Search Results (25)

Dual beam laser welding of UNS S32750 superduplex stainless steel was performed to investigate the effect of beam-power distribution on microstructure and mechanical properties. Plates with a thickness of 3 mm were welded at a constant total power and travel speed using leading and lagging power splits of 50:50, 80:20, and 65:35. The heat affected zone width was metallographically estimated at approximately 100 µm for all conditions, consistent with comparable gross thermal exposure under constant nominal linear energy input (P_total/v). A slight modification to the power distribution altered the solidification texture and austenite morphology. The 50:50 configuration produced a refined ferritic matrix with a continuous network of grain boundaries, Widmanstätten, and intragranular acicular austenite. The 80:20 condition increased ferrite path continuity, while the 65:35 split produced an intermediate morphology. Vickers hardness reached a maximum for the 80:20 split (HAZ: 345 HV; weld metal: 349 HV). Ultimate tensile strength remained statistically constant between 908 MPa and 914 MPa, whereas elongation decreased from 28% at 50:50 to 24% at 80:20 and 23% at 65:35. All welds exhibited ductile fracture with microvoid coalescence, and electrochemical performance was comparable, with critical pitting temperature values between 78 °C and 91 °C. Beam power distribution primarily affects solidification morphology and enables control of the hardness-to-ductility balance, with a 50:50 split providing the most favorable combination of properties. Full article

In order to find the optimal heat input for simulating the welding of the coarse-grained heat-affected zone (CGHAZ) of a novel Q690 MPa V-N microalloyed medium and heavy plate, the study investigated the precipitation of V (C, N), microstructural changes, and impact toughness under five different heat inputs (E). The results show that in the CGHAZ, as the heat input increases, the dominant microstructure changes from intragranular acicular ferrite (IGAF) and lath bainitic ferrite (LBF) to polygonal ferrite (PF) and a small amount of IGAF. At the same time, the area fraction of the brittle phase martensite/austenite (M/A) constituents increased from 4.96% to 7.95% as heat input increased, and the microhardness difference between the M/A constituents and the matrix significantly increased. In addition, with the E increases, the fraction of high-angle grain boundaries (HAGBs), which can hinder crack propagation, increases from 59.2% to 62.2% and then decreases from 62.2% to 49.3%. Moreover, the impact toughness of the simulated CGHAZ of the Q690 MPa V-N microalloyed medium and heavy plate first increases from 62 J to 100 J and then decrease to 20 J. Full article

High-strength low-alloy (HSLA) steels have garnered significant attention owing to their widespread applications across various industries, with weldability being a particularly critical aspect. However, the impact toughness of the coarse-grained heat-affected zone (CGHAZ) remains a notable challenge under high-heat-input welding conditions. Despite existing research acknowledging the beneficial effects of micro-alloying elements on steel properties, there are still numerous uncertainties and controversies regarding the specific influence of these elements on the microstructure and impact toughness of the CGHAZ under specific welding conditions. To address this issue, this study presents a comprehensive review of the impact of common micro-alloying elements on the microstructure and toughness of the CGHAZ during high-heat-input welding. The results indicate that elements such as cerium, magnesium, titanium, vanadium, nitrogen, and boron significantly improve the toughness of the CGHAZ by promoting intragranular nucleation of acicular ferrite and inhibiting the coarsening of austenite grains. In contrast, the addition of elements such as aluminum and niobium adversely affect the toughness of the CGHAZ. These findings offer crucial theoretical guidance and experimental evidence for further optimizing the welding performance of HSLA steels and enhancing the impact toughness of the CGHAZ. Full article

This study investigated the microstructure, mechanical properties, and nucleation mechanism of acicular ferrite (AF) present in hot-rolled Ti deoxidized steel. In our experiments, the impact toughness of Ti deoxidized steel is significantly increased to 144 J at −20 °C, while those Mn and Al deoxidized steels are only 9 J and 18 J, respectively. Interlocked AF is the primary microstructure of Ti deoxidized steel. The second-phase particles of the core–shell-type structure, in which Ti₂O₃ is the nucleus and TiO is the outermost shell, act as effective nucleating agents to stimulate AF nucleation. The low lattice disregistry between TiO and AF is the main factor contributing to the production of AF. It is also revealed that Ti₂O₃ and MnS fulfill the particular orientation relationship, contributing to the formation of an Mn-depleted zone (MDZ) adjacent to MnS, proposed to be one of the possible mechanisms for promoting AF nucleation. Full article

