Search Results (157)

The study evaluates the long-term environmental performance of natural filtration dams for leachate treatment at a municipal solid waste landfill. Field measurements of a system operating for 24 years, equipped with natural clay-loam filtration barriers, provide empirical validation for assessing the effectiveness and durability of natural material-based treatment approaches. Hydrogeological studies, including well drilling, water sampling, and comprehensive chemical analysis, demonstrate that the cascade filtration system achieves pollutant removal efficiencies of 80–95% for major contaminants. Physical property measurements reveal progressive density reduction from 1005 to 994 kg/m³ and viscosity decreases from 1.048 to 1.011 cSt across the treatment system. Numerical simulations demonstrate that contaminant transport under actual site conditions remains diffusion-dominated over multi-decadal timescales, with aquifer concentrations remaining below 1% of source values after 50 years. Parametric studies reveal that density-driven convective fingering develops only at source concentrations exceeding 100 g/L. The findings validate the long-term viability of natural geological barriers combined with cascade filtration systems for cost-effective leachate treatment, demonstrating that preliminary treatment through natural filtration effectively suppresses gravitational instabilities and protects underlying aquifers. Full article

Landfill leachate is highly concentrated wastewater containing non-biodegradable organic compounds and toxic substances. For this reason, advanced treatment methods are necessary for its treatment. The article discusses the possibility of treating leachate in a hybrid system combining ultrasonic pretreatment and anaerobic co-digestion with dairy wastewater in an anaerobic membrane bioreactor. Two laboratory-scale submerged anaerobic membrane reactors with a capillary module with membranes with a pore size of 0.1 μm and an effective filtration area of 0.35 m² were used in this study. An ultrasound disintegrator at 22 kHz (amplitude 14 µm) was used for leachate pretreatment. It was found that, as a result of leachate sonification (time > 10 min), the BOD₅/COD ratio in the wastewater increased from 0.1 to 0.4, and the content of dissolved organic compounds accounted for more than 40% of the total COD. Preliminary sonication of the leachate resulted in improved co-digestion efficiency in a reactor fed with conditioned leachate. A 92% reduction in organic pollutants was achieved, as well as a biogas production rate of 0.5 L biogas/g COD removed. Full article

By the time of this study, Kiteezi landfill was Uganda’s largest waste disposal site and received substantial volumes of municipal solid waste. In the present study, water (n = 36), leachates (n = 36), superficial sediments (n = 30), and Colocasia esculenta corms (n = 6) were sampled from Kiteezi landfill in the dry and wet seasons of 2022 before its tragic collapse in 2024. The physicochemical parameters (pH, electrical conductivity, temperature, and oxidation–reduction potential) and concentration of potentially toxic elements (As, Cu, Cr, Pb, and Zn) were analyzed using standard methods and inductively coupled plasma-optical emission spectrometry, respectively. Significant seasonal variations (p < 0.05) were observed for all the physicochemical parameters of water and leachates except temperature. Further, significantly higher concentrations (p < 0.05) of potentially toxic elements (PTXEs) were quantified in environmental matrices sampled during the dry season than the wet season. Arsenic and Pb concentrations in water surpassed their WHO permissible limit of 0.01 mg/L. The concentrations of PTXEs were higher in downstream samples (p < 0.05), indicating that landfill activities led to their enrichment in matrices near the facility. Ecological and pollution risk indices indicated that there is severe enrichment of Cu and Zn in the sediments, with dry season downstream samples having contamination factors and geoaccumulation indices of 539.3 and 74.7 and 8.5 and 5.6, respectively. Although ingestion of water may not cause probable health risks, consumption of Colocasia esculenta corms could lead to non-carcinogenic and cancer health risks in both children and adults (hazard indices = 0.085–189.0 and total cancer risk values of 7.33 × 10⁻⁶–4.87 × 10⁻³). These results emphasize the need that any new replacement for Kiteezi landfill should be properly planned and managed to mitigate potential environmental pollution with xenobiotics. Full article

Waste dumpsites in developing countries are primary pollution sources impacting nearby ecosystems. This study assessed seasonal changes in soils surrounding the Hulene-B landfill (Maputo, Mozambique) and evaluated the potential for surface water contamination by leachates. A total of 71 samples were collected during the rainy and dry periods and analyzed for pH, electrical conductivity (EC), organic matter (OM), and color. The contamination potential (Pbci) was determined considering the landfill’s characteristics and local hydrological context. During the dry season, soils exhibited higher EC and OM, indicating greater retention of potentially toxic elements (PTEs) and a strong tendency for accumulation. In the rainy season, leaching processes prevailed, leading to reduced EC and OM but increased potential for contaminant mobility. The Pbci values were consistently high across both periods, confirming elevated contamination risk. Overall, the Hulene-B landfill exerts a marked influence on surrounding soils and nearby surface waters, underscoring the urgent need for structural measures to control leachate release and ash dispersion. Full article

