Search Results (3,065)

The shipping sector is responsible for a considerable share of global CO₂ emissions and is under pressure to reduce emissions and adopt carbon-neutral fuels. Among the proposed alternatives, methanol produced from green hydrogen and biogenic CO₂ represents a promising option. However, the feasibility of its production is significantly influenced by the composition and variability of the bio-CO₂ feedstock, which can negatively impact the complete value chain. To address these challenges, sampling campaigns were carried out at actual bio-CO₂-emitting sites, namely biogas and biomass combustion facilities, to characterize the impurity profiles and determine the appropriate conditioning requirements. A novel membrane gas absorption system with a Diethanolamine solution was deployed directly in the field to capture, as well as purify to a certain extent, the CO₂ stream. The system demonstrated high efficiency in removing most impurities, achieving high CO₂ capture rates and impurity reduction close to 90%. However, residual chlorine species were detected in the CO₂ streams from biogas plants, suggesting the need for additional conditioning to meet the purity specifications required for methanol synthesis. Given that the feedstock composition and upstream process conditions could significantly affect the final output and present considerable variations, the implementation of additional cleaning measures is recommended before synthesis. Full article

During the operation of nuclear power plants, nuclear fuel undergoes significant compositional changes. After several cycles of use, the fuel must be removed and stored. Currently, spent fuel is stored mainly in pools or casks, and it is necessary to demonstrate the subcriticality of these systems. Spent nuclear fuel has a complex composition, and because computational codes are typically validated using fresh-fuel experiments, subcriticality assessments are usually performed conservatively with fresh-fuel compositions. These approaches demonstrate subcriticality but are very conservative and can lead to storage system designs that are more expensive or have reduced capacity. This paper focuses on the validation of computational codes using nuclear power plant critical start-up tests (referred to as reactor criticals). These tests include spent fuel and are well documented, allowing them to serve as validation experiments. Codes validated using reactor criticals can be applied to systems containing spent fuel calculation if sufficient similarity is demonstrated. Similarity is evaluated using the SCALE TSUNAMI-IP module, which is widely used for this purpose. Based on a database containing dozens of reactor criticals and similarity analyses, we developed a methodology for demonstrating the subcriticality of spent-fuel storage systems. Full article

The use of resource-saving technology in road construction material production is a current problem, the solution of which will allow us to increase the environmental and economic efficiency of the road construction industry. Nowadays, secondary raw materials are widely used in highway construction, obtained both from the waste of old road construction materials and collected from other industries. During asphalt production, up to 90% of raw materials can be replaced by reclaimed asphalt pavement (RAP). This technology requires residual binder modification to reduce the negative impact on the technological and operational asphalt concrete properties. On the other hand, the use of rubber crumbs or granules obtained from the disposal of old car tires in asphalt–concrete mixtures is widespread. However, some types of car tires cannot be used as raw materials to produce an effective modifier. Truck tires and tires from special vehicles are suitable for use as a modifier for asphalt–concrete mixtures. Tires designed for passenger cars do not contain enough polymer. As an experiment on asphalt–concrete mixture production using secondary resources only, a testing facility was developed. The testing facility uses hot gas obtained by burning automobile tires in a special oven as a heat source. Rubber residues from the recycling of automobile tires are used as fuel, which cannot be used to produce rubber powder or granules. RAP obtained by cold milling of the pavements of city and public roads was used as the object of the research. When studying the characteristics of the asphalt–concrete-mixture-based binder, it was found that the sulfur compounds present in the composition of hot gases change the properties of the binder, leading to a serious deterioration in the technological characteristics of asphalt–concrete mixtures. The asphalt–concrete mixture obtained during RAP processing is characterized by a narrow temperature range in which it can be laid and compacted to the required density values. After laying the pavement, quality control revealed a significant variation (the number of air voids ranged from 0.8 to 5.5%) in the average density of samples taken from the compacted layer. In addition, there were significant violations of the longitudinal evenness of the finished coating. Experiments were carried out to extract the binder from asphalt–concrete mixtures before and after regeneration. The physico-mechanical and rheological characteristics were studied and qualitative analysis of the binder was realized by IR spectroscopy. The data obtained allow us to establish the mechanism of how sulfur-containing gases influence the bitumen binder’s properties in asphalt mixtures. Additionally, the features of thermo-oxidative degradation occurring during the hot recycling of asphalt–concrete mixtures were established. A justification is also given for the need to use anti-aging modifiers to restore the properties of the residual binder. Full article