With the development of the pressure vessel industry, high-energy wire welding has a great future. However, this means higher demands on the weldability of pressure vessel steels. Controlling inclusions via oxidative metallurgy is a reliable method of improving the weldability of pressure vessel steels. Hence, in this paper, experimental steels with different Mg element mass fractions were prepared using vacuum metallurgy. Simulated welding for high-heat input welding was carried out using the Gleeble-2000 welding thermal simulation test machine. The inclusions in the welding heat-affected zone (HAZ) in the experimental steels were observed using an optical microscope (OM) and scanning electron microscope (SEM). The compositions of the inclusions were analyzed using an energy-dispersive spectrometer (EDS). The research results indicated that the addition of Mg could increase the number density of the inclusions in the welding HAZ. With the addition of Mg from 0 to 5 wt.%, the total number density of the inclusions increased from 133 to 687 pieces/mm^2, and the number density of the inclusions with a size of 0–5 μm² increased from 122 to 579 pieces/mm². The inclusions in the experimental steel welding HAZ with Mg elements were mainly elliptical composite inclusions composed of (Mg-Zr-O) + MnS. Moreover, MnS precipitated on the surface of the Mg-containing inclusions in the welding HAZ. Intragranular acicular ferrite (IAF) nucleation was primarily induced via the minimum lattice mismatch mechanism, supplemented with stress-strain energy and inert interface energy mechanisms. Full article

Pressure vessel steels are used in the manufacture of tanks for the storage of gases, chemical materials and oil. To meet the increasing production demands, high-wire-energy welding is widely used in the manufacture of pressure vessel steels. This means that the weldability of pressure vessel steels needs to be improved. Therefore, in order to reveal the microalloying effect of Ca in pressure vessel steel, this study took a commonly used pressure vessel steel as the research object, and three groups of experimental steels with different Ca mass fractions were prepared using vacuum metallurgy, controlled rolling and controlled cooling. Welding heat simulation technology was used to simulate the welding heat of experimental steel and the welding heat-affected zone (HAZ) was investigated. The inclusions of the welding HAZ in the experimental steels were observed by using a metallographic microscope and scanning electron microscope (SEM). The mechanism of intragranular acicular ferrite (IAF) nucleation induced by the inclusions containing Ca elements in the welding HAZ of pressure vessel steels was also discussed. The research results show that the addition of Ca increased the number density of effective inclusions in the welding HAZ of the experimental steel up to 535.60 pieces/mm². The addition of the Ca element was beneficial for producing more pinning inclusions in the experimental steel welding HAZ under the experimental conditions, and the inclusions were mainly elliptical oxide complex inclusions of Ca-Si with a size of about 2 μm. Meanwhile, Al₂O₃ and MnS were precipitated. After the addition of Ca elements, Mn-poor regions appeared around the inclusions containing Ca in the welding HAZ. IAF nucleation was mainly induced by the local compositional change mechanism and supplemented by the stress–strain energy mechanism and inert interface energy mechanism. This study provides a valuable reference for optimizing the welding process of pressure vessel steels and is of great importance for understanding the IAF nucleation mechanism of Ca-containing inclusions in the welding HAZ of pressure vessel steels. Full article

