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Keywords = in situ resorting

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31 pages, 9022 KiB  
Article
An Analysis of Powder, Hard-Packed, and Wet Snow in High Mountain Areas Based on SAR, Optical Data, and In Situ Data
by Andrey Stoyanov, Temenuzhka Spasova and Daniela Avetisyan
Remote Sens. 2025, 17(9), 1649; https://doi.org/10.3390/rs17091649 - 7 May 2025
Viewed by 736
Abstract
The following study presents the results obtained from a comparative analysis of dry (powder and hard snow) and wet snow based on satellite data and in situ data methods for monitoring in the high mountain belt of Bulgaria. The aim of the study [...] Read more.
The following study presents the results obtained from a comparative analysis of dry (powder and hard snow) and wet snow based on satellite data and in situ data methods for monitoring in the high mountain belt of Bulgaria. The aim of the study is to analyze the effectiveness of different spectral indices based on satellite data from Synthetic Aperture Radar (SAR), high-resolution (HR) imagery, and spectrometer data for assessing the state and dynamics of the snow cover. The methods studied and the results obtained were validated by instrument-based field observations, with instruments using thermal imaging cameras, spectrometer measurements, ground control points, and HR imagery. Satellite data offer an ever-widening view of trends in snow distribution over time. All these data combined provide a detailed picture of surface temperature and snow properties, which are crucial for understanding snowmelt processes and the energy balance in the high-altitude belt. The findings suggest that a multi-method approach, utilizing the combined advantages of SAR satellite data, offers the most comprehensive and accurate framework for satellite-based snow cover monitoring in the high mountain regions of Bulgaria, such as Rila Mountain. This integrative strategy not only improves the precision of snow cover estimates but can also support many water resource-related studies, such as snowmelt runoff studies, snow avalanche modeling, and better-informed decisions in the management and maintenance of winter tourism resorts. Full article
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23 pages, 6015 KiB  
Article
Behavioral Observations of Free-Living Scarlet Macaws (Ara macao) in Costa Rica, to Inform Ex Situ Management
by Ricardo Lemos de Figueiredo and Jackie Chappell
J. Zool. Bot. Gard. 2024, 5(4), 668-690; https://doi.org/10.3390/jzbg5040044 - 1 Nov 2024
Cited by 1 | Viewed by 3300
Abstract
The scarlet macaw (Ara macao) is a charismatic species that is native to Central and South America and commonly housed in captivity. Gaps in knowledge about these birds’ behavioral ecology in the wild hinders both in situ and ex situ management [...] Read more.
The scarlet macaw (Ara macao) is a charismatic species that is native to Central and South America and commonly housed in captivity. Gaps in knowledge about these birds’ behavioral ecology in the wild hinders both in situ and ex situ management and conservation efforts for this species. We conducted seventeen days of observations of free-living scarlet macaws in two locations in Costa Rica, in February 2022, with the aims of (1) advancing our knowledge of this species’ natural behavioral ecology, and (2) generating data for comparison with captive macaws to help to inform their ex situ management (e.g., enclosure design and enrichment). Routes were walked within two locations—Bosque Escondido (BE), release area for captive-bred reintroduced individuals and no extant wild population, and Punta Leona (PL), an area of natural habitat within a resort inhabited by wild scarlet macaws—and focal interval sampling of multiple scarlet macaws in a group was used to record behavior and space use. The macaws at both locations were generally active, spent most of their time high in the tree canopy, relied on climbing to move within it, and used a wide variety of supports. The macaws at PL spent significantly more time feeding and locomoting, and less time perching, than those at BE, possibly due to differences in resource availability, rearing conditions, and age. Furthermore, the wild scarlet macaws at PL exhibited a variety of foraging strategies to acquire and manipulate food items within the tree canopy, including frequent use of their feet during manipulation. Despite limitations caused by a small sample size, a short period of observations, and differences between the two populations observed, this study provides insights into the behavioral ecology of scarlet macaws in the wild, which can be used for behavioral assessments of captive macaws while informing their ex situ management, with applications to animal welfare and captive breeding programs. Full article
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21 pages, 14303 KiB  
Article
Pilot SERS Monitoring Study of Two Natural Hypersaline Lake Waters from a Balneary Resort during Winter-Months Period
by Csilla Molnár, Teodora Diana Drigla, Lucian Barbu-Tudoran, Ilirjana Bajama, Victor Curean and Simona Cîntă Pînzaru
Biosensors 2024, 14(1), 19; https://doi.org/10.3390/bios14010019 - 29 Dec 2023
Cited by 1 | Viewed by 2091
Abstract
Water samples from two naturally hypersaline lakes, renowned for their balneotherapeutic properties, were investigated through a pilot SERS monitoring program. Nanotechnology-based techniques were employed to periodically measure the ultra-sensitive SERS molecular characteristics of the raw water-bearing microbial community and the inorganic content. Employing [...] Read more.