The dual assessment of environmental risks and energy consumption of solid waste is crucial for ensuring environmental safety and energy consumption management. Using risk assessment tools to inform best management practices for reclamation is very important. In this paper, a former Extended Environmental Multimedia Modeling System (EEMMS) combined with the Monte Carlo Method (MCM) of risk assessment was further used for exploring the fate and migration of pollutant leakage in the CFSWMA landfill. Specifically, MODFLOW combined with the EEMMS–MCM system has been applied using Biochemical Oxygen Demand (BOD) as a typical indicator to model the behavior of leachate components. An EEMMS–MCM integrated risk assessment for a 20-year period was conducted. The case study of BOD emissions from the CFSWMA landfill shows that even the leachate did not have a serious impact on Canadian territory during the 20 years; however, non-sorption chemicals are mainly affected by the groundwater flow, whereas sorption chemicals are affected by the partition coefficient (or sorption). Further, this study introduces energy consumption factors such as soil and surface water bodies, and constructs an integrated dual assessment framework for the environmental risks and energy consumption of pollutants. In summary, by integrating the EEMMS pollutant migration model with an environmental risk and energy consumption assessment, a dual assessment of environmental risks and energy consumption is achieved. Full article

This study couples a carbon quantum dot photocatalyst with a proton relay installed (EDTA-CQDs) for efficient hydrogen peroxide (H₂O₂) production with an ozone (O₃) system. In situ activation of O₃ is achieved by the photogenerated H₂O₂, which integrates the photocatalytic hydrogen peroxide production (PHP) and advanced oxidation processes (AOPs) to form a new photocatalytic peroxone (H₂O₂/O₃) system, achieving highly efficient solar-driven degradation of recalcitrant organic pollutants in landfill leachate without the addition of external H₂O₂. The composite system exhibits efficient degradation ability for various typical pollutants in landfill leachate, among which the degradation percentage of 100 mg L⁻¹ hydroquinone (HQ) reaches 97% within 30 min. This is due to the synergistic effects of O₃ oxidation, photoactivation of O₃, activation of O₃ by EDTA-CQDs, and activation of O₃ by in situ-generated H₂O₂. In the EDTA-CQD-based H₂O₂/O₃ system, free radicals can be dynamically regenerated after the addition of pollutants, achieving sustained and efficient degradation. Therefore, in the treatment of actual leachate, the removal percentages of COD, TOC, and UV254 are nearly 90%, 70%, and 55%, respectively, demonstrating the significant advantage of this system in treating high-concentration recalcitrant organic pollutants in wastewater of complex quality. Full article

This study compared the effectiveness of the Sequencing Batch Biofilter Granular Reactor (SBBGR) plant with and without the integration of ozone (BIO-CHEM process) in the remediation of medium-aged landfill leachate. Special attention is given to the removal of per- and polyfluoroalkyl substances (PFAS) as a group of bioaccumulative and persistent pollutants. The findings highlight the high SBBGR performance under biological process only for key wastewater contaminants, with 82% for chemical oxygen demand (COD), 86% for total nitrogen, and 98% for ammonia. Moderate removal was observed for total (TSS) and volatile (VSS) suspended solids (41% and 44%, respectively), while phosphorus and colour removal remained limited. Remarkably, the SBBGR process achieved complete removal of long-chain PFAS, while its performance declined for shorter-chain PFAS. BIO-CHEM process significantly improved COD (87.7%), TSS (84.6%), VSS (86.7%), and colour (92–96%) removal. Conversely, ozonation led to an unexpected increase in the concentrations of several PFAS in the effluent, suggesting ozone-induced desorption from the biomass. SBBGR treatment was characterised by a low specific sludge production (SSP) value, i.e., 5–6 times less than that of conventional biological processes. SSP was further reduced during the application of the BIO-CHEM process. A key finding of this study is a critical challenge for PFAS removal in this combined treatment approach, different from other ozone-based methods. Full article

