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25 pages, 2760 KB  
Article
Impact of Pre- and Post-Emergence Herbicides on Controlling Predominant Weeds at Late-Rainy Season Sugarcane Plantations in Northeastern Thailand
by Sujittra Gongka, Nakorn Jongrungklang, Patcharin Songsri, Sompong Chankaew, Tidarat Monkham and Santimaitree Gonkhamdee
Agronomy 2025, 15(10), 2341; https://doi.org/10.3390/agronomy15102341 - 5 Oct 2025
Cited by 1 | Viewed by 2447
Abstract
Weeds are a primary factor affecting sugarcane production and productivity in Thailand. During the late-rainy season, when cultivation is carried out under rainfed conditions, weed competition becomes increasingly severe, prompting farmers to perform secondary weed control using post-emergence herbicides. Therefore, to guide farmers [...] Read more.
Weeds are a primary factor affecting sugarcane production and productivity in Thailand. During the late-rainy season, when cultivation is carried out under rainfed conditions, weed competition becomes increasingly severe, prompting farmers to perform secondary weed control using post-emergence herbicides. Therefore, to guide farmers on the appropriate use of herbicides for effective weed management and long-term control during the critical period of sugarcane growth, this study evaluates the effectiveness of pre- and post-emergence herbicides. Conducted in Northeast Thailand using a randomized complete block design (RCBD) with four replications, the experiment revealed that several pre-emergence herbicides, namely pendimethalin + imazapic (825 + 75 g a.i. ha−1), indaziflam (62.5 g a.i. ha−1), and sulfentrazone (875 g a.i. ha−1), and a combination of indaziflam + sulfentrazone (46.88 + 750 g a.i. ha−1) were applied one day after sugarcane planting, demonstrating high weed control efficacy. These treatments significantly reduced the summed dominance ratio (SDR) of both total weed (41.65–78.54%) and dominant weeds (70.13–86.04%), including Digitaria ciliaris (Retz.) Koel., Dactyloctenium aegyptium (L.), Brachiaria distachya (L.) Stapf, and Cyperus rotundus, compared with the no-weeding treatment. In summary, effective weed management in sugarcane fields under late-rainy season can be achieved through the application of pendimethalin + imazapic at 825 + 75 g a.i. ha−1, which produced the highest sugarcane yield (a 139.00% increasing compared with no weeding) and net profit (a 79.75% increasing compared with hand weeding) in loamy sand soil conditions, where D. ciliaris, D. aegyptium, and C. rotundus were dominant weeds. Similarly, indaziflam at 62.5 g a.i. ha−1 yielded the best results (a 71.68% increasing compared with no weeding) and net profit (a 121.04% increasing compared with no weeding) in sandy loam soil, where B. distachya was the only dominant weed. This weed management strategy is potentially transferable to sugarcane production systems in other regions that share comparable soil properties, climatic conditions, and dominant weed species. Full article
(This article belongs to the Special Issue Ecology and Management of Weeds in Different Situations)
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16 pages, 5752 KB  
Article
Residual Effect of Imidazolinone Herbicides on Emergence and Early Development of Forage Species in Rice-Livestock Systems
by Valentina Rodriguez-De-Barbieri, Pablo González-Barrios, Pablo Rovira, Claudia Marchesi, Robin Cuadro, Rodrigo Zarza and Tiago Edu Kaspary
Int. J. Plant Biol. 2025, 16(3), 110; https://doi.org/10.3390/ijpb16030110 - 18 Sep 2025
Viewed by 1304
Abstract
The intensification of rice–livestock systems has encouraged the integration of forage species into rice cultivation. However, the use of imidazolinone-tolerant rice cultivars (imazapyr + imazapic, IMIs), essential for weedy rice control, may hinder the establishment of sensitive forages due to herbicide residues. This [...] Read more.
