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Keywords = hemp natural fibers

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33 pages, 3561 KiB  
Article
A Robust Analytical Network Process for Biocomposites Supply Chain Design: Integrating Sustainability Dimensions into Feedstock Pre-Processing Decisions
by Niloofar Akbarian-Saravi, Taraneh Sowlati and Abbas S. Milani
Sustainability 2025, 17(15), 7004; https://doi.org/10.3390/su17157004 - 1 Aug 2025
Viewed by 250
Abstract
Natural fiber-based biocomposites are rapidly gaining traction in sustainable manufacturing. However, their supply chain (SC) designs at the feedstock pre-processing stage often lack robust multicriteria decision-making evaluations, which can impact downstream processes and final product quality. This case study proposes a sustainability-driven multicriteria [...] Read more.
Natural fiber-based biocomposites are rapidly gaining traction in sustainable manufacturing. However, their supply chain (SC) designs at the feedstock pre-processing stage often lack robust multicriteria decision-making evaluations, which can impact downstream processes and final product quality. This case study proposes a sustainability-driven multicriteria decision-making framework for selecting pre-processing equipment configurations within a hemp-based biocomposite SC. Using a cradle-to-gate system boundary, four alternative configurations combining balers (square vs. round) and hammer mills (full-screen vs. half-screen) are evaluated. The analytical network process (ANP) model is used to evaluate alternative SC configurations while capturing the interdependencies among environmental, economic, social, and technical sustainability criteria. These criteria are further refined with the inclusion of sub-criteria, resulting in a list of 11 key performance indicators (KPIs). To evaluate ranking robustness, a non-linear programming (NLP)-based sensitivity model is developed, which minimizes the weight perturbations required to trigger rank reversals, using an IPOPT solver. The results indicated that the Half-Round setup provides the most balanced sustainability performance, while Full-Square performs best in economic and environmental terms but ranks lower socially and technically. Also, the ranking was most sensitive to the weight of the system reliability and product quality criteria, with up to a 100% shift being required to change the top choice under the ANP model, indicating strong robustness. Overall, the proposed framework enables decision-makers to incorporate uncertainty, interdependencies, and sustainability-related KPIs into the early-stage SC design of bio-based composite materials. Full article
(This article belongs to the Special Issue Sustainable Enterprise Operation and Supply Chain Management)
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23 pages, 3279 KiB  
Article
Assessment of the Environmental Feasibility of Utilizing Hemp Fibers in Composite Production
by Denis da Silva Miranda, Douglas Alexandre Casetta, Leonardo Coelho Simon and Luiz Kulay
Polymers 2025, 17(15), 2103; https://doi.org/10.3390/polym17152103 - 31 Jul 2025
Viewed by 292
Abstract
This study investigated the impact of incorporating hemp fibers into composites for manufacturing industrial parts. The Global Warming Potential (GWP) of producing a traditional polymer matrix composite containing glass fibers was compared to that of producing a counterpart from natural hemp fibers. The [...] Read more.
This study investigated the impact of incorporating hemp fibers into composites for manufacturing industrial parts. The Global Warming Potential (GWP) of producing a traditional polymer matrix composite containing glass fibers was compared to that of producing a counterpart from natural hemp fibers. The investigation concluded that the partial replacement of synthetic fibers with biomass reduced the GWP of the product by up to 25% without compromising its mechanical properties. This study also quantified and discussed the GWP of intermediate products obtained from alternative routes, such as the manufacture of hemp stalks and pellets. In these cases, the findings showed that the amount of CO2 absorbed during plant growth exceeded the emissions related to soil preparation, farming, and processing of hemp stalks by up to 15 times, and the processing of row hemp bales into pellets could result in an even “greener” product. This study highlights the importance of using bio-based inputs in reducing greenhouse gas emissions in the materials manufacturing industry and concludes that even partial substitutions of synthetic inputs with natural fibers can show significant reductions in this type of environmental impact. Full article
(This article belongs to the Special Issue Advances in Composite Materials: Polymers and Fibers Inclusion)
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19 pages, 5847 KiB  
Article
Parametric Analysis of Rammed Earth Walls in the Context of the Thermal Protection of Environmentally Friendly Buildings
by Piotr Kosiński, Wojciech Jabłoński and Krystian Patyna
Sustainability 2025, 17(15), 6886; https://doi.org/10.3390/su17156886 - 29 Jul 2025
Viewed by 285
Abstract
Rammed earth (RE), a traditional material aligned with circular economy (CE) principles, has been gaining renewed interest in contemporary construction due to its low environmental impact and compatibility with sustainable building strategies. Though not a modern invention, it is being reintroduced in response [...] Read more.
