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17 pages, 5214 KiB  
Article
Geothermal–Peltier Hybrid System for Air Cooling and Water Recovery
by Michele Spagnolo, Paolo Maria Congedo, Alessandro Buscemi, Gianluca Falcicchia Ferrara, Marina Bonomolo and Cristina Baglivo
Energies 2025, 18(15), 4115; https://doi.org/10.3390/en18154115 (registering DOI) - 3 Aug 2025
Abstract
This study proposes a new air treatment system that integrates dehumidification, cooling, and water recovery using a Horizontal Air–Ground Heat Exchanger (HAGHE) combined with Peltier cells. The airflow generated by a fan flows through an HAGHE until it meets a septum on which [...] Read more.
This study proposes a new air treatment system that integrates dehumidification, cooling, and water recovery using a Horizontal Air–Ground Heat Exchanger (HAGHE) combined with Peltier cells. The airflow generated by a fan flows through an HAGHE until it meets a septum on which Peltier cells are placed, and then separates into two distinct streams that lap the two surfaces of the Peltier cells: one stream passes through the cold surfaces, undergoing both sensible and latent cooling with dehumidification; the other stream passes through the hot surfaces, increasing its temperature. The two treated air streams may then pass through a mixing chamber, where they are combined in the appropriate proportions to achieve the desired air supply conditions and ensure thermal comfort in the indoor environment. A Computational Fluid Dynamics (CFD) analysis was carried out to simulate the thermal interaction between the HAGHE and the surrounding soil. The simulation focused on a system installed under the subtropical climate conditions of Nairobi, Africa. The simulation results demonstrate that the HAGHE system is capable of reducing the air temperature by several degrees under typical summer conditions, with enhanced performance observed when the soil is moist. Condensation phenomena were triggered when the relative humidity of the inlet air exceeded 60%, contributing additional cooling through latent heat extraction. The proposed HAGHE–Peltier system can be easily powered by renewable energy sources and configured for stand-alone operation, making it particularly suitable for off-grid applications. Full article
(This article belongs to the Section A: Sustainable Energy)
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29 pages, 4812 KiB  
Article
Geochemical Assessment of Long-Term CO2 Storage from Core- to Field-Scale Models
by Paa Kwesi Ntaako Boison, William Ampomah, Jason D. Simmons, Dung Bui, Najmudeen Sibaweihi, Adewale Amosu and Kwamena Opoku Duartey
Energies 2025, 18(15), 4089; https://doi.org/10.3390/en18154089 (registering DOI) - 1 Aug 2025
Viewed by 26
Abstract
Numerical simulations enable us to couple multiphase flow and geochemical processes to evaluate how sequestration impacts brine chemistry and reservoir properties. This study investigates these impacts during CO2 storage at the San Juan Basin CarbonSAFE (SJB) site. The hydrodynamic model was calibrated [...] Read more.
Numerical simulations enable us to couple multiphase flow and geochemical processes to evaluate how sequestration impacts brine chemistry and reservoir properties. This study investigates these impacts during CO2 storage at the San Juan Basin CarbonSAFE (SJB) site. The hydrodynamic model was calibrated through history-matching, utilizing data from saltwater disposal wells to improve predictive accuracy. Core-scale simulations incorporating mineral interactions and equilibrium reactions validated the model against laboratory flow-through experiments. The calibrated geochemical model was subsequently upscaled into a field-scale 3D model of the SJB site to predict how mineral precipitation and dissolution affect reservoir properties. The results indicate that the majority of the injected CO2 is trapped structurally, followed by residual trapping and dissolution trapping; mineral trapping was found to be negligible in this study. Although quartz and calcite precipitation occurred, the dissolution of feldspars, phyllosilicates, and clay minerals counteracted these effects, resulting in a minimal reduction in porosity—less than 0.1%. The concentration of the various ions in the brine is directly influenced by dissolution/precipitation trends. This study provides valuable insights into CO2 sequestration’s effects on reservoir fluid dynamics, mineralogy, and rock properties in the San Juan Basin. It highlights the importance of reservoir simulation in assessing long-term CO2 storage effectiveness, particularly focusing on geochemical interactions. Full article
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37 pages, 7429 KiB  
Article
Study on the Influence of Window Size on the Thermal Comfort of Traditional One-Seal Dwellings (Yikeyin) in Kunming Under Natural Wind
by Yaoning Yang, Junfeng Yin, Jixiang Cai, Xinping Wang and Juncheng Zeng
Buildings 2025, 15(15), 2714; https://doi.org/10.3390/buildings15152714 (registering DOI) - 1 Aug 2025
Viewed by 47
Abstract
Under the dual challenges of global energy crisis and climate change, the building sector, as a major carbon emitter consuming 33% of global primary energy, has seen its energy efficiency optimization become a critical pathway towards achieving carbon neutrality goals. The Window-to-Wall Ratio [...] Read more.