The mechanical properties of a coarse-grained heat-affected zone (CGHAZ) are affected by welding thermal cycling with varied heat input (E_j), but its effect on tensile properties is rarely studied. In the present work, E_j = 15, 35, 55, 75 kJ/cm CGHAZ samples were prepared via Gleeble^TM (St. Paul, MN, USA) for a novel V-Ti-N microalloyed weathering steel. The tensile properties of CGHAZ with varied E_j were evaluated. The results indicated that mixed microstructures dominated by lath bainitic ferrite (LBF) and granular bainitic ferrite (GBF) were obtained at E_j = 15 and 35 kJ/cm, respectively, while a mixed microstructure composed of GBF, intragranular acicular ferrite (IGAF), and polygon ferrite (PF) formed at E_j = 55 and 75 kJ/cm, apart from martensite/austenite (M/A) constituents in each E_j condition. The above variation tendency in the microstructure with the increase in E_j led to coarsening of low-angle grain boundaries (LAGBs) and a decrease in dislocation density, which in turn resulted in a yield strength (YS) decrease from 480 MPa to 416 MPa. The mean equivalent diameter (MED), defined by the misorientation tolerance angles (MTAs) ranging from 2–6°, had the strongest contribution to YS due to their higher fitting coefficient of the Hall–Petch relationship. In addition, the increase in the average size (d_M/A) of M/A constituents from 0.98 μm to 1.81 μm and in their area fraction (f_M/A) from 3.11% to 4.42% enhanced the strain-hardening stress. The yield strength ratio (YR) reduced as the E_j increased, and the lower density and more uniform dislocations inside the ferrite led to a uniform elongation (uE) increase from 9.5% to 18.6%. Full article

Large-heat-input welding can effectively increase the efficiency and reduce the cost of manufacturing a super-large container ship for marine trade worldwide with thick, high-strength low-alloy (HSLA) steel plates; however, it significantly degrades the toughness of the welding heat-affected zone (HAZ). This paper describes the effect of Ca deoxidation on the impact toughness of simulated coarse-grained HAZs (CGHAZs) in HSLA steels after large-heat-input welding at 400 kJ cm⁻¹. The average impact energy of the CGHAZ increases with an increase in Ca content; in particular, the energy of the steel with 25 ppm Ca content is satisfactorily high, owing to the uniform and fine prior austenite grains. In contrast, the grains in the CGHAZs of the steels with relatively low Ca contents are not uniform, leading to large test variabilities at −20 °C. Failure analyses reveal that the major and secondary cracks preferentially propagate along the coarse and brittle grain boundary ferrite (GBF), but their propagation is retarded by the fine and interlocking intragranular acicular ferrite (IAF) as the grain size decreases. It is therefore recommended to increase the Ca content to about 25 ppm during the deoxidation of steelmaking to improve HAZ toughness by forming fine and uniform prior austenite grains and IAF within grains. Full article

The microstructure and mechanical properties of X70 pipeline steel with a ferrite/martensite dual-phase microstructure produced by thermo-mechanical controlled processing were investigated by tensile tests, Charpy V-notched (CVN) impact tests, drop-weight tear tests, guided-bend tests, scanning electron microscopy and transmission electron microscopy combined with thermodynamic simulation analysis. All the mechanical properties met the strength, ductility, toughness and deformability properties requirements of X70 grade pipeline steel with strain-based design. The shear fracture area and absorbed energy of CVN at −10 °C were >97% and >205 J in base metal (BM), weld metal (WM) and heat affected zone (HAZ) with low transition temperature, indicating adequate resistance to propagating fracture. The microstructure of WM was mainly intragranular acicular ferrite that can guarantee high strength, toughness and over matching requirements of the welded joint. Because of being exposed to successive heat inputs, the ferrite plus martensite/bainite microstructure of BM was heated between A_c1 and T_s forming the HAZ. However, a high CVN impact toughness of 345 J at −10 °C in HAZ was obtained, which indicated that the excellent mechanical properties of BM would not be seriously deteriorated during the welding thermal cycles with the reasonable addition of Ti and Nb. Full article

