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Search Results (7,166)

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Keywords = high pressure-temperature

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21 pages, 3336 KiB  
Article
A Computerized Analysis of Flow Parameters for a Twin-Screw Compressor Using SolidWorks Flow Simulation
by Ildiko Brinas, Florin Dumitru Popescu, Andrei Andras, Sorin Mihai Radu and Laura Cojanu
Computation 2025, 13(8), 189; https://doi.org/10.3390/computation13080189 (registering DOI) - 6 Aug 2025
Abstract
Twin-screw compressors (TSCs) are widely used in various industries. Their performance is influenced by several parameters, such as rotor profiles, clearance gaps, operating speed, and thermal effects. Traditionally, optimizing these parameters relied on experimental methods, which are costly and time-consuming. However, advancements in [...] Read more.
Twin-screw compressors (TSCs) are widely used in various industries. Their performance is influenced by several parameters, such as rotor profiles, clearance gaps, operating speed, and thermal effects. Traditionally, optimizing these parameters relied on experimental methods, which are costly and time-consuming. However, advancements in computational tools, such as Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEA), have revolutionized compressor analysis. This study presents a CFD analysis of a specific model of a TSC in a 5 male/6 female lobe configuration using the SolidWorks Flow Simulation environment—an approach not traditionally applied to such positive displacement machines. The results visually present internal flow trajectories, fluid velocities, pressure distributions, temperature gradients, and leakage behaviors with high spatial and temporal resolution. Additionally, torque fluctuations and isosurface visualizations revealed insights into mechanical loads and flow behavior. The proposed method allows for relatively easy adaptation to different TSC configurations and can also be a useful tool for engineering and educational purposes. Full article
(This article belongs to the Special Issue Advances in Computational Methods for Fluid Flow)
16 pages, 6404 KiB  
Article
The Study of Phase Behavior of Multi-Component Alkane–Flue Gas Systems Under High-Temperature Conditions Based on Molecular Dynamics Simulations
by Xiaokun Zhang, Jiagao Tang, Zongyao Qi, Suo Liu, Changfeng Xi, Fang Zhao, Ping Hu, Hongyun Zhou, Chao Wang and Bojun Wang
Energies 2025, 18(15), 4169; https://doi.org/10.3390/en18154169 (registering DOI) - 6 Aug 2025
Abstract
Injecting industrial high-temperature flue gas into hydrocarbon reservoirs has emerged as a novel approach for carbon sequestration. However, the complex high-temperature phase behavior between flue gas (CO2, N2) and reservoir fluids challenges this technology’s development, as traditional experimental methods [...] Read more.
Injecting industrial high-temperature flue gas into hydrocarbon reservoirs has emerged as a novel approach for carbon sequestration. However, the complex high-temperature phase behavior between flue gas (CO2, N2) and reservoir fluids challenges this technology’s development, as traditional experimental methods and theoretical models often fall short in capturing it accurately. To address this, molecular dynamics simulations were employed in this study to investigate the phase behavior of single-component alkanes, multicomponent alkane mixtures, and multicomponent alkane–flue gas systems under high-temperature conditions. The results reveal that CO2 can become miscible with alkanes, while N2 diffuses into the system, causing volumetric expansion and a reduction in density. The initially distinct phase interface between the multicomponent alkanes and the flue gas becomes progressively blurred and eventually disappears, indicating the formation of a fully miscible phase. Comparative simulations revealed that the diffusion coefficients of N2 and CO2 increased by up to 20% with rising temperature and pressure, while variations in flue gas composition had negligible effects, indicating that high-temperature and high-pressure conditions significantly enhance flue gas–alkane miscibility. Full article
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24 pages, 6492 KiB  
Review
Review on Multifactorial Coupling Effects and the Time-Dependent Behavior of Lateral Pressure on Concrete Formworks
by Kekuo Yuan, Min Zhang, Yichu Lu and Hongdan Yu
Buildings 2025, 15(15), 2764; https://doi.org/10.3390/buildings15152764 - 5 Aug 2025
Abstract
This critical review synthesizes evidence on the multifactorial coupling mechanisms and time-dependent evolution of lateral pressure in concrete formworks, addressing significant limitations in current design standards (GB50666, CIRIA 108, ACI 347). Through a structured analysis of 60+ experimental and theoretical studies, we establish [...] Read more.