Under the dual challenges of global energy crisis and climate change, the building sector, as a major carbon emitter consuming 33% of global primary energy, has seen its energy efficiency optimization become a critical pathway towards achieving carbon neutrality goals. The Window-to-Wall Ratio (WWR), serving as a core parameter in building envelope design, directly influences building energy consumption, with its optimized design playing a decisive role in balancing natural daylighting, ventilation efficiency, and thermal comfort. This study focuses on the traditional One-Seal dwellings (Yikeyin) in Kunming, China, establishing a dynamic wind field-thermal environment coupled analysis framework to investigate the impact mechanism of window dimensions (WWR and aspect ratio) on indoor thermal comfort under natural wind conditions in transitional climate zones. Utilizing the Grasshopper platform integrated with Ladybug, Honeybee, and Butterfly plugins, we developed parametric models incorporating Kunming’s Energy Plus Weather meteorological data. EnergyPlus and OpenFOAM were employed, respectively, for building heat-moisture balance calculations and Computational Fluid Dynamic (CFD) simulations, with particular emphasis on analyzing the effects of varying WWR (0.05–0.20) on temperature-humidity, air velocity, and ventilation efficiency during typical winter and summer weeks. Key findings include, (1) in summer, the baseline scenario with WWR = 0.1 achieves a dynamic thermal-humidity balance (20.89–24.27 °C, 65.35–74.22%) through a “air-permeable but non-ventilative” strategy, though wing rooms show humidity-heat accumulation risks; increasing WWR to 0.15–0.2 enhances ventilation efficiency (2–3 times higher air changes) but causes a 4.5% humidity surge; (2) winter conditions with WWR ≥ 0.15 reduce wing room temperatures to 17.32 °C, approaching cold thresholds, while WWR = 0.05 mitigates heat loss but exacerbates humidity accumulation; (3) a symmetrical layout structurally constrains central ventilation, maintaining main halls air changes below one Air Change per Hour (ACH). The study proposes an optimized WWR range of 0.1–0.15 combined with asymmetric window opening strategies, providing quantitative guidance for validating the scientific value of vernacular architectural wisdom in low-energy design. Full article
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18 pages, 1583 KiB  
Article
Heat Transfer Characteristics of Thermosyphons Used in Vacuum Water Heaters
by Zied Lataoui, Adel M. Benselama and Abdelmajid Jemni
Fluids 2025, 10(8), 199; https://doi.org/10.3390/fluids10080199 - 31 Jul 2025
Viewed by 61
Abstract
A two-phase closed thermosyphon (TPCT), a gravity-assisted heat pipe, is a highly efficient heat transmitter involving liquid–vapor phase change. It is used in many applications, including heat spreading, thermal management and control, and energy saving. The main objective of this study is to [...] Read more.
A two-phase closed thermosyphon (TPCT), a gravity-assisted heat pipe, is a highly efficient heat transmitter involving liquid–vapor phase change. It is used in many applications, including heat spreading, thermal management and control, and energy saving. The main objective of this study is to investigate the effects of the operating conditions for a thermosyphon used in solar water heaters. The study particularly focuses on the influence of the inclination angle. Thus, a comprehensive simulation model is developed using the volume of fluid (VOF) approach. Complex and related phenomena, including two-phase flow, phase change, and heat exchange, are taken into account. To implement the model, an open-source CFD toolbox based on finite volume formulation, OpenFOAM, is used. The model is then validated by comparing numerical results to the experimental data from the literature. The obtained results show that the simulation model is reliable for investigating the effects of various operating conditions on the transient and steady-state behavior of the thermosyphon. In fact, bubble creation, growth, and advection can be tracked correctly in the liquid pool at the evaporator. The effects of the designed operating conditions on the heat transfer parameters are also discussed. In particular, the optimal tilt angle is shown to be 60° for the intermediate saturation temperature (<50 °C) and 90° for the larger saturation temperature (>60 °C). Full article
(This article belongs to the Special Issue Convective Flows and Heat Transfer)
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21 pages, 8015 KiB  
Article
Differential Mechanism of 3D Motions of Falling Debris in Tunnels Under Extreme Wind Environments Induced by a Single Train and by Trains Crossing
by Wei-Chao Yang, Hong He, Yi-Kang Liu and Lun Zhao
Appl. Sci. 2025, 15(15), 8523; https://doi.org/10.3390/app15158523 (registering DOI) - 31 Jul 2025
Viewed by 81
Abstract
The extended operation of high-speed railways has led to an increased incidence of tunnel lining defects, with falling debris posing a significant safety threat. Within tunnels, single-train passage and trains-crossing events constitute the most frequent operational scenarios, both generating extreme aerodynamic environments that [...] Read more.
