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21 pages, 7203 KiB  
Article
Experimental Lateral Behavior of Porcelain-Clad Cold-Formed Steel Shear Walls Under Cyclic-Gravity Loading
by Caeed Reza Sowlat-Tafti, Mohammad Reza Javaheri-Tafti and Hesam Varaee
Infrastructures 2025, 10(8), 202; https://doi.org/10.3390/infrastructures10080202 - 2 Aug 2025
Viewed by 202
Abstract
Lightweight steel-framing (LSF) systems have become increasingly prominent in modern construction due to their structural efficiency, design flexibility, and sustainability. However, traditional facade materials such as stone are often cost-prohibitive, and brick veneers—despite their popularity—pose seismic performance concerns. This study introduces an innovative [...] Read more.
Lightweight steel-framing (LSF) systems have become increasingly prominent in modern construction due to their structural efficiency, design flexibility, and sustainability. However, traditional facade materials such as stone are often cost-prohibitive, and brick veneers—despite their popularity—pose seismic performance concerns. This study introduces an innovative porcelain sheathing system for cold-formed steel (CFS) shear walls. Porcelain has no veins thus it offers integrated and reliable strength unlike granite. Four full-scale CFS shear walls incorporating screwed porcelain sheathing (SPS) were tested under combined cyclic lateral and constant gravity loading. The experimental program investigated key seismic characteristics, including lateral stiffness and strength, deformation capacity, failure modes, and energy dissipation, to calculate the system response modification factor (R). The test results showed that configurations with horizontal sheathing, double mid-studs, and three blocking rows improved performance, achieving up to 21.1 kN lateral resistance and 2.5% drift capacity. The average R-factor was 4.2, which exceeds the current design code values (AISI S213: R = 3; AS/NZS 4600: R = 2), suggesting the enhanced seismic resilience of the SPS-CFS system. This study also proposes design improvements to reduce the risk of brittle failure and enhance inelastic behavior. In addition, the results inform discussions on permissible building heights and contribute to the advancement of CFS design codes for seismic regions. Full article
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22 pages, 12147 KiB  
Technical Note
Effects of the Aggregate Shape and Petrography on the Durability of Stone Mastic Asphalt
by Alain Stony Bile Sondey, Vincent Aaron Maleriado, Helga Ros Fridgeirsdottir, Damian Serwin, Carl Christian Thodesen and Diego Maria Barbieri
Infrastructures 2025, 10(8), 198; https://doi.org/10.3390/infrastructures10080198 - 26 Jul 2025
Viewed by 320
Abstract
Compared to traditional dense asphalt concrete mixtures, stone mastic asphalt (SMA) generally offers superior performance in terms of its mechanical resistance and extended pavement lifespan. Focusing on the Norwegian scenario, this laboratory-based study investigated the durability of SMA considering the influence of the [...] Read more.
Compared to traditional dense asphalt concrete mixtures, stone mastic asphalt (SMA) generally offers superior performance in terms of its mechanical resistance and extended pavement lifespan. Focusing on the Norwegian scenario, this laboratory-based study investigated the durability of SMA considering the influence of the aggregate shape and petrography. The rock aggregates were classified according to three different-shaped refinement stages involving vertical shaft impact crushing. Further, the aggregates were sourced from three distinct locations (Jelsa, Tau and Dirdal) characterized by different petrographic origins: granodiorite, quartz diorite and granite, respectively. Two mixtures with maximum aggregate sizes of 16 mm (SMA 16) and 11 mm (SMA 11) were designed according to Norwegian standards and investigated in terms of their durability performance. In this regard, two main functional tests were performed for the asphalt mixture, namely resistance against permanent deformation and abrasion by studded tyres, and one for the asphalt mortar, namely water sensitivity. Overall, the best test results were related to the aggregates sourced from Jelsa and Tau, thus highlighting that the geological origin exerts a major impact on SMA’s durability performance. On the other hand, the different aggregate shapes related to the crushing refinement treatments seem to play an effective but secondary role. Full article
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16 pages, 8474 KiB  
Article
Multiproxy Petrological Analysis for Provenance Determination of Two Granitic Stone Anchors in the Western Mediterranean
by Javier Martínez-Martínez, Hugo Corbí, Nicoletta Fusi, Jaime Molina Vidal, José A. Moya-Montoya, Alberto J. Lorrio, Felio Lozano Quijada and José Manuel Pérez Burgos
Minerals 2025, 15(7), 675; https://doi.org/10.3390/min15070675 - 24 Jun 2025
Viewed by 453
Abstract
A multiproxy methodology has been employed to characterise two granite anchors discovered on the seabed near the island of Nueva Tabarca (Alicante, Southeast Spain). According to the significant archaeological context where they were found, the studied anchors can be dated from the Roman [...] Read more.