Rammed earth (RE), a traditional material aligned with circular economy (CE) principles, has been gaining renewed interest in contemporary construction due to its low environmental impact and compatibility with sustainable building strategies. Though not a modern invention, it is being reintroduced in response to the increasingly strict European Union (EU) regulations on carbon footprint, life cycle performance, and thermal efficiency. RE walls offer multiple benefits, including humidity regulation, thermal mass, plasticity, and structural strength. This study also draws attention to their often-overlooked ability to mitigate indoor overheating. To preserve these advantages while enhancing thermal performance, this study explores insulation strategies that maintain the vapor-permeable nature of RE walls. A parametric analysis using Delphin 6.1 software was conducted to simulate heat and moisture transfer in two main configurations: (a) a ventilated system insulated with mineral wool (MW), wood wool (WW), hemp shives (HS), and cellulose fiber (CF), protected by a jute mat wind barrier and finished with wooden cladding; (b) a closed system using MW and WW panels finished with lime plaster. In both cases, clay plaster was applied on the interior side. The results reveal distinct hygrothermal behavior among the insulation types and confirm the potential of natural, low-processed materials to support thermal comfort, moisture buffering, and the alignment with CE objectives in energy-efficient construction. Full article
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18 pages, 6078 KiB  
Article
Composites with Flax and Hemp Fibers Obtained Using Osmotic Degumming, Water-Retting, and Dew-Retting Processes
by Wanda Różańska and Szymon Rojewski
Materials 2025, 18(13), 3200; https://doi.org/10.3390/ma18133200 - 7 Jul 2025
Viewed by 345
Abstract
This study presents the application of flax (Linum usitatissimum L.) and hemp (Cannabis sativa L.) fibers into composites with polyethylene matrices. The applied fibers were obtained using osmotic, water-retting, and dew-retting processes. The study determined the impact of the fiber extraction [...] Read more.
This study presents the application of flax (Linum usitatissimum L.) and hemp (Cannabis sativa L.) fibers into composites with polyethylene matrices. The applied fibers were obtained using osmotic, water-retting, and dew-retting processes. The study determined the impact of the fiber extraction method on the properties of the composites obtained from natural filler and polyethylene matrix. These properties included color, tensile strength, thermal stability, adhesion of filler to the polymer, and flammability. It has been shown that the addition of flax and hemp fibers improves the mechanical properties of the composite compared to pure polymer. The tensile strength of the pure polymer samples was 24.64 MPa, while the tensile strength of composites reinforced with flax fibers ranged from 31.26 to 34.45 MPa, and those reinforced with hemp fibers ranged from 31.41 to 33.36 MPa. Studying the composites’ flammability showed that filling them with osmotic degummed hemp fibers reduced the maximum heat release rate by over 34% for hemp compared to pure polymer. This research shows that the composites filled with flax and hemp fibers, regardless of extraction method, are characterized by reduced flammability and improved mechanical properties compared to the pure polyethylene samples. Full article
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15 pages, 1066 KiB  
Article
Analysis and Numerical Simulation of the Behavior of Composite Materials with Natural Fibers Under Quasi-Static Frictional Contact
by Mirela Roxana Apsan, Ana Maria Mitu, Nicolae Pop, Tudor Sireteanu, Vicentiu Marius Maxim and Adrian Musat
J. Compos. Sci. 2025, 9(7), 338; https://doi.org/10.3390/jcs9070338 - 29 Jun 2025
Viewed by 378
Abstract
This paper analyzed the behavior of polymer composite materials reinforced with randomly oriented short natural fibers (hemp, flax, etc.) subjected to external stresses under quasistatic contact conditions with dry Coulomb friction. We presumed the composite body, a 2D flat rectangular plate, being in [...] Read more.