The extended operation of high-speed railways has led to an increased incidence of tunnel lining defects, with falling debris posing a significant safety threat. Within tunnels, single-train passage and trains-crossing events constitute the most frequent operational scenarios, both generating extreme aerodynamic environments that alter debris trajectories from free fall. To systematically investigate the aerodynamic differences and underlying mechanisms governing falling debris behavior under these two distinct conditions, a three-dimensional computational fluid dynamics (CFD) model (debris–air–tunnel–train) was developed using an improved delayed detached eddy simulation (IDDES) turbulence model. Comparative analyses focused on the translational and rotational motions as well as the aerodynamic load coefficients of the debris in both single-train and trains-crossing scenarios. The mechanisms driving the changes in debris aerodynamic behavior are elucidated. Findings reveal that under single-train operation, falling debris travels a greater distance compared with trains-crossing conditions. Specifically, at train speeds ranging from 250–350 km/h, the average flight distances of falling debris in the X and Z directions under single-train conditions surpass those under trains crossing conditions by 10.3 and 5.5 times, respectively. At a train speed of 300 km/h, the impulse of CFx and CFz under single-train conditions is 8.6 and 4.5 times greater than under trains-crossing conditions, consequently leading to the observed reduction in flight distance. Under the conditions of trains crossing, the falling debris is situated between the two trains, and although the wind speed is low, the flow field exhibits instability. This is the primary factor contributing to the reduced flight distance of the falling debris. However, it also leads to more pronounced trajectory deviations and increased speed fluctuations under intersection conditions. The relative velocity (CRV) on the falling debris surface is diminished, resulting in smaller-scale vortex structures that are more numerous. Consequently, the aerodynamic load coefficient is reduced, while the fluctuation range experiences an increase. Full article
(This article belongs to the Special Issue Transportation and Infrastructures Under Extreme Weather Conditions)
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20 pages, 4117 KiB  
Review
Analytical Strategies for Tocopherols in Vegetable Oils: Advances in Extraction and Detection
by Yingfei Liu, Mengyuan Lv, Yuyang Wang, Jinchao Wei and Di Chen
Pharmaceuticals 2025, 18(8), 1137; https://doi.org/10.3390/ph18081137 - 30 Jul 2025
Viewed by 123
Abstract
Tocopherols, major lipid-soluble components of vitamin E, are essential natural products with significant nutritional and pharmacological value. Their structural diversity and uneven distribution across vegetable oils require accurate analytical strategies for compositional profiling, quality control, and authenticity verification, amid concerns over food fraud [...] Read more.
Tocopherols, major lipid-soluble components of vitamin E, are essential natural products with significant nutritional and pharmacological value. Their structural diversity and uneven distribution across vegetable oils require accurate analytical strategies for compositional profiling, quality control, and authenticity verification, amid concerns over food fraud and regulatory demands. Analytical challenges, such as matrix effects in complex oils and the cost trade-offs of green extraction methods, complicate these processes. This review examines recent advances in tocopherol analysis, focusing on extraction and detection techniques. Green methods like supercritical fluid extraction and deep eutectic solvents offer selectivity and sustainability, though they are costlier than traditional approaches. On the analytical side, hyphenated techniques such as supercritical fluid chromatography-mass spectrometry (SFC-MS) achieve detection limits as low as 0.05 ng/mL, improving sensitivity in complex matrices. Liquid chromatography-tandem mass spectrometry (LC-MS/MS) provides robust analysis, while spectroscopic and electrochemical sensors offer rapid, cost-effective alternatives for high-throughput screening. The integration of chemometric tools and miniaturized systems supports scalable workflows. Looking ahead, the incorporation of Artificial Intelligence (AI) in oil authentication has the potential to enhance the accuracy and efficiency of future analyses. These innovations could improve our understanding of tocopherol compositions in vegetable oils, supporting more reliable assessments of nutritional value and product authenticity. Full article
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17 pages, 5896 KiB  
Article
Simulation Study of the Effect of Oil Injection Speed on the Air Curtain of High-Speed Bearings
by Yanfang Dong, Botao Ye, Zibo Yan, Hai Zhang, Wei Yu, Jianyong Sun and Wenbo Zhou
Lubricants 2025, 13(8), 334; https://doi.org/10.3390/lubricants13080334 (registering DOI) - 30 Jul 2025
Viewed by 160
Abstract
In order to improve the lubrication efficiency in the bearing cavity, this study establishes a simulation model of the fluid domain of the bearing cavity based on the computational fluid dynamics (CFD) method and systematically studies the flow characteristics of the lubricant and [...] Read more.