A multiproxy methodology has been employed to characterise two granite anchors discovered on the seabed near the island of Nueva Tabarca (Alicante, Southeast Spain). According to the significant archaeological context where they were found, the studied anchors can be dated from the Roman ages (late Republican period). One of the most interesting aspects is the absence of regional geological outcrops with rocks compatible with the granite used in the production of the anchor, which shows a foreign origin consistent with the connection of the anchor to maritime transport across the Mediterranean Sea. The lack of precise information about the artifact’s origin underscores the interest and need for the application of petrological techniques to determine its provenance. The methodology utilised encompasses five distinct techniques: (1) non-destructive textural analysis using X-ray microcomputed tomography; (2) K–Ar dating; (3) petrological characterisation through optical microscopy; (4) geochemical characterisation using X-ray fluorescence and atomic absorption spectrometry. The results allow for a comparison of the anchor rock’s characteristics with various granite outcrops along the Mediterranean coasts (Eastern, Central, and Western sectors), suggesting potential source areas based on petrological compatibility with the material under study. The findings point to the origin of the Nueva Tabarca granite anchor being granite outcrops in Southern Italy (Calabria), reinforcing the connection between the Spanish southeastern coasts and Southern Italy. These results highlight the utility and significance of multiproxy petrological methodologies in the geoarchaeological study of decontextualised artifacts. Full article
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21 pages, 5864 KiB  
Article
Study on Abrasion Resistance of Granite Manufactured Sand Concrete Based on Indoor Abrasion Tester
by Zhitang Li, Yuankuo Wang, Xiaolong Yang, Junlin Liang, Yuanfeng Chen and Minqiang Pan
Coatings 2025, 15(6), 659; https://doi.org/10.3390/coatings15060659 - 30 May 2025
Viewed by 455
Abstract
The long-term wear resistance of granite manufactured sand (HGY) concrete has not been sufficiently investigated. This deficiency makes it difficult to accurately predict and evaluate the service life and durability of such concrete pavements in practical engineering applications. Consequently, this study employed a [...] Read more.
The long-term wear resistance of granite manufactured sand (HGY) concrete has not been sufficiently investigated. This deficiency makes it difficult to accurately predict and evaluate the service life and durability of such concrete pavements in practical engineering applications. Consequently, this study employed a self-developed indoor abrasion test device and combined it with scanning electron microscope (SEM) and X-ray diffraction (XRD) technologies. From the two dimensions of macroscopic performance and microscopic structure, the mechanisms’ influence of the effective sand ratio, stone powder content, and fine aggregate lithology on the wear resistance of HGY concrete were systematically investigated. The optimal content of the effective sand and stone powder content were determined, and the long-term evolution law of the wear resistance of HGY concrete was revealed. The results demonstrate that increasing the effective sand content will reduce the mass loss of concrete. When the stone powder content is 9%, the wear resistance of the concrete is optimal. The order of mass loss of different fine aggregate lithologies is river sand (HS) > limestone mechanism sand (SHY) > HGY, and the wear resistance of HGY is better than that of other fine aggregates. Increasing the effective sand content can enhance the bonding strength between the aggregate and the cement matrix and reduce the porosity, which is conducive to improving the wear resistance of the concrete. Under a relatively small stone powder content, as the amount of stone powder added increases, the pore structure becomes tighter, and the wear resistance of the concrete becomes better. Compared to HS, the manufactured sand (MS) containing stone powder can optimize the pore structure and hydration products of concrete, improve the pore structure of concrete, and improve the wear resistance. Full article
(This article belongs to the Special Issue Synthesis and Application of Functional Polymer Coatings)
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21 pages, 2917 KiB  
Article
A Water Consumption Assessment in the Production of Marble, Granite, and Quartz-Based Composites Using Life Cycle Assessment: A Case Study in Bahia, Brazil
by José Oduque Nascimento de Jesus, Luciano José da Silva, Virginia Parente, Karla Patricia Oliveira Esquerre, Oz Sahin and Wanderbeg Correia de Araujo
Water 2025, 17(10), 1438; https://doi.org/10.3390/w17101438 - 10 May 2025
Viewed by 769
Abstract
Given the relevance of sustainability, this study analyzed the impacts on water consumption in the production chain of ornamental stone pieces (marble and granite) and quartz-based composites. The goal was to compare the water demand throughout the process, from extraction to manufacturing, using [...] Read more.
