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Search Results (3,620)

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Keywords = geometric property

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18 pages, 19901 KiB  
Article
A Novel Polysilicon-Fill-Strengthened Etch-Through 3D Trench Electrode Detector: Fabrication Methods and Electrical Property Simulations
by Xuran Zhu, Zheng Li, Zhiyu Liu, Tao Long, Jun Zhao, Xinqing Li, Manwen Liu and Meishan Wang
Micromachines 2025, 16(8), 912; https://doi.org/10.3390/mi16080912 (registering DOI) - 6 Aug 2025
Abstract
Three-dimensional trench electrode silicon detectors play an important role in particle physics research, nuclear radiation detection, and other fields. A novel polysilicon-fill-strengthened etch-through 3D trench electrode detector is proposed to address the shortcomings of traditional 3D trench electrode silicon detectors; for example, the [...] Read more.
Three-dimensional trench electrode silicon detectors play an important role in particle physics research, nuclear radiation detection, and other fields. A novel polysilicon-fill-strengthened etch-through 3D trench electrode detector is proposed to address the shortcomings of traditional 3D trench electrode silicon detectors; for example, the distribution of non-uniform electric fields, asymmetric electric potential, and dead zone. The physical properties of the detector have been extensively and systematically studied. This study simulated the electric field, potential, electron concentration distribution, complete depletion voltage, leakage current, capacitance, transient current induced by incident particles, and weighting field distribution of the detector. It also systematically studied and analyzed the electrical characteristics of the detector. Compared to traditional 3D trench electrode silicon detectors, this new detector adopts a manufacturing process of double-side etching technology and double-side filling technology, which results in a more sensitive detector volume and higher electric field uniformity. In addition, the size of the detector unit is 120 µm × 120 µm × 340 µm; the structure has a small fully depleted voltage, reaching a fully depleted state at around 1.4 V, with a saturation leakage current of approximately 4.8×1010A, and a geometric capacitance of about 99 fF. Full article
(This article belongs to the Special Issue Photonic and Optoelectronic Devices and Systems, Third Edition)
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25 pages, 2458 KiB  
Article
Numerical Analysis of Heat Transfer in a Double-Pipe Heat Exchanger for an LPG Fuel Supply System
by Seongwoo Lee, Younghun Kim, Ancheol Choi and Sungwoong Choi
Energies 2025, 18(15), 4179; https://doi.org/10.3390/en18154179 - 6 Aug 2025
Abstract
LPG fuel supply systems are increasingly important for improving energy efficiency and reducing carbon emissions in the shipping industry. The primary objective of this research is to investigate the heat transfer phenomena to enhance the thermal performance of double-pipe heat exchangers (DPHEs) in [...] Read more.
LPG fuel supply systems are increasingly important for improving energy efficiency and reducing carbon emissions in the shipping industry. The primary objective of this research is to investigate the heat transfer phenomena to enhance the thermal performance of double-pipe heat exchangers (DPHEs) in LPG fuel supply systems. This study investigates the heat transfer performance of a glycol–steam double-pipe heat exchanger (DPHE) within an LPG fuel supply system under varying operating conditions. A computational model and methodology were developed and validated by comparing the numerical results with experimental data obtained from commissioning tests. Additionally, the effects of turbulence models and parametric variations were evaluated by analyzing the glycol–water mixing ratio and flow direction—both of which are critical operational parameters for DPHE systems. Numerical validation against the commissioning data showed a deviation of ±2% under parallel-flow conditions, confirming the reliability of the proposed model. With respect to the glycol–water mixing ratio and flow configuration, thermal conductance (UA) decreased by approximately 11% in parallel flow and 13% in counter flow for every 20% increase in glycol concentration. Furthermore, parallel flow exhibited approximately 0.6% higher outlet temperatures than counter flow, indicating superior heat transfer efficiency under parallel-flow conditions. Finally, the heat transfer behavior of the DPHE was further examined by considering the effects of geometric characteristics, pipe material, and fluid properties. This study offers significant contributions to the engineering design of double-pipe heat exchanger systems for LPG fuel supply applications. Full article
(This article belongs to the Collection Advances in Heat Transfer Enhancement)
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14 pages, 671 KiB  
Communication
Engineering Thermodynamic Approach to the Analysis of Elastic Properties: Elastomers as a Case Study
by Umberto Lucia and Giulia Grisolia
Appl. Sci. 2025, 15(15), 8705; https://doi.org/10.3390/app15158705 (registering DOI) - 6 Aug 2025
Abstract
The thermophysical behavior of solids (such as oxide compounds, for example) is crucial in applied physics and engineering, with particular regard to heterogeneous catalysis, sensors, high-temperature superconductors, and solid-state batteries. Research in geometric nonlinear theory has provided insights into crystal symmetry and phase [...] Read more.
