Search Results (875)

The interfacial behavior of polyelectrolytic flocculants is governed not only by their chemical composition but also by the molecular-scale distribution of charged and neutral segments, which directly influences transport, adsorption, and interfacial stability. In this work, classical molecular dynamics simulations are used to elucidate how charge-site architecture controls the conformation, dynamics, and adsorption stability of anionic polyacrylamides at the quartz–water interface. Polymer architectures ranging from homogeneous charge distributions to block-like arrangements were systematically analyzed at constant molecular weight and global charge density. The results show that increasing charge segregation induces more compact conformations, enhanced translational mobility in solution, and reduced solvent accessibility. At the interface, polymers containing extended neutral blocks exhibit significantly more stable adsorption on quartz than polymers with homogeneously distributed charges, consistent with the low surface charge density of silica. These findings demonstrate that charge-site distribution is an independent and critical design parameter governing polymer–surface interactions. From a chemical engineering perspective, the results provide fundamental insight relevant to the rational design of polymeric additives for solid–liquid separation, flocculation, and sustainable mineral processing applications. Full article

This study systematically investigates the microstructure evolution, mechanical properties, and residual stress distribution in diffusion-bonded joints between Al₂O₃ ceramic and TC4 alloy. Motivated by the need for reliable high-temperature joints in advanced applications, this work addresses the challenges posed by the materials’ physicochemical differences. Joints were fabricated at temperatures ranging from 800 °C to 950 °C under a pressure of 3 MPa for 2 h. Microstructural characterization revealed the formation of a multi-layered interfacial structure, dominated by a Ti₃Al reaction layer, whose thickness increased with bonding temperature. The highest shear strength of 54 MPa was achieved at 850 °C, representing a key quantitative outcome of this parameter optimization. Beyond this temperature, excessive growth of the brittle Ti₃Al layer and associated residual stresses led to strength degradation and interfacial cracking. A three-dimensional finite element model was developed to simulate residual stress distributions, highlighting significant tensile stresses within the Ti₃Al layer and compressive stresses in the Al₂O₃ near the interface. The model further identified critical tensile stress concentrations along the vertical edges of the ceramic, which contribute to failure during shear testing. Full article

Hypo-peritectic steels are susceptible to interfacial cracking during thin-slab continuous casting, in which non-metallic inclusions play a critical role. This study systematically investigates the effects of inclusion type and morphology on interface cracking behavior in the steel matrix, with the aim of improving billet shell quality. Hot tensile experiments were conducted using a Gleeble 3800 thermal simulator, and a finite element–based cohesive zone model was developed to simulate inclusion-induced crack nucleation and propagation. The results demonstrate that inclusions markedly influence interfacial stress distribution and damage evolution. The maximum interfacial stresses associated with MnS, Al₂O₃, and composite inclusions are 20.7, 23.4, and 30.5 MPa, respectively. Owing to severe stress concentration at sharp corners, composite inclusions exhibit the earliest crack nucleation at an applied stress of 11.3 MPa and the highest energy dissipation. In all cases, cracks initially nucleate at the location of maximum tensile stress (α = 90°), propagate along the interface, and subsequently penetrate into the matrix, ultimately leading to failure. The strong agreement between numerical simulations and experimental results confirms that angular inclusions accelerate damage by disrupting matrix continuity. These findings provide theoretical guidance for improving hypo-peritectic steel quality through inclusion morphology control during continuous casting. Full article

