Search Results (319)

The poor moisture resistance of gypsum remains one of the main factors limiting its wider application in construction. This study investigates a novel approach to improving the moisture resistance of gypsum through the addition of soluble salts capable of reacting with dissolved calcium sulfate to form insoluble products within the gypsum matrix. The formation of insoluble reaction products was considered as one of the possible mechanisms contributing to this effect. Three salts were examined—trisodium phosphate dodecahydrate (TSP), potassium sodium tartrate tetrahydrate (PS), and sodium oxalate (SO)—each added at 2 wt.% of gypsum mass. The influence of the salts on phase composition, microstructure, setting behavior, density, porosity, mechanical properties, and water-vapor transport was evaluated. The reference gypsum exhibited compressive strengths of 5.18 MPa and 0.79 MPa and flexural strengths of 3.01 MPa and 0.57 MPa after storage in laboratory conditions and water, respectively. The results showed that salt chemistry strongly affected gypsum performance. TSP significantly altered crystal morphology, accelerated the initial setting time from 16.0 min to approximately 4.0 min, and delayed the final setting to the third day after mixing. Consequently, TSP exhibited the poorest mechanical performance, with compressive strengths of 2.77 MPa and 0.09 MPa and flexural strengths of 2.03 MPa and 0.27 MPa in dry and wet conditions, respectively. In contrast, the organic salts PS and SO preserved a gypsum crystal network similar to that of the reference material. PS achieved compressive strengths of 4.89 MPa and 0.79 MPa and flexural strengths of 2.84 MPa and 0.67 MPa, while SO reached 4.43 MPa and 0.34 MPa in compression and 2.59 MPa and 0.55 MPa in flexure. Moreover, PS and SO improved the flexural softening coefficient by 24% and 11%, respectively, whereas TSP reduced it by approximately 30%. Total porosity ranged from 53 to 61% for specimens stored in laboratory conditions and decreased to 35–39% after water storage. Water-vapor diffusion resistance was affected only marginally, and the vapor-open character typical of gypsum materials was preserved. Among the investigated admixtures, potassium sodium tartrate exhibited the most promising overall performance, maintaining compressive strength after water exposure at the same level as the reference gypsum while improving moisture resistance. The results indicate that the selected organic salts represent a promising route for improving the moisture resistance of gypsum-based materials. However, the present results suggest that the observed improvement cannot be attributed solely to the formation of insoluble reaction products, and further research is required to clarify the relative contribution of the underlying mechanisms. Full article

Phosphogypsum (PG) is the main by-product of the wet processing of phosphate rock for phosphoric acid production and is generated worldwide in hundreds of millions of tons per year. With an increasing demand for gypsum-based materials for industrial and agricultural applications and the predictable gypsum shortage in the coming years, PG can be considered a valuable replacement. However, the presence of fluorine in PG can limit its use, given the negative effects it can have on human health and the environment. In this work, it is presented a new methodology which determines with high sensitivity the fluorine concentrations in PG by a combination of Ion Beam Analytical (IBA) techniques, with a focus on PIGE (Particle Induced $\gamma$-ray Emission). Seventeen PG samples were analyzed, fifteen of which originated from processing experiments. Fluorine was detected in concentrations ranging from 0.003 to 0.691 wt.%. The upper end of this range is comparable to or higher than typical values reported for PG and may require treatment depending on the intended end use and environmental compliance criteria. Full article

This study presents a data-driven evaluation of recycled-aggregate gypsum composites by examining the relationships between dry density, mechanical performance, thermal conductivity, and formaldehyde adsorption. Analysis of published experimental data shows that dry density is the primary parameter governing overall material performance. Compressive strength increases with density, whereas lower-density composites provide superior thermal insulation. An optimal multifunctional performance range was identified at 900–1100 kg/m³, where a favorable balance between strength and insulation efficiency is achieved. Aggregate type also influences performance: polymer-based aggregates produce the greatest density reduction, biomass-derived aggregates offer a balanced combination of properties, and mineral-based aggregates generally maintain higher stiffness. Assessment of environmental functionality indicates that conventional gypsum composites possess limited formaldehyde and CO₂ adsorption capacity, although biochar and other bio-based modifications can significantly enhance adsorption performance. These findings provide a practical framework for designing sustainable gypsum composites with balanced structural, thermal, and indoor air quality benefits. Full article