The thermophysical behavior of solids (such as oxide compounds, for example) is crucial in applied physics and engineering, with particular regard to heterogeneous catalysis, sensors, high-temperature superconductors, and solid-state batteries. Research in geometric nonlinear theory has provided insights into crystal symmetry and phase compatibility under thermal and elastic stress. High-temperature stress significantly affects phase stability, making an understanding of solid thermodynamics essential for material performance. This study focuses on the mechanical and thermal interactions in solids, analyzing variations in mechanical stress and strain under extreme conditions. We propose a theoretical approach for a thermophysical model that, based on the study of the properties of the global thermal behavior of solids, can describe the thermodynamic effects of elastic deformations. Elastomers are used as a case study to validate the proposed approach. Full article
(This article belongs to the Section Applied Thermal Engineering)
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14 pages, 330 KiB  
Article
Sharp Bounds on Hankel Determinants for Starlike Functions Defined by Symmetry with Respect to Symmetric Domains
by Alina Alb Lupaş, Adel Salim Tayyah and Janusz Sokół
Symmetry 2025, 17(8), 1244; https://doi.org/10.3390/sym17081244 - 5 Aug 2025
Abstract
This work investigates the behavior of the coefficients of analytic functions within certain subclasses characterized by inherent symmetric structures. By leveraging deep connections with functions exhibiting positive real part properties, the approach introduces a modern analytical framework that links the studied coefficients to [...] Read more.
This work investigates the behavior of the coefficients of analytic functions within certain subclasses characterized by inherent symmetric structures. By leveraging deep connections with functions exhibiting positive real part properties, the approach introduces a modern analytical framework that links the studied coefficients to those of auxiliary functions with regulated behavior. This connection allows for the derivation of sharp estimates and facilitates computational treatment. The proposed method builds upon certain classical and modern coefficient inequalities. The study focuses on obtaining precise bounds for specific determinant expressions associated with initial, inverse, and inverse logarithmic coefficients, all within a subclass of starlike functions exhibiting internal symmetry aligned with a recently introduced canonical structure. This symmetric perspective reveals how geometric properties can lead to refined quantitative outcomes that enhance contemporary analytic theory. Full article
(This article belongs to the Special Issue Functional Equations and Inequalities: Topics and Applications)
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18 pages, 2357 KiB  
Article
Nitrogen Fertilizer Reduction in Rice–Eel Co-Culture System Improves the Soil Microbial Diversity and Its Functional Stability
by Mengqian Ma, Weiguang Lv, Yu Huang, Juanqin Zhang, Shuangxi Li, Naling Bai, Haiyun Zhang, Xianpu Zhu, Chenglong Xu and Hanlin Zhang
Plants 2025, 14(15), 2425; https://doi.org/10.3390/plants14152425 - 5 Aug 2025
Abstract
The ecological rice–eel co-culture system is not only beneficial for enhancing productivity and sustainability in agriculture but also plays a crucial role in promoting environmental health. In the present study, based on the long-term positioning trial of the rice–eel co-culture system that began [...] Read more.