Given the relevance of sustainability, this study analyzed the impacts on water consumption in the production chain of ornamental stone pieces (marble and granite) and quartz-based composites. The goal was to compare the water demand throughout the process, from extraction to manufacturing, using 1 m3 blocks as the unit of analysis. This study was conducted in Bahia, a state with significant ornamental stone production, located in a semi-arid region with limited water availability. The methodology included data collection from participating companies, combined with sectorial information and the Ecoinvent version 3.3 database, modeled using the SimaPro 8.0 software. The impact assessment was carried out using the AWaRE (Water Scarcity Footprint) and ReCiPe Endpoint methods, following the guidelines of Life Cycle Assessment (LCA), as per ABNT NBR ISO 14040 standards. The results showed that marble and granite have lower water demand and environmental impact in the categories of particulate matter, human toxicity, ecotoxicity, eutrophication, and acidification when compared to quartz composites. The highest environmental impact occurred during the processing stage, which requires a large amount of water and generates effluents, losses, and particulate matter. The results indicate that marble and granite demand less water and exhibit lower environmental impacts—across categories like particulate matter, human toxicity, ecotoxicity, eutrophication, and acidification—than quartz composites. Notably, the processing stage incurred the highest environmental burden due to its intensive water use and consequent generation of effluents, losses, and particulate matter. These findings highlight the necessity of efficient water management and the adoption of circular economy principles—including water reuse and waste valorization—to promote long-term sustainability in the ornamental stone industry. Full article
(This article belongs to the Section Water Use and Scarcity)
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25 pages, 75362 KiB  
Article
Comprehensive Technical Inspection of a Medieval Bridge (Ponte de Vilanova, in Allariz) Using Microtechnological Tools
by Rubén Rodríguez Elizalde
Eng 2024, 5(4), 3259-3283; https://doi.org/10.3390/eng5040171 - 10 Dec 2024
Cited by 3 | Viewed by 1208
Abstract
Ponte de Vilanova, a masonry bridge, was built in Allariz, Galicia in the 13th–14th centuries. It is still standing. The structure, generally well preserved, shows minor deformations and wear signs caused by environmental factors. To conduct a comprehensive assessment without impacting the bridge’s [...] Read more.
Ponte de Vilanova, a masonry bridge, was built in Allariz, Galicia in the 13th–14th centuries. It is still standing. The structure, generally well preserved, shows minor deformations and wear signs caused by environmental factors. To conduct a comprehensive assessment without impacting the bridge’s integrity, drones equipped with thermal and underwater imaging technology were employed. Aerial inspections revealed vegetation growth and minor efflorescence (salt deposits) in some areas, while aerial thermography detected temperature variations along the stone joints, indicating the presence of moisture. The granite blocks comprising the bridge showed consistent quality and preservation. The underwater inspection confirmed that the bridge’s piers are well set on the riverbed, with no major damage observed, ruling out the immediate need for repair. This approach allowed a thorough evaluation of submerged parts without requiring divers, enhancing safety and reducing costs. Full article
(This article belongs to the Section Materials Engineering)
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18 pages, 8062 KiB  
Article
Assessment of Mechanical Behavior and Microstructure of Unsaturated Polyester Resin Composites Reinforced with Recycled Marble Waste
by Rahima Baghloul, Laidi Babouri, Houria Hebhoub, Fouad Boukhelf and Yassine El Mendili
Buildings 2024, 14(12), 3877; https://doi.org/10.3390/buildings14123877 - 3 Dec 2024
Cited by 1 | Viewed by 1416
Abstract
The quarrying and utilization of natural stones such as marble and granite are growing rapidly in developing countries. However, the processing, cutting, sizing, and shaping of these stones to render them functional generates huge quantities of waste and dust. These materials are often [...] Read more.