This paper analyzed the behavior of polymer composite materials reinforced with randomly oriented short natural fibers (hemp, flax, etc.) subjected to external stresses under quasistatic contact conditions with dry Coulomb friction. We presumed the composite body, a 2D flat rectangular plate, being in frictional contact with a rigid foundation for the quasistatic case. The manuscript proposes the finite element method approximation in space and the finite difference approximation in time. The problem of quasistatic frictional contact is described with a special finite element, which can analyze the state of the nodes in the contact area, and their modification, between open, sliding, and fixed contact states, in the analyzed time interval. This finite element also models the Coulomb friction law and controls the penetrability according to a power law. Moreover, the quasi-static case analyzed allows for the description of the load history using an incremental and iterative algorithm. The discrete problem will be a static and nonlinear one for each time increment, and in the case of sliding contact, the stiffness matrix becomes non-symmetric. The regularization of the non-differentiable term comes from the modulus of the normal contact stress, with a convex function and with the gradient in the sub-unit modulus. The non-penetration condition was achieved with the penalty method, and the linearization was conducted with the Newton–Raphson method. Full article
(This article belongs to the Special Issue Characterization and Modeling of Composites, 4th Edition)
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14 pages, 4406 KiB  
Article
Craftsmanship and Techniques of a Lacquered Ear Cup from the Ancient Nanyue Kingdom
by Lin Zheng, Xia Li, Zichen Zhao, Shuang’e Tian, Jianling Tang, Siming Li, Xiaocen Li, Na Wang and Tengfei Yu
Coatings 2025, 15(7), 752; https://doi.org/10.3390/coatings15070752 - 25 Jun 2025
Viewed by 408
Abstract
This study analyzes a lacquered ear cup excavated from the Luobowan tomb complex in Guigang, Guangxi, attributed to the Nanyue Kingdom of the early Han dynasty. A range of analytical techniques, including optical microscopy (OM), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), [...] Read more.
This study analyzes a lacquered ear cup excavated from the Luobowan tomb complex in Guigang, Guangxi, attributed to the Nanyue Kingdom of the early Han dynasty. A range of analytical techniques, including optical microscopy (OM), scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), pyrolysis–gas chromatography–mass spectrometry (Py-GC-MS), Fourier transform infrared spectroscopy (FT-IR), and X-ray diffraction (XRD), were employed to investigate the structural layers, material composition, and preservation state of the artifact. The lacquerware consists of four traditional layers: a wooden core, fabric reinforcement, lacquer ground, and lacquer film, reflecting Central Plains lacquerware techniques. The wooden core was identified as Phoebe sp., and the fabric layer is likely hemp, though fiber degradation limited exact identification. The lacquer ground layer contains natural lacquer mixed with SiO2 from brick or tile powder. The lacquer film is a blend of Chinese and Vietnamese lacquer, with no synthetic additives or plant oils detected. The red lacquer layer contains cinnabar (HgS) as a pigment, while the black lacquer uses carbon black. Differences in moisture content between the red and black lacquer films are attributed to variations in surface porosity and pigment characteristics. This research provides valuable insights into Nanyue lacquer technology and preservation challenges. Full article
(This article belongs to the Special Issue Research and Conservation of Ancient Lacquer)
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36 pages, 4774 KiB  
Review
Exploring the Role of Advanced Composites and Biocomposites in Agricultural Machinery and Equipment: Insights into Design, Performance, and Sustainability
by Ehsan Fartash Naeimi, Kemal Çağatay Selvi and Nicoleta Ungureanu
Polymers 2025, 17(12), 1691; https://doi.org/10.3390/polym17121691 - 18 Jun 2025
Viewed by 758
Abstract
The agricultural sector faces growing pressure to enhance productivity and sustainability, prompting innovation in machinery design. Traditional materials such as steel still dominate but are a cause of increased weight, soil compaction, increased fuel consumption, and corrosion. Composite materials—and, more specifically, fiber-reinforced polymers [...] Read more.