The ecological rice–eel co-culture system is not only beneficial for enhancing productivity and sustainability in agriculture but also plays a crucial role in promoting environmental health. In the present study, based on the long-term positioning trial of the rice–eel co-culture system that began in 2016 and was sampled in 2023, the effects of reduced nitrogen fertilizer application on soil physico-chemical properties and the bacterial community were investigated. Treatments included a conventional regular fertilization treatment (RT), rice–eel co-culture system regular fertilization (IT), and nitrogen-reduction 10%, 30%, and 50% fertilization treatments (IT90, IT70, and IT50). Our research demonstrated the following: (1) Compared to RT, IT significantly increased soil water-stable macroaggregates (R0.25), mean weight diameter (MWD), geometric mean diameter (GMD), and available phosphorus content, with the increases of 15.66%, 25.49%, 36.00%, and 18.42%, respectively. Among the nitrogen-reduction fertilization treatments, IT90 showed the most significant effect. Compared to IT, IT90 significantly increased R0.25, MWD, GMD, and available nitrogen content, with increases of 4.4%, 7.81%, 8.82%, and 28.89%, respectively. (2) Compared to RT, at the phylum level, the diversity of Chloroflexi was significantly increased under IT and IT50, and the diversity of Gemmatimonadota was significantly increased under IT90, IT70, and IT50. The diversity of Acidobacteriota was significantly higher in IT90 and IT70 compared to IT. It was shown that the rice–eel co-culture system and nitrogen fertilizer reduction could effectively improve the degradation capacity of organic matter and promote soil nitrogen cycling. In addition, redundancy analysis (RDA) identified total phosphorus, total nitrogen, and available nitrogen (p = 0.007) as the three most important environmental factors driving changes in the bacterial community. (3) The functional prediction analysis of soil microbiota showed that, compared to RT, the diversity of pathways related to biosynthesis (carbohydrate biosynthesis and cell structure biosynthesis) and metabolism (L-glutamate and L-glutamine biosynthesis) was significantly higher under IT70, IT90, IT, and IT50 (in descending order). However, the diversity of pathways associated with degradation/utilization/assimilation (secondary metabolite degradation and amine and polyamine degradation) was significantly lower under all the rice–eel co-culture treatments. In conclusion, the rice–eel co-culture system improved soil physicochemical properties and the soil microbial environment compared with conventional planting, and the best soil improvement was achieved with 10% less N fertilizer application. Full article
(This article belongs to the Special Issue Chemical Properties of Soils and its Impact on Plant Growth)
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29 pages, 12422 KiB  
Article
Real-Time Foreshock–Aftershock–Swarm Discrimination During the 2025 Seismic Crisis near Santorini Volcano, Greece: Earthquake Statistics and Complex Networks
by Ioanna Triantafyllou, Gerassimos A. Papadopoulos, Constantinos Siettos and Konstantinos Spiliotis
Geosciences 2025, 15(8), 300; https://doi.org/10.3390/geosciences15080300 - 4 Aug 2025
Abstract
The advanced determination of the type (foreshock–aftershock–swarm) of an ongoing seismic cluster is quite challenging; only retrospective solutions have thus far been proposed. In the period of January–March 2025, a seismic cluster, recorded between Santorini volcano and Amorgos Island, South Aegean Sea, caused [...] Read more.