The global population explosion and accelerated industrialization have led to an increasing shortage of fossil fuels and environmental contamination, underscoring the urgent need to develop innovative energy storage technologies to improve energy utilization efficiency. As pivotal components in thermal energy storage (TES) systems, phase change materials (PCMs) enable spatiotemporal matching between thermal energy supply and demand through latent heat absorption and release during phase transitions. Organic PCMs are considered ideal candidates for thermal energy storage due to their high energy storage density, stable phase transition temperature, low supercooling, and negligible phase separation. However, inherent drawbacks such as low thermal conductivity, liquid leakage, limited light absorption, and lack of functionality have hindered their widespread application in advanced thermal management systems. Herein, we systematically summarize cutting-edge functionalization strategies for PCMs, progressing from conventional methods like thermal conductive particle blending and microencapsulation to the emerging design of 3D porous thermally conductive skeletons, including metal foams, boron nitride aerogels, carbon-based aerogels, and MXene aerogels. These frameworks not only enhance thermal transport via continuous conductive pathways and impart shape stability through capillary encapsulation but also, when integrated with photo-thermal, electro-thermal, and magneto-thermal conversion properties, enable broad applications in solar photo-thermal/photo-thermo-electric conversion, thermal management of electronics and batteries, building efficiency, and wearable thermal regulation. The review further addresses current challenges and future directions, highlighting scalable 3D framework fabrication, the shift to active thermal management, and innovative applications beyond conventional domains. By establishing a microstructure–property–application correlation, this work provides valuable insights for developing next-generation high-performance multifunctional phase change composites. Full article

Cellular automata-based wildfire simulation models are widely used to support fire management, risk assessment, and operational decision-making, due to their efficiency and computational advantages. However, the accuracy of these models heavily depends on the quality of input data provided by the user, including the composition and geospatial extend of forest fuels, current meteorological conditions and terrain information. This publication examines how quantitative and spatial input data uncertainties affect the estimates of the impacted areas. Using a series of simulation experiments, inaccurate data are introduced to specific input variables (such as the vegetation type and the fuel moisture content) to reflect realistic levels of uncertainty commonly observed in operational scenarios, where users with different cognitive backgrounds fail to properly identify key characteristics of a fire. Model outputs are then compared using spatial and temporal performance metrics, including the rate of spread and burned area extent. The results demonstrate that uncertainties in fuel models and meteorological inputs exert a dominant influence on simulated fire behavior. Our findings highlight the sensitivity of wildfire simulations to compounded input uncertainties and stress the need for improved in-field data acquisition strategies. Full article

Pressure swing adsorption (PSA) is a viable method for separating hydrogen from gas mixtures, an important aspect of long-term hydrogen storage in depleted gas fields. This study explores optimizing a 12-step PSA process for recovering high-purity hydrogen from varying compositions of hydrogen–methane mixtures, simulating the conditions likely encountered during hydrogen storage and recovery. Step-time optimization was performed on four different hydrogen–methane mixtures using the toPSAil simulation package—an open-source dynamic PSA simulator developed by researchers at the Georgia Institute of Technology—integrated with a particle swarm optimization (PSO) algorithm. The goal was to develop an optimization framework that can reliably identify PSA step times for different operating scenarios and satisfy specified purity and recovery constraints under fluctuating wellhead feed conditions. The optimization converged within 25–30 iterations, even in high-contaminant, low-pressure scenarios, where PSA performance is traditionally weak. The product purity in the optimized cycles was above 99.1% with more than 80% recovery for all cases, while fuel cell quality (99.7%) hydrogen was achieved in two out of the four scenarios. The purge-to-feed ratio of the best-performing cycles was between 0.07 and 0.32. These findings show the potential of the proposed approach in overcoming the difficulty of designing PSA cycles for non-constant gas compositions and achieving a hydrogen purification process suitable for variable feed conditions. The workflow generates a large synthetic dataset that can support surrogate or hybrid modeling. The results can help advance research in other gas separation areas with non-constant conditions, like flue gas or biogas purification. Full article