The agricultural sector faces growing pressure to enhance productivity and sustainability, prompting innovation in machinery design. Traditional materials such as steel still dominate but are a cause of increased weight, soil compaction, increased fuel consumption, and corrosion. Composite materials—and, more specifically, fiber-reinforced polymers (FRPs)—offer appealing alternatives due to their high specific strength and stiffness, corrosion resistance, and design flexibility. Meanwhile, increasing environmental awareness has triggered interest in biocomposites, which contain natural fibers (e.g., flax, hemp, straw) and/or bio-based resins (e.g., PLA, biopolyesters), aligned with circular economy principles. This review offers a comprehensive overview of synthetic composites and biocomposites for agricultural machinery and equipment (AME). It briefly presents their fundamental constituents—fibers, matrices, and fillers—and recapitulates relevant mechanical and environmental properties. Key manufacturing processes such as hand lay-up, compression molding, resin transfer molding (RTM), pultrusion, and injection molding are discussed in terms of their applicability, benefits, and limits for the manufacture of AME. Current applications in tractors, sprayers, harvesters, and planters are covered in the article, with advantages such as lightweighting, corrosion resistance, flexibility and sustainability. Challenges are also reviewed, including the cost, repairability of damage, and end-of-life (EoL) issues for composites and the moisture sensitivity, performance variation, and standardization for biocomposites. Finally, principal research needs are outlined, including material development, long-term performance testing, sustainable and scalable production, recycling, and the development of industry-specific standards. This synthesis is a practical guide for researchers, engineers, and manufacturers who want to introduce innovative material solutions for more efficient, longer lasting, and more sustainable agricultural machinery. Full article
(This article belongs to the Special Issue Biopolymers for Food Packaging and Agricultural Applications)
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21 pages, 3633 KiB  
Article
Enhancing Mechanical Properties of Hemp and Sisal Fiber-Reinforced Composites Through Alkali and Fungal Treatments for Sustainable Applications
by Rahul Kovuru and Jens Schuster
J. Manuf. Mater. Process. 2025, 9(6), 191; https://doi.org/10.3390/jmmp9060191 - 10 Jun 2025
Viewed by 738
Abstract
The growing demand for sustainable materials has driven interest in natural fiber-reinforced composites as eco-friendly alternatives to synthetic materials. This research investigates the fabrication and mechanical performance of hemp and sisal fiber-reinforced composites, with a focus on improving fiber–matrix bonding through alkali and [...] Read more.
The growing demand for sustainable materials has driven interest in natural fiber-reinforced composites as eco-friendly alternatives to synthetic materials. This research investigates the fabrication and mechanical performance of hemp and sisal fiber-reinforced composites, with a focus on improving fiber–matrix bonding through alkali and fungal treatments. Experimental results show that fungal treatment significantly improves tensile and flexural strength, while hardness slightly decreases. Water absorption tests revealed moderate reductions in hydrophilicity compared to untreated samples, although absolute water uptake remains higher than conventional glass/epoxy composites. Microscopy analysis further confirmed enhanced fiber adhesion and structural integrity in treated specimens. These findings suggest that hybrid composites reinforced with hemp and sisal, particularly with fungal treatment, hold promise for low-to-medium load sustainable applications in the automotive interiors, packaging, and construction industries, where moderate mechanical performance and partial biodegradability are acceptable. This research contributes to the advancement of bio-based composite materials while acknowledging current limitations in long-term durability and complete biodegradability. Full article
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13 pages, 3459 KiB  
Article
Incremental Forming of Natural Fiber-Reinforced Polypropylene Composites: Considerations on Formability Limits and Energy Consumption
by Antonio Formisano, Dario De Fazio, Giuseppe Irace and Massimo Durante
Materials 2025, 18(12), 2688; https://doi.org/10.3390/ma18122688 - 7 Jun 2025
Viewed by 483
Abstract
Incremental sheet forming originated as an excellent alternative to conventional forming techniques for incrementally deforming flat metal sheets into complex three-dimensional profiles. Recently, its use has been extended to polymers and composites. Among these, the use of natural fiber-reinforced composites is increasing considerably [...] Read more.