In order to improve the lubrication efficiency in the bearing cavity, this study establishes a simulation model of the fluid domain of the bearing cavity based on the computational fluid dynamics (CFD) method and systematically studies the flow characteristics of the lubricant and its lubrication mechanism in the high-speed rotary bearing. In the process of high-speed bearing operation, the lubricant is subject to the combined effect of centrifugal force and contact pressure, gradually spreads to both sides of the steel ball, and forms a stable oil film after injection from the nozzle. However, due to the influence of high pressure distribution in the contact area, the actual formation of the oil film coverage is relatively limited. In order to further optimize the lubrication effect, this study focuses on investigating the influence law of different injection speeds and rotational speeds on the bearing air curtain effect. The results of the study show that when the air curtain effect is enhanced, there will be significant shear interference on the trajectory of the lubricant, which is manifested in the phenomenon of “buckling” at the end of the lubricant, thus reducing the lubrication efficiency. To address this problem, this study innovatively proposes the air curtain obstruction coefficient K as a quantitative evaluation index, and through numerical simulation, it is found that the lubricant can effectively overcome the air curtain obstruction and achieve a better lubrication coverage when the value of K is reduced to below 0.4. Based on this finding, the study further confirmed that the lubrication efficiency of bearings can be significantly improved under different operating conditions by rationally regulating the injection rate. Full article
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23 pages, 9293 KiB  
Article
Numerical and Experimental Investigations of Oil Return Efficiency in Tapered Roller Bearings Under Oil Jet Lubrication
by Yu Dai, Cheng Yu, Hongmei Wu, Jianfeng Zhong, Xiang Zhu and Gang Wang
Lubricants 2025, 13(8), 333; https://doi.org/10.3390/lubricants13080333 - 30 Jul 2025
Viewed by 84
Abstract
Tapered roller bearings are extensively utilized in the aerospace industry owing to their superior load-carrying capacity and extended service life. However, the majority of research conducted by scholars on the subject of bearing lubrication has focused on ball and cylindrical roller bearings. There [...] Read more.
Tapered roller bearings are extensively utilized in the aerospace industry owing to their superior load-carrying capacity and extended service life. However, the majority of research conducted by scholars on the subject of bearing lubrication has focused on ball and cylindrical roller bearings. There is a paucity of research on the internal lubricants and air distribution of tapered roller bearings under oil jet lubrication conditions. This paper presents a computational fluid dynamics (CFD) simulation model specifically designed for the oil jet lubrication of tapered roller bearings. The flow field inside the bearing cavity is analyzed under various operating conditions, and the impact of different parameters on lubrication performance is quantitatively assessed using the oil return efficiency as a metric. Additionally, an experimental test stand for the jet lubrication of tapered roller bearings was developed. The simulated oil return efficiency was compared with experimental data, revealing discrepancies within 10%, thereby validating the accuracy of the CFD model. The findings suggest that directing the oil jet toward the smaller end of the bearing, appropriately increasing the nozzle flow rate, and utilizing positive jetting can significantly improve the lubrication performance of tapered roller bearings. Full article
(This article belongs to the Special Issue Tribological Characteristics of Bearing System, 3rd Edition)
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21 pages, 2189 KiB  
Article
Surface Modification, Characterization, and Cytotoxicity of Ti-6Al-4V Alloy Enriched by EDM Process
by Bárbara A. B. dos Santos, Elaine C. S. Corrêa, Wellington Lopes, Liszt Y. C. Madruga, Ketul C. Popat, Roberta M. Sabino and Hermes de Souza Costa
Appl. Sci. 2025, 15(15), 8443; https://doi.org/10.3390/app15158443 - 30 Jul 2025
Viewed by 282
Abstract
This study investigates the surface modification of Ti-6Al-4V alloy through the electrical discharge machining (EDM) process to improve its suitability for orthopedic and dental implant applications. The analysis focused on evaluating the morphological, wettability, roughness, hardness, and biocompatibility properties of the modified surfaces. [...] Read more.