Cultural customs often condition solid waste management, especially in developing countries. The decomposition of solid waste depends on climatic conditions and is related to geomorphology and anthropogenic practices. Leachate generated in landfills can migrate superficially and underground, contaminating soils and aquifers. Knowing the level of contaminant load in leachate is important for proper solid waste management. However, in the Andean regions of Peru, there is scarce data on the polluting potential of leachates. This research aimed to determine the Leachate Pollution Index (LPI) according to the sub-indexes of organic, inorganic, and heavy metals from landfills in the high Andean regions of Peru. Physical, chemical, and microbiological parameters were evaluated in fresh and retained leachate samples, in both dry and rainy seasons, from two landfills located at around 3000 m of altitude. The results showed high contamination levels, particularly in BOD₅, COD, NH₃-N, and total coliforms, with high organic and inorganic sub-indexes that affect the LPI, indicating high levels of contamination and posing a potential risk to surrounding ecosystems. It was also found that the high Andean landfills studied have a good-to-high biodegradability. This research contributes essential baseline information for environmental monitoring and supports the need for improved leachate management in high-altitude landfills in Peru and similar Andean contexts. Full article

The contamination due to coastal landfill is a growing environmental concern, particularly in fragile marine ecosystems, where leachate can mobilize toxic elements into soil, water, air, and sediment. This study aims to assess the impact of a coastal landfill in Al-Qunfudhah, western Saudi Arabia, on nearby coastal sediments by identifying the concentration, distribution, and ecological risk of potentially toxic elements (PTEs) using geospatial and multivariate analysis tools. The results indicate significant accumulation of Pb, Zn, Cu, and Fe, with Pb reaching alarming levels of up to 1160 mg/kg in the landfill area, compared to 120 mg/kg in the coastal sediments. Zn contamination also exhibited substantial elevation, with values reaching 278 mg/kg in landfill soil and 157 mg/kg in coastal sediment. The enrichment factor values indicate moderate to severe enrichment for Pb (up to 73.20) and Zn (up to 6.91), confirming anthropogenic influence. The contamination factor analysis categorized Pb contamination as very high (CF > 6), suggesting significant ecological risk. Comparison with sediment quality guidelines suggest that Pb, Zn, and Cu concentrations exceeded threshold effect levels (TEL) in some samples, posing potential risks to marine organisms. The spatial distribution maps revealed pollutant migration from the landfill toward the coastal zone, emphasizing the necessity of monitoring and mitigation strategies. As the first comprehensive study on landfill-induced PTEs contamination in Al-Qunfudhah, these findings provide essential insights for environmental management and pollution control policies along the Red Sea coast. Full article

In the context of increasing concern over long-term environmental impacts of closed landfill sites, this study investigates the composition of groundwater and leachate at a municipal waste landfill in southwestern Poland, two decades after its closure. The research, conducted in 2023, aimed to assess groundwater quality using 11 physico-chemical and 13 microplastic indicators. Groundwater and leachate samples were collected seasonally to assess of groundwater quality around landfill, including presence of heavy metals (Cd, Cr⁶⁺, Cu, Pb), PAHs and TOC, and microplastics. The results revealed persistent environmental degradation, with elevated concentrations of total organic carbon (24.8 mg/L) and cadmium (0.0211 mg/L), particularly in the second half of the year. Additionally, PET microplastics were detected in correlation with increased precipitation and leachate generation. These findings indicate that pollutants continue to migrate from the waste deposit into the surrounding groundwater, with seasonal patterns amplifying their presence. The study confirms that even decades after closure, municipal landfills can remain significant sources of both chemical and microplastic contamination, underlining the need for long-term monitoring and remediation strategies to protect groundwater resources. Full article

Landfill leachates in tropical regions represent a critical environmental challenge due to their complex composition and pronounced seasonal variability. This study sought to characterize leachates from a tropical landfill in Valledupar, Colombia, and to evaluate advanced treatment technologies for the removal of organic pollutants. An ARIMA (3,0,3) model was implemented on an eight-year time series (2016–2023) of leachate flow data to identify seasonal patterns and support hydraulic load forecasting. Physicochemical characterization was conducted following APHA standard methods, which revealed high levels of COD, BOD₅, chlorides, and lead. Two treatment technologies were assessed independently: (i) adsorption using granular activated carbon in batch and continuous-flow systems, under 36 experimental conditions that combined pH levels (2–7) and carbon dosages (20–120 g); and (ii) reverse osmosis employing polyamide membranes operated at 18 bar and at pH values of 6.0, 7.0, and natural (unaltered) conditions. The results confirmed that leachate generation exhibits clear seasonal variability correlated with rainfall patterns. The Langmuir isotherm demonstrated the best fit at pH 4.0 (R² = 0.9685), and the continuous system achieved 97% COD removal within 90 min. Reverse osmosis consistently removed over 94% of COD and BOD₅ across all pH conditions. These findings highlight the value of integrating time-series forecasting with optimized treatment technologies to support effective and adaptive leachate management strategies in tropical environments. Full article