This study investigates the effect of the laser surface melting and consecutive point-mode forging process (LSM-CPF) on the mechanical properties and the microstructure of DH36 marine steel. The microstructual revolution during the LSM-CPF process are revealed by metallographic microscope (OM) and scanning electron microscope (SEM) technique, and the strengthening mechanisms for different samples are also elucidated. The results show that the best yield strength (σ_0.2) and tensile strength (σ_b) for the sample treated with 4000 W laser power and 10% reduction ratio are 721.3 and 884.2 MPa, which are 49.55% and 41.54% higher than that of the DH36 matrix, respectively. The hardness of the coatings decreases along the normal direction with the maximum value of 586.4 HV in the CPF zone for the sample treated with 2000 W laser power and 20% reduction ratio. During the low power LSM-CPF treatment, the nanoscale cementite appear as intragranular due to the inhibited carbon diffusion. The coherent boundary of (110)_NbC‖(110)_Ferrite, [1$\overline{1}$0]_NbC‖[001]_Ferrite between NbC and ferrite reduces the nucleation barrier to promote the nucleation of acicular ferrite (AF). The strengthening mechanism for samples treated at 2000 W is found to be dislocation strengthening. During high power laser treatment, pearlite transformation is found to occur with a low cooling rate. In this case, the strengthening mechanism is the boundary strengthening of lamellar pearlite and dislocation strengthening. Full article

To understand and clarify the formation mechanisms and evolution of complex inclusions in Ti-Ca deoxidized offshore structural steel, inclusions in industrial steel were systematically investigated. The number density of total inclusions generally decreased from Ladle Furnace (LF), Vacuum Degassing (VD), Tundish to the final product except for Ti and Ca addition. The major inclusions during the refining process were CaO-Al₂O₃-SiO₂-(MgO)-TiO_x and CaO-Al₂O₃-SiO₂. CaO-Al₂O₃-SiO₂-(MgO)-TiO_x inclusion initially originated from the combination of CaO-SiO₂-(MgO) in refining slag or refractory and deoxidization product Al₂O₃ and TiO₂. With the refining process proceeding and Ca addition, the Al₂O₃ concentration in the CaO-Al₂O₃-SiO₂-(MgO)-TiO_x inclusions gradually dropped while the CaO and TiO₂ concentrations gradually increased. The CaO-Al₂O₃-SiO₂ inclusions originally came from refining slag, existing as 2CaO∙ Al₂O₃∙ SiO₂, and maintained a liquid state during the early stage of LF. After Ca treatment, it was gradually transferred to 2CaO∙ SiO₂ due to Al₂O₃ continuously being reduced by Ca. The liquidus of 2CaO∙ SiO₂ inclusion was higher than that of molten steel, so they presented as a solid-state during the refining process. After welding thermal simulation, CaO-Al₂O₃-SiO₂-(MgO)-TiO_x inclusions were proven effective for inducing intragranular acicular ferrite (IAF) while CaO-Al₂O₃-SiO₂ was inert for IAF promotion. Additionally, Al₂O₃-MgO spinel in multiphase CaO-Al₂O₃-SiO₂-(MgO)-TiO_x inclusion has different formation mechanisms: (1) initial formation as individual Al₂O₃-MgO spinel as a solid-state in molten steel; (2) and it presented as a part of liquid inclusion CaO-Al₂O₃-SiO₂-(MgO)-TiO_x and firstly precipitated due to its low solubility. Full article

Welding thermal cycles with heat inputs ranging from 25 to 75 kJ/cm were performed on a Gleeble 3500. The impact energy improved significantly (from 10 to 112 J), whereas the simulated coarse-grain heat-affected zone (CGHAZ) microstructure changed from lath bainite ferrite (LBF) and granular bainite ferrite (GBF) + martensite/austenite (M/A) to acicular ferrite (AF) + polygonal ferrite (PF) + M/A as the heat input increased. Simultaneously, the mean coarse precipitate sizes and the degree of V(C,N) enrichment on the precipitate surface increased, which provided favorable conditions for intragranular ferrite nucleation. The Ar₃ of CGHAZ increased from 593 °C to 793 °C with increasing heat inputs; the longer high-temperature residence time inhibited the bainite transformation and promoted the ferrite transformation. As a result, acicular ferrite increased and bainite decreased in the CGHAZ. The CGHAZ microstructure was refined for the acicular ferrite segmentation of the prior austenite, and the microstructure mean equivalent diameter (MED) in the CGHAZ decreased from 7.6 µm to 4.2 µm; the densities of grain boundaries higher than 15° increased from 20.3% to 45.5% and significantly increased the impact toughness. The correlation of heat input, microstructure, and impact toughness was investigated in detail. These results may provide new ideas for the development of high welding heat input multiphase steels. Full article