The advanced determination of the type (foreshock–aftershock–swarm) of an ongoing seismic cluster is quite challenging; only retrospective solutions have thus far been proposed. In the period of January–March 2025, a seismic cluster, recorded between Santorini volcano and Amorgos Island, South Aegean Sea, caused considerable social concern. A rapid increase in both the seismicity rate and the earthquake magnitudes was noted until the mainshock of ML = 5.3 on 10 February; afterwards, activity gradually diminished. Fault-plane solutions indicated SW-NE normal faulting. The epicenters moved with a mean velocity of ~0.72 km/day from SW to NE up to the mainshock area at a distance of ~25 km. Crucial questions publicly emerged during the cluster. Was it a foreshock–aftershock activity or a swarm of possibly volcanic origin? We performed real-time discrimination of the cluster type based on a daily re-evaluation of the space–time–magnitude changes and their significance relative to background seismicity using earthquake statistics and the topological metric betweenness centrality. Our findings were periodically documented during the ongoing cluster starting from the fourth cluster day (2 February 2025), at which point we determined that it was a foreshock and not a case of seismic swarm. The third day after the ML = 5.3 mainshock, a typical aftershock decay was detected. The observed foreshock properties favored a cascade mechanism, likely facilitated by non-volcanic material softening and the likely subdiffusion processes in a dense fault network. This mechanism was possibly combined with an aseismic nucleation process if transient geodetic deformation was present. No significant aftershock expansion towards the NE was noted, possibly due to the presence of a geometrical fault barrier east of the Anydros Ridge. The 2025 activity offered an excellent opportunity to investigate deciphering the type of ongoing seismicity cluster for real-time discrimination between foreshocks, aftershocks, and swarms. Full article
(This article belongs to the Special Issue Editorial Board Members' Collection Series: Natural Hazards)
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17 pages, 5353 KiB  
Article
Evaluation of Hardfacing Layers Applied by FCAW-S on S355MC Steel and Their Influence on Its Mechanical Properties
by Fineas Morariu, Timotei Morariu, Alexandru Bârsan, Sever-Gabriel Racz and Dan Dobrotă
Materials 2025, 18(15), 3664; https://doi.org/10.3390/ma18153664 - 4 Aug 2025
Abstract
Enhancing the wear resistance of structural steels used in demanding industrial applications is critical for extending components’ lifespan and ensuring mechanical reliability. In this study, we investigated the influence of flux-cored arc welding (FCAW) hardfacing on the tensile behavior of S355MC steel. Protective [...] Read more.
Enhancing the wear resistance of structural steels used in demanding industrial applications is critical for extending components’ lifespan and ensuring mechanical reliability. In this study, we investigated the influence of flux-cored arc welding (FCAW) hardfacing on the tensile behavior of S355MC steel. Protective Fe-Cr-C alloy layers were deposited in one and two successive passes using automated FCAW, followed by tensile testing of specimens oriented at varying angles relative to the weld bead direction. The methodology integrated 3D scanning and digital image correlation to accurately capture geometric and deformation parameters. The experimental results revealed a consistent reduction in tensile strength and ductility in all the welded configurations compared to the base material. The application of the second weld layer further intensified this effect, while specimen orientation influenced the degree of mechanical degradation. Microstructural analysis confirmed carbide refinement and good adhesion, but also identified welding-induced defects and residual stresses as factors that contributed to performance loss. The findings highlight a clear trade-off between improved surface wear resistance and compromised structural properties, underscoring the importance of process optimization. Strategic selection of welding parameters and bead orientation is essential to balance functional durability with mechanical integrity in industrial applications. Full article
(This article belongs to the Special Issue Advances in Welding of Alloy and Composites (2nd Edition))
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18 pages, 1156 KiB  
Review
Increased Velocity (INVELOX) Wind Delivery System: A Review of Performance Enhancement Advances
by Anesu Godfrey Chitura, Patrick Mukumba and Ngwarai Shambira
Wind 2025, 5(3), 19; https://doi.org/10.3390/wind5030019 - 4 Aug 2025
Abstract
Residential areas are characterized by closely packed buildings which disturb wind flow resulting in low wind speeds (below 2 m/s) with a high turbulence intensity (above 20%). In order to interface between off-the-shelf wind turbines and low-quality wind, the Increased velocity (INVELOX) wind [...] Read more.
