Search Results (171)

Hydrogels comprise three-dimensional networks of hydrophilic polymers and have attracted considerable interest in various sectors, including the biomedical, pharmaceutical, agricultural, and food industries. These materials offer significant benefits for food packaging applications, such as high mechanical strength and excellent water absorption capacity, thereby contributing to the extension of product shelf life. Therefore, the aim of this study is to compare the performance of citric acid and glutaraldehyde as crosslinking agents in gelatine-based hydrogels reinforced with cellulose nanocrystals (CNC), contributing to the development of safe and environmentally responsible materials. The hydrogels were prepared using the casting method and characterised in terms of their physical, mechanical, and structural properties. The results indicated that hydrogels crosslinked with glutaraldehyde exhibited higher opacity, lower transparency, and greater mechanical strength, whereas those crosslinked with citric acid demonstrated improved clarity, reduced water permeability, and enhanced swelling capacity. The incorporation of CNC further improved mechanical strength, reduced weight loss, and altered both surface homogeneity and optical properties. Microstructural results obtained by SEM were consistent with the mechanical properties evaluated (TS, %E, and EM). The Gel-ca hydrogel displayed the highest elongation value (98%), reflecting better cohesion within the polymeric matrix. In contrast, films incorporating CNC exhibited greater roughness and cracking, which correlated with increased rigidity and mechanical strength, as evidenced by the high Young’s modulus (420 MPa in Gel-ga-CNC2). These findings suggest that the heterogeneity and porosity induced by CNC limit the mobility of polymer chains, resulting in less flexible and more rigid structures. Additionally, the DSC analysis revealed that gelatine hydrogels did not exhibit a well-defined Tg, due to the predominance of crystalline domains. Systems crosslinked with citric acid showed greater thermal stability (higher Tm and ΔH_m values), while those crosslinked with glutaraldehyde, although mechanically stronger, exhibited lower thermal stability. These results confirm the decisive effect of the crosslinking agent and CNC incorporation on the structural and thermal behaviour of hydrogels. In this context, the application of hydrogels in packaged products represents an eco-friendly alternative that enhances product presentation. This research supports the reduction in plastic consumption whilst promoting the principles of a circular economy and facilitating the development of materials with lower environmental impact. Full article

Polymers have long been central to modern materials science, but their durability has also made them major contributors to environmental pollution. A new generation of bio-based and nanostructured polymers is now reshaping this field, offering materials that are functional, reversible, and sustainable. This review examines their role across three interconnected domains: cultural heritage conservation, the protection of medicinal and aromatic plants (MAPs), and environmental sustainability. In heritage science, polymers are moving away from synthetic resins toward renewable systems such as chitosan, nanocellulose, and PLA, which provide stability while remaining reversible and compatible with delicate substrates. In agriculture, biodegradable coatings, controlled-release carriers, and edible films are improving MAP protection, extending shelf life, and reducing reliance on synthetic pesticides. In environmental applications, polymers are being reinvented as solutions rather than problems—through degradable mulches, functional hydrogels, and nanocomposites that clean soils and waters within a circular economy framework. Looking across these domains reveals strong synergies. The same principles—biodegradability, multifunctionality, and responsiveness—apply in each context, turning polymers from passive barriers into intelligent, adaptive systems. Their future success will depend not only on chemistry but also on life-cycle design, policy alignment, and public trust, making polymers key enablers of sustainability. Full article

Feeding a growing population under the pressures of climate change requires solutions that safeguard yields while strengthening agricultural resilience. Integrated Crop Management (ICM)—which combines precise fertilization, efficient water use, and targeted pest control—offers a promising framework. Hydrogels, with their water retention and controlled release properties, can enhance ICM by improving fertilizer efficiency, reducing water loss, and supporting soil health. Despite extensive research, their optimal use in agriculture remains unclear, and limitations continue to restrict large-scale adoption. To address this gap, this study applies the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) methodology alongside bibliometric analysis to examine hydrogel applications in ICM from 2000 to 2024. Ninety Scopus-indexed publications were analyzed across four domains: pesticides, nutritional growth inputs, soil conditioners, and bioactive substances. The results reveal a marked increase in hydrogel structural complexity, greater diversity in characterization methods, ongoing reliance on high-impact pesticides despite advances in bio-based hydrogels, and persistent gaps in assessing environmental impacts and regulatory compliance. These findings underscore the need for stronger collaboration between academia and industry to translate hydrogel research into effective, sustainable agricultural practices under changing climatic conditions. Full article