This paper presents the analysis and results of the numerical simulation of the biofuel combustion process: namely, the volumetric mixture of diesel oil (ON) and camelina seed oil methyl ester (CSME) in a diesel engine. The mathematical model used in the simulation is based on a four-stroke diesel engine acting as a power generator. To enable simulations depending on the type of biofuel, a model algorithm was developed in the MATLAB/Simulink environment that allowed for the conditions and parameters to be adjusted according to specific test requirements. The numerical simulation was built on the basis of a real stand, in order to confirm the results of previous research both theoretically and in real applications. The calculation approach starts with the elemental composition of the fuel and goes through the intake, compression, combustion, and expansion stages, culminating in the thermal balance of the engine. The mathematical model confirmed the obtained results, which are comparable to the results from the research station. The obtained results confirm the legitimacy of using CSME as an additive to diesel and show its impact on engine performance that can be optimized to achieve the desired results. The use of pure CSME (100%) resulted in an increase in engine power and torque, probably due to the oxygen content of the biofuel molecules and its higher cetane number, which improves its ignition characteristics. However, an increase in unit fuel consumption has been observed, indicating lower energy efficiency compared to clean diesel, which is partially offset by the higher density of biofuel. The model takes into account the physicochemical properties of the fuel, such as the viscosity, cetane number and density, which significantly affect the fuel injection and atomization processes. Although the simulation is based on simplified assumptions, its results highlight the potential of biofuels in heavy transport and their cost-effectiveness as an alternative to fossil fuels. The developed model is used not only to evaluate the engine performance, but also as a tool for assessing the thermal efficiency, and optimizing the composition of the fuel mixture. Full article

The application of ammonia decomposition technology for hydrogen production enables hydrogen-enriched combustion in marine diesel-ignited ammonia engines. This study presents experimental and simulation investigations of a diesel-ignited ammonia engine operating with hydrogen-containing fuels derived from ammonia decomposition at various blending ratios. The combustion and emission characteristics of the engine were systematically examined, and a comparative analysis was conducted on the combustion behavior of the engine between using ammonia decomposition-derived hydrogen-containing fuel and pure hydrogen. The result shows that under constant engine output power, at 1200 rpm and 75% load, increasing the hydrogen energy rate results in largely unchanged cylinder pressure and heat release rate. The diesel substitution rate exhibits an initial increase followed by a decrease, while the energy consumption rate demonstrates the opposite trend. At 1500 rpm and 75% load, an increase in hydrogen enrichment leads to an earlier rise in cylinder pressure and heat release rate, a continuous increase in diesel substitution rate, and a consistent decrease in energy consumption rate. The early stage of in-cylinder combustion is dominated by diesel combustion, followed predominantly by the combustion of ammonia and hydrogen. Regarding the difference between using decomposition-derived hydrogen-containing fuel and pure hydrogen, within the hydrogen enrichment range of 0–20%, the discrepancies in intake composition and equivalence ratio between the two hydrogen-addition modes gradually widen but remain within 1.3%. Taking a hydrogen energy rate of 10.56% as an example, the differences in in-cylinder pressure and heat release rate between the two hydrogen-addition modes are not significant, indicating that the N₂ generated from ammonia decomposition has a relatively weak influence on the engine. With increasing hydrogen enrichment, NH₃ emissions gradually decrease, while NO emissions increase. For N₂O, hydrogen enrichment promotes its consumption, resulting in lower emissions. Under various hydrogen enrichment conditions, equivalent greenhouse gas emissions are mainly influenced by CO₂ emissions. Full article

To address the corrosion protection issues for hot components of high-end equipment in extreme service environments, the C276 alloy coating was deposited on the surface of 304 stainless steel via high-velocity air fuel (HVAF) spraying. The extreme conditions of 1000 °C temperature, an atmosphere containing 6% HCl, and a flow rate of 30 m/s were simulated in the study using a high-temperature airflow corrosion erosion device. The C276 coating and the 304 stainless steel substrates were subjected to a corrosion test for 25 min. The surface phase composition, element distribution, corrosion product characteristics, and cross-section structure of the samples before and after corrosion were systematically analyzed by means of a scanning electron microscope, an energy dispersive spectrometer, and an X-ray diffractometer. The mechanism of high-temperature chlorination corrosion was deduced through thermodynamic and kinetic analysis. The results show that compared with 304 stainless steel, the C276 alloy coating exhibits better corrosion resistance in an extremely high-temperature environment containing HCl, and the average weight gain and growth rate of the corrosion layer were lower. The main corrosion products on the C276 coating surface are Fe₂O₃, FeO, FeCl₂, NiO, and Cr₂O₃, among which the oxides of Ni and Cr form a continuous and dense protective oxide layer that effectively inhibits the intrusion of corrosive media. The high-temperature HCl corrosion follows the ‘chlorination–oxidation’ cycle mechanism, and Cl₂ plays a catalytic role in the reaction and accelerates the corrosion process. Full article