Residential areas are characterized by closely packed buildings which disturb wind flow resulting in low wind speeds (below 2 m/s) with a high turbulence intensity (above 20%). In order to interface between off-the-shelf wind turbines and low-quality wind, the Increased velocity (INVELOX) wind delivery system is an attractive wind augmentation option for such regions. The INVELOX setup can harness more energy than conventional bare wind turbines under the same incident wind conditions. However, these systems also have drawbacks and challenges that they face in their operation, which amplify the need to review, understand, and expose gaps and flaws in pursuit of increased power production in low wind quality environments. This paper seeks to review and simplify the advances done by various scholars towards improving the INVELOX delivery system. It provides the mathematical foundation on which these advances are rooted and gives an understanding of how the improvements better the geometric properties of INVELOX. The article concludes by proposing future research directions. Full article
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20 pages, 5875 KiB  
Article
Optimizing Rock Bolt Support for Large Underground Structures Using 3D DFN-DEM Method
by Nooshin Senemarian Isfahani, Amin Azhari, Hem B. Motra, Hamid Hashemalhoseini, Mohammadreza Hajian Hosseinabadi, Alireza Baghbanan and Mohsen Bazargan
Geosciences 2025, 15(8), 293; https://doi.org/10.3390/geosciences15080293 - 2 Aug 2025
Viewed by 193
Abstract
A systematic sensitivity analysis using three-dimensional discrete element models with discrete fracture networks (DEM-DFN) was conducted to evaluate underground excavation support in jointed rock masses at the CLAB2 site in Southeastern Sweden. The site features a joint network comprising six distinct joint sets, [...] Read more.
A systematic sensitivity analysis using three-dimensional discrete element models with discrete fracture networks (DEM-DFN) was conducted to evaluate underground excavation support in jointed rock masses at the CLAB2 site in Southeastern Sweden. The site features a joint network comprising six distinct joint sets, each with unique geometrical properties. The study examined 10 DFNs and 19 rock bolt patterns, both conventional and unconventional. It covered 200 scenarios, including 10 unsupported and 190 supported cases. Technical and economic criteria for stability were assessed for each support system. The results indicated that increasing rock bolt length enhances stability up to a certain point. However, multi-length rock bolt patterns with similar consumption can yield significantly different stability outcomes. Notably, the arrangement and properties of rock bolts are crucial for stability, particularly in blocks between bolting sections. These blocks remain interlocked in unsupported areas due to the induced pressure from supported sections. Although equal-length rock bolt patterns are commonly used, the analysis revealed that triple-length rock bolts (3, 6, and 9 m) provided the most effective support across all ten DFN scenarios. Full article
(This article belongs to the Special Issue Computational Geodynamic, Geotechnics and Geomechanics)
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25 pages, 8312 KiB  
Article
Quantitative Assessment of Woven Fabric Surface Changes During Martindale Abrasion Using Contactless Optical Profilometry
by Małgorzata Matusiak and Gabriela Kosiuk
Materials 2025, 18(15), 3636; https://doi.org/10.3390/ma18153636 - 1 Aug 2025
Viewed by 184
Abstract
The abrasion resistance of fabrics is one of the basic properties determining the utility performance and durability. The abrasion resistance of textile materials is measured using the Martindale device according to appropriate standards. The sample breakage method is the most commonly used of [...] Read more.
The abrasion resistance of fabrics is one of the basic properties determining the utility performance and durability. The abrasion resistance of textile materials is measured using the Martindale device according to appropriate standards. The sample breakage method is the most commonly used of the three methods. The method is based on organoleptic assessment of fabric breakage. The method is time-consuming, and results may be subject to error resulting from the subjective nature of the assessment. The aim of the presented work was to check the possibility of the application of contactless 3D surface geometry measurement using an optical profilometer in an assessment of changes in fabrics’ surface due to the abrasion process. The obtained results confirmed that some parameters of the geometric structure of fabric surfaces, such as the highest height of the roughness profile Rz, the height of the highest pick of the roughness profile Rp, the depth of the lowest valley of the roughness profile Rv, the depth of the total height of the roughness profile Rt, and the kurtosis Rku, can be used to assess the abrasion resistance of fabrics. It is also stated that using the non-contact optical measurement of fabric surface geometry allows for an assessment of the directionality of surface texture. For this purpose, the autocorrelation function and angle distribution function can be applied. Full article
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24 pages, 2751 KiB  
Article
Double Wishbone Suspension: A Computational Framework for Parametric 3D Kinematic Modeling and Simulation Using Mathematica
by Muhammad Waqas Arshad, Stefano Lodi and David Q. Liu
Technologies 2025, 13(8), 332; https://doi.org/10.3390/technologies13080332 - 1 Aug 2025
Viewed by 138
Abstract
The double wishbone suspension (DWS) system is widely used in automotive engineering because of its favorable kinematic properties, which affect vehicle dynamics, handling, and ride comfort; hence, it is important to have an accurate 3D model, simulation, and analysis of the system in [...] Read more.