This study developed hydrogels from durian rind-derived carboxymethyl cellulose (CMC_d) blended with poly(vinyl) alcohol (PVA) for biomedical applications. The influence of NaOH concentration (10–60% w/v) on the degree of substitution (DS) of CMC_d and the crosslinking properties of the resulting hydrogels was examined. Durian rind, a biodegradable and renewable resource, was transformed into CMC_d with DS values ranging from 0.17 to 0.94. The highest yield (230.96%) was achieved using 30% NaOH (CMC_d-30). This CMC_d-30 was combined with PVA and crosslinked using citric acid to form a hydrogel with maximum crosslinking efficiency (86.16%). The resulting CMC_d-30/PVA hydrogel exhibited a high swelling ratio (125.54%), reflecting its superior water absorption and functional group availability—key traits for biomedical use. Methylene blue (MB) release from the hydrogel extended up to 1440 min, confirming its drug delivery potential. Overall, the CMC_d-30/PVA hydrogel demonstrated promising biocompatibility potential and performance, making it a promising candidate for wound dressings and controlled drug delivery systems. This work highlights the potential of agricultural waste valorization in developing sustainable and efficient biomaterials for pharmaceutical and medical applications. Full article

The global issues of resource depletion and environmental pollution have led to increased interest in a circular bioeconomy focusing on converting renewable biomass into functional biomaterials. This article explores the transformative potential of hemicellulosic biogels as a sustainable platform to address critical societal challenges, such as water scarcity, food solutions and environmental pollution. Derived from hemicelluloses, an abundant and underutilized polysaccharide in lignocellulose biomass, these biogels offer a fundamentally new approach to developing high-performance, ecofriendly based materials. The review examines their development, characterization, and diverse applications in water treatment, food, agriculture, adhesive and coating systems. In water treatment, these gels exhibit exceptional performance, demonstrating a maximum NaCl uptake of 0.26 g/g and rapid pseudo-second-order adsorption kinetics for desalination. They also show high selectivity for heavy metal removal, with a remarkable binding capacity for lead if 2.9 mg/g at pH 5. For adhesive and coating applications, hemicellulose crosslinked with ammonium zirconium carbonate (AZC) forms water-resistant gels that significantly enhance paper properties, including gloss, smoothness, liquid resistance, and adhesive strength. Furthermore, hemicellulosics exhibit controlled biodegradation in physiological solutions while maintaining their mechanical integrity, underscoring their broad application promise. Overall, this review highlights how hemicellulose-based hydrogels can transform a low-value byproduct from biorefinery into high-performance solutions, contributing significantly to a sustainable economy. Full article

Biofumigation was originally proposed as an alternative to toxic fumigants for the treatment of agricultural soils, owing to the biocidal effect of isothiocyanates (ITCs) released by some plant species like Brassicaceae. However, biofumigation also presents limitations; thus, an advanced and viable alternative could be the use of controlled-release systems such as gelled polymer networks. In the present work, we explore the use of biocompatible hydrogels based on sodium alginate (ALG) and sodium carboxymethylcellulose (CMC), conveniently loaded with a Brassicaceae extract for this purpose. The extract was characterized by means of HPLC-MS, showing its high glucosinolate content, especially glucoraphanin, a secondary metabolite produced by several species of this family. The physicochemical properties of the synthesized gels were investigated by means of differential scanning calorimetry (DSC), rheometry, and scanning electron microscopy (SEM), both in the presence and absence of the loaded extract. Loading and release kinetics (in water) were studied by means of HPLC-DAD, and the Weibull model was employed to interpret the results. It was found that both hydrogels can effectively confine the Brassicaceae extract’s active principle, slowly releasing it in an aqueous environment. Both systems possess excellent properties for real applications, with the CMC-based hydrogels being slightly preferable over the ALG ones due to their higher encapsulation efficiency, mechanical properties, and overall features. These systems are promising tools for combating harmful microorganisms due to the biocidal properties of glucosinolates, but their potential goes beyond their use in agriculture, as they could be applied as antifouling or antimicrobial agents in cultural heritage cleaning or other fields. Full article