Incremental sheet forming originated as an excellent alternative to conventional forming techniques for incrementally deforming flat metal sheets into complex three-dimensional profiles. Recently, its use has been extended to polymers and composites. Among these, the use of natural fiber-reinforced composites is increasing considerably compared to synthetic fiber-reinforced composites, due to the availability and unique properties of natural fibers in polymer applications. One of the dominant thermoplastics used as a matrix is polypropylene. This experimental study focuses on the incremental forming of natural fiber-reinforced polypropylene composites. Cones and spherical caps were manufactured from composite laminates of polypropylene reinforced with hemp and flax long-fiber fabrics. The formability limits, observed through failures and defects, as well as the forming forces, power, and energy consumption, were investigated to examine the feasibility of incremental forming applied to these composite materials; based on the results obtained, it is possible to say that the process can manufacture components with not very high wall angles but under low load conditions and allowing to limit the energy impact. Full article
(This article belongs to the Special Issue Manufacturing and Recycling of Natural Fiber-Reinforced Composites)
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38 pages, 4607 KiB  
Review
Rubber-Based Sustainable Textiles and Potential Industrial Applications
by Bapan Adak, Upashana Chatterjee and Mangala Joshi
Textiles 2025, 5(2), 17; https://doi.org/10.3390/textiles5020017 - 8 May 2025
Viewed by 2200
Abstract
This review explores the evolving landscape of sustainable textile manufacturing, with a focus on rubber-based materials for various industrial applications. The textile and rubber industries are shifting towards eco-friendly practices, driven by environmental concerns and the need to reduce carbon footprints. The integration [...] Read more.
This review explores the evolving landscape of sustainable textile manufacturing, with a focus on rubber-based materials for various industrial applications. The textile and rubber industries are shifting towards eco-friendly practices, driven by environmental concerns and the need to reduce carbon footprints. The integration of sustainable textiles in rubber-based products, such as tires, conveyor belts, and defense products, is becoming increasingly prominent. This review discusses the adoption of natural fibers like flax, jute, and hemp, which offer biodegradability and improved mechanical properties. Additionally, it highlights sustainable elastomer sources, including natural rubber from Hevea brasiliensis and alternative plants like Guayule and Russian dandelion, as well as bio-based synthetic rubbers derived from terpenes and biomass. The review also covers sustainable additives, such as silica fillers, nanoclay, and bio-based plasticizers, which enhance performance while reducing environmental impact. Textile–rubber composites offer a cost-effective alternative to traditional fiber-reinforced polymers when high flexibility and impact resistance are needed. Rubber matrices enhance fatigue life under cyclic loading, and sustainable textiles like jute can reduce environmental impact. The manufacturing process involves rubber preparation, composite assembly, consolidation/curing, and post-processing, with precise control over temperature and pressure during curing being critical. These composites are versatile and robust, finding applications in tires, conveyor belts, insulation, and more. The review also highlights the advantages of textile–rubber composites, innovative recycling and upcycling initiatives, addressing current challenges and outlining future perspectives for achieving a circular economy in the textile and rubber sectors. Full article
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18 pages, 3364 KiB  
Article
Specificity of Thermal Destruction of Nonwoven Mixture Systems Based on Bast and Viscose Fibers
by Altynay S. Kalauova, Ekaterina E. Palchikova, Igor S. Makarov, Georgiy A. Shandryuk, Amangeldi I. Abilkhairov, Danagul Zh. Kalimanova, Meirbek Zh. Naukenov, Gulbarshin K. Shambilova, Egor M. Novikov, Junlong Song and Alexander G. Smyslov
Polymers 2025, 17(9), 1223; https://doi.org/10.3390/polym17091223 - 29 Apr 2025
Viewed by 529
Abstract
The research investigates the thermal behavior of mixed systems based on natural and artificial cellulose fibers used as precursors for carbon nonwoven materials. Flax and hemp fibers were employed as natural components; they were first chemically treated to remove impurities and enriched with [...] Read more.