The double wishbone suspension (DWS) system is widely used in automotive engineering because of its favorable kinematic properties, which affect vehicle dynamics, handling, and ride comfort; hence, it is important to have an accurate 3D model, simulation, and analysis of the system in order to optimize its design. This requires efficient computational tools for parametric study. The development of effective computational tools that support parametric exploration stands as an essential requirement. Our research demonstrates a complete Wolfram Mathematica system that creates parametric 3D kinematic models and conducts simulations, performs analyses, and generates interactive visualizations of DWS systems. The system uses homogeneous transformation matrices to establish the spatial relationships between components relative to a global coordinate system. The symbolic geometric parameters allow designers to perform flexible design exploration and the kinematic constraints create an algebraic equation system. The numerical solution function NSolve computes linkage positions from input data, which enables fast evaluation of different design parameters. The integrated 3D visualization module based on Mathematica’s manipulate function enables users to see immediate results of geometric configurations and parameter effects while calculating exact 3D coordinates. The resulting robust, systematic, and flexible computational environment integrates parametric 3D design, kinematic simulation, analysis, and dynamic visualization for DWS, serving as a valuable and efficient tool for engineers during the design, development, assessment, and optimization phases of these complex automotive systems. Full article
(This article belongs to the Section Manufacturing Technology)
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17 pages, 351 KiB  
Article
Special Curves and Tubes in the BCV-Sasakian Manifold
by Tuba Ağırman Aydın and Ensar Ağırman
Symmetry 2025, 17(8), 1215; https://doi.org/10.3390/sym17081215 - 1 Aug 2025
Viewed by 147
Abstract
In this study, theorems and proofs related to spherical and focal curves are presented in the BCV-Sasakian space. An approximate solution to the differential equation characterizing spherical curves in the BCV-Sasakian manifold M3 is obtained using the Taylor matrix collocation method. The [...] Read more.
In this study, theorems and proofs related to spherical and focal curves are presented in the BCV-Sasakian space. An approximate solution to the differential equation characterizing spherical curves in the BCV-Sasakian manifold M3 is obtained using the Taylor matrix collocation method. The general equations of canal and tubular surfaces are provided within this geometric framework. Additionally, the curvature properties of the tubular surface constructed around a non-vertex focal curve are computed and analyzed. All of these results are presented for the first time in the literature within the context of the BCV-Sasakian geometry. Thus, this study makes a substantial contribution to the differential geometry of contact metric manifolds by extending classical concepts into a more generalized and complex geometric structure. Full article
(This article belongs to the Section Mathematics)
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21 pages, 1569 KiB  
Article
A Multibody-Based Benchmarking Framework for the Control of the Furuta Pendulum
by Gerardo Peláez, Pablo Izquierdo, Gustavo Peláez and Higinio Rubio
Actuators 2025, 14(8), 377; https://doi.org/10.3390/act14080377 - 31 Jul 2025
Viewed by 143
Abstract
The Furuta pendulum is a well-known benchmark in the field of underactuated mechanical systems due to its reduced number of control inputs compared to its degrees of freedom, and richly nonlinear behavior. This work addresses the challenge of accurately modeling and controlling such [...] Read more.