The quarrying and utilization of natural stones such as marble and granite are growing rapidly in developing countries. However, the processing, cutting, sizing, and shaping of these stones to render them functional generates huge quantities of waste and dust. These materials are often disposed of openly in the environment, and their potentially hazardous nature has negative repercussions on both the environment and human health. In this study, marble waste (MW) was used as a filler in the unsaturated polyester resin (UPR) matrix to enhance performance and characteristics while adding value to the waste and minimizing manufacturing costs. For this purpose, samples of UPR/MW composites were produced with 0, 5, 10, 15, and 20 wt.% of MW incorporated into the UPR. A full characterization that focused on the microstructure, thermal stability, and physical and mechanical properties was carried out. The results revealed that the use of 10 to 15% of MW improves mechanical performance, with increases from 17 to 26 kJ/m2, 14 to 17 MPa, and 794 to 1522 GPa in impact strength, tensile strength, and elastic modulus, respectively. By introducing a 20% MW filler, the composite loses its performance, particularly Shore D hardness, and becomes very brittle. Thermogravimetric analysis (TGA) indicated significant thermal stabilization, with a delay in the start decomposition temperature of 28 °C for 20 UPR/MW compared to 0 UPR/MW. Additionally, morphological and microstructural tests, namely, FT-IR, XRD, and SEM analysis, show a microstructural change, including the formation of crystalline phases, enhancing matrix-filler interactions due to the creation of Mg-O and Ca-O chemical bonds and the forming of filler agglomeration at high introduction rates that lead to defects in the microstructure. These results confirmed the mechanical results of the UPR/MW composites. Full article
(This article belongs to the Collection Utilization of Waste Materials in Building Engineering)
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28 pages, 90148 KiB  
Article
Spatial, Functional, and Constructive Analysis of the Water Resource at the Archaeological Center of Tipon, Cusco, Peru, 2023
by Doris Esenarro, Jorge Lescano, Brenda Chalco, Nicole Tapia, Jesica Vilchez Cairo, Carlos Vargas Beltran, Cecilia Arriola and Rosa Ruiz Reyes
Heritage 2024, 7(12), 6629-6656; https://doi.org/10.3390/heritage7120307 - 26 Nov 2024
Cited by 1 | Viewed by 2433
Abstract
The objective of this research is to analyze the spatial, functional, and constructive aspects of the water resource at the Archaeological Center of Tipon, given the lack of awareness towards the timely preservation of archaeological heritage, the deterioration of the terraces, and the [...] Read more.
The objective of this research is to analyze the spatial, functional, and constructive aspects of the water resource at the Archaeological Center of Tipon, given the lack of awareness towards the timely preservation of archaeological heritage, the deterioration of the terraces, and the contamination of the rivers adjacent to the archaeological site due to the discharge of waste into the water bodies. The methodology employed consists of a site study analysis, considering data on terrain, environment, climate, and water flow in the spatial, functional, and constructive aspects, supported by digital tools (Google Earth Pro 2024, AutoCAD 2024, SketchUP 2024, Sun Path 3D 2024, Photoshop 2024, and Twinmotion 2024). The results yielded a spatial–functional–constructive hydrological analysis; the water flow, constructed underground through a masonry system with an approximate angle of 60° in stone or pink granite, also maintained a negative slope, generally between 1% and 3%, which facilitated a rapid and direct distribution, presenting a greater flow with a width and depth of 30 cm, in addition to a vertical drop of 240 cm. The efficient use of water in agriculture through interconnected terraces ensured the population’s sustenance by approximately 80%. In conclusion, the analysis not only provides information on the infrastructure and water management but also addresses current issues. Full article
(This article belongs to the Section Archaeological Heritage)
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23 pages, 2933 KiB  
Article
Shear Bond Strength in Stone-Clad Façades: Effect of Polypropylene Fibers, Curing, and Mechanical Anchorage
by Vahid Shafaie, Oveys Ghodousian, Amin Ghodousian, Mohammad Gorji, Hossein Mehdikhani and Majid Movahedi Rad
Polymers 2024, 16(21), 2975; https://doi.org/10.3390/polym16212975 - 24 Oct 2024
Cited by 12 | Viewed by 1217
Abstract
This study investigates the shear bond strength between four widely used façade stones—travertine, granite, marble, and crystalline marble—and concrete substrates, with a particular focus on the role of polypropylene fibers in adhesive mortars. The research evaluates the effects of curing duration, fiber dosage, [...] Read more.
