Search Results (383)

The global energy transition and increasingly rigorous legal regulations aimed at climate protection are driving the search for alternative energy sources, including renewable energy sources (RESs) and waste heat. However, the mismatch between supply and demand presents a significant challenge. Thermal energy storage (TES) technologies, particularly mobile thermal energy storage (M-TES), offer a potential solution to address this gap. M-TES can not only balance supply and demand but also facilitate the transportation of heat from the source to the recipient. This paper reviews the current state of M-TES technologies, focusing on their technology readiness level, key operating parameters, and advantages and disadvantages. It is found that M-TES can be based on sensible heat, latent heat, or thermochemical reactions, with the majority of research and projects centered around latent heat storage. Regarding the type of research, significant progress has been made at the laboratory and simulation levels, while real-world implementation remains limited, with few pilot projects and commercially available systems. Despite the limited number of real-world M-TES implementations, currently existing M-TES systems can store up to 5.4 MWh in temperatures ranging from 58 °C to as high as 1300 °C. These findings highlight the potential of the M-TES and offer data for technology selection, simultaneously indicating the research gaps and future research directions. Full article

This study investigates the thermal stability and microstructural evolution of the solid electrolyte medium used in DLyte^® dry electropolishing and dry anodizing processes. Samples were thermally aged between 30 °C and 45 °C to simulate Joule heating during industrial operation. Visual and SEM analyses revealed shape deformation and microcrack formation at temperatures above 40 °C, potentially reducing particle packing efficiency and electrolyte performance. Particle size distribution shifted from bimodal to trimodal upon aging, with an overall size reduction of up to 39.5% due to dehydration effects, impacting ionic transport properties. Weight-loss measurements indicated a diffusion-limited dehydration mechanism, stabilizing at 15–16% mass loss. Fourier transform infrared analysis confirmed water removal while maintaining the essential sulfonic acid groups responsible for ionic conductivity. In dry anodizing tests on titanium, aged electrolytes enhanced process efficiency, producing TiO₂ films with improved optical properties—color and brightness—while preserving thickness and uniformity (~70 nm). The results highlight the need to carefully control thermal exposure to maintain electrolyte integrity and ensure consistent process performance. Full article

Thermoplastic polyurethane (TPU) electrospun fiber membranes possess unique micro-nano structures and excellent properties. Adjusting their wettability enables the directional transportation of lubricants. A conventional method for adjusting porosity and wettability involves inducing membrane shrinkage using absolute ethanol and heat treatment. However, the shrinkage response and the corresponding changes in the tensile properties of TPU fiber membranes after induction remain unclear, limiting their applications. Thus, in this study, after being peeled off, the samples were first left to stand at room temperature (RT) for 24 h to release residual stress and stabilize their dimensions, and then treated with dehydrated ethanol at RT and high temperature, respectively, with their shrinkage behaviors observed and recorded. The results showed that TPU nanofiber membranes shrank significantly in absolute ethanol, and the degree of shrinkage was temperature-dependent. The shrinkage rates were 2% and 4% in dehydrated ethanol at room temperature and high temperature, respectively, and heating increased the shrinkage effect by 200%. These findings prove that absolute ethanol causes TPU fibers to shrink, and high temperatures further promote shrinkage. However, although the strong synergistic effect of heat and solvent accelerates shrinkage, it may induce internal structural defects, resulting in the deterioration of mechanical properties. The contraction response induced by anhydrous ethanol stimulation can be used to directionally adjust the local density and modulus of TPU nanofiber membranes, thereby changing the wettability. This approach provides new opportunities for applications in areas such as medium transportation and interface friction reduction in lubrication systems. Full article

Mesoscale coastal eddies are key components of ocean circulation, mediating the transport of heat, nutrients, and marine debris. The Surface Water and Ocean Topography (SWOT) mission provides high-resolution sea surface height data, offering a novel opportunity to improve the observation and characterization of these features, especially in coastal regions where conventional altimetry is limited. In this study, we investigate a mesoscale anticyclonic coastal eddy observed southwest of Mallorca Island, in the Balearic Sea, to assess the impact of SWOT-enhanced altimetry in resolving its structure and dynamics. Initial eddy identification is performed using satellite ocean color imagery, followed by a qualitative and quantitative comparison of multiple altimetric datasets, ranging from conventional nadir altimetry to wide-swath products derived from SWOT. We analyze multiple altimetric variables—Sea Level Anomaly, Absolute Dynamic Topography, Velocity Magnitude, Eddy Kinetic Energy, and Relative Vorticity—highlighting substantial differences in spatial detail and intensity. Our results show that SWOT-enhanced observations significantly improve the spatial characterization and dynamical depiction of the eddy. Furthermore, Lagrangian transport simulations reveal how altimetric resolution influences modeled transport pathways and retention patterns. These findings underline the critical role of SWOT in advancing the monitoring of coastal mesoscale processes and improving our ability to model oceanic transport mechanisms. Full article

