveness and safety of long-term storage. By reviewing 15 typical global CCS projects, this paper identifies that ideal reservoirs are gently structured sandstones with few faults (characterized by high porosity, high permeability, and large scale, which are conducive to CO₂ diffusion) or basalts (which can react with CO₂ for mineralization, enabling permanent storage). Caprocks are mainly composed of thick mudstone and shale; composite caprocks consisting of multi-layer low-permeability formations and tight interlayers within reservoirs have stronger sealing performance. Additionally, they should be far from faults, and sufficient caprock thickness is required to reduce leakage risks. Meanwhile, this paper points out the challenges faced by CCS technology, such as complex site selection, limitations in long-term monitoring, difficulties in designing injection parameters, and challenges in large-scale deployment. It proposes suggestions including establishing a quantitative site selection system, building a comprehensive monitoring network, and strengthening collaborative optimization of parameters, so as to provide a basis for safe site selection and assessment. Full article

The lithological composition of deep coal rock reservoirs in the Ordos Block is complex. The characteristics of hydraulic fracture propagation directly impact reservoir stimulation effectiveness. Therefore, efficient development requires an in-depth understanding of the cross-layer propagation mechanisms of fractures in deep coal rock. To clarify the cross-layer patterns and explore the controlling factors in deep coal rock, large-scale laboratory true triaxial hydraulic fracturing physical simulation experiments were conducted. These experiments, combined with CT scanning and post-fracture 3D reconstruction technology, investigated Ordos Block deep coal rock under different perforation locations, and the complexity of fractures was quantitatively characterized. Due to the well-developed weak planes such as natural fractures in coal rock, perforations in coal rock significantly reduce the breakdown pressure compared to perforations in sandstone. The complexity of perforation fractures in coal rock is far greater than in sandstone. Quantitative characterization of fracture complexity shows that the number of perforation fractures in coal rock fracturing reached 450% of that in sandstone, and the fracture area ratio reached 131.7%. Under high-rate and high-viscosity fracturing conditions, dominant hydraulic fractures tend to form, while the well-developed natural fractures in the coal rock interact with each other, resulting in a complex fracture network. Perforations in coal rock can effectively connect adjacent sandstone layers through cross-layer propagation, whereas perforations in sandstone form dominant hydraulic fractures without connecting the adjacent coal rock layers. The findings can provide operational guidance for optimizing field fracturing operations. Full article

Steel-reinforced thermoplastic pipe is widely used for water transportation in sour gas fields. However, under the combined effects of corrosive media, internal high pressure, and long-term environmental aging, premature failures such as leakage and bursting often occur. To clarify the failure causes and primary contributing factors of the composite pipes, this study conducted a comprehensive analysis through microscopic morphology examination of different typical failure cases, differential scanning calorimetry, Fourier transform infrared spectroscopy, and mechanical property testing. The main failure mechanisms were investigated, and targeted protective measures are proposed. Key findings reveal that the typical failure modes are ductile cracking, aging-induced brittle cracking, and aging creep cracking. These failures follow a mechanism of degradation of the inner and outer polyethylene protective layers, penetration of the medium and corrosion of the steel wires, reduction in pressure-bearing capacity, and eventual structural damage or leakage propagation through the pipe wall. Notably, oxidation induction time values dropped as low as 1.4–17 min—far below the standard requirement of >20 min—indicating severe antioxidant depletion and material aging. The main controlling factors are poor material quality, external stress or mechanical damage, and long-term aging. The polyethylene used for the inner and outer protective layers is critical to the overall pipe performance; therefore, emphasis should be placed on evaluating its anti-aging properties and on protecting the pipe body during installation to ensure the long-term safety and stable operation of the pipeline system. Full article