This study investigates the shear bond strength between four widely used façade stones—travertine, granite, marble, and crystalline marble—and concrete substrates, with a particular focus on the role of polypropylene fibers in adhesive mortars. The research evaluates the effects of curing duration, fiber dosage, and mechanical anchorage on bond strength. Results demonstrate that Z-type anchorage provided the highest bond strength, followed by butterfly-type and wire tie systems. Extended curing had a significant impact on bond strength for specimens without anchorage, particularly for travertine. The incorporation of polypropylene fibers at 0.2% volume in adhesive mortar yielded the strongest bond, although lower and higher dosages also positively impacted the bonding. Furthermore, the study introduces a novel fuzzy logic model using the Dombi family of t-norms, which outperformed linear regression in predicting bond strength, achieving an R2 of up to 0.9584. This research emphasizes the importance of optimizing fiber dosage in adhesive mortars. It proposes an advanced predictive model that could enhance the design and safety of stone-clad façades, offering valuable insights for future applications in construction materials. Full article
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17 pages, 1666 KiB  
Article
Measuring the Primary and Secondary Bioreceptivity of Stone and Their Implications for Heritage Conservation
by Philip J. A. Skipper and Lynda K. Skipper
Heritage 2024, 7(9), 5103-5119; https://doi.org/10.3390/heritage7090241 - 13 Sep 2024
Viewed by 1476
Abstract
Bioreceptivity measures the ability of a surface to develop and maintain a permanent ecosystem of microorganisms. In the historic built environment, this is characterised visually by the greening of monuments and other outdoor heritage. Primary and secondary bioreceptivity refer to the potential for [...] Read more.
Bioreceptivity measures the ability of a surface to develop and maintain a permanent ecosystem of microorganisms. In the historic built environment, this is characterised visually by the greening of monuments and other outdoor heritage. Primary and secondary bioreceptivity refer to the potential for biological growth on fresh and weathered stone, respectively. Measuring bioreceptivity helps us understand biological growth rates and allows researchers to characterise the impact of stone conservation treatments on colonisation. Understanding the relative bioreceptivity of stones allows heritage professionals to make more informed selection of replacement stone types for repairs to existing structures. The primary bioreceptivity of stones from different geographical areas cannot currently be easily compared due to a lack of consistency in approaches to measurement. We propose a repeatable lab-based methodology for measuring colour and chlorophyll a levels from a standard algal culture grown on the stone surface as a standardised testing protocol for primary and secondary bioreceptivity. This protocol controls for the effects of mineralogical colour change during testing, which is something that has not been addressed in other methodologies. This method was successfully applied to case studies measuring the bioreceptivity of English granite, sandstone and limestone, determining their position in a bioreceptivity index. Our results demonstrated that for the stones tested, primary bioreceptivity was categorised as very low or low. Secondary bioreceptivity was increased compared to primary bioreceptivity. This research is the first to fully categorise any stones for secondary bioreceptivity and provides the first primary and secondary bioreceptivity data for any UK stones. We encourage others to follow this standard protocol to add additional data and build an international bioreceptivity database accessible to heritage practitioners. Full article
(This article belongs to the Special Issue Deterioration and Conservation of Materials in Built Heritage)
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12 pages, 1474 KiB  
Article
Optimizing Porous Concrete Using Granite Stone-Crushing Waste: Composition, Strength, and Density Analysis
by Leonid Dvorkin, Oleh Bordiuzhenko, Tomasz Tracz and Katarzyna Mróz
Appl. Sci. 2024, 14(16), 6934; https://doi.org/10.3390/app14166934 - 8 Aug 2024
Cited by 3 | Viewed by 1436
Abstract
This study examines the utilization of granite stone-crushing waste in the production of porous concrete, with a particular emphasis on the influence of aggregate composition and cement paste layer thickness on the material’s strength and density. Two types of aggregates were employed in [...] Read more.