To address the inherent defects in the fabrication of AlCrN titanium alloy coatings and enhance interfacial bonding strength as well as tribological performance, an AlCrN coating was employed as an absorption layer and subjected to laser shock processing to form an AlCrN/TC4 transition layer. Subsequently, a secondary AlCrN coating was deposited to construct a gradient coating architecture. The surface and cross-sectional morphologies and elemental distributions under varying laser energies were systematically investigated, and the influence of laser energy on the adhesion and wear resistance of the gradient coatings was analyzed. The results demonstrate that with increasing laser impact energy, the thickness of the AlCrN/TC4 transition layer gradually decreases from 3.75 μm to 1.32 μm, accompanied by significant changes in elemental distribution across the surface and cross-section. The interfacial bonding strength of the gradient coating increases substantially from 13.6 N to 43.3 N, while the average friction coefficient rises from 0.436 to 0.507. Concurrently, the wear track depth is reduced, and the wear rate decreases from 86.46 × 10⁻⁵ mm³/(N·m) to 7.67 × 10⁻⁵ mm³/(N·m). Laser shock peening promotes elemental diffusion, enabling the formation of a diffusion-aided interlayer. The incorporation of this diffused zone facilitates the successful construction of a high-quality TC4 titanium alloy gradient coating, effectively broadening the film–substrate interface, enhancing surface hardness, and significantly improving both interfacial adhesion and wear resistance. Full article

Geogrids significantly enhance the soil matrix stability and foundation bearing capacity. Despite the development of numerous geogrid configurations, their geometric design has not yet been systematically optimized. The design of geogrid aperture geometry aims to maximize geogrid performance while maintaining material efficiency. Nevertheless, topology optimized geogrid designs remain underexplored, particularly regarding the influence of aperture shape on interface shear behavior. To address this gap, this study developed SIMP-based variable density topology optimization models for three types of tensile geogrid structures: uniaxial, biaxial, and triaxial geogrid. The effects of key model parameters on the optimization results are examined, resulting in new geogrid geometries optimized primarily to minimize compliance, achieving weight reductions of 7%, 10%, and 12%, respectively. Subsequently, FLAC3D was used for tensile performance analysis, while coupled PFC3D–FLAC3D was employed for interfacial friction performance analysis. In FLAC3D, numerical simulations demonstrated that the topologically optimized geogrid outperformed conventional ones in both tensile resistance and strain distribution. Consequently, conventional biaxial and triaxial geogrids, along with their topologically optimized versions, were chosen for further analysis. Pull-out interface simulations of these geogrids were conducted using the coupled discrete element–finite difference method (PFC3D–FLAC3D) to investigate the influence of geogrid aperture shape and aperture ratio on the soil–geogrid interface. The results indicate that the reinforcement efficiency of the topologically optimized biaxial and triaxial geogrids was 10% and 8% higher, respectively, than that of the conventional geogrids. Taking the biaxial geogrid as an example, a comprehensive comparison of performance parameters between the conventional and topology-optimized versions revealed that the optimized design achieved a 10% reduction in weight. Simultaneously, it reduced stress concentration at critical locations by approximately 60% and increased the interface pull-out resistance by 20%. These findings demonstrate that the new topologically optimized geogrid exhibits significant potential for further promotion and application in practical engineering. Full article

Copper–aluminum layered composites offer a promising combination of high conductivity, light weight, and cost-effectiveness, making them attractive for applications in electric vehicles, electronics, and power transmission. However, achieving reliable interfacial bonding while avoiding excessive work hardening and brittle intermetallic formation remains a significant challenge. In this study, a Cu18150/Al1060/Cu18150 trilayer composite was fabricated through a three-stage high-temperature oxygen-free rolling process. Subsequently, the produced composite was subjected to annealing treatments to systematically investigate the effects of rolling passes, annealing temperature/time on interfacial evolution and mechanical behavior. Results indicate that rolling passes primarily influence interfacial topography and defect distribution. Fewer passes lead to wavy, mechanically bonded interfaces, while more passes improve flatness but reduce intermetallic continuity. Annealing temperature critically governs diffusion kinetics; temperatures up to 400 °C promote the formation of a uniform Al₂Cu layer, whereas 450 °C accelerates the growth of brittle Al₄Cu₉, thickening the intermetallic layer to 18 μm and compromising toughness. Annealing duration further modulates diffusion mechanisms, with short-term (0.5 h) treatments favoring defect-assisted diffusion, resulting in a porous, rapidly thickened layer. In contrast, longer annealing (≥1 h) shifts toward lattice diffusion, which densifies the interface but risks excessive brittle phase formation if prolonged. Mechanical performance evolves accordingly; as-rolled strength increases with the number of rolling passes, but at the expense of ductility. Annealing transforms bonding from a mechanical to a metallurgical condition, shifting fracture from delamination to collaborative failure. The identified optimal process, single-pass rolling followed by annealing at 420 °C for 1 h, yields a balanced interfacial structure of Al₂Cu, AlCu, and Al₄Cu₉ phases, achieving a tensile strength of 258.9 MPa and an elongation of 28.2%, thereby satisfying the target performance criteria (≥220 MPa and ≥20%). Full article