The intensification of rice–livestock systems has encouraged the integration of forage species into rice cultivation. However, the use of imidazolinone-tolerant rice cultivars (imazapyr + imazapic, IMIs), essential for weedy rice control, may hinder the establishment of sensitive forages due to herbicide residues. This study evaluated the emergence and early growth of six forage species through bioassays in soils with different IMI use histories. Over three years (2021–2023), soils were collected from three rice-growing regions in Uruguay with contrasting soil properties, at depths of 0–15 and 16–30 cm, under three IMI conditions: Control (no prior use), IMI-1 (applied one season before sampling), and IMI-2 (applied in the season before sampling). Emergence, plant height, and shoot and root biomass were analyzed using linear mixed models and principal component analysis. Shoot biomass was reduced by up to 60% in IMI-2 soils. Poaceae species and T. pratense were the most affected, while T. repens and L. corniculatus exhibited higher tolerance. Multivariate analysis indicated stronger residual effects on sandy loam soils. These findings highlight that imidazolinone persistence varies with forage species and soil properties, underscoring the need for careful planning in rice–pasture rotations to prevent adverse effects on forage establishment and system sustainability. Full article
(This article belongs to the Section Plant Response to Stresses)
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14 pages, 3823 KB  
Article
Investigation and Analysis of the Residual Status and Distribution of Long-Lasting-Effect Herbicides in Field Soil: A Case Study of Henan Province, a Major Agricultural Producing Area in China
by Guangling Li, Yang Yang, Shoumeng Wang, Dongzhi Li, Runqiang Liu, Youduo Zhang and Yanbing Wu
Agriculture 2025, 15(9), 996; https://doi.org/10.3390/agriculture15090996 - 3 May 2025
Cited by 1 | Viewed by 1428
Abstract
The results demonstrated that among the total 365 investigated samples, the proportion of samples detecting three target herbicides simultaneously, two herbicides, one herbicide, and none were 0.3%, 6.4%, 65.2%, and 23.2%, respectively. For samples with only one detected herbicide, the detection rates in [...] Read more.
The results demonstrated that among the total 365 investigated samples, the proportion of samples detecting three target herbicides simultaneously, two herbicides, one herbicide, and none were 0.3%, 6.4%, 65.2%, and 23.2%, respectively. For samples with only one detected herbicide, the detection rates in Jiyuan, Luohe, Puyang, Luoyang, Xuchang, and Hebi were relatively high (ranging from 44% to 100%), whereas those in Sanmenxia, Nanyang, Xinxiang, and Kaifeng were relatively low (ranging from 6% to 20%). Regarding individual herbicides, the detection rates of mesosulfuron-methyl, quinclorac, halosulfuron-methyl, diflufenican, imazethapyr, pyroxasulfone, imazapic, fomesafen, and atrazine were 1.2%, 3.8%, 5.5%, 6.1%, 8.7%, 8.7%, 10.4%, 11.0%, and 33.9%, respectively. Based on these findings, the current reliance on long-acting effect herbicides for weed management in China’s agricultural management practices was systematically analyzed. Within the framework of agricultural sustainability, it is proposed that there is an urgent need to promote the concept of scientific herbicide use among farmers and that pesticide scientists must recognize the extreme importance of continuous innovation and the development of alternative herbicides with new mechanisms of action as a long-term strategic goal. Full article
(This article belongs to the Section Agricultural Soils)
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10 pages, 1806 KB  
Article
Glyphosate- and Imazapic-Resistant Chloris virgata Populations in the Southeastern Cropping Region of Australia
by Bhagirath Singh Chauhan and Gulshan Mahajan
Agronomy 2023, 13(1), 173; https://doi.org/10.3390/agronomy13010173 - 5 Jan 2023
Cited by 5 | Viewed by 2236
Abstract
Chloris virgata is one of the most problematic summer grass species in southeastern Australia. A total of 40 populations of C. virgata were evaluated in the spring–summer season of 2021–2022 in an open environment at the Gatton Farms of the University of Queensland, [...] Read more.