The research investigates the thermal behavior of mixed systems based on natural and artificial cellulose fibers used as precursors for carbon nonwoven materials. Flax and hemp fibers were employed as natural components; they were first chemically treated to remove impurities and enriched with alpha-cellulose. The structure, chemical composition, and mechanical properties of both natural and viscose fibers were studied. It was shown that fiber properties depend on the fiber production process history; natural fibers are characterized by a high content of impurities and exhibit high strength characteristics, whereas viscose fibers have greater deformation properties. The thermal behavior of blended compositions was investigated using TGA and DSC methods across a wide range of component ratios. Carbon yield values at 1000 °C were found to be lower for blended systems containing 10–40% by weight of bast fibers, with carbon yield increasing as the quantity of natural fibers increased. Thus, the composition of the cellulose composite affects carbon yield and thermal processes in the system. Using the Kissinger method, data were obtained on the value of the activation energy of thermal decomposition for various cellulose and composite systems. It was found that natural fiber systems have three-times higher activation energy than viscose fiber systems, indicating their greater thermal stability. Blends of natural and artificial fibers combine the benefits of both precursors, enabling the deliberate regulation of thermal behavior and carbon material yield. This approach opens up prospects for the creation of functional carbon materials used in various high-tech areas, including thermal insulation. Full article
(This article belongs to the Special Issue Natural Fiber-Based Green Materials, Second Edition)
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23 pages, 7536 KiB  
Article
Development of Sustainable Polymer Composites Containing Waste Glass and Natural Fibers for Strengthening Purposes
by Cihan Karademir, Hasan Murat Tanarslan, Çağlar Yalçınkaya, Mustafa Furkan Güler, Hasan Ateş, Kutlay Sever, Yasemin Seki and Metehan Atagür
Polymers 2025, 17(8), 1116; https://doi.org/10.3390/polym17081116 - 20 Apr 2025
Cited by 1 | Viewed by 884
Abstract
This study investigates the development of sustainable polymer composites for structural strengthening by incorporating waste glass fibers and natural fibers (flax and hemp) into an epoxy matrix, in response to the growing environmental concerns. Mechanical, thermal, and durability-related properties were evaluated through tensile [...] Read more.