Water samples from two naturally hypersaline lakes, renowned for their balneotherapeutic properties, were investigated through a pilot SERS monitoring program. Nanotechnology-based techniques were employed to periodically measure the ultra-sensitive SERS molecular characteristics of the raw water-bearing microbial community and the inorganic content. Employing the Pearson correlation coefficient revealed a robust linear relationship between electrical conductivity and pH and Raman and SERS spectral data of water samples, highlighting the interplay complexity of Raman/SERS signals and physicochemical parameters within each lake. The SERS data obtained from raw waters with AgNPs exhibited a dominant, reproducible SERS feature resembling adsorbed β-carotene at submicromole concentration, which could be related to the cyanobacteria-AgNPs interface and supported by TEM analyses. Notably, spurious SERS sampling cases showed molecular traces attributed to additional metabolites, suggesting multiplexed SERS signatures. The conducted PCA demonstrated observable differences in the β-carotene SERS band intensities between the two lakes, signifying potential variations in picoplankton abundance and composition or environmental influences. Moreover, the study examined variations in the SERS intensity ratio I245/I1512, related to the balance between inorganic (Cl-induced AgNPs aggregation) and organic (cyanobacteria population) balance, in correlation with the electrical conductivity. These findings signify the potential of SERS data for monitoring variations in microorganism concentration, clearly dependent on ion concentration and nutrient dynamics in raw, hypersaline water bodies. Full article
(This article belongs to the Special Issue Surface-Enhanced Raman Scattering Biosensors—2nd Edition)
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12 pages, 1980 KiB  
Article
Evaluation of Early Age Concrete Pavement Strength by Combined Nondestructive Tests
by Katelyn Kosar, Lev Khazanovich and Lucio Salles
Appl. Sci. 2023, 13(4), 2240; https://doi.org/10.3390/app13042240 - 9 Feb 2023
Cited by 5 | Viewed by 2236
Abstract
During concrete pavement construction, comprehensive information on concrete strength development is necessary for knowledgeable scheduling decisions. To improve in situ strength estimation, nondestructive tests can be combined to maximize available information and increase collection efficiency. Ultrasonic testing has a higher accuracy in strength [...] Read more.
During concrete pavement construction, comprehensive information on concrete strength development is necessary for knowledgeable scheduling decisions. To improve in situ strength estimation, nondestructive tests can be combined to maximize available information and increase collection efficiency. Ultrasonic testing has a higher accuracy in strength estimation for early age concrete and the external device allows for more data to be easily collected, while maturity testing can use temperature models to predict strength development. A procedure was created that combines these methods and their strength models in the laboratory for improved and increased field strength data. Using the procedure allows more data to be collected with greater accuracy and provides an adjustable, predicted strength development. This improves the efficiency of fast-track construction projects without resorting to costly alternatives by providing more information on strength development of in situ concrete than traditional strength testing or nondestructive methods individually. Full article
(This article belongs to the Special Issue Diagnostics and Monitoring of Steel and Concrete Structures)
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19 pages, 2788 KiB  
Article
Impacts of Mechanized Crop Residue Management on Rice-Wheat Cropping System—A Review
by Santosh Korav, Gandhamanagenahalli A. Rajanna, Dharam Bir Yadav, Venkatesh Paramesha, Chandra Mohan Mehta, Prakash Kumar Jha, Surendra Singh and Shikha Singh
Sustainability 2022, 14(23), 15641; https://doi.org/10.3390/su142315641 - 24 Nov 2022
Cited by 16 | Viewed by 6016
Abstract
Residue management has become a new challenge for Indian agriculture and agricultural growth, as well as environmental preservation. The rice-wheat cropping system (RWCS) is predominantly followed cropping system in the Indo-Gangetic plain (IGP), resulting in generating a large volume of agricultural residue. Annually, [...] Read more.