Chloris virgata is one of the most problematic summer grass species in southeastern Australia. A total of 40 populations of C. virgata were evaluated in the spring–summer season of 2021–2022 in an open environment at the Gatton Farms of the University of Queensland, Queensland, Australia, for their response to two acetyl-coenzyme-A carboxylase (ACCase) inhibitors (clethodim and haloxyfop), a 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS) inhibitor (glyphosate), and an acetolactate synthase (ALS) inhibitor (imazapic). In the first experiment, all populations were screened at the field rate of each herbicide, and the second experiment evaluated the response of seven populations of C. virgata to different rates of glyphosate and imazapic. There were three replications of each treatment and both experiments were repeated over time. None of the populations survived the field rate of clethodim and haloxyfop, possibly suggesting a low exposure of the populations to these herbicides. Individuals in about 90% of populations survived (1% to 100% of individuals surviving) the field rates of glyphosate and individuals in all populations survived (1% to 100%) the imazapic field rate. The dose-response study revealed up to 14- and 5-fold glyphosate resistance in C. virgata populations based on survival and biomass values, respectively, compared to the most susceptible population. Imazapic resistance was up to 2.3- and 16-fold greater than the most susceptible population in terms of survival and biomass values, respectively. The increased cases of glyphosate- and imazapic-resistant C. virgata warrant a nationwide survey and diversified management strategies. Full article
(This article belongs to the Special Issue Herbicides Toxicology and Weeds Herbicide-Resistant Mechanism)
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11 pages, 255 KB  
Article
Evaluating Branched Broomrape (Phelipanche ramosa) Management Strategies in California Processing Tomato (Solanum lycopersicum)
by Matthew J. Fatino and Bradley D. Hanson
Plants 2022, 11(3), 438; https://doi.org/10.3390/plants11030438 - 5 Feb 2022
Cited by 10 | Viewed by 3019
Abstract
Detections of the regulated noxious parasitic weed branched broomrape (Phelipanche ramosa) in California tomato fields have led to interest in eradication, sanitation, and management practices. Researchers in Israel developed a decision-support system and herbicide treatment regime for management of Egyptian broomrape [...] Read more.
Detections of the regulated noxious parasitic weed branched broomrape (Phelipanche ramosa) in California tomato fields have led to interest in eradication, sanitation, and management practices. Researchers in Israel developed a decision-support system and herbicide treatment regime for management of Egyptian broomrape (P. aegyptiaca) in tomato. Research was conducted in 2019 and 2020 to evaluate whether similar treatments could be used to manage branched broomrape in California processing tomatoes and to provide registration support data for the herbicide use pattern. Treatment programs based on preplant incorporated (PPI) sulfosulfuron and chemigated imazapic were evaluated in 2019 and 2020 to determine safety on the processing tomato crop and on common rotational crops. Three single-season tomato safety experiments were conducted and a single rotational crop study was conducted in which a tomato crop received herbicide treatments in 2019 and several common rotational crops were planted and evaluated in 2020 in a site without branched broomrape. In 2020, an efficacy study was conducted in a commercial tomato field known to be infested with branched broomrape to evaluate the efficacy of PPI sulfosulfuron and chemigated imazapic, imazapyr, imazethapyr, and imazamox. After two field seasons, sulfosulfuron and imazapic appeared to have reasonable crop safety on tomato in California; however, rotational crop restrictions will need to be considered if sulfosulfuron is used to manage branched broomrape. In the efficacy study, there was a trend in which the sulfosulfuron and imidazolinone treatments had fewer broomrape shoots per plot than the grower standard treatments, however, none were fully effective and there were no significant differences among the various sulfosulfuron and imidazolinone treatment combinations. Additional research is needed to optimize the treatment timing for management of branched broomrape in this cropping system. Because of registration barriers with imazapic in the California market, future research will focus on treatment combinations of PPI sulfosulfuron and chemigated imazamox rather than imazapic. Full article
(This article belongs to the Special Issue Parasitic Weeds: Biology and Control)
11 pages, 568 KB  
Article
Evaluation of Preemergent Herbicides for Chloris virgata Control in Mungbean
by Gulshan Mahajan and Bhagirath S. Chauhan
Plants 2021, 10(8), 1632; https://doi.org/10.3390/plants10081632 - 9 Aug 2021
Cited by 6 | Viewed by 3656
Abstract
Chloris virgata is a problematic weed in mungbean crops due to its high seed production, resistance to glyphosate and high dispersal ability. Pot and field experiments were conducted in 2020 and 2021 to evaluate a range of preemergent (PRE) herbicides for C. virgata [...] Read more.