This study investigates the surface modification of Ti-6Al-4V alloy through the electrical discharge machining (EDM) process to improve its suitability for orthopedic and dental implant applications. The analysis focused on evaluating the morphological, wettability, roughness, hardness, and biocompatibility properties of the modified surfaces. Samples were subjected to different dielectric fluids and polarities during EDM. Subsequently, optical microscopy, roughness measurements, Vickers microhardness, contact angle tests, and in vitro cytotoxicity assays were performed. The results demonstrated that EDM processing led to the formation of distinct layers on the sample surfaces, with surface roughness increasing under negative polarity by up to ~304% in Ra and 305% in Rz. Additionally, wettability measurements indicated that the modified surfaces presented a lower water contact angle, which suggests enhanced hydrophilicity. Moreover, the modified samples showed a significant increase in Vickers microhardness, with the highest value reaching 1520 HV in the recast layer, indicating improvements in the mechanical properties. According to ISO 10993-5, all treated samples were classified as non-cytotoxic, presenting RGR values above 75%, similar to the untreated Ti-6Al-4V alloy. Therefore, it is concluded that surface modification through the EDM process has the potential to enhance the properties and safety of biomedical implants made with this alloy. Full article
(This article belongs to the Special Issue Titanium and Its Compounds: Properties and Innovative Applications)
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20 pages, 3890 KiB  
Article
Numerical Analysis of Pressure Drops in Single-Phase Flow Through Channels of Brazed Plate Heat Exchangers with Dimpled Corrugated Plates
by Lorenzo Giunti, Francesco Giacomelli, Urban Močnik, Giacomo Villi, Adriano Milazzo and Lorenzo Talluri
Appl. Sci. 2025, 15(15), 8431; https://doi.org/10.3390/app15158431 (registering DOI) - 29 Jul 2025
Viewed by 165
Abstract
The presented research examines the performance characteristics of Brazed Plate Heat Exchangers through computational fluid dynamics (CFD), focusing on pressure drop calculations for single-phase flow within full channels of plates featuring dimpled corrugation. This work aims to bridge gaps in the literature, particularly [...] Read more.
The presented research examines the performance characteristics of Brazed Plate Heat Exchangers through computational fluid dynamics (CFD), focusing on pressure drop calculations for single-phase flow within full channels of plates featuring dimpled corrugation. This work aims to bridge gaps in the literature, particularly regarding the underexplored behavior near the ports for the studied technology and establishing a framework for future conjugate heat transfer studies. A methodology for the domain generation was developed, integrating a preliminary forming simulation to reproduce the complex plate geometry. Comprehensive sensitivity analyses were conducted to evaluate the influence of different parameters and identify the optimal settings for obtaining reliable results. The findings indicate that the kε realizable turbulence model with enhanced wall treatment offers superior accuracy in predicting pressure drops, with errors within ±4.4%. Additionally, leveraging the information derived from CFD, a strategy to estimate contributions from different channel sections without a direct reliance on those simulations was developed, offering practical implications for plate design. Full article
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18 pages, 7553 KiB  
Article
Investigating Experimental and Computational Fluid Dynamics of 3D-Printed TPMS and Lattice Porous Structures
by Guru Varun Penubarthi, Kishore Bhaskar Suresh Babu, Senthilkumar Sundararaj and Shung Wen Kang
Micromachines 2025, 16(8), 883; https://doi.org/10.3390/mi16080883 - 29 Jul 2025
Viewed by 145
Abstract
This study investigates the capillary performance and wetting behavior of SLA (Stereolithography) 3D-printed porous structures, focusing on TPMS (triply periodic minimal surfaces)-Gyroid, Octet, Diamond, and Isotruss lattice designs. High-speed imaging was used to analyze droplet interactions, including penetration, spreading, and contact angles, with [...] Read more.