Residue management has become a new challenge for Indian agriculture and agricultural growth, as well as environmental preservation. The rice-wheat cropping system (RWCS) is predominantly followed cropping system in the Indo-Gangetic plain (IGP), resulting in generating a large volume of agricultural residue. Annually, India produces 620 MT of crop residue, with rice and wheat accounting for 234 MT of the surplus and 30% of the total. Farmers are resorting to burning crop residue due to the short window between paddy harvest and seeding of rabi season crops, namely wheat, potato, and vegetables, for speedy field preparation. Burning of residues pollutes the environment, thus having adverse effects on human and animal health, as well as resulted in a loss of plant important elements. This problem is particularly prevalent in rice-wheat-dominant states such as Punjab, Haryana, Uttarakhand, and Uttar Pradesh. If we may use in situ management as residue retention after chopper and spreader, sowing wheat with Happy seeder/zero drill/special drill with full residue load, full residue, or full residue load incorporation with conventional tillage, burning is not the sole approach for residue management. In addition, off-farm residues generated are being utilized for animal feed and raw materials for industries. While there are regional variations in many mechanization drivers and needs, a wide range of mechanization components can be transported to new places to fit local conditions. This article focuses on innovations, methods, and tactics that are relevant to various mechanization systems in particular geographical areas. This article also stresses the need for a thorough analysis of the amount of residue generated, residue utilization using modern mechanical equipment, and their positive and negative effects on crop yield and yield attributes, weed diversity, soil physic-chemical, biological properties, beneficial, and harmful nematode populations in the IGP, which will aid researchers and policymakers in farming research priorities and policy for ensuring sustainability in RWCS. Full article
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12 pages, 4070 KiB  
Article
Heat Transfer Performance of a Downhole Electric Tubular Resistive Heater
by Yu Chen, Hao Zeng, Jianli Wang, Haoran Chen and Jianjun Zhu
Appl. Sci. 2022, 12(19), 9508; https://doi.org/10.3390/app12199508 - 22 Sep 2022
Cited by 4 | Viewed by 2355
Abstract
A downhole electric tubular resistive heater is proposed for the oil-shale in situ resorting. After flowing through a set of heating tubes, the outlet temperature and the flow rate of the injected gas can be conveniently adjusted to match the requirement of the [...] Read more.
A downhole electric tubular resistive heater is proposed for the oil-shale in situ resorting. After flowing through a set of heating tubes, the outlet temperature and the flow rate of the injected gas can be conveniently adjusted to match the requirement of the pyrolysis temperature of the oil shale. The calculation demonstrates the effects of the inner diameter, the length of the heating tube, and the inlet flow rate on the heat transfer performance of the electric heater. It was found that, compared with the armored electric heaters, even with a small inject flow rate of 5 Nm3/min, the convective heat transfer coefficient of the inner flow exceeds 300 W/m2 K, resulting in a much smaller thermal resistance. The outlet temperature of the heating gas can conveniently reach up to 900 °C with the absence of the complex structure of enhanced fins. Though the pressure loss is relatively larger under a high flow rate, the comprehensive index is still 40% higher, indicating that the present tubular electric heater is a promising candidate to deal with complex downhole conditions. Full article
(This article belongs to the Special Issue Modeling and Numerical Simulations in Petroleum Engineering)
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26 pages, 21776 KiB  
Article
Mapping Underwater Bathymetry of a Shallow River from Satellite Multispectral Imagery
by Shayan Salavitabar, S. Samuel Li and Behzad Lak
Geosciences 2022, 12(4), 142; https://doi.org/10.3390/geosciences12040142 - 23 Mar 2022
Cited by 8 | Viewed by 5624
Abstract
Rivers play an important role in water supply, waterway transport, and riverine species habitations. The underwater depth of a river channel is a fundamental geometric element and a key input to studies for the aforementioned and other applications. Traditional in-situ field surveys for [...] Read more.