Chloris virgata is a problematic weed in mungbean crops due to its high seed production, resistance to glyphosate and high dispersal ability. Pot and field experiments were conducted in 2020 and 2021 to evaluate a range of preemergent (PRE) herbicides for C. virgata control in mungbean. In the field and pot studies, isoxaflutole 75 g ai ha−1 caused crop injury, and in the field experiment, it reduced mungbean yield by 61% compared with the best treatment (pyroxasulfone 100 g ai ha−1). In the field and pot experiments, dimethenamid-P 720 g ai ha−1, pyroxasulfone 100 g ai ha−1 and S-metolachlor 1400 g ai ha−1 provided >88% control of C. virgata (for reduced biomass) and in the field experiment, these herbicides resulted in improved yield by 230%, 270% and 170%, respectively, compared with nontreated control (250 kg ha−1). Similarly, pendimethalin 1000 g ai ha−1 and trifluralin 600 g ai ha−1 provided >89% control (biomass) of C. virgata, and in the field experiment, these resulted in improved yields of 230% and 160%, respectively, compared with the nontreated control. PRE herbicides such as diuron 750 g ai ha−1, linuron 1100 g ai ha−1, metribuzin 360 g ha−1, terbuthylazine 750 g ai ha−1, imazapic 48 g ai ha−1 and imazethapyr 70 g ha−1 although did not cause crop injury; however, these herbicides did not control C. virgata. Flumioxazin 90 g ai ha−1 caused reduced biomass of C. virgata by 80% compared with the nontreated control, and in the field experiment, it resulted in improved yield by 140% compared with the nontreated control. This study suggests the potential use of herbicides, such as dimethenamid-P, pyroxasulfone and S-metolachlor in addition to pendimethalin and trifluralin, for C. virgata control in mungbean. Further studies are needed to determine the efficacy of dimethenamid-P, S-metolachlor and pyroxasulfone for controlling other troublesome weeds in mungbean. Full article
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11 pages, 1400 KB  
Article
Imazapic Herbigation for Egyptian Broomrape (Phelipanche aegyptiaca) Control in Processing Tomatoes—Laboratory and Greenhouse Studies
by Yaakov Goldwasser, Onn Rabinovitz, Zev Gerstl, Ahmed Nasser, Amit Paporisch, Hadar Kuzikaro, Moshe Sibony and Baruch Rubin
Plants 2021, 10(6), 1182; https://doi.org/10.3390/plants10061182 - 10 Jun 2021
Cited by 6 | Viewed by 4278
Abstract
Parasitic plants belonging to the Orobanchaceae family include species that cause heavy damage to crops in Mediterranean climate regions. Phelipanche aegyptiaca is the most common of the Orobanchaceae species in Israel inflicting heavy damage to a wide range of broadleaf crops, including processing [...] Read more.
Parasitic plants belonging to the Orobanchaceae family include species that cause heavy damage to crops in Mediterranean climate regions. Phelipanche aegyptiaca is the most common of the Orobanchaceae species in Israel inflicting heavy damage to a wide range of broadleaf crops, including processing tomatoes. P. aegyptiaca is extremely difficult to control due to its minute and vast number of seeds and its underground association with host plant roots. The highly efficient attachment of the parasite haustoria into the host phloem and xylem enables the diversion of water, assimilates and minerals from the host into the parasite. Drip irrigation is the most common method of irrigation in processing tomatoes in Israel, but the delivery of herbicides via drip irrigation systems (herbigation) has not been thoroughly studied. The aim of these studies was to test, under laboratory and greenhouse conditions, the factors involved in the behavior of soil-herbigated imazapic, and the consequential influence of imazapic on P. aegyptiaca and tomato plants. Dose-response Petri dish studies showed that imazapic does not impede P. aegyptiaca seed germination and non-attached seedlings, even at the high rate of 5000 ppb. Imazapic applied to tomato roots inoculated with P. aegyptiaca seeds in a PE bag system revealed that the parasite is killed only after its attachment to the tomato roots, at concentrations as low as 2.5 ppb. Imazapic sorption curves and calculated Kd and Koc values indicated that the herbicide Kd is similar in all soils excluding a two-fold higher coefficient in the Gadash farm soil, while the Koc was similar in all soils except the Eden farm soil, in which it was more than twofold lower. In greenhouse studies, control of P. aegyptiaca was achieved at >2.5 ppb imazapic, but adequate control requires repeated applications due to the 7-day half-life (t1/2) of the herbicide in the soil. Tracking of imazapic in soil and tomato roots revealed that the herbicide accumulates in the tomato host plant roots, but its movement to newly formed roots is limited. The data obtained in the laboratory and greenhouse studies provide invaluable knowledge for devising field imazapic application strategies via drip irrigation systems for efficient and selective broomrape control. Full article
(This article belongs to the Special Issue Parasitic Weeds: Biology and Control)
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12 pages, 1732 KB  
Article
Recurrent Selection with Low Herbicide Rates and Salt Stress Decrease Sensitivity of Echinochloa colona to Imidazolinone
by Lariza Benedetti, Vívian Ebeling Viana, Pâmela Carvalho-Moore, Vinicios Rafael Gehrke, Gustavo Maia Souza, Edinalvo Rabaioli Camargo, Luis Antonio de Avila and Nilda Roma-Burgos
Agriculture 2021, 11(3), 187; https://doi.org/10.3390/agriculture11030187 - 25 Feb 2021
Cited by 3 | Viewed by 3295
Abstract
Weeds represent an increasing challenge for crop systems since they have evolved adaptability to adverse environmental conditions, such as salinity stress. Herbicide effectiveness can be altered by the quality of water in which the weed is growing. This research aimed to study the [...] Read more.