This study identifies the technological signature of ancient and alternative “Chu” and “Kriab” gold glass mosaic mirrors from Thailand. Although these mirrors play an important role in Thai decorative heritage, their production routes and interfacial chemistry at the lead-to-glass interface have remained unclear. A survey of 154 sites across Thailand shows mosaic glass was widely distributed and likely produced during the Ayutthaya period (~300 years ago). Portable X-Ray Fluorescence (pXRF), Wavelength-Dispersive XRF (WD-XRF), scanning electron microscopy (SEM), and X-ray Photoelectron Spectroscopy (XPS) were used to examine the material properties of observed Chu mirrors. Most samples can be classified as a mixed lead–alkaline glass type, with a PbO content ranging from 4.28 to 48.17 wt%. Their yellow tone is controlled by iron and manganese redox states. Chemical and physical analyses distinguish between Chu from the northern part of Thailand and Kriab from the central part of Thailand, which share a silica source but rely on different fluxes, pointing to different glass workshops. Crucially, XPS depth profiling reveals a well-defined interfacial reaction zone extending to approximately 6 nm in the ancient mirrors, predominantly characterized by disordered, chain-like Pb–O–Pb linkages. These polymeric structures enable a “chemical bridging” mechanism that effectively accommodates interfacial strain arising from thermal expansion mismatch, thereby ensuring exceptional long-term adhesion. Furthermore, the depth-dependent distribution of hydrated lead species and the emergence of photoelectron energy-loss features beyond ~6 nm distinguish the superior metallic integrity of the ancient coatings from the alternative reproductions. This distinct stratification confirms that ancient artisans achieved a sophisticated balance between a chemically bonded interface and a coherent metallic bulk. These findings offer significant insights into the ingenuity of ancient Thai artisans, providing a scientific foundation for the conservation, restoration, and replication of these culturally significant artifacts. Full article

The development of innovative cosmetic ingredients has driven growing interest in emulsion systems that combine performance, stability, and sustainability. Pickering emulsions can form physically stable systems by adsorbing solid particles at the oil–water interface. In this study, bacterial cellulose nanofibers (CNFs) and nanocrystals (CNCs), obtained via acid hydrolysis, were evaluated as stabilizing agents in Pickering emulsions containing jojoba, castor, and grape seed oils for hair conditioning applications. Structural and physicochemical characterization revealed that CNCs exhibited higher crystallinity, a narrower size distribution, and a higher negative surface charge than CNFs, resulting in enhanced colloidal stability. Emulsion analyses showed that CNCs more effectively reduced interfacial tension and produced smaller, more homogeneous droplets. Stability assessments under pH variation, thermal stress, and storage demonstrated that CNC-stabilized emulsions, particularly with castor oil, maintained stability indices above 95% for up to 60 days, whereas CNF-based systems showed greater sensitivity to environmental conditions. The incorporation of CNCs into a prototype conditioning cream resulted in a creamy texture and improved physical stability without compromising formulation performance. Overall, these results highlight CNCs as robust and efficient stabilizing materials for Pickering emulsions, reinforcing the potential of bacterial nanocellulose in advanced cosmetic formulations. Full article