The thermal properties and flammability of rigid polyurethane foams (RPUFs) containing various flame retardants, including solid (melamine, expanded graphite (EG), Exolit OP 935, ammonium polyphosphate (APP)) and liquid (Roflam B7, Roflam PLO) types, added at 30 wt.% and 60 wt.% by weight have been evaluated. Thermogravimetric analysis (TGA) demonstrated enhanced thermal stability, with the maximum 10% weight loss temperature (292 °C, +34 °C vs. reference) observed for foams containing 60 wt.% Exolit OP 935 and APP. The limiting oxygen index (LOI) test demonstrated the optimal performance for 30 wt.% APP and melamine (26.4 vol.% vs. 18.7 vol.% reference). In the UL-94 test, Exolit OP 935 and APP achieved a V-0 rating. The 60 wt.% Exolit with an EG blend also demonstrated a substantial reduction in heat release rate. These findings underscore the cooperative effects of hybrid flame retardants, thereby supporting their utilization in fire-safe RPUFs for construction and transport. Full article

Diamond is an attractive substrate candidate for GaN high-electron-mobility transistors (HEMT) to enhance heat dissipation due to its exceptional thermal conductivity. However, the thermal boundary resistance (TBR) at the GaN–diamond interface poses a significant bottleneck to heat transport, exacerbating self-heating and limiting device performance. In this work, TCAD simulations were employed to systematically investigate the effects of thermal boundary layer (TBL) thickness (d_TBL) and thermal conductivity (κ_TBL) on the electrothermal behavior of GaN-on-diamond HEMTs. Results show that increasing the TBL thickness (5–20 nm) or decreasing its thermal conductivity (0.1–1.0 W/(m·K)) leads to elevated hotspot temperatures and degraded electron mobility, resulting in a notable deterioration of I–V characteristics. The nonlinear dependence of device performance on κ_TBL is attributed to Fourier’s law, where heat flux is inversely proportional to thermal resistance. Furthermore, the co-analysis of substrate thermal conductivity and interfacial quality reveals that interface TBR has a more dominant impact on device behavior than substrate conductivity. Remarkably, devices with low thermal conductivity substrates and optimized interfaces can outperform those with high-conductivity substrates but poor interfacial conditions. These findings underscore the critical importance of interface engineering in thermal management of GaN–diamond HEMTs and provide a theoretical foundation for future work on phonon transport and defect-controlled thermal interfaces. Full article

Thermally conductive polymer composites are essential for effective heat dissipation in electronic packaging, where both thermal management and mechanical reliability are critical. Although diglycidyl ether of bisphenol-A (DGEBA)-based epoxies exhibit favorable properties, their intrinsically low thermal conductivity limits broader applications. Incorporating conductive fillers, such as expanded graphite (EG) and metal powders, enhances heat transport but often compromises mechanical strength due to poor filler–matrix compatibility. In this study, we address this trade-off by employing a titanate coupling agent to surface-modify aluminum (Al) fillers, thereby improving interfacial adhesion and dispersion within the DGEBA matrix. Our results show that incorporating 10 wt% untreated Al increases thermal conductivity from 7.35 to 9.60 W/m·K; however, this gain comes at the cost of flexural strength, which drops to 18.29 MPa. In contrast, titanate-modified Al (Ti@Al) not only preserves high thermal conductivity but also restores mechanical performance, achieving a flexural strength of 35.31 MPa (at 5 wt% Ti@Al) and increasing impact strength from 0.60 to 1.01 kJ/m². These findings demonstrate that interfacial engineering via titanate coupling offers a compelling strategy to overcome the thermal–mechanical trade-off in hybrid composites, enabling the development of high-performance materials for advanced thermal interface and structural applications. Full article

Under the accelerating global energy restructuring and the deepening carbon neutrality strategy, hydrogen energy has emerged with increasing strategic value as a zero-carbon secondary energy carrier. Water electrolysis technology based on renewable energy is regarded as an ideal pathway for large-scale green hydrogen production. However, polymer electrolyte membrane (PEM) conventional water electrolysis faces dual constraints in economic feasibility and scalability due to its high electrical energy consumption and reliance on noble metal catalysts. The mixed ionic-electronic conducting oxygen transport membrane (MIEC–OTM) reactor technology offers an innovative solution to this energy efficiency-cost paradox due to its thermo-electrochemical synergistic energy conversion mechanism and process integration. This not only overcomes the thermodynamic equilibrium limitations in traditional electrolysis but also reduces electrical energy demand by effectively coupling with medium- to high-temperature heat sources such as industrial waste heat and solar thermal energy. Therefore, this review, grounded in the physicochemical mechanisms of oxygen transport membrane reactors, systematically examines the influence of key factors, including membrane material design, catalytic interface optimization, and parameter synergy, on hydrogen production efficiency. Furthermore, it proposes a roadmap and breakthrough directions for industrial applications, focusing on enhancing intrinsic material stability, designing multi-field coupled reactors, and optimizing system energy efficiency. Full article