Weeds represent an increasing challenge for crop systems since they have evolved adaptability to adverse environmental conditions, such as salinity stress. Herbicide effectiveness can be altered by the quality of water in which the weed is growing. This research aimed to study the combined effect of salt stress and recurrent selection with a sublethal dose of imidazolinone herbicides in the shifting of the sensitivity of Echinochloa colona (L.) Link (junglerice) to imidazolinone herbicides. This study was divided into two experiments; in experiment I, three recurrent selection cycles were conducted in Pelotas/RS/Brazil with imazapic + imazapyr at 0.125× the field rate; and in experiment II, three recurrent selection cycles were conducted in Fayetteville/AR/USA with imazethapyr, at 0.125× the recommended dose. Salt stress was implemented by irrigation with 120 mM sodium chloride (NaCl) solution. The effective dose for 50% control of the population (ED50) values increased from the field population to the second generation (G2) after recurrent selection with a sublethal dose of imidazolinone combined with salt stress, supporting the hypothesis of reduced susceptibility by the combination of these abiotic factors. Recurrent exposure to a sublethal dose of imazapic + imazapyr or imazethapyr, combined with salt stress, reduced susceptibility of Echinochloa colona (L.) plants to imidazolinone herbicides. Full article
(This article belongs to the Special Issue Herbicide Physiology and Environmental Fate)
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19 pages, 1771 KB  
Article
First Report of Herbicide-Resistant Echinochloa crus-galli in Uruguayan Rice Fields
by Claudia Marchesi and Nestor E. Saldain
Agronomy 2019, 9(12), 790; https://doi.org/10.3390/agronomy9120790 - 22 Nov 2019
Cited by 11 | Viewed by 6185
Abstract
Echinochloa crus-galli is the main weed in direct dry-seeded rice systems worldwide and is the target of most herbicide applications. Numerous cases of E. crus-galli biotypes with resistance to herbicides have been reported in different regions of the world; however, to date, no [...] Read more.
Echinochloa crus-galli is the main weed in direct dry-seeded rice systems worldwide and is the target of most herbicide applications. Numerous cases of E. crus-galli biotypes with resistance to herbicides have been reported in different regions of the world; however, to date, no cases have been reported in Uruguay. The purpose of this research is to assess the presence of herbicide-resistant E. crus-galli in the rice fields of Uruguay. More than 40 E. crus-galli biotypes were sampled from eastern to northern regions in different years and assessed following the Herbicide Resistance Action Committee (HRAC) protocols of confirmation, using the herbicides propanil, quinclorac, clomazone, bispyribac–sodium, penoxsulam, imazapyr + imazapic, profoxidim and cyhalofop. Herbicides rates included 0, 0.125, 0.25, 0.50, 1, 2, 4 and 8 times the label rate. Most E. crus-galli biotypes (35) resulted as resistant to quinclorac. Furthermore, resistance was confirmed to propanil in at least seven biotypes, 12 to imazapyr + imazapic, and three to penoxsulam. Five biotypes showed multiple resistance to propanil and quinclorac, and one biotype was resistant to quinclorac, penoxsulam and imazapyr + imazapic. No biotype showed confirmed resistance to clomazone, bispyribac-sodium, cyhalofop or profoxidim—herbicides that ensure satisfactory control. The presence of E. crus-galli herbicide resistant-biotypes reduces herbicide options, threatening rice production in Uruguay. In this context, a redesign of the productive systems would represent an opportunity to complement the chemical control, integrating larger-scale cultural and management practices. Full article
(This article belongs to the Special Issue Weed Management & New Approaches)
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21 pages, 1076 KB  
Article
Integrated Management of Cheatgrass (Bromus tectorum) with Sheep Grazing and Herbicide
by Erik A. Lehnhoff, Lisa J. Rew, Jane M. Mangold, Tim Seipel and Devon Ragen
Agronomy 2019, 9(6), 315; https://doi.org/10.3390/agronomy9060315 - 14 Jun 2019
Cited by 14 | Viewed by 5500
Abstract
Cheatgrass (Bromus tectorum L.) is one of the most problematic weeds in western United States rangelands and sagebrush steppe. It responds positively to different forms of disturbance, and its management has proven difficult. Herbicide or targeted grazing alone often fail to provide [...] Read more.