To comparatively evaluate the shear behavior of controlled low-strength materials (CLSM) prepared from different local soil sources, three representative soils from the Yellow River alluvial plain, namely, silt, silty clay, and sand, were used to prepare CLSM with a cement–slag–fly ash–gypsum blended cementitious binder. Triaxial shear tests and scanning electron microscopy (SEM) observations were conducted to compare the failure modes, stress–strain responses, strength characteristics, and hardened microstructures of the three CLSM types under different binder contents and confining pressures. The specimens generally exhibited inclined shear planes, conjugate shear planes, vertical cracks, and plastic bulging. Their stress–strain responses could generally be divided into four stages: linear elastic deformation, plastic yielding, strain softening, and residual stabilization. Within the tested binder-content ranges, the peak strength generally followed the order of sand-based CLSM > silt-based CLSM > silty clay-based CLSM. On average, the residual strength retained approximately 75% of the peak strength. The failure stress states of the tested CLSM could be reasonably represented by the Mohr–Coulomb criterion within the investigated confining-pressure range, and preliminary empirical relationships were established within the tested ranges to estimate peak strength, residual strength, and shear strength parameters. SEM observations suggested that C–S–H-like gel and needle-like products appeared to fill pores and form cemented connections between soil particles, providing a possible qualitative interpretation of the macroscopic strength differences among the three CLSM types. These findings provide a basis for shear strength evaluation and the mix design of CLSM prepared from Yellow River alluvial soils. Full article

Low-frequency impact sound control remains a critical challenge for floating floor systems. Conventional resilient underlayment materials exhibit insufficient damping and are prone to long-term deformation, making stable low-frequency sound insulation difficult to achieve. This study presents the development of a composite floating floor underlayment comprising recycled rubber granules, polymer resin, and quartz sand. Based on the constrained layer damping-inspired (CLD-inspired) perspective, the vibration attenuation and noise reduction mechanism is elucidated, and the material’s physical properties, mechanical behavior, microstructure, and acoustic performance are systematically investigated. The results indicate that excessively large rubber granules aggravate curing shrinkage cracking. Optimal processing characteristics are achieved with a binder content of 20 wt% and a rubber granule size of 50 mesh. Laboratory characterization reveals that, compared with conventional cross-linked polyethylene (XLPE) foam underlayments, the proposed composite underlayment reduces the impact sound pressure level by an average of 3–5 dB in the low-frequency band below 250 Hz, and the overall sound insulation performance is improved by 10.77%. Dynamic mechanical analysis shows the composite storage modulus declines from 280 MPa at −20 °C to 10 MPa at 80 °C, while the loss factor remains above 0.2 under typical indoor conditions. Such stable viscoelastic behavior enables efficient shear dissipation of low-frequency vibration energy under the CLD-inspired mechanism. Full-scale field testing combined with long-term observation over 3000 loading cycles demonstrates excellent structural compatibility between the underlayment and the gypsum screed, with no cracking or appreciable deformation observed during prolonged service. The weighted impact sound improvement index (ΔLw) attains 15 dB. These findings verify that the CLD-inspired composite underlayment simultaneously achieves efficient low-frequency impact sound control and superior long-term structural stability, providing an innovative material solution and design strategy for impact noise mitigation in residential floating floor applications. Full article

The transition towards carbon-neutral construction materials requires innovative solutions that combine reduced embodied energy, enhanced durability and improved building energy efficiency. This study investigates and compares two novel bioaerated low-density composites—BAAC and BIOAERMAC—developed through biologically driven aeration processes incorporating industrial byproducts. BAAC is produced using Saccharomyces cerevisiae and hydrogen peroxide, replacing conventional aluminum powder and improving safety while enabling the valorization of waste-derived yeast. BIOAERMAC is a gypsum-based composite incorporating synthetic anhydrite, microorganisms, peroxides, and recycled rubber from end-of-life tires. The materials were characterized in terms of hygrothermal behavior and dimensional stability, and compared with commercial autoclaved aerated concrete under equivalent mechanical strength conditions. The results highlight significant differences in moisture transport and shrinkage, primarily governed by pore structure and connectivity. BAAC exhibits behavior comparable to conventional AAC, whereas BIOAERMAC shows reduced capillary and hygroscopic absorption, indicating limited pore connectivity, but higher drying shrinkage. These findings demonstrate the effectiveness of bioaeration in tailoring pore structure and controlling the trade-off between moisture transport, durability, and dimensional stability, highlighting the potential of bioaerated composites for low-carbon and energy-efficient building applications. Full article