Hydrogel films are a promising class of materials due to their peculiar property of retaining water as well as responding to external stimuli. In contrast with conventional hydrogels, films provide enhanced responsiveness along with greater compliance to be integrated into devices as well as on surfaces. This review is designed to comprehensively explore the many aspects of hydrogel films. It covers the principles of gelation; preparation methods, such as solvent casting, spin coating, and photolithography; and characterization. This review also presents the most common polymers (both natural and synthetic) utilized for the preparation of the hydrogel, the systems, such as nanoparticles, liposomes and hybrid metal–organic structure, that can be used as additives and the aspects related to the biocompatibility of hydrogels. In the second part, this review discusses the potential applications of hydrogel films and the challenges that still need to be overcome. Particular attention is given to biomedical applications, such as drug delivery, wound healing, and tissue engineering, but environmental and agricultural uses are also explored. Finally, this review presents recent examples of real-world applications of hydrogel films and explores the possibility they have for a wide variety of needs. Full article

Trichlorfon, an organophosphorus pesticide widely used in agriculture and other fields, poses a severe risk to both food safety and human health. We developed a photonic crystal film sensing platform for detecting trichlorfon, a hazardous organophosphorus pesticide. The method exploits trichlorfon’s inhibition of acetylcholinesterase (AChE). Normally, AChE catalyzes acetylcholine hydrolysis to produce acetic acid, which decomposes CaCO₃ to release Ca²⁺. This triggers calcium alginate hydrogel formation, increasing solution viscosity and trapping water. When trichlorfon inhibits AChE, hydrogel formation fails, leaving the solution in a low-viscosity sol state with abundant free water. Immersing the film in trichlorfon-containing sodium alginate solutions causes water absorption and film swelling due to free water. Higher trichlorfon concentrations reduce hydrogel formation, increase free water, and amplify film swelling, resulting in proportionally higher reflectivity. The platform demonstrates a wide linear range (1–250 ng/mL) and a low detection limit (0.4 ng/mL) for trichlorfon. Successful analysis of real samples confirms its practicality for residue detection. This label-free thin-film sensor shows significant potential for monitoring trichlorfon and other organophosphorus pesticides. Full article

The use of agrochemicals in agriculture is widespread globally, as it enables increased crop yields. However, they also contain heavy metals such as copper and nickel, which can leach into the drinking water and harm the environment and human health. As such, it is imperative that they are removed from drinking water. One way to achieve this is through adsorption using biosorbents. This proof-of-concept study aimed to synthesize and characterize environmentally friendly hydrogels from sodium alginate (SA) and pomegranate peel powder (PPP). The gels were characterized using Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), and water uptake tests. The FTIR analysis confirmed the presence of the expected functional groups, SEM revealed that incorporating PPP enhanced the roughness and porosity of the gels, and gels with PPP incorporation were able to absorb 1.58 times more water than SA-only gels. Moreover, their ability to remediate copper and nickel from contaminated water was tested. Here, the effects of contact time, pH, and adsorbent amount were tested for copper, demonstrating that the optimal contact time was 60 min, the optimal pH was ~5, and 0.01 g of adsorbent was needed for optimal adsorption. The effect of contact time was tested for nickel, and it was found that the optimal contact time was 5 min. Overall, these gels show promising results for the remediation of copper and nickel from contaminated water. Full article