The distribution of leachate in landfill systems significantly influences landfill stability, pollutant migration, and gas transport. However, existing methods for measuring leachate levels in landfills with multiple intermediate cover layers remain insufficient. This study introduces a novel in situ testing method to determine multi-layer leachate levels. Field experiments at a landfill site in northwestern China successfully quantified leachate levels on each intermediate cover layer. Seepage analysis simulated the leachate level recovery test method used in field investigations, enabling examination of the formation mechanisms and drainage characteristics of multi-layer leachate systems. Measurement results demonstrated that each intermediate cover layer retained a corresponding perched leachate level. Variations in perched water head across waste layers arise from differences in drainage capacity between waste strata. Differential settlement of the intermediate cover layers in localized areas generated adverse hydraulic gradients, contributing to spatial heterogeneity in perched leachate distribution. Back analysis yields an in situ saturated hydraulic conductivity ranging from 1 × 10⁻⁴ to 3.3 × 10⁻³ cm/s. Low-permeability intermediate cover layers were identified as the primary factors contributing to multi-layer leachate formation. The implementation of effective horizontal drainage can reduce perched leachate accumulation above intermediate layers. Full article

Landfill leachate, characterized by its high concentration of organic matter (high COD), elevated ammonia and nitrogen levels, high salinity, and toxicity, poses a significant challenge for environmental pollution control. In recent years, extensive research efforts have been dedicated to treating landfill leachate, resulting in the implementation of various engineering technologies. However, with the advancement of analytical techniques, an increasing number of emerging contaminants (ECs) have been detected in landfill leachate. These pollutants pose potential environmental and health risks, yet traditional wastewater treatment technologies struggle to effectively remove them, necessitating innovative upgrades to existing methods. This paper reviews the current research status of landfill leachate treatment technologies, compares the advantages and disadvantages of various techniques, and emphasizes the importance of technological innovation in treatment processes. Full article

Landfill leachate, a complex wastewater generated from municipal solid waste (MSW) landfills, presents significant environmental challenges due to its high organic content and toxic pollutants. This study proposes a sustainable solution by employing the green synthesis of copper oxide nanoparticles (CuO NPs) using durian (Durio zibethinus) husk extract, which serves as a natural reducing and stabilizing agent. This approach transforms agricultural waste into a valuable resource for environmental remediation. The synthesis was carried out under mild conditions, avoiding harmful chemicals and reducing energy consumption. The CuO NPs were characterized by scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), Fourier-transform infrared spectroscopy (FTIR), and UV-Vis spectroscopy to examine their morphology, crystallinity, purity, and optical properties. SEM and HR-TEM analyses revealed mainly spherical nanoparticles with an average size of 35–50 nm and minimal aggregation. XRD analysis confirmed the presence of a highly crystalline monoclinic phase of CuO, while the EDX spectrum showed distinct peaks corresponding to copper (72%) and oxygen (28%) by weight, confirming the high purity of the material. Preliminary tests demonstrated the photocatalytic efficiency of the CuO NPs, achieving up to a 79% reduction in chemical oxygen demand (COD) in landfill leachate. These findings underscore the potential of green-synthesized CuO NPs for environmental applications, offering an innovative, sustainable method for wastewater treatment and supporting the advancement of solid waste management practices. Full article

Currently, solid waste storage systems generate secondary pollutants such as leachates, derived from rainwater infiltration or produced during their storage, which affect water quality, human health, and the environment. This study evaluated a bioremediation system for leachates from the “Rancho Triste” landfill using Spirulina sp. as a microalgal strain. Its rapid adaptation to the leachate was identified through respirometry based on CO₂ measurement, allowing the modeling of microalgal adaptation using a Log-Normal Peak Shifted with Offset function. Tests conducted in a 0.5 L reactor determined an optimal treatment time of 10 days, achieving removals of 87.17% for iron, 28.96% for magnesium, and 90.74% for manganese. Subsequently, a 2³ factorial design was implemented to optimize the reduction of chemical oxygen demand (COD), evaluating agitation, lighting, and nitrogen supplementation, achieving a COD removal efficiency exceeding 50% under optimal conditions. The fed-batch technique enabled an enrichment of microbiological populations, which, together with bio-stimulation, bioventilation, and photoperiods, demonstrated the scalability of the bioprocess and the significant reduction of metallic and recalcitrant contaminants present in the leachate. This approach proposes an ecological alternative with potential application in water treatment industries aiming for carbon neutrality and optimal transformation of high-effluent volumes. Full article