SrTiO₃ has attracted considerable attention owing to its favorable electronic structure and chemical stability among various semiconductor photocatalysts. However, its practical application is hindered by a wide bandgap and rapid recombination of photogenerated charge carriers. Herein, we report the fabrication of a SrTiO₃/carbon quantum dot (CQD) heterojunction via a two-step hydrothermal method for efficient CO₂-to-CH₄ photocatalysis, a strategy that circumvents the need for high-temperature treatment and noble metals. TEM images revealed well-defined lattice fringes and intimate interfacial contact between SrTiO₃ and CQDs, suggesting efficient charge transfer pathways. Optical measurements confirmed that CQD modification extends the visible-light absorption range of SrTiO₃ to 420 nm while significantly enhancing charge separation efficiency. The SrTiO₃/CQDs composite with 10 wt% CQD loading exhibited optimal activity, achieving a CH₄ evolution rate of 1.16 μmol·g⁻¹·h⁻¹—16.3 times higher than that of pristine SrTiO₃. Mechanistic investigations demonstrate that CQDs serve as efficient electron reservoirs, facilitating interfacial charge transfer and suppressing the recombination of photogenerated charge carriers. The catalyst maintained stable performance over four consecutive cycles, confirming its structural robustness and reusability. This work demonstrates that CQD modification effectively enhances the visible-light response and charge separation efficiency of SrTiO₃, offering a viable strategy for designing high-performance photocatalysts toward solar fuel production. Full article

The paper explores the association between macroeconomic conditions (MCI), energy-related factors (ENI), and sustainable entrepreneurial capacity at the macro level (SEI) in Denmark, Germany, the Netherlands, Poland, and Sweden over the period 2008–2024. SEI is constructed as a composite index that reflects the macro-level economic, social, and environmental dimensions of enterprise activity rather than firm-level entrepreneurial behaviour. Both MCI and ENI capture multidimensional external macroeconomic and energy-related conditions. The study employs correlation analysis, ordinary least squares (OLS), and seemingly unrelated regressions (SUR). The results indicate cross-country heterogeneity (p < 0.05). MCI has heterogeneous effects that support SEI in more advanced countries and have weaker or context-dependent effects in less advanced countries. ENI has heterogeneous effects that support SEI in systems based on renewables and weaken SEI in situations with high costs and fossil fuels. SUR results indicate strong systemic interdependence among the economic, social, and environmental pillars, highlighting their joint and mutually reinforcing role at the macro level. In general, the results indicate that macroeconomic and energy policies are related to SEI in country-specific ways, underscoring the importance of policy frameworks tailored to national structural characteristics. Full article

The 2011 Fukushima accident highlighted the vulnerability of traditional Zr alloy fuel cladding under loss-of-coolant accident (LOCA) conditions, prompting the development of accident-tolerant fuel (ATF) systems. A promising near-term solution involves depositing protective coatings on existing Zr alloy cladding. Among various deposition techniques, cold spray technology has emerged as one of the leading methods due to its solid-state, low-temperature process, which minimises thermal degradation and allows for the deposition of a wide range of high-performance materials. This review provides a comprehensive examination of recent advances in cold-sprayed coatings for ATF cladding, beginning with an overview of the fundamentals of cold spray technology and its specific advantages for nuclear applications. The core of the review critically analyses three primary coating systems: Cr, FeCrAl alloys, and MAX phase composites, with a particular focus on Cr coatings, as they have been more extensively studied compared to the other two material systems. Key coating properties, including microstructure of the coating-substrate interface, mechanical properties, thermal conductivity, oxidation resistance, irradiation tolerance, and performance under normal operation and simulated LOCA conditions, are discussed in detail, with particular emphasis on the potential of cold-sprayed Cr coatings to enhance Zr alloy cladding. Cr coatings demonstrate significant improvements in oxidation resistance and irradiation stability, but also face challenges such as high-temperature interfacial reactions. To address these issues, promising solutions, such as diffusion-barrier bilayer systems, are being explored. Additionally, the review discusses FeCrAl and MAX phase composite coatings, highlighting their promising long-term performance under extreme conditions. The review concludes with recommendations for further research to optimise cold spray processes and ensure the robustness of coatings in operational reactor environments. Full article