Functional hydrogels have significant potential for applications in the pharmaceutical, agricultural, and environmental sectors. This study focuses on the synthesis of polyampholytic hydrogels through free radical polymerization using functionalized chitosans. The chitosan was modified with mono and disulfonic groups at different temperatures (25 °C and 60 °C) and reaction times (1, 8, 24 h), followed by further modification with glycidyl methacrylate to introduce vinyl groups into the polymers structure. The modified polymers were analyzed using proton nuclear magnetic resonance, Fourier transform infrared, scanning electron spectroscopy, thermogravimetric analysis, and solubility tests. Specifically, 0.74 mmol/g and 1.58 mmol/g of the primary amine groups available in the chitosan chain (out of a total of 4.93 mmol/g) were substituted with mono- and disulfonic groups, respectively. Following treatment with glycidyl methacrylate, 3.39 mmol/g and 2.21 mmol/g of the remaining primary amine groups in the mono- and disulfonic polymers, respectively, were substituted. The hydrogels obtained by the modified polymers at optimal conditions of 1 h and 25 °C, were characterized by the techniques already mentioned in addition to rheological tests, and water absorption studies across different pHs. The hydrogels demonstrated potential for environmental remediation, particularly in adsorptions of ciprofloxacin (CPX) and copper (Cu²⁺) from aqueous solutions at pH 7, achieving adsorption efficiencies of 24–25% for CPX and 83% for Cu²⁺. The results suggest that the synthesized hydrogels could provide an eco-friendly and efficient solution to challenges in wastewater treatment. Full article

The increasing demand for food necessitates that agri-food systems adopt innovative techniques to enhance food production while optimizing the use of limited resources, such as water. In agriculture, hydrogels are being increasingly used to enhance water retention and reduce irrigation requirements. However, most of these materials are based on synthetic polymers that are not biodegradable. This raises serious environmental and health concerns, highlighting the urgent need for sustainable, biodegradable alternatives. Biomass-derived from agro-industrial waste presents a substantial potential for producing hydrogels, which can effectively function as water collectors and suppliers for crops. This review article provides a comprehensive overview of recent advancements in the application of agro-industrial waste for the formulation of hydrogels. Additionally, it offers a critical analysis of the development of hydrogels utilizing natural and compostable materials. Agro-industrial and food waste, which are rich in hemicellulose and cellulose, have been utilized to enhance the mechanical properties and water absorption capacity of hydrogels. These biomaterials hold significant potential for the development of effective hydrogels in agricultural applications; they can be either hybrid or natural materials that exhibit efficacy in enhancing seed germination, improving water retention capabilities, and facilitating the controlled release of fertilizers. Natural hydrogels derived from agro-industrial waste present a sustainable technological alternative that is environmentally benign. Full article

Prolonged drought and soil degradation severely affect soil fertility and limit crop productivity. Superabsorbent hydrogels offer an effective solution for improving water retention in soil and supporting plant growth. In this work, we examined the performance of superabsorbent hydrogels based on sodium alginate, acrylic acid (AA), and poly (ethylene oxide) (PEO) cross-linked with 12.5 kGy using e-beam irradiation. The hydrogels were assessed in various aqueous environments by examining network characteristics, swelling capacity, and swelling kinetics to evaluate the impact of water’s electrical conductivity (which ranges from 0.05 to 321 μS/cm). Morphological and chemical structure changes were evaluated using SEM and FTIR techniques. The results demonstrated that water conductivity significantly affected the physicochemical properties of the hydrogels. Swelling behavior showed notable sensitivity to electrical conductivity variations, with swelling degrees reaching 28,400% at 5 μS/cm and 14,000% at 321 μS/cm, following first-order and second-order kinetics. FTIR analysis confirmed that structural modifications correlated with water conductivity, particularly affecting the O–H, C–H, and COOH groups sensitive to the ionic environment. SEM characterization revealed a porous morphology with an interconnected microporous network that facilitates efficient water diffusion. These hydrogels show exceptional swelling capacity and are promising candidates for sustainable agriculture applications. Full article