The dynamics of large lake circulations are strongly modulated by wind forcing, thermal gradients, and shoreline topography, yet their integrated effects remain insufficiently quantified. To address this, numerical simulations were conducted in Lake Biwa to clarify the mechanisms underlying wind- and thermally driven gyres, with a focus on the influence of bathymetric asymmetry. In wind-driven cases, zonal and meridional wind stress gradients were imposed, revealing that cyclonic wind shear generated strong surface vorticity (up to 2.0 × 10⁻⁶ s⁻¹) in regions with gently sloped shores, while steep slopes suppressed anticyclonic responses. Cyclonic forcing induced upwelling in the lake center, with baroclinic return flows stabilizing the vertical circulation structure. In windless thermal experiments, surface temperature gradients of ±2.5 °C were applied to simulate seasonal heating and cooling. Cyclonic circulation predominated in warm seasons due to convergence and heat accumulation along gently sloping shores, whereas winter cooling produced divergent flows and anticyclonic gyres. The southern and eastern lake margins, characterized by mild slopes, consistently enhanced convergence and vertical mixing, while steep western and northern slopes limited circulation intensity. These results demonstrate that shoreline slope asymmetry plays a decisive role in regulating both wind- and thermally induced circulations, offering insights into physical controls on transport and stratification in enclosed lake systems. Full article

An analysis is presented of the irreversibility of flow and thermal phenomena in innovative streamlined structured packing of catalytic chemical reactors. The fundamental equations of irreversible thermodynamics defining entropy production as a result of flow friction and heat transport are formulated. The parameters describing the flow and heat transport in these equations are determined using the Computational Fluid Dynamics (CFD) methodology. Local entropy production due to flow friction and heat transport in the channel structure is plotted and compared with flow-temperature maps and relations for flow resistance, pressure gradient, and Nusselt number derived from CFD. The calculations were performed for three gas velocities: 0.3; 2.0, and 6.0 ms⁻¹. It was found that the entropy due to flow friction increases strongly with increasing gas velocity, while the entropy due to heat transport decreases with gas velocity, but to a limited extent. These opposing tendencies mean that there is always a minimum of the total entropy production (including these due to flow friction and heat transport), usually for moderate gas velocity. This minimum constitutes the optimum operating point of the reactor from the thermodynamic point of view. Full article

This paper addresses the critical need for detailed electricity and peak power demand maps for urban public transportation vehicles. Current approaches often rely on overly general assumptions, leading to considerable errors in specific applications or, conversely, overly specific measurements that limit generalisability. We aim to present a comprehensive data-driven methodology for analysing energy consumption within a large urban agglomeration. The method leverages a unique and extensive set of real-world performance data, collected over two years from onboard recorders on all public bus lines in the Capital City of Warsaw. This large dataset enables a robust probabilistic analysis, ensuring high accuracy of the results. For this study, three representative bus lines were selected. The approach involves isolating inter-stop trips, for which instantaneous power waveforms and energy consumption are determined using classical mathematical models of vehicle drive systems. The extracted data for these sections is then characterised using probability distributions. This methodology provides accurate calculation results for specific operating conditions and allows for generalisation with additional factors like air conditioning or heating. The direct result of this paper is a detailed urban map of energy demand and peak power for public transport vehicles. Such a map is invaluable for planning new traffic routes, verifying existing ones regarding energy consumption, and providing a reliable input source for strategic charger deployment analysis along the route. Full article

The global market for flame-retardant materials is expected to grow steadily, from USD 7.0 billion in 2022 to USD 16.6 billion in 2030, driven by increasing demand for environment-friendly fire safety solutions in transportation, construction, and electronics. Polylactic acid (PLA), a biodegradable polymer which possesses excellent mechanical properties, is increasingly being considered for future mobility applications. However, it is characterized by high heat release and toxic smoke during combustion, which are significant drawbacks. In order to address this, the chemical modification of Kraft lignin was achieved through a phenolation and subsequent silylation with tetraethoxysilane, aiming to mitigate the degradation of PLA’s mechanical properties while utilizing its inherent char-forming ability. The modified lignins were combined with ammonium polyphosphate (APP) and melt-mixed with PLA using an injection-mixing molder to prepare test specimens. Analysis by FT-IR, NMR spectroscopy, and SEM-EDS confirmed successful grafting of phenolic and silane functionalities, and thermogravimetric analysis demonstrated enhanced thermal stability of the modified lignins compared to unmodified ones. Vertical burning tests and limiting oxygen index (LOI) measurements showed that the PLA/APP/SPKL composite material achieved a V-0 UL-94 rating and 31.95% LOI, demonstrating the highest level of flame retardancy. This compares to the LOI of neat PLA, 19 to 21%. Despite the enhancement in flame retardancy to the V-0 level, the decline in tensile strength was limited, and the composite retained comparable mechanical strength to PLA-APP composites with V-2 flame retardancy. The findings indicate that the combination of phenolation and silylation of lignin with APP, a flame-retardant material, offers a viable and sustainable methodology for the fabrication of PLA composites that exhibit both flame retardancy and mechanical strength. Full article