This study examines the utilization of granite stone-crushing waste in the production of porous concrete, with a particular emphasis on the influence of aggregate composition and cement paste layer thickness on the material’s strength and density. Two types of aggregates were employed in this study: granite crushing screenings and granite crushed stone. The impact of aggregate grain size on the properties of porous concrete properties was investigated, and it was found that the use of granite screenings (2.5–5 mm) resulted in superior concrete characteristics compared to granite crushed stone (5–10 mm). This study puts forward a method for optimizing the composition of porous concrete to achieve an optimal balance of compressive strength and density. A method for the design of porous concrete was proposed, incorporating experimental results and the dependencies of strength on the water/cement ratio (W/C). Equations were developed to predict concrete strength based on W/C and cement paste layer thicknesses (CPLTs). The method provides preliminary mix proportions, which should be validated and adjusted for the final design. The findings demonstrate the potential for utilizing stone-crushing waste to produce environmentally sustainable and high-quality porous concrete. Full article
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31 pages, 2446 KiB  
Article
A Microscale Framework for Seismic Stability Analysis of Bridge Pier Rocking Isolation Using the Discrete Element Method
by Idowu Itiola and Usama El Shamy
Geotechnics 2024, 4(3), 742-772; https://doi.org/10.3390/geotechnics4030039 - 12 Jul 2024
Viewed by 1446
Abstract
This study presents a microscale framework for investigating the seismic stability of bridge-pier structures using the discrete element method (DEM), with a focus on rocking isolation mechanisms. The piers and the deck are modeled as rigid blocks that follow rigid body dynamics. The [...] Read more.
This study presents a microscale framework for investigating the seismic stability of bridge-pier structures using the discrete element method (DEM), with a focus on rocking isolation mechanisms. The piers and the deck are modeled as rigid blocks that follow rigid body dynamics. The rigid block is modeled as a collection of glued particles with geometrical arrangement and physical properties that mimic an actual block. To facilitate numerical contact points between the base of the block and the flat base wall, smaller particle sizes were introduced at the base of the block. A Hertz contact model was employed to model the interaction between contacting entities for better estimation of the contact constitutive parameters. Validation was performed using well-documented experimental data featuring the free-rocking of a granite stone block as well as existing analytical techniques. DEM simulations were performed on single blocks as well as on a bridge deck-pier system subjected to dynamic and seismic loadings. The study shows the effectiveness of rocking isolation through a comparative analysis of acceleration and angular velocity under varying seismic intensities, with acceleration reduction up to 70% for piers and 60% for the deck in a high-intensity scenario, affirming the potential of rocking isolation as a viable seismic mitigation strategy. The study monitors the structural response, contact mechanics, and energy dissipation of the pier–deck system. The application of the DEM model advances the analysis of bridge pier and deck interactions under seismic loads, providing new insights into the detailed behavior of rocking bridge piers and their potential for seismic isolation. Full article
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16 pages, 12704 KiB  
Article
Provenance Studies of Natural Stones Used in Historical Buildings of the Peninsula de Barbanza, Galicia, Spain (North-Western Iberia)
by Ana C. Hernández, Jorge Sanjurjo-Sánchez, Carlos Alves and Carlos A. M. Figueiredo
Minerals 2024, 14(6), 595; https://doi.org/10.3390/min14060595 - 5 Jun 2024
Cited by 1 | Viewed by 1336
Abstract
Traditionally, the building stones used in the architectural heritage of Galicia (Spain) during the past were mainly extracted from quarries located in the surrounding areas of the historical buildings. Thus, a great variety of monuments were built with the same type of granite [...] Read more.