Cheatgrass (Bromus tectorum L.) is one of the most problematic weeds in western United States rangelands and sagebrush steppe. It responds positively to different forms of disturbance, and its management has proven difficult. Herbicide or targeted grazing alone often fail to provide adequate long-term control. Integrating both may afford better control by providing multiple stressors to the weed. We assessed herbicide application, targeted sheep grazing and integrated herbicide and grazing on B. tectorum and the plant community in rangeland in southwestern Montana from 2015 until 2017. Herbicide treatments included spring-applied (May 2015 and 2016) glyphosate, fall-applied (October 2015) glyphosate, imazapic and rimsulfuron, and spring-applied glyphosate plus fall-applied imazapic. Targeted grazing, consisting of four sheep/0.01 ha for a day in 5 m × 20 m plots (all vegetation removed to the ground surface), occurred twice (May 2015 and 2016). While no treatments reduced B. tectorum biomass or seed production, grazing integrated with fall-applied imazapic or rimsulfuron reduced B. tectorum cover from approximately 26% to 14% in 2016 and from 33% to 16% in 2017, compared to ungrazed control plots, and by an even greater amount compared to these herbicides applied without grazing. By 2017, all treatments except spring-applied glyphosate increased total plant cover (excluding B. tectorum) by 8%–12% compared to the control plots, and forbs were generally responsible for this increase. Bromus tectorum management is difficult and our results point to a potential management paradox: Integrating grazing and fall-applied herbicide decreased B. tectorum cover but did not increase native grass cover, while some herbicides without grazing increased native grass cover, but failed to control B. tectorum. Additional research is necessary to determine grazing strategies that will complement herbicide control of B. tectorum while also stimulating native grass recovery, but this initial study demonstrates the potential of integrated management of B. tectorum compared to grazing or herbicide alone. Full article
(This article belongs to the Special Issue Management and Control Methods for Invasive Plants in Agroecosystems)
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5 pages, 643 KB  
Proceeding Paper
A Highly Sensitive Impedimetric Metamitron Microsensor Based on All-Solid-State Membrane Using a New Ion-Pair Complex, [3,3′-Co(1,2-closo-C2B9H11)2][C10H11ON4]+
by Zakaria Ayroud, Juan Gallardo-Gonzalez, Abdoullatif Baraket, Marie Hangouet, Albert Alcácer, Angelos Streklas, Joan Bausells, Abdelhamid Errachid and Nadia Zine
Proceedings 2018, 2(13), 1093; https://doi.org/10.3390/proceedings2131093 - 11 Dec 2018
Cited by 1 | Viewed by 2763
Abstract
An all-solid-state impedimetric microsensor based on impedimetric measurements for detecting the herbicide metamitron (MM) is reported in the present work. For this purpose, a novel metamitron ionophore has been prepared. It was based on the isolation of the metamitron monoprotonated form coupled to [...] Read more.
An all-solid-state impedimetric microsensor based on impedimetric measurements for detecting the herbicide metamitron (MM) is reported in the present work. For this purpose, a novel metamitron ionophore has been prepared. It was based on the isolation of the metamitron monoprotonated form coupled to the metallocarborane anion, cobalt bis (dicarbollide), ([3,3′-Co(1,2-closo-C2B9H11)2]) as an ion-pair complex of the type [3,3′-Co(1,2-closo-C2B9H11)2][C10H11ON4]+. Once the ion-pair complex was synthetized, it was incorporated to a PVC-type membrane including o-Nitrophenyloctylether (o-NPOE) as plasticizer. The membrane was then drop-cast on top of polypyrrole-modified gold working microelectrodes. A quick response of 30 s has been provided by the microsensor in the range of metamitron concentrations between 10−8 M and 10−4 M with a limit of detection of 10−8 M. Furthermore, it was highly selective toward metamitron, when compared to some possible interfering compounds as imazapic and carbetamide. Full article
(This article belongs to the Proceedings of EUROSENSORS 2018)
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