This review examines the pharmaceutical applications of essential oils (EOs) and terpenes, highlighting their dual role as therapeutic agents and natural penetration enhancers. These volatile, hydrophobic compounds have well-documented antimicrobial, antioxidant, and anti-inflammatory properties. However, their clinical potential is limited by poor water solubility, high volatility, and sensitivity to environmental factors, including light, heat, and oxygen. To address these challenges, various advanced delivery systems have been developed to enhance stability, bioavailability, and controlled release. These systems not only protect chemical integrity but also exploit these compounds’ abilities to interact with lipid membranes, facilitating the transport of active compounds across biological barriers. Additionally, their inherent antimicrobial properties can contribute to the overall stability of formulations. The review critically examines the incorporation of terpenes and major essential oil (EO) components, such as limonene, linalool, eugenol, α-pinene, and menthol, into delivery systems, assessing their performance in enhancing drug permeability and targeting specific tissues. Current challenges and future directions in terpenes and EO-based delivery strategies are discussed, highlighting their promising role in developing multifunctional and efficient pharmaceutical formulations. Full article

Local temperature measurement is crucial for understanding nanoscale thermal transport and developing nanodevices for biomedical, photonic, and optoelectronic applications. The rise of photothermal therapy for cancer treatment has increased the demand for high-resolution nanothermometric techniques capable of non-contact intracellular temperature measurement and modification. Raman spectroscopy meets this need: the ratio of anti-Stokes to Stokes Raman intensities for a specific vibrational mode correlates with local temperature through the Boltzmann distribution. The present study proposes a novel photothermal therapy agent designed to advance the current state of the art while adhering to green chemistry principles, thereby favoring low-temperature synthesis involving limited energy consumption. A key challenge in this field is to achieve close contact between plasmonic nanosystems, which act as nanoheaters, and local temperature sensors. This is achieved by employing silver nanoparticles as a heat release agent, coated with anatase-phase titanium dioxide, as a local temperature sensor. The proposed synthesis, which combines refluxing and subcritical solvothermal treatments, enables direct anatase formation, despite its metastability under standard conditions, thus eliminating the need for a calcination step. Structural characterization through SAED-HRTEM and Raman spectroscopy confirms the successful crystallization of the desired phase. Moreover, the nanothermometry measurements conducted at various wavelengths ultimately demonstrate both the effectiveness of these nanomaterials as thermometric probes, with a relative sensitivity of about 0.24 K⁻¹%, and their capability as local heaters, with a release of a few tens of degrees. This work demonstrates a new synthetic strategy for these nanocomposites, which offers a promising pathway for the optimization of nanosystems in therapeutic applications. Full article

As the attention to using hydrogen as a potential energy storage medium for power generation and mobility increases, hydrogen production, storage, and transportation safety should be considered. For instance, hydrogen’s extreme physical and chemical properties and the wide range of flammable concentrations raise many concerns about the current safety measures in processing other flammable gases. Hydrogen cloud accumulation in the case of leakage in confined spaces can lead to reaching the hydrogen lower flammability limit (LFL) within seconds if the hydrogen is not properly evacuated from the space. At Jülich Research Centre, hydrogen mixed with natural gas is foreseen to be used as a fuel for the central heating system of the campus. In this work, the release, dispersion, formation, and spread of the hydrogen cloud in the case of hydrogen leakage inside the central utility building of the campus are numerically simulated using the OpenFOAM-based containmentFOAM CFD codes. Additionally, different ventilation scenarios are simulated to investigate the behavior of the hydrogen cloud. The results show that locating exhaust openings close to the ceiling and the potential leakage source can be the most effective way to safely evacuate hydrogen from the building. Additionally, locating the exhaust outlets near the ceiling can decrease the combustible cloud volume by more than 25% compared to side openings far below the ceiling. Also, hydrogen concentrations can reach the LFL in case of improper forced ventilation after only 8 s, while it does not exceed 0.15% in the case of natural ventilation under certain conditions. The results of this work show the significant effect of locating exhaust outlets near the ceiling and the importance of natural ventilation to mitigate the effects of hydrogen leakage. The approach illustrated in this study can be used to study hydrogen dispersion in closed buildings in case of leakage and the proper design of the ventilation outlets for closed spaces with hydrogen systems. Full article