This paper builds a one-dimensional transient numerical model of mixed fuel of woody and non-woody biomass to simulate the multistage conversion process of biomass in a moving grate-fired bed, including drying, pyrolysis, gasification, and char combustion. Based on time and space discretization, the model comprehensively considers the conservation of mass, momentum, and energy. It also introduces reaction kinetics and freeboard radiation coupling effects to more accurately describe the bed temperature distribution and reaction process. The analysis focuses on the effects of different non-woody biomass mixing ratios and moisture content. This provides references for optimization of the design of future furnaces and operating parameters and mixed fuel composition. The simulation results show that, for pure woody biomass, the surface temperature reaches approximately 200 °C in the first zone, followed by char reactions with peak temperatures up to 592 °C. The whole conversion process takes about 62% of the grate length. Increasing the pepper mixing ratio leads to lower bed temperatures due to the higher moisture content. The maximum bed temperature in the first zone decreases from 592 °C for pure wood to 551 °C at 30 wt.% pepper, with delayed pyrolysis and a thinner char reaction zone. When the pepper mixing ratio is below 20 wt.%, the combustion process maintains a stable temperature gradient and a continuous reaction front, compared to the mixing ratio of 30% pepper case. This confirms the feasibility of non-woody biomass application to combustion technology. Although a higher pepper mixing ratio leads to a slight temperature decrease, the reaction remains stable along the grate, indicating reliable combustion performance. Full article

This study presents a comprehensive investigation into the application of Life Cycle Assessment (LCA) for advanced manufacturing and recycling processes, with a focus on achieving sustainability goals. The environmental and economic impacts of additive manufacturing (AM) and innovative recycling strategies for materials like carbon fiber-reinforced plastics (CFRPs) and 3D printing polymers are analyzed. Experimental efforts detail the preparation of recycled plastic–carbon fiber composite filaments suitable for Fused Filament Fabrication (FFF). The composite exhibits enhanced mechanical, thermal, and flame-resistant properties through optimal blending of plastic waste and carbon fibers. Sustainability assessments using Open LCA 2.2.0 and SolidWorks 2022 demonstrate significant environmental benefits aligned with circular economy principles. The analysis highlights that the weight reduction results in lifetime fuel savings combined with end-of-life credits of −1.32 kg CO₂-eq for composite core versus +0.10 kg CO₂-eq for plastic parts. The recycled composite achieves a net global warming potential of −12.55 kg CO₂-eq, compared to +2.44 kg CO₂-eq for plastic components. The study emphasizes challenges such as recyclability, material degradation, and regional applicability of global LCA models, while proposing pathways for future advancements. Full article

The non-repeatability of the internal combustion engine’s cycle-by-cycle (CCN-R) operation directly affects pollutant emissions, fuel consumption, and energy efficiency. Reducing this non-repeatability is an important part of efforts to improve the environmental performance of power units. Cycle variability analysis allows the identification of engine operating areas that promote unstable combustion and increased emissions of harmful exhaust components. The aim of the study was to quantitatively assess the cycle-to-cycle non-repeatability COV of selected operating parameters of the Perkins 1104D-E44TA diesel engine. The analyses covered the maximum cylinder pressure (p_max), the mean indicated pressure (IMEP), and the crankshaft rotation angle corresponding to the occurrence of maximum pressure (α). The measurements were carried out on an engine dynamometer at 25 operating points, covering speeds 1000–2200 r./min and load torques 200–400 N × m, recording 500 consecutive operating cycles at each point. The results showed that the most stable engine operation occurred at medium rotational speeds and moderate loads, where COV_pmax values did not exceed 0.5% and COV_IMEP values were lower than 1.0%. Increased pmax non-repeatability (up to 2.10%) and very high α angle variability (up to 100–140%) were observed at high rotational speeds and high loads. Only in the case of COV_IMEP was a significant reduction in repeatability observed compared to idling. The results obtained from cycle-by-cycle non-repeatability analyses can ultimately, after being supplemented with exhaust gas composition testing, be used as tools to support engine control optimization in order to reduce pollutant emissions and improve combustion efficiency. Full article