This study investigates the development of sustainable polymer composites for structural strengthening by incorporating waste glass fibers and natural fibers (flax and hemp) into an epoxy matrix, in response to the growing environmental concerns. Mechanical, thermal, and durability-related properties were evaluated through tensile testing, dynamic mechanical analysis (DMA), thermogravimetric analysis (TGA), water absorption, and water immersion aging tests. Results showed that incorporating waste glass fibers enhanced the tensile strength and thermal decomposition temperature by 88% and 5.4%, respectively, compared to composites reinforced with solely natural fibers. Water absorption tests indicated that waste glass fiber-reinforced hybrid composites exhibited lower water uptake than flax and hemp fiber-reinforced composites. After water immersion, the tensile strength loss was recorded as 22, 25, and 8.5% for the composites reinforced with hemp, flax, and waste glass fiber, respectively. The findings confirm that incorporating waste glass fibers into natural fiber composites effectively mitigates moisture sensitivity and improves mechanical performance. Hybridizing flax and hemp fibers with waste glass fibers provides a practical and sustainable approach to enhancing composite performance, making them a viable alternative for strengthening reinforced concrete structures requiring long-term resistance. The recycled waste glass fibers employed in this study offered comparable mechanical performance while drastically lowering raw material consumption and environmental impact, in contrast to virgin glass fibers frequently used in earlier investigations. This demonstrates how recycling-oriented composite design can provide both sustainability and performance benefits. Full article
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23 pages, 6802 KiB  
Article
Thermal Comfort Properties of Biodegradable Hemp and Polylactide Fiber Knitted Fabrics
by Ingrida Padleckienė, Laimutė Stygienė, Sigitas Krauledas, Aušra Abraitienė and Audronė Sankauskaitė
Polymers 2025, 17(7), 903; https://doi.org/10.3390/polym17070903 - 27 Mar 2025
Viewed by 837
Abstract
According to the global strategy of Green course, the production of sustainable textiles using different biodegradable fibres has immense potential for the development of sustainable products. Using one of the most sustainable biobased pure hemp and polylactide fibers yarns, four new biodegradable three-layer [...] Read more.
According to the global strategy of Green course, the production of sustainable textiles using different biodegradable fibres has immense potential for the development of sustainable products. Using one of the most sustainable biobased pure hemp and polylactide fibers yarns, four new biodegradable three-layer weft knitted fabrics with good thermal comfort properties were developed. The inner layer (worn next to the skin) and the middle layer of the knits were formed of hydrophobic polylactide fibers, the outer layer of different amounts (36–55%) of hydrophilic natural hemp fibers. Biodegradable polylactide fiber yarns were used as a replacement for conventional petroleum-based synthetic fibers. Natural hemp fibers are one of the most sustainable fibers derived directly from Cannabis sativa L. plants. The properties of the knitted fabrics were analysed and compared under thermoregulatory-moisture management, thermal resistance, air and water vapour permeability-properties. The results showed that all newly developed knits are ascribed to ‘moisture management’ fabrics according to the summary grading of all indices of moisture management parameters. In addition, it was found that the highest overall moisture management capability is related to the quantity of natural hemp fiber composition in different knitting structures. Based on the overall moisture management capacity (OMMC) index and thermal resistance values of developed knitted fabrics, the performance levels for these materials contacting the skin and intended for the intermediate layer were determined. Full article
(This article belongs to the Section Biobased and Biodegradable Polymers)
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11 pages, 2912 KiB  
Article
Bacterial-Retted Hemp Fiber/PLA Composites
by Lee M. Smith, Yu Fu, Raj Kumar Pittala, Xun Wang, Chloe Jabel, Kelvin Masignag, Josue Arellanes, Mahan Ghosh, Sheldon Q. Shi, Melanie Ecker and Cuicui Wang
Processes 2025, 13(4), 1000; https://doi.org/10.3390/pr13041000 - 27 Mar 2025
Cited by 1 | Viewed by 687
Abstract
The push for sustainability in all facets of manufacturing has led to an increased interest in biomass as an alternative to non-renewable materials. Hemp bast fiber mats were produced from a bacterial retting process, named BFM, as the fiber reinforcement. The objective of [...] Read more.