This critical review synthesizes evidence on the multifactorial coupling mechanisms and time-dependent evolution of lateral pressure in concrete formworks, addressing significant limitations in current design standards (GB50666, CIRIA 108, ACI 347). Through a structured analysis of 60+ experimental and theoretical studies, we establish that lateral pressure is governed by nonlinear interactions between concrete rheology, casting dynamics, thermal conditions, and formwork geometry. The key findings reveal that (1) casting rate increments >5 m/h amplify peak pressure by 15–27%, while SCC thixotropy (Athix > 0.5) reduces it by 15–27% at <5 m/h; (2) secondary vibration induces 52–61% pressure surges through liquefaction; and (3) sections with a width >2 m exhibit 40% faster pressure decay due to arching effects. (4) Temporal evolution follows three distinct phases—rapid rise (0–2 h), slow decay (2–10 h), and sharp decline (>10 h)—with the temperature critically modulating transition kinetics. Crucially, the existing codes inadequately model temperature dependencies, SCC/HPC rheology, and high-speed casting (>10 m/h). This work proposes a parameter-specific framework integrating rheological thresholds (Athix, Rstr), casting protocols, and real-time monitoring to enhance standard accuracy, enabling an optimized formwork design and risk mitigation in complex scenarios, such as water conveyance construction and slipforming. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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17 pages, 2219 KiB  
Article
Assessing Lithium-Ion Battery Safety Under Extreme Transport Conditions: A Comparative Study of Measured and Standardised Parameters
by Yihan Pan, Xingliang Liu, Jinzhong Wu, Haocheng Zhou and Lina Zhu
Energies 2025, 18(15), 4144; https://doi.org/10.3390/en18154144 - 5 Aug 2025
Abstract
The safety of lithium-ion batteries during transportation is critically important. However, current standards exhibit limitations, as their environmental testing parameter thresholds fail to fully encompass actual transportation conditions. To enhance both safety and standard applicability, in this study, we focused on four representative [...] Read more.
The safety of lithium-ion batteries during transportation is critically important. However, current standards exhibit limitations, as their environmental testing parameter thresholds fail to fully encompass actual transportation conditions. To enhance both safety and standard applicability, in this study, we focused on four representative environmental conditions: temperature, vibration, shock, and low atmospheric pressure. Field measurements were conducted across road, rail, and air transport modes using a self-developed data acquisition system based on the NearLink communication technology. The measured data were then compared with the threshold values defined in current international and national standards. The results reveal that certain measured values exceeded the upper limits prescribed by existing standards, indicating limitations in their applicability under extreme transport conditions. Based on these findings, we propose revised testing parameters that better reflect actual transport risks, including a temperature cycling range of 72 ± 2 °C (high) and −40 ± 2 °C (low), a shock acceleration limit of 50 gn, adjusted peak frequencies in the vibration PSD profile, and a minimum pressure threshold of 11.6 kPa. These results provide a scientific basis for optimising safety standards and improving the safety of lithium-ion battery transportation. Full article
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21 pages, 3283 KiB  
Article
Atypical Pressure Dependent Structural Phonon and Thermodynamic Characteristics of Zinc Blende BeO
by Devki N. Talwar and Piotr Becla
Materials 2025, 18(15), 3671; https://doi.org/10.3390/ma18153671 - 5 Aug 2025
Abstract
Under normal conditions, the novel zinc blende beryllium oxide (zb BeO) exhibits in a metastable crystalline phase, which is less stable than its wurtzite counterpart. Ultrathin zb BeO epifilms have recently gained significant interest to create a wide range of advanced high-resolution, high-frequency, [...] Read more.