Rivers play an important role in water supply, waterway transport, and riverine species habitations. The underwater depth of a river channel is a fundamental geometric element and a key input to studies for the aforementioned and other applications. Traditional in-situ field surveys for flow depth measurements would incur high costs and encounter technical and/or logistical difficulties, particularly for river channels of large extents, very shallow channels, and remote, inaccessible channels. Recent advances in satellite remote sensing of inland water bodies like rivers, streams, and creeks have allowed mapping flow depth in an inexpensive, convenient, and efficient manner. The purpose of this paper is to demonstrate the retrieval of river flow depth from high-resolution (1.2 m) WorldView-3 satellite imagery. The depth retrieval methods are based on the ratio of top-of-atmosphere reflectance between two pairing wavelength bands of multispectral imagery. The originality of the methods lies in using analytical relationships without resorting to ground data of river flow depth for calibration, which improves from previous studies of remote sensing of river flow depth. The methods are successfully applied to mapping the underwater bathymetry of a 26 km reach of the Nicolet River in Quebec, Canada. This study shows the importance of geometric and radiometric corrections to the satellite images. The obtained flow depths using the ratio of reflectance of the red band (630–690 nm) to that of the green band (510–580 nm), among the eight bands in the visible spectrum, agree best with in-situ measurements. This study is perhaps the first use of the analytical approach for mapping river bathymetry. It is feasible to implement the approach to other river channels, with a good potential to reduce the costs and increase the efficiency of mapping river bathymetries. Full article
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22 pages, 3265 KiB  
Article
Temporal and Spatial Geophysical Data Analysis in the Issues of Natural Hazards and Risk Assessment (in Example of North Ossetia, Russia)
by Dmitry Melkov, Vladislav Zaalishvili, Olga Burdzieva and Aleksandr Kanukov
Appl. Sci. 2022, 12(6), 2790; https://doi.org/10.3390/app12062790 - 9 Mar 2022
Cited by 7 | Viewed by 3012
Abstract
The paper considers the aspects of hazard assessment within the framework of a generalized approach. The aim of the study is to improve the methodology for more accurate and detailed probabilistic assessments of risks of various nature. A complex hazard map is constructed [...] Read more.
The paper considers the aspects of hazard assessment within the framework of a generalized approach. The aim of the study is to improve the methodology for more accurate and detailed probabilistic assessments of risks of various nature. A complex hazard map is constructed in an example of the territory of the Republic of North Ossetia-Alania and the construction site of the Mamison resort. Based on the analysis of data on Quaternary formations and quantitative estimates, it was concluded that the natural average static environmental evolution proceeds in the mode of the dynamic balance of two factors: mountain building and the equivalent increase in denudation, of which about 90% is transported and deposited by river waters and winds outside the territory. The remaining 10% is deposited in intermountain depressions and river valleys in situ. Geodynamic and climatic factors of influence on the geoenvironment create the danger of excessive environmental impact and disruption of its equilibrium development under anthropogenic impacts, which must be taken into account in designing. Full article
(This article belongs to the Collection Geoinformatics and Data Mining in Earth Sciences)
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12 pages, 337 KiB  
Article
Pedestrians’ Perception of Pedestrian Bridges—A Qualitative Study in Dar es Salaam
by Daudi Katopola, Fredirick Mashili and Marie Hasselberg
Int. J. Environ. Res. Public Health 2022, 19(3), 1238; https://doi.org/10.3390/ijerph19031238 - 22 Jan 2022
Cited by 12 | Viewed by 4371
Abstract
Background: About 30 percent of all road traffic deaths in Tanzania involve pedestrians. As one of the strategies to protect them, pedestrian overhead bridges have been constructed across busy roads, and plans to build more bridges are in place. It has, however, been [...] Read more.
Background: About 30 percent of all road traffic deaths in Tanzania involve pedestrians. As one of the strategies to protect them, pedestrian overhead bridges have been constructed across busy roads, and plans to build more bridges are in place. It has, however, been shown that such pedestrian bridges do not necessarily discourage street-level road crossing, even when pedestrians must cross multiple lanes with heavy traffic. This paper explores the perceptions of pedestrians when crossing urban roads emphasizing pedestrian bridge users. Methods: Nineteen semi-structured interviews were conducted in situ around six pedestrian bridges in Dar es Salaam. All interviews were conducted in Swahili, recorded using digital devices, transcribed verbatim then translated into English. Content analysis was employed using qualitative data analysis software (MAXQDA). Results: We identified three overarching themes, namely, I don’t know if it’s right or wrong, they already decided; the bridge is just a crossing facility, not for other purposes; and follow your gut feeling, even if you don’t know how things will end. The results suggest that many participants prefer to look for alternative means of transport and resorted to more alternative routes just to avoid using pedestrian bridges due to bridges length and crossing time. Conclusion: These findings highlight the concerns caused by alternative uses of pedestrian bridges and underscore the importance of involving local communities and other stakeholders during planning. Full article
(This article belongs to the Section Global Health)
13 pages, 3724 KiB  
Article
Analysis of Building Archetypes for Optimising New Photovoltaic Energy Facilities: A Case Study
by Jesica Fernández-Agüera, Samuel Domínguez-Amarillo, Nerea García-Cortés and Miguel Ángel Campano
Sustainability 2021, 13(21), 12249; https://doi.org/10.3390/su132112249 - 6 Nov 2021
Cited by 6 | Viewed by 2564
Abstract
Fuel poverty rates are high in southern Europe, particularly in social housing, despite the enormous potential for capturing solar power inherent in the roofs of apartment buildings. The in situ generation, distribution and consumption of photovoltaic energy carry obvious advantages including vastly improved [...] Read more.