For investigating the impact of ferritic morphology on yield strength (YS) of the high-heat-input welding induced coarse-grained heat-affected zone (CGHAZ) of a low carbon Mo-V-N-Ti-B steel, a group of particular welding heat inputs were designed to obtain different ferritic microstructures in CGHAZ. The tensile properties were estimated from typical samples with ferritic microstructures. The mixed microstructures dominated by the intragranular polygonal ferrite (IGPF), the intragranular acicular ferrite (IGAF), and the granular bainite (GB) were obtained at the heat inputs of 35, 65, 85 and 120 kJ/cm, respectively. When the main microstructure changed from IGPF to IGAF and GB, YS increased first and then decreased. The microstructure consisting mainly of IGAF possessed the maximum YS. As the main microstructure changed from IGPF to IGAF and GB, the contribution of grain refinement strengthening to YS was estimated to be elevated remarkably. This means the strength of CGHAZ in a low-carbon steel subjected to the high-heat-input welding could be enhanced by promoting the fine-grained AF and GB formation. Full article

Isothermal transformation characteristics of a medium carbon Ti-V microalloyed steel were investigated using light microscopy, scanning electron microscopy (SEM) equipped with energy dispersive spectroscopy (EDS), and by uniaxial compressive testing. Samples austenitized on 1100 °C were isothermally treated in the range from 350 to 600 °C and subsequently water quenched. The final microstructure of the samples held at 350 °C consisted of bainitic sheaves and had compressive yield strength, approximately from 1000 MPa, which is attributed to high dislocation density of low bainite. At 400 and 450 °C, acicular ferrite became prevalent in the microstructure. It was also formed by a displacive mechanism, but the dislocation density was lower, leading to a decrease of compressive yield strength to approximately 700 MPa. The microstructure after the heat treatment at 500 °C consisted of coarse non-polygonal ferrite grains separated by pearlite colonies, principally dislocation free grains, so that the compressive YS reached a minimum value of about 700 MPa. The microstructure of the samples heat-treated at 550 and 600 °C consisted of pearlite and both grain boundary and intragranular ferrite, alongside with some martensite. After 600 s, austenite became stable and transformed to martensite after water quenching. Therefore, the presence of martensite increased the compressive YS to approx. 800 MPa. Full article

In this study, the acicular ferrite transformation behavior of a Ti–Ca deoxidized low carbon steel was studied using a high-temperature laser scanning confocal microscopy (HT-LSCM). The in situ observation of the transformation behavior on the sample surface with different cooling rates was achieved by HT-LSCM. The microstructure between the surface and interior of the HT-LSCM sample was compared. The results showed that Ti–Ca oxide particles were effective sites for acicular ferrite (AF) nucleation. The start transformation temperature at grain boundaries and intragranular particles decreased with an increase in cooling rate, but the AF nucleation rate increased and the surface microstructure was more interlocked. The sample surface microstructure obtained at 3 °C/s was dominated by ferrite side plates, while the ferrite nucleating sites transferred from grain boundaries to intragranular particles when the cooling rate was 15 °C/s. Moreover, it was interesting that the microstructure and microhardness of the sample surface and interior were different. The AF dominating microstructure, obtained in the sample interior, was much finer than the sample surface, and the microhardness of the sample surface was much lower than the sample interior. The combined factors led to a coarse size of AF on the sample surface. AF formed at a higher temperature resulted in the coarse size. The available particles for AF nucleation on the sample surface were quite limited, such that hard impingement between AF plates was much weaker than that in the sample interior. In addition, the transformation stress in austenite on the sample surface could be largely released, which contributed to a coarser AF plate size. The coarse grain size, low dislocation concentration and low carbon content led to lower hardness on the sample surface. Full article