Under normal conditions, the novel zinc blende beryllium oxide (zb BeO) exhibits in a metastable crystalline phase, which is less stable than its wurtzite counterpart. Ultrathin zb BeO epifilms have recently gained significant interest to create a wide range of advanced high-resolution, high-frequency, flexible, transparent, nano-electronic and nanophotonic modules. BeO-based ultraviolet photodetectors and biosensors are playing important roles in providing safety and efficiency to nuclear reactors for their optimum operations. In thermal management, BeO epifilms have also been used for many high-tech devices including medical equipment. Phonon characteristics of zb BeO at ambient and high-pressure P ≠ 0 GPa are required in the development of electronics that demand enhanced heat dissipation for improving heat sink performance to lower the operating temperature. Here, we have reported methodical simulations to comprehend P-dependent structural, phonon and thermodynamical properties by using a realistic rigid-ion model (RIM). Unlike zb ZnO, the study of the Grüneisen parameter γ(T) and thermal expansion coefficient α(T) in zb BeO has revealed atypical behavior. Possible reasons for such peculiar trends are attributed to the combined effect of the short bond length and strong localization of electron charge close to the small core size Be atom in BeO. Results of RIM calculations are compared/contrasted against the limited experimental and first-principle data. Full article
(This article belongs to the Special Issue The Heat Equation: The Theoretical Basis for Materials Processing)
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20 pages, 1801 KiB  
Article
Territorially Stratified Modeling for Sustainable Management of Free-Roaming Cat Populations in Spain: A National Approach to Urban and Rural Environmental Planning
by Octavio P. Luzardo, Ruth Manzanares-Fernández, José Ramón Becerra-Carollo and María del Mar Travieso-Aja
Animals 2025, 15(15), 2278; https://doi.org/10.3390/ani15152278 - 4 Aug 2025
Abstract
This study presents the scientific and methodological foundation of Spain’s first national framework for the ethical management of community cat populations: the Action Plan for the Management of Community Cat Colonies (PACF), launched in 2025 under the mandate of Law 7/2023. This pioneering [...] Read more.
This study presents the scientific and methodological foundation of Spain’s first national framework for the ethical management of community cat populations: the Action Plan for the Management of Community Cat Colonies (PACF), launched in 2025 under the mandate of Law 7/2023. This pioneering legislation introduces a standardized, nationwide obligation for trap–neuter–return (TNR)-based management of free-roaming cats, defined as animals living freely, territorially attached, and with limited socialization toward humans. The PACF aims to support municipalities in implementing this mandate through evidence-based strategies that integrate animal welfare, biodiversity protection, and public health objectives. Using standardized data submitted by 1128 municipalities (13.9% of Spain’s total), we estimated a baseline population of 1.81 million community cats distributed across 125,000 colonies. These data were stratified by municipal population size and applied to national census figures to generate a model-ready demographic structure. We then implemented a stochastic simulation using Vortex software to project long-term population dynamics over a 25-year horizon. The model integrated eight demographic–environmental scenarios defined by a combination of urban–rural classification and ecological reproductive potential based on photoperiod and winter temperature. Parameters included reproductive output, mortality, sterilization coverage, abandonment and adoption rates, stochastic catastrophic events, and territorial carrying capacity. Under current sterilization rates (~20%), our projections indicate that Spain’s community cat population could surpass 5 million individuals by 2050, saturating ecological and social thresholds within a decade. In contrast, a differentiated sterilization strategy aligned with territorial reproductive intensity (50% in most areas, 60–70% in high-pressure zones) achieves population stabilization by 2030 at approximately 1.5 million cats, followed by a gradual long-term decline. This scenario prioritizes feasibility while substantially