This study investigates the ballistic performance of epoxy matrix composites reinforced with raffia fabric, aiming to evaluate their potential as the second layer in multilayered armor systems (MAS), replacing conventional synthetic aramid (Kevlar™) laminates. Composite plates with different volumetric fractions of raffia fabric (10, 20, and 30%) were manufactured and integrated with a ceramic front layer (Al₂O₃/Nb₂O₅) in MAS structures, which were then subjected to ballistic impact tests using high-energy 7.62 mm caliber ammunition. The backface signature (indentation depth) measured in ballistic clay, used as a human body simulant, showed that only the 10% raffia-reinforced composite (ER10) met the National Institute of Justice (NIJ 0101.06) safety threshold of 44 mm. Higher raffia contents (20% and 30%) led to increased indentation, compromising ballistic integrity. Scanning electron microscopy (SEM) of the fractured surfaces revealed typical energy dissipation mechanisms, such as fiber rupture, fiber pull-out, and interfacial delamination. The results indicate that raffia fabric composites with 10% fiber content can serve as a cost-effective and sustainable alternative to Kevlar™ in personal armor applications, while maintaining compliance with ballistic protection standards. Full article

This study focuses on the design and optimization of a cooling layer system integrated into a thin-thickness mold insert to enhance heat transfer efficiency, control mold temperature, and improve the quality of composite products during injection molding. The Taguchi method with an L25 (5⁴) orthogonal array was employed to investigate four key parameters: insert thickness, cooling layer thickness, water flow rate, and coolant temperature. Among 25 experimental combinations, five representative cases were selected for detailed analysis. The results indicate that the optimal configuration (0.5 mm insert, 10 mm cooling layer, 3.5 L/min flow rate, and 80 °C coolant temperature) successfully maintained a high and stable mold temperature, with a cavity temperature difference of only 3.6 °C at steady state and a simulation–experiment deviation ranging from 2.4% to 7.2%. This condition not only improved melt flowability and surface quality but also reduced defects such as weld lines, warpage, and shrinkage. In parallel, displacement measurements on PA6 and glass fiber-reinforced PA6 (PA6 + GF) composites revealed that increasing the fiber content from 0% to 30% reduced output displacement by more than 19% compared to neat PA6, highlighting the reinforcing effect of glass fibers and the relationship between temperature distribution and mechanical displacement behavior. The findings confirm that integrating a cooling layer into a thin-thickness mold, combined with Taguchi-based optimization, provides an effective approach to enhance through-thickness heat transfer, reduce deformation, and ensure the overall quality of composite injection-molded products in industrial applications. Full article

Glucosinolates (GSLs) are nitrogen- and sulfur-containing secondary metabolites central to the defense, development, and environmental responsiveness of Brassicaceae species. While the enzymatic steps and transcriptional networks underlying GSL biosynthesis have been extensively characterized, mounting evidence reveals that chromatin-based processes add a critical, yet underexplored, layer of regulatory complexity. Recent studies highlight the roles of DNA methylation, histone modifications, and non-coding RNAs in modulating the spatial and temporal expression of GSL biosynthetic genes and their transcriptional regulators in response to developmental cues and environmental signals. This review provides a comprehensive overview of GSL classification, biosynthetic pathway architecture, transcriptional regulation, and metabolite transport, with a focus on emerging epigenetic mechanisms that shape pathway plasticity. We also discuss how these insights may be leveraged in precision breeding and epigenome engineering, including the use of CRISPR/dCas9-based chromatin editing and epigenomic selection, to optimize GSL content, composition, and stress resilience in cruciferous crops. Integrating transcriptional and epigenetic regulation thus offers a novel framework for the dynamic control of specialized metabolism in plants. Full article

The high-temperature and hot corrosion behavior of Diamalloy 2002 coatings with a WC/Co–NiCrFeBSiC composite structure applied to a 316 L stainless steel surface using the atmospheric plasma spraying (APS) method was investigated. The coatings were held at 900 °C in air for 5, 25, 50, and 100 h and in a molten salt bath of Na₂SO₄ + V₂O₅ at 900 °C for 1, 3, and 5 h. SEM, EDS, and XRD analyses revealed that the oxide layer on the surface thickened with increasing temperature and corrosion duration, forming NiO, Cr₂O₃, and mixed metal oxides. These oxide phases created a protective barrier effect by limiting diffusion between the coating and the substrate. Despite a slight increase in porosity and minor WC dissolution under long-term oxidation conditions, the coatings maintained their structural integrity up to 900 °C, demonstrating significant resistance to high-temperature oxidation and molten salt corrosion. These results demonstrate that Diamalloy 2002 coatings provide an effective surface protection solution in abrasive and oxidizing high-temperature environments. Full article