The Furuta pendulum is a well-known benchmark in the field of underactuated mechanical systems due to its reduced number of control inputs compared to its degrees of freedom, and richly nonlinear behavior. This work addresses the challenge of accurately modeling and controlling such a system without relying on traditional linearization techniques. In contrast to the common approach based on Lagrangian analytical modeling and state–space linearization, we propose a methodology that integrates a high-fidelity multibody model developed in Simscape Multibody (MATLAB), capturing the complete nonlinear dynamics of the system. The multibody model includes all geometric, inertial, and joint parameters of the physical hardware and interfaces directly with Simulink, enabling realistic simulation and control integration. To validate the physical fidelity of the multibody model, we perform a frequency-domain analysis of the pendulum’s natural free response. The dominant vibration frequency extracted from the simulation is compared with the theoretical prediction, demonstrating accurate capture of the system’s inertial and dynamic properties. This validation strategy strengthens the reliability of the model as a digital twin. The classical analytical formulation is provided to validate the simulation model and serve as a comparative framework. This dual modeling strategy allows for benchmarking control strategies against a trustworthy nonlinear digital twin of the Furuta pendulum. Preliminary experimental results using a physical prototype validate the feasibility of the proposed approach and set the foundation for future work in advanced nonlinear control design using the multibody representation as a digital validation tool. Full article
(This article belongs to the Special Issue Dynamics and Control of Underactuated Systems)
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21 pages, 7202 KiB  
Article
Monocular Vision-Based Swarm Robot Localization Using Equilateral Triangular Formations
by Taewon Kang, Ji-Wook Kwon, Il Bae and Jin Hyo Kim
Machines 2025, 13(8), 667; https://doi.org/10.3390/machines13080667 - 29 Jul 2025
Viewed by 277
Abstract
Localization of mobile robots is crucial for deploying robots in real-world applications such as search and rescue missions. This work aims to develop an accurate localization system applicable to swarm robots equipped only with low-cost monocular vision sensors and visual markers. The system [...] Read more.
Localization of mobile robots is crucial for deploying robots in real-world applications such as search and rescue missions. This work aims to develop an accurate localization system applicable to swarm robots equipped only with low-cost monocular vision sensors and visual markers. The system is designed to operate in fully open spaces, without landmarks or support from positioning infrastructures. To achieve this, we propose a localization method based on equilateral triangular formations. By leveraging the geometric properties of equilateral triangles, the accurate two-dimensional position of each participating robot is estimated using one-dimensional lateral distance information between robots, which can be reliably and accurately obtained with a low-cost monocular vision sensor. Experimental and simulation results demonstrate that, as travel time increases, the positioning error of the proposed method becomes significantly smaller than that of a conventional dead-reckoning system, another low-cost localization approach applicable to open environments. Full article
(This article belongs to the Section Robotics, Mechatronics and Intelligent Machines)
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20 pages, 11218 KiB  
Article
Solvatochromic and Computational Study of Three Benzo-[f]-Quinolinium Methylids with Photoinduced Charge Transfer
by Mihaela Iuliana Avadanei, Ovidiu Gabriel Avadanei and Dana Ortansa Dorohoi
Molecules 2025, 30(15), 3162; https://doi.org/10.3390/molecules30153162 - 29 Jul 2025
Viewed by 176
Abstract
The solvatochromic properties of 48 solvents of three benzo-[f]-quinolinium methylids (BfQs) were analyzed within the theories of the variational model and Abe’s model of the liquid. The electro-optical properties of BfQs in the first excited state were determined based on the charge transfer [...] Read more.
The solvatochromic properties of 48 solvents of three benzo-[f]-quinolinium methylids (BfQs) were analyzed within the theories of the variational model and Abe’s model of the liquid. The electro-optical properties of BfQs in the first excited state were determined based on the charge transfer process that occurs from the ylid carbon to the nitrogen atom. The dipole moments and the polarizabilities in the first excited state were calculated according to the two models. The quantum chemical calculations helped in understanding the relationship between the molecular structure and absorption properties of the ground state. It is concluded that several key parameters modulate the strength of the charge transfer and they work in synergy, and the most important are as follows: (i) isomerism around the single polar bond, and (ii) the properties of the solvent. The link between geometrical conformation and the zwitterionic character make the studied BfQs very sensitive chromophores for sensors and optical switching devices. Full article
(This article belongs to the Special Issue Feature Papers in Applied Chemistry: 4th Edition)
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