Fuel poverty rates are high in southern Europe, particularly in social housing, despite the enormous potential for capturing solar power inherent in the roofs of apartment buildings. The in situ generation, distribution and consumption of photovoltaic energy carry obvious advantages including vastly improved efficiency attendant upon the reduction in distribution-related losses and costs, and the energy empowerment afforded lower income communities. The primary drawback is the imbalance between photovoltaic production patterns and users’ actual needs (peak consumption vs. peak generation). That mismatch is difficult to reconcile without resorting to energy storage or net metering, both of which entail grid involvement and greater management complexity. The present study introduces a methodology for analysing residential archetypes to determine the values of the parameters essential to optimising photovoltaic energy production and use. The aim is to determine where excess generation can be shared with other users in the vicinity and optimally pool residential rooftop facilities to meet community-scale energy demand, ultimately enhancing such disadvantaged neighbourhoods’ self-sufficiency. The case study discussed defines archetypes for just such a neighbourhood in Madrid, Spain. The solar energy production potential of the example is promising for its application in large southern European cities, with self-sufficiency rates obtained ranging from 15% to 25% and self-consumption rates from 61% to 80%. Full article
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14 pages, 2775 KiB  
Article
Identification and Characterization of the Most Common Genetic Variant Responsible for Acephalic Spermatozoa Syndrome in Men Originating from North Africa
by Caroline Cazin, Yasmine Boumerdassi, Guillaume Martinez, Selima Fourati Ben Mustapha, Marjorie Whitfield, Charles Coutton, Nicolas Thierry-Mieg, Pierre Di Pizio, Nathalie Rives, Christophe Arnoult, Aminata Touré, Pierre F. Ray, Raoudha Zouari, Christophe Sifer and Zine-Eddine Kherraf
Int. J. Mol. Sci. 2021, 22(4), 2187; https://doi.org/10.3390/ijms22042187 - 22 Feb 2021
Cited by 10 | Viewed by 4002
Abstract
Acephalic spermatozoa syndrome (ASS) is a rare but extremely severe type of teratozoospermia, defined by the presence of a majority of headless flagella and a minority of tail-less sperm heads in the ejaculate. Like the other severe monomorphic teratozoospermias, ASS has a strong [...] Read more.
Acephalic spermatozoa syndrome (ASS) is a rare but extremely severe type of teratozoospermia, defined by the presence of a majority of headless flagella and a minority of tail-less sperm heads in the ejaculate. Like the other severe monomorphic teratozoospermias, ASS has a strong genetic basis and is most often caused by bi-allelic variants in SUN5 (Sad1 and UNC84 domain-containing 5). Using whole exome sequencing (WES), we investigated a cohort of nine infertile subjects displaying ASS. These subjects were recruited in three centers located in France and Tunisia, but all originated from North Africa. Sperm from subjects carrying candidate genetic variants were subjected to immunofluorescence analysis and transmission electron microscopy. Moreover, fluorescent in situ hybridization (FISH) was performed on sperm nuclei to assess their chromosomal content. Variant filtering permitted us to identify the same SUN5 homozygous frameshift variant (c.211+1_211+2dup) in 7/9 individuals (78%). SUN5 encodes a protein localized on the posterior part of the nuclear envelope that is necessary for the attachment of the tail to the sperm head. Immunofluorescence assays performed on sperm cells from three mutated subjects revealed a total absence of SUN5, thus demonstrating the deleterious impact of the identified variant on protein expression. Transmission electron microscopy showed a conserved flagellar structure and a slightly decondensed chromatin. FISH did not highlight a higher rate of chromosome aneuploidy in spermatozoa from SUN5 patients compared to controls, indicating that intra-cytoplasmic sperm injection (ICSI) can be proposed for patients carrying the c.211+1_211+2dup variant. These results suggest that the identified SUN5 variant is the main cause of ASS in the North African population. Consequently, a simple and inexpensive genotyping of the 211+1_211+2dup variant could be beneficial for affected men of North African origin before resorting to more exhaustive genetic analyses. Full article
(This article belongs to the Special Issue The Development, Differentiation, and Toxicity of Gametes)
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21 pages, 2271 KiB  
Article
Community Faecal Management Strategies and Perceptions on Sludge Use in Agriculture
by Matthew Mamera, Johan J. van Tol, Makhosazana P. Aghoghovwia and Gabriel T. Mapetere
Int. J. Environ. Res. Public Health 2020, 17(11), 4128; https://doi.org/10.3390/ijerph17114128 - 10 Jun 2020
Cited by 15 | Viewed by 4161
Abstract
Most people in rural areas in South Africa (SA) rely on untreated drinking groundwater sources and pit latrine sanitations. A minimum basic sanitation facility should enable safe and appropriate removal of human waste, and although pit latrines provide this, they are still contamination [...] Read more.