This study investigates the mechanical performance and surface morphology of polyamide-based materials commonly used in plastic injection molding. Two resins, PA6 and PA66, were analyzed in both neat and 20 wt% glass fiber-reinforced (GF20) forms. The influence of reinforcement and material type on tensile strength and ductility was examined through integrated experimental and numerical approaches, complemented by microstructural and elemental analyses. PA6 and PA66 specimens were produced in accordance with ISO 527, and tensile tests revealed a significant increase in elastic modulus and tensile strength with glass fiber reinforcement, accompanied by a reduction in elongation at break. Flammability was evaluated via Glow Wire and Tracking tests. SEM–EDS analyses provided insights into fracture morphology and elemental distribution, showing that fiber–matrix interfacial debonding and fiber pull-out dominated failure in reinforced specimens, whereas neat polymers exhibited homogeneous surfaces. Finite element simulations performed in ANSYS Explicit Dynamics supported the experimental findings by identifying stress concentration zones and failure initiation regions. Although numerical simulations successfully captured stress distribution trends, quantitative differences were attributed to idealized modeling assumptions and processing-induced microstructural effects. Overall, this work provides a comprehensive assessment of the reinforcement effects in PA6 and PA66 systems, offering valuable guidance for material selection and design optimization in polymer-based engineering components. Full article

Owing to the substantial polarity difference and weak interfacial interaction, the large-scale application of fly ash (FA) in rubber materials still faces substantial challenges. To solve this issue, this study prepared a modified hybrid SSBR@FA filler through a solution mechanochemical reaction between solution-polymerized styrene-butadiene rubber (SSBR) and FA in a lab planetary ball mill. Fourier transform infrared spectroscopy (FTIR) and energy-dispersive spectroscopy (EDS) analyses demonstrated the in situ grafting-neutralization between the carboxyl in the SSBR chains and metal oxides in FA. Transmission electron microscopy (TEM) showed that surface-grafted SSBR formed a rubber-constrained layer on FA particle surfaces, which can reduce their surface energy and improve the wettability between FA and SBR matrix. Compared with the SBR vulcanizate, the mechanical properties, thermal conductivity, and flame-retardant properties of the SBR/SSBR@FA vulcanizates were obviously improved. This was because of the uniform distribution of FA and the improved interfacial interaction between FA and the rubber matrix. For example, the tensile strength, tear strength, and elongation at break increased by 66.3%, 52.9%, and 17.7%, respectively. This easy, efficient, and environmentally modified method for FA was expected offer a practical and creative solution for its application in rubber manufacturing. Full article

Carbon fibre-reinforced polymer (CFRP) bonded steel structures are increasingly adopted in offshore floating structures, yet their interfacial performance is highly susceptible to corrosion in marine environments. Corrosion-induced degradation of the CFRP–steel interface can significantly affect load transfer mechanisms and long-term structural reliability. This paper reports an experimental study on corrosion-induced degradation mechanisms and bond–slip behaviour of CFRP–steel double-strap joints. Controlled corrosion damage was generated using an accelerated electrochemical technique calibrated to ISO 9223 corrosivity categories. Tension tests were performed to examine the effects of corrosion degree, CFRP bond length, and the inclusion of glass fibre sheets (GFS) in the adhesive layer on failure modes, ultimate load capacity, and effective bond length. Digital image correlation (DIC) was employed to obtain strain distributions along the CFRP plates and to establish a bond–slip model for corroded interfaces. The results indicate that corrosion promotes a transition from CFRP delamination to steel–adhesive interface debonding, reduces interfacial shear strength to 17.52 MPa and fracture energy to 5.49 N/mm, and increases the effective bond length to 130 mm. Incorporating GFS mitigates corrosion-induced bond degradation and enhances joint performance. The proposed bond–slip model provides a basis for more reliable durability assessment and design of bonded joints in corrosive environments. Full article

Partitioning is an important characteristic of the biomass gasification process in a downdraft fixed-bed gasifier, so simulating the partition characteristics has practical guiding significance for revealing the essence of gasification reactions. In this paper, based on the real gasifier, a fluid-solid interfacial reaction method was proposed to simulate heterogeneous reactions based on a holistic gasification model. The partition characteristics, such as the boundary, position, step points, and area of zones, were explored and defined through analyzing the species concentration field, kinetic rate field of reactions, and temperature field. The results indicate that the partition characteristics of kinetic rate distributions are the root cause for zoning in fixed-bed gasification. On the center line of the fixed-bed gasifier, the change nodes of CO concentration tend to be consistent with the nodes of the high kinetic rate of reactions. These results provide a theoretical foundation for the online monitoring of and intervention in biomass gasification. Full article