reducing reproductive output, particularly in rural and high-intensity contexts. The PACF combines stratified demographic modeling with spatial sensitivity, offering a flexible framework adaptable to local conditions. It incorporates One Health principles and introduces tools for adaptive management, including digital monitoring platforms and standardized welfare protocols. While ecological impacts were not directly assessed, the proposed demographic stabilization is designed to mitigate population-driven risks to biodiversity and public health without relying on lethal control. By integrating legal mandates, stratified modeling, and realistic intervention goals, this study outlines a replicable and scalable framework for coordinated action across administrative levels. It exemplifies how national policy can be operationalized through data-driven, territorially sensitive planning tools. The findings support the strategic deployment of TNR-based programs across diverse municipal contexts, providing a model for other countries seeking to align animal welfare policy with ecological planning under a multi-level governance perspective. Full article
(This article belongs to the Section Animal System and Management)
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27 pages, 30231 KiB  
Article
Modelling and Simulation of a 3MW, Seventeen-Phase Permanent Magnet AC Motor with AI-Based Drive Control for Submarines Under Deep-Sea Conditions
by Arun Singh and Anita Khosla
Energies 2025, 18(15), 4137; https://doi.org/10.3390/en18154137 - 4 Aug 2025
Abstract
The growing need for high-efficiency and reliable propulsion systems in naval applications, particularly within the evolving landscape of submarine warfare, has led to an increased interest in multiphase Permanent Magnet AC motors. This study presents a modelling and simulation approach for a 3MW, [...] Read more.
The growing need for high-efficiency and reliable propulsion systems in naval applications, particularly within the evolving landscape of submarine warfare, has led to an increased interest in multiphase Permanent Magnet AC motors. This study presents a modelling and simulation approach for a 3MW, seventeen-phase Permanent Magnet AC motor designed for submarine propulsion, integrating an AI-based drive control system. Despite the advantages of multiphase motors, such as higher power density and enhanced fault tolerance, significant challenges remain in achieving precise torque and variable speed, especially for externally mounted motors operating under deep-sea conditions. Existing control strategies often struggle with the inherent nonlinearities, unmodelled dynamics, and extreme environmental variations (e.g., pressure, temperature affecting oil viscosity and motor parameters) characteristic of such demanding deep-sea applications, leading to suboptimal performance and compromised reliability. Addressing this gap, this research investigates advanced control methodologies to enhance the performance of such motors. A MATLAB/Simulink framework was developed to model the motor, whose drive system leverages an AI-optimised dual fuzzy-PID controller refined using the Harmony Search Algorithm. Additionally, a combination of Indirect Field-Oriented Control (IFOC) and Space Vector PWM strategies are implemented to optimise inverter switching sequences for precise output modulation. Simulation results demonstrate significant improvements in torque response and control accuracy, validating the efficacy of the proposed system. The results highlight the role of AI-based propulsion systems in revolutionising submarine manoeuvrability and energy efficiency. In particular, during a test case involving a speed transition from 75 RPM to 900 RPM, the proposed AI-based controller achieves a near-zero overshoot compared to an initial control scheme that exhibits 75.89% overshoot. Full article
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13 pages, 2036 KiB  
Article
Aluminum Extractions by the Alkali Method Directly from Alkali-Acid (NaOH-HCl) Chemical Deashing of Coals
by Lijun Zhao
Materials 2025, 18(15), 3661; https://doi.org/10.3390/ma18153661 - 4 Aug 2025
Abstract
An advanced alkali-acid (NaOH-HCl) chemical method was used to deash aluminum-rich coals (ARCs) with a high ash content of 27.47 wt% to achieve a low ash content of 0.46 wt%. In the deashing process, aluminum in the coal ashes was dissolved in both [...] Read more.