This study aims to enhance the hydration performance and mechanical strength of steel slag-based cementitious materials via the synergistic activation of Na₂SiO₃ and triethanolamine (TEA), solving the early-age hydration and low reactivity of steel slag. The mix is 32% steel slag (SS), 43% blast furnace slag (BFS), 12% desulfurized gypsum (DG), and 13% ordinary Portland cement (OPC). The full factorial design uses Na₂SiO₃ (4–6%) and TEA (0.03–0.08%) as composite activators. Mortar specimens were tested for compressive and flexural strengths at 3d, 7d, 10d, and 28d. XRD, SEM, FTIR, and TG revealed the hydration mechanism and microstructure evolution. The results show an optimal dosage of 5% Na₂SiO₃ and 0.05% TEA increasing compressive strengths at 3d and 28d by 43.10% and 22.09%, respectively, compared with the control group. This synergy improves matrix compactness, supporting the high-value utilization of steel slag and development of steel slag-based cementitious materials. Full article

Partially replacing cement with mine tailings offers a sustainable strategy for solid waste resource utilization. As a cement admixture, the compressive strength of tailings-based cement materials serves as a critical performance indicator. Machine learning (ML) techniques offer high efficiency, cost-effectiveness, and superior predictive accuracy. However, variations in the chemical composition of tailings often introduce uncertainties into model predictions. Consequently, this study developed an integrated approach incorporating chemical composition and activation methods as input parameters. Four optimized ML models were deployed to predict the compressive strength of tailings-based cementitious materials. Multiple metrics were employed to evaluate model performance, which identified the PSO-XGBoost model as the superior predictive architecture. SHAP analysis revealed that mechanical grinding, NaOH concentration, and the proportions of gypsum and tailings were the primary features influencing compressive strength. Experimental validation yielded a low prediction error of 8.7%, confirming the model’s high predictive accuracy. This research establishes a robust framework for predicting the strength of tailings-based cementitious materials, providing a theoretical foundation for solid waste upcycling. Full article

A quaternary solid-waste-based binder was prepared from low-titanium slag, municipal solid waste incineration (MSWI) fly ash, steel slag, and flue-gas desulfurization gypsum (FGDG) to clarify the activating effect of MSWI fly ash on low-titanium slag and its influence on hydrate evolution. Unlike conventional solid-waste-based binders in which MSWI fly ash is mainly regarded as a hazardous residue requiring stabilization, this study demonstrates its specific role as a Ca-rich alkaline activator for promoting low-titanium slag depolymerization and coordinated hydrate formation. The results showed that the compressive strength first increased and then decreased with increasing MSWI fly ash content. Considering both strength development and MSWI fly ash utilization, the optimum mixture was identified as low-titanium slag:MSWI fly ash:steel slag:FGDG = 43.0:17.2:25.8:14.0, with compressive strengths of 9.51 and 46.32 MPa at 3 and 90 d, respectively. These values corresponded to 5.66 and 1.04 times those of the reference mixture without MSWI fly ash, respectively. Ettringite and C-(A)-S-H gel were the main strength-contributing hydration products, while Friedel’s salt was identified as a chloride-bearing AFm phase. Moderate MSWI fly ash addition promoted alkaline activation and low-titanium slag depolymerization, leading to increased formation of ettringite, C-(A)-S-H gel, and Friedel’s salt, which contributed to improved compressive strength. In contrast, excessive MSWI fly ash disturbed the Ca-Si-Al balance and inhibited effective hydrate formation. These results demonstrate that MSWI fly ash can serve as an effective Ca-rich activator for low-titanium-slag-based low-carbon cementitious materials and provide a feasible route for the synergistic utilization of multiple solid wastes. Full article