This paper presents an analytical model for one-dimensional consolidation analysis of multi-layered unsaturated soils under depth-dependent initial conditions. The general solutions are derived explicitly using the Laplace transform. By combining these general solutions with interfacial continuity conditions between layers and the boundary conditions, the reduced-order system is solved via the Euler method to obtain analytical solutions in the Laplace domain. Numerical inversion of the Laplace transform is then performed using Crump’s method to yield the final analytical solutions in the time domain. The model incorporates initial conditions that account for both uniform and linear distributions of initial excess pore pressure within the soil stratum. The proposed solution is verified by reducing it to degenerated cases (e.g., uniform initial pressure) and comparing it with existing analytical solutions, showing excellent agreement. This confirms the model’s correctness and demonstrates its generalization to multi-layered systems with depth-dependent initial conditions. Focusing on a double-layered unsaturated soil system, the one-dimensional consolidation characteristics under depth-dependent initial conditions are investigated by varying the physical parameters of individual layers. The proposed solution can serve as a theoretical reference for the consolidation analysis of multi-layered unsaturated soils with depth-dependent initial conditions. Full article

Steel bridge deck pavements (SBDPs) are susceptible to complex mechanical and service environmental conditions, yet current design methods often struggle to simultaneously capture global bridge system behavior and local pavement responses. To address this issue, this study develops a multi-scale finite element modeling framework that integrates a full-bridge model, a refined girder-segment model, and a detailed pavement submodel. The framework is applied to an extra-long suspension bridge to evaluate the mechanical responses of five typical pavement structural configurations—including double-layer SMA, double-layer Epoxy Asphalt (EA), EA-SMA combinations, and a composite scheme with a thin epoxy resin aggregate overlay. By coupling global deformations from a full-bridge model to the local pavement submodel, the proposed method enables a consistent assessment of both bridge-level effects and pavement-level stress concentrations. The analysis reveals that pavement structures significantly alter the stress and strain distributions within the deck system. The results indicate that while the composite configuration with a thin overlay effectively reduces shear stress at the pavement–deck interface, it results in excessive tensile strain, posing a high risk of fatigue cracking. Conversely, the double-layer EA configuration exhibits the lowest fatigue-related strain, demonstrating superior deformation coordination, while the optimized EA-SMA combination offers a robust balance between fatigue control and interfacial stress distribution. These findings validate the effectiveness of the multi-scale approach for SBDP analysis and highlight that rational structural configuration selection—specifically balancing layer stiffness and thickness—is critical for enhancing the durability and long-term performance of steel bridge deck pavements. Full article

Li₃PO₄ is a promising raw material for the low-cost synthesis of high-performance LiFePO₄. Reactive crystallization from low-concentration lithium-rich brine is a key process for the efficient preparation of high-quality Li₃PO₄ products. The effect of operating conditions (temperature/supersaturation/impurities/ultrasonic) on the induction time was investigated using a focused beam reflectance measurement. The evaluation of the primary nucleation, growth kinetics, and parameters for the extraction of Li₃PO₄ from low-concentration lithium-rich brine was conducted using an induction time method. The dominant mechanisms at different stages were inferred through online monitoring of the particle size distribution during the Li₃PO₄ crystallization process. Results show that induction time decreases with increasing operating conditions (temperature/supersaturation/ultrasonic frequency), indicating that their increases all promote nucleation. Impurities (NaCl/KCl) did not significantly affect the induction time, whereas Na₂SO₄ and Na₂B₄O₇ significantly increased it, with Na₂B₄O₇ showing the most notable effect. Classical nucleation theory was applied to determine kinetic parameters (nucleation activation energy/interfacial tension/contact angle/critical nucleus size/surface entropy factor). Results indicate that Li₃PO₄ mainly nucleates through heterogeneous nucleation, with a temperature increase weakening the role of heterogeneous nucleation. Fitted models indicate that Li₃PO₄ predominantly follows the secondary nucleation and spiral growth mechanism. Our findings are crucial for crystallization design and control in producing high-quality Li₃PO₄ from lithium-rich brines. Full article