Cultured meat is emerging as a sustainable alternative to conventional animal agriculture, with scaffolds playing a central role in supporting cellular attachment, growth, and tissue maturation. This review focuses on the development of gel-based hybrid biomaterials that meet the dual requirements of biocompatibility and food safety. We explore recent advances in the use of naturally derived gel-forming polymers such as gelatin, chitosan, cellulose, alginate, and plant-based proteins as the structural backbone for edible scaffolds. Particular attention is given to the integration of food-grade functional additives into hydrogel-based scaffolds. These include nanocellulose, dietary fibers, modified starches, polyphenols, and enzymatic crosslinkers such as transglutaminase, which enhance mechanical stability, rheological properties, and cell-guidance capabilities. Rather than focusing on fabrication methods or individual case studies, this review emphasizes the material-centric design strategies for building scalable, printable, and digestible gel scaffolds suitable for cultured meat production. By systemically evaluating the role of each component in structural reinforcement and biological interaction, this work provides a comprehensive frame work for designing next-generation edible scaffold systems. Nonetheless, the field continues to face challenges, including structural optimization, regulatory validation, and scale-up, which are critical for future implementation. Ultimately, hybrid gel-based scaffolds are positioned as a foundational technology for advancing the functionality, manufacturability, and consumer readiness of cultured meat products, distinguishing this work from previous reviews. Unlike previous reviews that have focused primarily on fabrication techniques or tissue engineering applications, this review provides a uniquely food-centric perspective by systematically evaluating the compositional design of hybrid hydrogel-based scaffolds with edibility, scalability, and consumer acceptance in mind. Through a comparative analysis of food-safe additives and naturally derived biopolymers, this review establishes a framework that bridges biomaterials science and food engineering to advance the practical realization of cultured meat products. Full article

Hydrogels exhibit remarkable physicochemical properties, including high water absorption and retention capacities, as well as controlled release behavior. Their inherent biodegradability, biocompatibility, and non-toxicity make them suitable for a wide range of applications. Cellulose, a biodegradable, renewable, and abundantly available polysaccharide, is a viable source for hydrogel preparation. Ionizing radiation, using electron-beam (EB) or gamma (γ) irradiation, provides a promising approach for synthesizing hydrogels. This study reviews recent advancements in cellulose-based hydrogels, focusing on cellulose and its derivatives, brief information regarding ionizing radiation, comparison between EB and γ-irradiation, synthesis and modification through ionizing radiation technology, and their environmental and agricultural applications. For environmental remediation, these hydrogels have demonstrated significant potential in water purification, particularly in the removal of heavy metals, dyes, and organic contaminants. In agricultural applications, cellulose-based hydrogels function as soil conditioners by enhancing water retention and serving as carriers for agrochemicals. Full article

Hydrogels are widely known for their ability to increase soil water retention and for their potential slow nutrient release mechanism. They have been constantly improved to meet the growing demand for sustainability in agriculture. Research focused on the development of biodegradable hydrogels, produced from industrial cellulose waste, are an ecological and efficient alternative soil ameliorant for the improvement of agricultural land. The objective of this study was to evaluate the impacts of two types of hydrogel (processed in a glass reactor versus a twin-screw extruder) on soils with different textures (clay and sandy loam), testing their water retention capacity, nitrogen leaching, and effects on seed germination. The methodology included the evaluation of water retention capacity at different pressures with different hydrogel addition rates in the soil, leaching tests in columns filled with soil and hydrogel layers, and germination tests of sorghum and corn. The results indicated that the addition of hydrogel significantly improved water retention, especially in sandy loam soils. The hydrogels also reduced nitrogen leaching, acting as nitrification inhibitors and limiting the conversion of ammonium to nitrate, with greater effectiveness in clayey soils. In the tested formulations, it was observed that the hydrogel doses applied to the columns favored nitrogen retention in the region close to the roots, directly influencing the initial stages of germination. This behavior highlights the potential of hydrogels as tools for directing nutrients in the soil profile, indicating that adjustments to the C:N ratio, nutrient release rate, and applied doses can optimize their application for different crops. Full article