An advanced alkali-acid (NaOH-HCl) chemical method was used to deash aluminum-rich coals (ARCs) with a high ash content of 27.47 wt% to achieve a low ash content of 0.46 wt%. In the deashing process, aluminum in the coal ashes was dissolved in both alkali solutions and acid solutions. The deashing alkali solutions with dissolved coal ashes were regenerated by adding CaO, and the resulting precipitates were added with sodium bicarbonate for aluminum extraction. High temperatures increased aluminum extraction, and excessive sodium bicarbonate addition decreased aluminum extraction. The deashing acid solutions were concentrated by evaporation, and silica gels formed during the process. The obtained mixtures were calcinated at 350 °C for the decomposition of aluminum chlorides, and soaked with water at 60 °C to remove the soluble chlorides. For the insoluble oxides after soaking, diluted alkali solutions were used to extract the aluminum at 90 °C, and aluminum extraction failed due to the formation of albite in the presence of sodium, aluminum and silicon elements as proved by XRD and SEM/EDS. When silica gels were separated by pressure filtering, aluminum extraction greatly increased. Aluminum extractions were accordingly made in the form of sodium aluminate from the deashing solutions of coals, which could be advantageous for sandy alumina production. Full article
(This article belongs to the Section Materials Chemistry)
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17 pages, 5451 KiB  
Article
Study of Efficient and Clean Combustion of Diesel–Natural Gas Engine at High Loads with TAC-HCCI Combustion
by Min Zhang, Wenyu Gu, Zhi Jia and Wanhua Su
Energies 2025, 18(15), 4121; https://doi.org/10.3390/en18154121 - 3 Aug 2025
Viewed by 224
Abstract
This study proposes an innovative Thermodynamic Activity Controlled Homogeneous Charge Compression Ignition (TAC-HCCI) strategy for diesel–natural gas dual-fuel engines, aiming to achieve high thermal efficiency while maintaining low emissions. By employing numerical simulation methods, the effects of the intake pressure, intake temperature, EGR [...] Read more.
This study proposes an innovative Thermodynamic Activity Controlled Homogeneous Charge Compression Ignition (TAC-HCCI) strategy for diesel–natural gas dual-fuel engines, aiming to achieve high thermal efficiency while maintaining low emissions. By employing numerical simulation methods, the effects of the intake pressure, intake temperature, EGR rate, intake valve closing timing, diesel injection timing, diesel injection pressure, and diesel injection quantity on engine combustion, energy distribution, and emission characteristics were systematically investigated. Through a comprehensive analysis of optimized operating conditions, a high-efficiency and low-emission TAC-HCCI combustion technology for dual-fuel engines was developed. The core mechanism of TAC-HCCI combustion control was elucidated through an analysis of the equivalence ratio and temperature distribution of the in-cylinder mixture. The results indicate that under the constraints of PCP ≤ 30 ± 1 MPa and RI ≤ 5 ± 0.5 MW/m2, the TAC-HCCI technology achieves a gross indicated mean effective pressure (IMEPg) of 24.0 bar, a gross indicated thermal efficiency (ITEg) of up to 52.0%, and indicated specific NOx emissions (ISNOx) as low as 1.0 g/kW∙h. To achieve low combustion loss, reduced heat transfer loss, and high thermal efficiency, it is essential to ensure the complete combustion of the mixture while maintaining low combustion temperatures. Moreover, a reduced diesel injection quantity combined with a high injection pressure can effectively suppress NOx emissions. Full article
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23 pages, 1517 KiB  
Article
Physics-Informed Neural Network Enhanced CFD Simulation of Two-Dimensional Green Ammonia Synthesis Reactor
by Ran Xu, Shibin Zhang, Fengwei Rong, Wei Fan, Xiaomeng Zhang, Yunlong Wang, Liang Zan, Xu Ji and Ge He
Processes 2025, 13(8), 2457; https://doi.org/10.3390/pr13082457 - 3 Aug 2025
Viewed by 136
Abstract
The synthesis of “green ammonia” from “green hydrogen” represents a critical pathway for renewable energy integration and industrial decarbonization. This study investigates the green ammonia synthesis process using an axial–radial fixed-bed reactor equipped with three catalyst layers. A simplified two-dimensional physical model was [...] Read more.