Lithium-ion battery (LIB) cells are available in various sizes, formats, and chemistries. Should a LIB be exposed to conditions outside its operating parameters, each variation affects the cell failure mechanisms and any resultant fire dynamic. Battery fires can be dynamic events that differ significantly from those solid-, liquid- or gas-based fire curves often used in standard building material fire resistance tests. This preliminary research aimed to investigate how standard building materials, sometimes used as a compartment fire envelope, such as gypsum plasterboard, react when exposed to a dynamic battery fire. The research explored batteries that produced jet fires, could act as projectiles, or produced overpressures when they failed. The results showed that cylindrical cells can travel at significant speeds and distances due to expulsing the cell’s contents through the cell’s vent or ejected end cap. These cells were shown to be capable of piercing plasterboard and remain hot enough to present a fire risk where they fall on the far side of the plasterboard. It was also found that the overpressures produced by failing prismatic cells affected the structural integrity of some building materials. The results show a need for further research into the effectiveness of standard building fire controls when exposed to LIB fires. Full article

The stability of upstream tailings remains a critical geotechnical challenge due to the inherently weak mechanical properties of fine-grained mine tailings. This study investigated a tailing improvement method using (i) emulsified polymer and (ii) combinations of recycled gypsum and cement kiln dust (CKD). A comprehensive experimental program—including unconfined compressive strength (UCS) analysis, direct shear tests (DSTs), and oedometer consolidation tests—was conducted to assess the performance of various treatment mixtures. The results showed that blends of CKD and gypsum, particularly at a 1:2 ratio and a 10% dosage, significantly improved shear strength, reduced compressibility, and lowered hydraulic conductivity by over an order of magnitude. The inclusion of plaster (commercial gypsum) further enhanced the UCS by more than 100% compared to recycled gypsum and increased the cohesion (c’) values from 0 to 32.8–47.2 kPa. The compression index (c_c) decreased from 0.15 to 0.05, and the maximum volumetric strain (ε_v) at an applied effective stress of 800 kPa decreased from 17% to 5%. Emulsified polymer treatments also enhanced the mechanical and hydraulic properties of the clayey tailings; however, the overall improvements were lower than those achieved with CKD–gypsum blends, suggesting that further optimization of the polymer concentration or its combination with mineral additives may yield better results. These findings offer a foundation for further research into the use of polymers in geoenvironmental applications, particularly for erosion control, contaminant encapsulation, and hydraulic barrier development. Overall, this study highlights the potential of using industrial by-products, such as CKD and gypsum, as sustainable, cost-effective materials to improve tailing performance, while identifying promising directions for polymer-based solutions in geotechnical engineering. Full article

Background/Objectives: Delivering consistent preclinical instruction for implant attachment procedures can be challenging in large dental cohorts. This report describes the development and implementation of institutionally produced training tools designed to support Locator housing pick-up exercises for second-year predoctoral dental students. Methods: Modified typodont-based simulation tools were integrated into the preclinical curriculum. Clear dentures and gypsum models were fabricated to allow visualization of seating relationships and identification of common interferences. Complete seating of the denture was verified using inspection windows, flange evaluation, and polyvinylsiloxane disclosing materials before housings were incorporated with autopolymerizing acrylic resin. After each session, components were collected, inspected, and prepared for reuse in subsequent cycles. Learner perceptions were obtained through an anonymous voluntary survey. Results: The configuration enabled visualization of seating conditions and identification of misalignment during the exercise. Removal of anterior teeth reduced material use and emphasized posterior stabilization during the pick-up procedure. Of 83 learners, 28 completed the survey (34% response rate), with responses tending toward agreement across items (mean range: 4.5–4.9/5), indicating favorable learner perceptions of the exercise and its organization within the scheduled laboratory period. Across three academic cycles, six dentures required replacement, whereas all gypsum models remained serviceable and no additional fabrication was necessary. Conclusions: This structured simulation approach provided an alternative method for delivering Locator housing pick-up training in a high-volume preclinical environment. The model allowed repeated implementation of the exercise across academic cycles. Full article