The push for sustainability in all facets of manufacturing has led to an increased interest in biomass as an alternative to non-renewable materials. Hemp bast fiber mats were produced from a bacterial retting process, named BFM, as the fiber reinforcement. The objective of this study was to evaluate the feasibility of laminating BFM with polylactic acid (PLA) for a composite panel product. Since both BFM and PLA are biodegradable, the resulting BFM-PLA composites will be 100% biodegradable. PLA pallets were processed into thin polymer sheets which served as the matrix. The BFM and PLA plates were laminated in five layers and compression-molded into composite panels. Experiments were conducted on the three BFM-to-PLA ratios (35/65, 45/55, and 50/50). Mechanical properties (tensile and bending properties) and physical properties (thickness swell and water absorption) were tested and compared to the currently commercial sheet molding compound (SMC) from fiber glass. The thermal behavior of the BFM/PLA composites was characterized using dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC). The developed BFM/PLA composite product is a sustainable alternative to existing synthetical fiber-reinforced polymer (FRP) that is biodegradable in landfill at the end of life. Full article
(This article belongs to the Special Issue Bioprocess Engineering: Sustainable Manufacturing for a Green Society)
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26 pages, 7065 KiB  
Article
Influence of Alkaline Treatment and Fiber Morphology on the Mechanical, Physical, and Thermal Properties of Polypropylene and Polylactic Acid Biocomposites Reinforced with Kenaf, Bagasse, Hemp Fibers and Softwood
by Zeinab Osman, Mohammed Elamin, Elhem Ghorbel and Bertrand Charrier
Polymers 2025, 17(7), 844; https://doi.org/10.3390/polym17070844 - 21 Mar 2025
Viewed by 1029
Abstract
This novel study explores a comprehensive approach, combining fiber and matrix structure–property relationships. By integrating alkali treatment, fiber mapping, and intrinsic fiber properties, this work offers a unique perspective on the mechanical, physical, and thermal properties of biodegradable composites of reinforced polypropylene (PP) [...] Read more.
This novel study explores a comprehensive approach, combining fiber and matrix structure–property relationships. By integrating alkali treatment, fiber mapping, and intrinsic fiber properties, this work offers a unique perspective on the mechanical, physical, and thermal properties of biodegradable composites of reinforced polypropylene (PP) and plasticized poly (lactic acid) (PLA), with 25 wt% Kenaf (KBF), Bagasse, Hemp fibers and softwood fibers serving as a control. To enhance fiber–matrix interaction, fibers underwent alkaline treatment using 5% sodium hydroxide (NaOH) for one hour. The mechanical properties, including tensile strength, Young’s modulus, and impact strength, were evaluated alongside physical and thermal properties such as fiber mapping, brightness, heat deflection temperature (HDT), melting temperature, melt flow ratio (MFR), and melt flow index (MFI). Scanning electron microscopy (SEM) was used to assess the biocomposites’ morphology. The results showed that fiber reinforcement improved the tensile and impact strength of PP composites, particularly for treated Bagasse (6.6% and 22%) and Hemp (7% and 44.7%), while Kenaf exhibited minimal change, indicating its inherently high strength. A slight increase in tensile strength and Young’s modulus was observed in all PLA-based composites. The addition of 25% fiber enhanced the thermal properties of both treated and untreated fiber-reinforced composites. Among PP composites, those reinforced with treated fibers exhibited the highest HDT, with Kenaf achieving the best performance (124 °C), followed by Bagasse (93 °C). The HDT values for untreated fibers were 119 °C for KBF, 100 °C for softwood, 86 °C for Bagasse, and 79 °C for Hemp. PLA composites showed a slight increase in HDT with fiber reinforcement. Differential Scanning Calorimetry (DSC) revealed a slight decrease in melting temperature for PP composites and a slight increase for PLA composites. Fiber mapping analysis indicated that Kenaf had the highest aspect ratio, contributing to superior mechanical performance, while Hemp had the lowest aspect ratio and exhibited weaker mechanical properties. Overall, Kenaf and Bagasse fibers demonstrated superior mechanical and thermal properties, comparable to those of softwood fibers, whereas Hemp exhibited moderate performance. The variations in composites behavior were attributed to differences in fiber mapping, alkaline treatment, and the intrinsic properties of both the polymer matrices and the reinforcing fibers. These findings highlight the potential of treated natural fibers, particularly Kenaf and Bagasse, in enhancing the mechanical and thermal properties of biodegradable composites, reinforcing their suitability for sustainable material applications. Full article
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