The synthesis of “green ammonia” from “green hydrogen” represents a critical pathway for renewable energy integration and industrial decarbonization. This study investigates the green ammonia synthesis process using an axial–radial fixed-bed reactor equipped with three catalyst layers. A simplified two-dimensional physical model was developed, and a multiscale simulation approach combining computational fluid dynamics (CFD) with physics-informed neural networks (PINNs) employed. The simulation results demonstrate that the majority of fluid flows axially through the catalyst beds, leading to significantly higher temperatures in the upper bed regions. The reactor exhibits excellent heat exchange performance, ensuring effective preheating of the feed gas. High-pressure zones are concentrated near the top and bottom gas outlets, while the ammonia mole fraction approaches 100% near the bottom outlet, confirming superior conversion efficiency. By integrating PINNs, the prediction accuracy was substantially improved, with flow field errors in the catalyst beds below 4.5% and ammonia concentration prediction accuracy above 97.2%. Key reaction kinetic parameters (pre-exponential factor k0 and activation energy Ea) were successfully inverted with errors within 7%, while computational efficiency increased by 200 times compared to traditional CFD. The proposed CFD–PINN integrated framework provides a high-fidelity and computationally efficient simulation tool for green ammonia reactor design, particularly suitable for scenarios with fluctuating hydrogen supply. The reactor design reduces energy per unit ammonia and improves conversion efficiency. Its radial flow configuration enhances operational stability by damping feed fluctuations, thereby accelerating green hydrogen adoption. By reducing fossil fuel dependence, it promotes industrial decarbonization. Full article
(This article belongs to the Section AI-Enabled Process Engineering)
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23 pages, 3916 KiB  
Article
Leveraging Wearable Sensors for the Identification and Prediction of Defensive Pessimism Personality Traits
by You Zhou, Dongfen Li, Bowen Deng and Weiqian Liang
Micromachines 2025, 16(8), 906; https://doi.org/10.3390/mi16080906 (registering DOI) - 2 Aug 2025
Viewed by 219
Abstract
Defensive pessimism, an important emotion regulation and motivation strategy, has increasingly attracted scholarly attention in psychology. Recently, sensor-based methods have begun to supplement or replace traditional questionnaire surveys in personality research. However, current approaches for collecting vital signs data face several challenges, including [...] Read more.
Defensive pessimism, an important emotion regulation and motivation strategy, has increasingly attracted scholarly attention in psychology. Recently, sensor-based methods have begun to supplement or replace traditional questionnaire surveys in personality research. However, current approaches for collecting vital signs data face several challenges, including limited monitoring durations, significant data deviations, and susceptibility to external interference. This paper proposes a novel approach using a NiCr/NiSi alloy film temperature sensor, which has a K-type structure and flexible piezoelectric pressure sensor to identify and predict defensive pessimism personality traits. Experimental results indicate that the Seebeck coefficients for K-, T-, and E-type thermocouples are approximately 41 μV/°C, 39 μV/°C, and 57 μV/°C, respectively, which align closely with national standards and exhibit good consistency across multiple experimental groups. Moreover, radial artery frequency experiments demonstrate a strong linear relationship between pulse rate and the intensity of external stimuli, where stronger stimuli correspond to faster pulse rates. Simulation experiments further reveal a high correlation between radial artery pulse frequency and skin temperature, and a regression model based on the physiological sensor data shows a good fit (p < 0.05). These findings verify the feasibility of using temperature and flexible piezoelectric pressure sensors to identify and predict defensive pessimism personality characteristics. Full article
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21 pages, 20135 KiB  
Article
Strain-Rate Effects on the Mechanical Behavior of Basalt-Fiber-Reinforced Polymer Composites: Experimental Investigation and Numerical Validation
by Yuezhao Pang, Chuanlong Wang, Yue Zhao, Houqi Yao and Xianzheng Wang
Materials 2025, 18(15), 3637; https://doi.org/10.3390/ma18153637 - 1 Aug 2025
Viewed by 241
Abstract
Basalt-fiber-reinforced polymer (BFRP) composites, utilizing a natural high-performance inorganic fiber, exhibit excellent weathering resistance, including tolerance to high and low temperatures, salt fog, and acid/alkali corrosion. They also possess superior mechanical properties such as high strength and modulus, making them widely applicable in [...] Read more.