Most people in rural areas in South Africa (SA) rely on untreated drinking groundwater sources and pit latrine sanitations. A minimum basic sanitation facility should enable safe and appropriate removal of human waste, and although pit latrines provide this, they are still contamination concerns. Pit latrine sludge in SA is mostly emptied and disposed off-site as waste or buried in-situ. Despite having knowledge of potential sludge benefits, most communities in SA are reluctant to use it. This research captured social perceptions regarding latrine sludge management in Monontsha village in the Free State Province of SA through key informant interviews and questionnaires. A key informant interview and questionnaire was done in Monontsha, SA. Eighty participants, representing 5% of all households, were selected. Water samples from four boreholes and four rivers were analyzed for faecal coliforms and E.coli bacteria. On average, five people in a household were sharing a pit latrine. Eighty-three percent disposed filled pit latrines while 17% resorted to closing the filled latrines. Outbreaks of diarrhoea (69%) and cholera (14%) were common. Sixty percent were willing to use treated faecal sludge in agriculture. The binary logistic regression model indicated that predictor variables significantly (p ˂ 0.05) described water quality, faecal sludge management, sludge application in agriculture and biochar adaption. Most drinking water sources in the study had detections ˂ 1 CFU/100 mL. It is therefore imperative to use both qualitative surveys and analytical data. Awareness can go a long way to motivate individuals to adopt to a new change. Full article
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16 pages, 3331 KiB  
Article
Mesoporous Titania Powders: The Role of Precursors, Ligand Addition and Calcination Rate on Their Morphology, Crystalline Structure and Photocatalytic Activity
by Elisabetta Masolo, Manuela Meloni, Sebastiano Garroni, Gabriele Mulas, Stefano Enzo, Maria Dolors Baró, Emma Rossinyol, Agnieszka Rzeszutek, Iris Herrmann-Geppert and Maria Pilo
Nanomaterials 2014, 4(3), 583-598; https://doi.org/10.3390/nano4030583 - 30 Jul 2014
Cited by 21 | Viewed by 8339
Abstract
We evaluate the influence of the use of different titania precursors, calcination rate, and ligand addition on the morphology, texture and phase content of synthesized mesoporous titania samples, parameters which, in turn, can play a key role in titania photocatalytic performances. The powders, [...] Read more.
We evaluate the influence of the use of different titania precursors, calcination rate, and ligand addition on the morphology, texture and phase content of synthesized mesoporous titania samples, parameters which, in turn, can play a key role in titania photocatalytic performances. The powders, obtained through the evaporation-induced self-assembly method, are characterized by means of ex situ X-Ray Powder Diffraction (XRPD) measurements, N2 physisorption isotherms and transmission electron microscopy. The precursors are selected basing on two different approaches: the acid-base pair, using TiCl4 and Ti(OBu)4, and a more classic route with Ti(OiPr)4 and HCl. For both precursors, different specimens were prepared by resorting to different calcination rates and with and without the addition of acetylacetone, that creates coordinated species with lower hydrolysis rates, and with different calcination rates. Each sample was employed as photoanode and tested in the water splitting reaction by recording I-V curves and comparing the results with commercial P25 powders. The complex data framework suggests that a narrow pore size distribution, due to the use of acetylacetone, plays a major role in the photoactivity, leading to a current density value higher than that of P25. Full article
(This article belongs to the Special Issue Ordered Mesoporous Nanomaterials)
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