As an eco-friendly flame-retardant additive, magnesium hydroxide (MH) is widely employed in low-smoking, halogen-free polymer materials due to its environmentally benign nature. In order to enhance flame retardancy performance, the modified MH was modified with tetrakis(hydroxymethyl)phosphonium sulfate (THPS) by a one-pot hydrothermal method. The resulting morphology was characterized using scanning electron microscopy (SEM), and it shows the dispersion of nanometer particles and almost no aggregation. The X-ray photoelectron spectroscopy (XPS) along with Raman spectroscopy show that the THPS is connected with the Mg(OH)₂ by chemical bond. The sample was incorporated into ethylene–vinyl acetate (EVA) to evaluate the flame retardancy was assessed via limiting oxygen index (LOI) and vertical burning tests (UL-94). The results show that THPS modified MH effectively enhanced the flame retardancy, achieving a V-0 rating and an LOI value of 31.3%. In addition, the composites retain good mechanical integrity. The thermal analysis with TGA and DTG shows the formation of the MgO decomposition product, along with water vapor and phosphorus-containing radicals released by modified MH in the combustion process, forming a strong flame-retardant protective layer. In addition, the maximum smoke density of EVA/MHP-3 composite was 155.4, lower than 411.3 for EVA/MH, with a 62.2% reduction in total smoke production. The result shows that THPS is effective for improving the flame-retardant efficiency of inorganic metal hydroxide in polymer composites. Full article

This work concerns a thermoplastic composite manufactured by thermal pressing of a nonwoven layered system. The composite structure consists of two layers: a thicker porous fibrous/plastic layer that responds to sound absorption and a thinner, rigid polymer (plastic) layer on the outside, enhancing sound absorption at selected frequencies. The novelty of this work is the creation of two interconnected holes of different diameters in a real fibrous composite, passing through both composite layers, acting as the neck and cavity of a Helmholtz resonator. Both the neck and the cavity are located within the composite structure, creating the shape of interconnected cylinders. The sound absorption of a composite with a varying neck diameter and a constant cavity diameter was studied using an impedance tube. The effect of the neck diameter on the resonant frequency and the corresponding sound absorption value was investigated. For various neck diameter variants, the resonant frequency was calculated using not constant, but a variable effective neck length. To achieve this, appropriate neck length corrections have been made for each neck diameter. The experimental results are consistent with the calculated results. These studies show that based on the relationship between the resonant frequency and the resonator neck diameter determined for a given composite, the resonant frequency (absorption peak) can be controlled by changing the neck diameter. Full article

Driven by the global energy transition and the dual carbon goals, developing low-carbon and zero-carbon alternative fuels has become a core issue for sustainable development in the internal combustion engine sector. Ammonia is a promising zero-carbon fuel with broad application prospects. However, its inherent combustion characteristics, including slow flame propagation, high ignition energy, and narrow flammable range, limit its use in internal combustion engines, necessitating the addition of auxiliary fuels. To address this issue, this paper proposes a composite injection technology combining “ammonia duct injection + hydrogen cylinder direct injection.” This technology utilizes highly reactive hydrogen to promote ammonia combustion, compensating for ammonia’s shortcomings and enabling efficient and smooth engine operation. This study, based on bench testing, investigated the effects of hydrogen direct injection timing (180, 170, 160, 150, 140°, 130, 120 °CA BTDC), hydrogen direct injection pressure (4, 5, 6, 7, 8 MPa) on the combustion and emissions of the ammonia–hydrogen engine. Under hydrogen direct injection timing and hydrogen direct injection pressure conditions, the hydrogen mixture ratios are 10%, 20%, 30%, 40%, and 50%, respectively. Test results indicate that hydrogen injection timing that is too early or too late prevents the formation of an optimal hydrogen layered state within the cylinder, leading to prolonged flame development period and CA10-90. The peak HRR also exhibits a trend of first increasing and then decreasing as the hydrogen direct injection timing is delayed. Increasing the hydrogen direct injection pressure to 8 MPa enhances the initial kinetic energy of the hydrogen jet, intensifies the gas flow within the cylinder, and shortens the CA0-10 and CA10-90, respectively. Under five different hydrogen direct injection ratios, the CA10-90 is shortened by 9.71%, 11.44%, 13.29%, 9.09%, and 13.42%, respectively, improving the combustion stability of the ammonia–hydrogen engine. Full article