Basalt-fiber-reinforced polymer (BFRP) composites, utilizing a natural high-performance inorganic fiber, exhibit excellent weathering resistance, including tolerance to high and low temperatures, salt fog, and acid/alkali corrosion. They also possess superior mechanical properties such as high strength and modulus, making them widely applicable in aerospace and shipbuilding. This study experimentally investigated the mechanical properties of BFRP plates under various strain rates (10−4 s−1 to 103 s−1) and directions using an electronic universal testing machine and a split Hopkinson pressure bar (SHPB).The results demonstrate significant strain rate dependency and pronounced anisotropy. Based on experimental data, relationships linking the strength of BFRP composites in different directions to strain rate were established. These relationships effectively predict mechanical properties within the tested strain rate range, providing reliable data for numerical simulations and valuable support for structural design and engineering applications. The developed strain rate relationships were successfully validated through finite element simulations of low-velocity impact. Full article
(This article belongs to the Special Issue Mechanical Properties of Advanced Metamaterials)
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18 pages, 1621 KiB  
Article
The Evaluation of Cellulose from Agricultural Waste as a Polymer for the Controlled Release of Ibuprofen Through the Formulation of Multilayer Tablets
by David Sango-Parco, Lizbeth Zamora-Mendoza, Yuliana Valdiviezo-Cuenca, Camilo Zamora-Ledezma, Si Amar Dahoumane, Floralba López and Frank Alexis
Bioengineering 2025, 12(8), 838; https://doi.org/10.3390/bioengineering12080838 (registering DOI) - 1 Aug 2025
Viewed by 278
Abstract
This research demonstrates the potential of plant waste cellulose as a remarkable biomaterial for multilayer tablet formulation. Rice husks (RC) and orange peels (OC) were used as cellulose sources and characterized for a comparison with commercial cellulose. The FTIR characterization shows minimal differences [...] Read more.
This research demonstrates the potential of plant waste cellulose as a remarkable biomaterial for multilayer tablet formulation. Rice husks (RC) and orange peels (OC) were used as cellulose sources and characterized for a comparison with commercial cellulose. The FTIR characterization shows minimal differences in their chemical components, making them equivalent for compression into tablets containing ibuprofen. TGA measurements indicate that the RC is slightly better for multilayer formulations due to its favorable degradation profile. This is corroborated by an XRD analysis that reveals its higher crystalline fraction (~55%). The use of a heat press at combined high pressures and temperatures allows the layer-by-layer tablet formulation of ibuprofen, taken as a model drug. Additionally, this study compares the release profile of three types of tablets compressed with cellulose: mixed (MIX), two-layer (BL), and three-layer (TL). The MIX tablet shows a profile like that of conventional ibuprofen tablets. Although both BL and TL tablets significantly reduce their release percentage in the first hours, the TL ones have proven to be better in the long run. In fact, formulations made of extracted cellulose sandwiching ibuprofen display a zero-order release profile and prolonged release since the drug release amounts to ~70% after 120 h. This makes the TL formulations ideal for maintaining the therapeutic effect of the drug and improving patients’ wellbeing and compliance while reducing adverse effects. Full article
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21 pages, 3744 KiB  
Article
A First-Principles Modeling of the Elastic Properties and Generalized Stacking Fault Energy of Ir-W Solid Solution Alloys
by Pengwei Shi, Jianbo Ma, Fenggang Bian and Guolu Li
Materials 2025, 18(15), 3629; https://doi.org/10.3390/ma18153629 - 1 Aug 2025
Viewed by 260
Abstract
Iridium, with its excellent high-temperature chemical inertness, is a preferred cladding material for radioisotope batteries. However, its inherent room-temperature brittleness severely restricts its application. In this research, pure Ir and six Ir-W solid solutions (Ir31W1 to Ir26W6 [...] Read more.