Traditionally, the building stones used in the architectural heritage of Galicia (Spain) during the past were mainly extracted from quarries located in the surrounding areas of the historical buildings. Thus, a great variety of monuments were built with the same type of granite but with different degrees of weathering depending on local conditions, geological context (facies), and period of construction. The main purpose of this work is to evaluate the probable origin of the construction materials of six historical buildings on the Barbanza Peninsula, Galicia (Spain), based on the degree of weathering and petrographic-mineralogical characteristics. The evaluation was performed on six different samples of granite according to the geological context in outcrops of places where there are old quarries. We used X-ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), and petrographic microscopy (PM) to attempt to address whether the origin is really local to the Barbanza Peninsula or whether the stone was brought from more distant places, based on our knowledge of the geological context of the study area. Based on the chemical, textural, and mineralogical analyses obtained, the material used for construction has a local origin and comes from small quarries spread over a wide area within the Peninsula itself. Barbanza-type granite is the most abundant within the geological context of the area and also the most used as a construction material. Other types of granites identified are the Confurco Granite and other granitoids of the Noya complex. The Chemical Alteration Index (CIA) shows low to moderate weathering in the granites, fitting petrographic observations. In monuments, samples show higher concentrations of Na and K due to salt crystallization. They show microcracks due to extraction, cutting, and finishing processes and common alteration processes of the main minerals, such as sericitization of plagioclase and chloritization of biotite. This work consists of a multidisciplinary study focused on the geological perspective for the identification and preservation of historic quarries. Knowledge of the original material also presents a unique opportunity for the restoration and/or reconstruction of monuments, which allows for the maintenance of their conceptual and constructive homogeneity. Full article
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18 pages, 5249 KiB  
Article
Efficacy of Chitosan-Carboxylic Acid Hydrogels in Reducing and Chelating Iron for the Removal of Rust from Stone Surface
by Francesco Gabriele, Cinzia Casieri and Nicoletta Spreti
Gels 2024, 10(6), 359; https://doi.org/10.3390/gels10060359 - 22 May 2024
Cited by 2 | Viewed by 1820
Abstract
In the field of stone conservation, the removal of iron stains is one of the most challenging issues due to the stability and low solubility of the ferrous species. In the present paper, three different chitosan-based hydrogels added with acetic, oxalic or citric [...] Read more.
In the field of stone conservation, the removal of iron stains is one of the most challenging issues due to the stability and low solubility of the ferrous species. In the present paper, three different chitosan-based hydrogels added with acetic, oxalic or citric acids are applied on different lithotypes, i.e., granite, travertine and marble, widely diffused in monumental heritages, and artificially stained by deposition of a rust dispersion. The reducing power of carboxylic acids is combined with the good chelating properties of chitosan to effectively remove rust from stone surfaces. As evidenced by colorimetry on three samples of each lithotype and confirmed by 1H-NMR relaxometry and SEM/EDS analyses, the chitosan-oxalic acid hydrogel shows the best performance and a single application of 24 h is enough to get a good restoration of the stone original features. Lastly, the chitosan-oxalic acid hydrogel performs well when a rusted iron grid is placed directly on the lithic surfaces to simulate a more realistic pollution. Current work in progress is devoted to finding better formulations for marble, which is the most challenging to clean or, with a different approach, to developing protective agents to prevent rust deposition. Full article
(This article belongs to the Special Issue Gels for Removal and Adsorption (2nd Edition))
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11 pages, 568 KiB  
Article
Low-Level Respirable Crystalline Silica and Silicosis: Long-Term Follow-Up of Vermont Granite Workers
by Pamela M. Vacek, Robert E. Glenn and John E. Parker
Int. J. Environ. Res. Public Health 2024, 21(5), 608; https://doi.org/10.3390/ijerph21050608 - 10 May 2024
Cited by 1 | Viewed by 2555
Abstract
The lifetime risk of silicosis associated with low-level occupational exposure to respirable crystalline silica remains unclear because most previous radiographic studies included workers with varying exposure concentrations and durations. This study assessed the prevalence of silicosis after lengthy exposure to respirable crystalline silica [...] Read more.
The lifetime risk of silicosis associated with low-level occupational exposure to respirable crystalline silica remains unclear because most previous radiographic studies included workers with varying exposure concentrations and durations. This study assessed the prevalence of silicosis after lengthy exposure to respirable crystalline silica at levels ≤ 0.10 mg/m3. Vermont granite workers employed any time during 1979–1987 were traced and chest radiographs were obtained for 356 who were alive in 2017 and residing in Vermont. Work history, smoking habits and respiratory symptoms were obtained by interview, and exposure was estimated using a previously developed job-exposure matrix. Associations between radiographic findings, exposure, and respiratory symptoms were assessed by ANOVA, chi-square tests and binary regression. Fourteen workers (3.9%) had radiographic evidence of silicosis, and all had been employed ≥30 years. They were more likely to have been stone cutters or carvers and their average exposure concentrations and cumulative exposures to respirable crystalline silica were significantly higher than workers with similar durations of employment and no classifiable parenchymal abnormalities. This provides direct evidence that workers with long-term exposure to low-level respirable crystalline silica (≤0.10 mg/m3) are at risk of developing silicosis. Full article
(This article belongs to the Section Environmental Health)
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