Thaumasite sulfate attack (TSA) under elevated water pressure has important implications for the durability of deep underground concrete structures, yet the deterioration process and the coupled effect of water pressure and carbonate supply remain insufficiently understood. In this study, laboratory pressurized sulfate exposure tests were conducted to investigate the evolution of macroscopic performance and microstructure of cement mortars with different limestone powder contents (0%, 15%, and 30%) under water pressures of 0, 2.5, and 5.0 MPa. The results show that elevated water pressure promotes sulfate ingress into the mortar and accelerates later-stage strength loss; this interpretation is supported by the depth-dependent distribution of soluble SO₄²⁻ measured in mortars without limestone powder. Two-way ANOVA indicates that both water pressure and limestone powder content have significant effects on compressive strength, and their interaction becomes statistically significant at 120 d. XRD, FT-IR, and SEM/EDS results show that, under elevated water pressure and high limestone powder content, the corrosion products gradually evolve from gypsum-related products to ettringite- and thaumasite-related products, with a certain spatial differentiation. Specifically, the gray–white, mud-like surface products are consistent with thaumasite-rich assemblages, whereas the needle- and column-like crystals in the interior are consistent with ettringite-rich assemblages. Overall, elevated water pressure mainly promotes sulfate transport, while limestone powder mainly increases carbonate availability. These two factors may jointly intensify TSA deterioration in mortar through a pathway involving transport enhancement, carbonate supply, corrosion product evolution, and aggravated macroscopic damage. This study provides a reference for understanding the sulfate deterioration mechanism of limestone powder-containing cement-based materials in deep underground environments under elevated water pressure. Full article

Paraffins are attractive as phase-change materials (PCMs) due to their high latent heat capacity and adjustable phase transition temperatures. However, the individual high-purity paraffins, especially the long-chain ones, are labor-intensive and costly to produce and capable of storing and releasing latent heat only within a limited temperature range. Herein, we demonstrate the feasibility of a high-purity paraffin wax fraction (C13–C49) obtained via the Fischer–Tropsch (FT) process as a versatile latent heat storage additive within a wide range of phase transition temperatures (8.1–98.2 °C). To avoid the leakage, the FT wax was encapsulated via nanoemulsion interfacial polymerization of melamine formaldehyde (MF) shells with various core-to-monomer and melamine/formaldehyde ratios. Differential scanning calorimetry revealed that the latent heat storage capacity of the FT/MF capsules was 104.5–163.4 J/g depending on the FT loading efficiency, with the heat storage and release range of −0.7–100.2 °C and −9.8–85.8 °C, respectively. The capsules were tested as a thermoregulating additive to commercially available gypsum plaster. Unlike employment of the additives based on individual paraffins, the addition of FT/MF capsules led to a smooth reduction in heating/cooling rates of plaster layers in an extended temperature range. This makes FT/MF capsules a promising and versatile additive for a diversity of thermal energy storage applications. Full article

Driven by global carbon reduction targets, supersulfated cement has emerged as a promising low-carbon cementitious material. This study investigates the influence of a polycarboxylate superplasticizer (PCE) on the rheological behavior and early interfacial evolution of phosphogypsum-based supersulfated cement (PSSC). Rheological measurements, pore solution ion analysis, hydration heat analysis, X-ray diffraction (XRD), and scanning electron microscopy coupled with energy-dispersive spectroscopy (SEM–EDS) are employed to correlate early hydration processes with structural development. The results indicate that the incorporation of PCE significantly reduces the initial yield stress and moderates the structural build-up rate. At a PCE dosage of 0.3 wt.%, the initial static yield stress decreases from 1313 Pa to approximately 125 Pa, while the structural build-up index I_s,s reaches 10.19, indicating improved particle dispersion while maintaining progressive structural reconstruction during hydration. Phosphogypsum (PG) functions not only as a sulfate source but also as an active interfacial substrate that promotes the preferential nucleation of AFt on its surface. In the absence of PCE, continuous Ca–P-enriched layers form on PG particles, accompanied by localized AFt accumulation. After the incorporation of PCE, the primary crystalline phases remain unchanged; however, gypsum dissolution and AFt formation are delayed. Meanwhile, Ca–P enrichment shifts from continuous coverage to a more dispersed distribution, promoting the spatially separated growth of AFt crystals rather than dense localized aggregation. Overall, PCE influences the evolution of the structure and properties of the system by regulating early interfacial reactions and the spatial organization of hydration products. Full article