Iridium, with its excellent high-temperature chemical inertness, is a preferred cladding material for radioisotope batteries. However, its inherent room-temperature brittleness severely restricts its application. In this research, pure Ir and six Ir-W solid solutions (Ir31W1 to Ir26W6) were modeled. The effects of W on the elastic properties, generalized stacking fault energy, and bonding properties of Ir solid solution alloys were investigated by first-principles simulation, aiming to find a way to overcome the intrinsic brittleness of Ir. With the W concentration increasing from 0 to 18.75 at %, the calculated Cauchy pressure (C12C44) increases from −22 to 5 GPa, Pugh’s ratio (B/G) increases from 1.60 to 1.72, the intrinsic stacking fault energy reduces from 337.80 to 21.16 mJ/m2, and the unstable stacking fault energy reduces from 636.90 to 547.39 mJ/m2. According to these results, it is predicted that the addition of W improves the toughness of iridium alloys. The alloying of W weakens the covalency properties of the Ir-Ir bond (the ICOHP value increases from −0.8512 to −0.7923 eV). These phenomena result in a decrease in the energy barrier for grain slip. Full article
(This article belongs to the Section Metals and Alloys)
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17 pages, 1522 KiB  
Article
Characterization of Solid Particulates to Be Used as Storage as Well as Heat Transfer Medium in Concentrated Solar Power Systems
by Rageh Saeed, Syed Noman Danish, Shaker Alaqel, Nader S. Saleh, Eldwin Djajadiwinata, Hany Al-Ansary, Abdelrahman El-Leathy, Abdulelah Alswaiyd, Zeyad Al-Suhaibani, Zeyad Almutairi and Sheldon Jeter
Appl. Sci. 2025, 15(15), 8566; https://doi.org/10.3390/app15158566 (registering DOI) - 1 Aug 2025
Viewed by 128
Abstract
Using solid particulates as a heat transfer medium for concentrated solar power (CSP) systems has many advantages, positioning them as a superior option compared with conventional heat transfer media such as steam, oil, air, and molten salt. However, a critical imperative lies in [...] Read more.
Using solid particulates as a heat transfer medium for concentrated solar power (CSP) systems has many advantages, positioning them as a superior option compared with conventional heat transfer media such as steam, oil, air, and molten salt. However, a critical imperative lies in the comprehensive evaluation of the properties of potential solid particulates intended for utilization under such extreme thermal conditions. This paper undertakes an exhaustive examination of both ambient and high-temperature thermophysical properties of four naturally occurring particulate materials, Riyadh white sand, Riyadh red sand, Saudi olivine sand, and US olivine sand, and one well-known engineered particulate material. The parameters under scrutiny encompass loose bulk density, tapped bulk density, real density, sintering temperature, and thermal conductivity. The results reveal that the theoretical density decreases with the increase in temperature. The bulk density of solid particulates depends strongly on the particulate size distribution, as well as on the compaction. The tapped bulk density was found to be larger than the loose density for all particulates, as expected. The sintering test proved that Riyadh white sand is sintered at the highest temperature and pressure, 1300 °C and 50 MPa, respectively. US olivine sand was solidified at 800 °C and melted at higher temperatures. This proves that US olivine sand is not suitable to be used as a thermal energy storage and heat transfer medium in high-temperature particle-based CSP systems. The experimental results of thermal diffusivity/conductivity reveal that, for all particulates, both properties decrease with the increase in temperature, and results up to 475.5 °C are reported. Full article
(This article belongs to the Section Applied Thermal Engineering)
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