This study investigates the capillary performance and wetting behavior of SLA (Stereolithography) 3D-printed porous structures, focusing on TPMS (triply periodic minimal surfaces)-Gyroid, Octet, Diamond, and Isotruss lattice designs. High-speed imaging was used to analyze droplet interactions, including penetration, spreading, and contact angles, with 16 μL water droplets dropping from 30 mm at 0.77 m/s. Results showed variable contact angles, with Isotruss and Octet having higher angles, while Diamond faced measurement challenges due to surface roughness. Numerical simulations of TPMS-Gyroid of 2 mm3 unit cells validated the experimental results, and Diamond, Octet, and Isotruss structures were simulated. Capillary performance was assessed through deionized (DI) water weight–time (w-t) measurements, identifying that the TPMS-Gyroid structure performed adequately. Structures with 4 mm3 unit cells had low capillary performance, excluding them from permeability testing, whereas smaller 2 mm3 structures demonstrated capillary effects but had printability and cleaning issues. Permeability results indicated that Octet performed best, followed by Isotruss, Diamond, and TPMS-Gyroid. Findings emphasize unit cell size, beam thickness, and droplet positioning as key factors in optimizing fluid dynamics for cooling, filtration, and fluid management. Full article
(This article belongs to the Special Issue Micro Thermal Devices and Their Applications, 2nd Edition)
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15 pages, 2361 KiB  
Article
Geochemical Characteristics of the Hida Granitoids in the Unazuki and Katakaigawa Areas, Central Japan
by Kazuki Oishi, Rui Kuwahara, Kazuya Shimooka and Motohiro Tsuboi
Geosciences 2025, 15(8), 285; https://doi.org/10.3390/geosciences15080285 - 29 Jul 2025
Viewed by 210
Abstract
The Hida Belt in central Japan is a key geological unit for understanding the crustal growth of the Eurasian continent in the Mesozoic. However, while previous studies have focused primarily on geochronology, the geochemical characteristics of its rocks and minerals remain largely unexplored. [...] Read more.
The Hida Belt in central Japan is a key geological unit for understanding the crustal growth of the Eurasian continent in the Mesozoic. However, while previous studies have focused primarily on geochronology, the geochemical characteristics of its rocks and minerals remain largely unexplored. This study investigates the geochemical characteristics and magmatic processes of the Hida granitoids, including adakitic rocks, distributed in the Unazuki and Katakaigawa areas. Whole-rock major oxides and trace elements, as well as Rb-Sr isotopes, were analyzed. Based on Rb–Sr isotopic compositions, the Hida granitoids are classified into two types. The younger and older granitoids in the Unazuki area, categorized as Type I, exhibit a narrow range of isotopic ratios, whereas the older granitoids in the Katakaigawa area, classified as Type II, display significantly higher values than those of Type I. The geochemical data suggest that the adakitic rocks in the older granitoids originated from interaction with alkali-rich melts or fluids, while those in the younger granitoids were derived from hydrous felsic magmas sourced from subducted oceanic crust. These findings provide new insights into the formation and evolution of granitic magmatism in the Hida Belt. Full article
(This article belongs to the Section Geochemistry)
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18 pages, 11346 KiB  
Article
Comparative CFD Analysis Using RANS and LES Models for NOx Dispersion in Urban Streets with Active Public Interventions in Medellín, Colombia
by Juan Felipe Rodríguez Berrio, Fabian Andres Castaño Usuga, Mauricio Andres Correa, Francisco Rodríguez Cortes and Julio Cesar Saldarriaga
Sustainability 2025, 17(15), 6872; https://doi.org/10.3390/su17156872 - 29 Jul 2025
Viewed by 172
Abstract
The Latin American and Caribbean (LAC) region faces persistent challenges of inequality, climate change vulnerability, and deteriorating air quality. The Aburrá Valley, where Medellín is located, is a narrow tropical valley with complex topography, strong thermal inversions, and unstable atmospheric conditions, all of [...] Read more.
The Latin American and Caribbean (LAC) region faces persistent challenges of inequality, climate change vulnerability, and deteriorating air quality. The Aburrá Valley, where Medellín is located, is a narrow tropical valley with complex topography, strong thermal inversions, and unstable atmospheric conditions, all of which exacerbate the accumulation of pollutants. In Medellín, NO2 concentrations have remained nearly unchanged over the past eight years, consistently approaching critical thresholds, despite the implementation of air quality control strategies. These persistent high concentrations are closely linked to the variability of the atmospheric boundary layer (ABL) and are often intensified by prolonged dry periods. This study focuses on a representative street canyon in Medellín that has undergone recent urban interventions, including the construction of new public spaces and pedestrian areas, without explicitly considering their impact on NOx dispersion. Using Computational Fluid Dynamics (CFD) simulations, this work evaluates the influence of urban morphology on NOx accumulation. The results reveal that areas with high Aspect Ratios (AR > 0.65) and dense vegetation exhibit reduced wind speeds at the pedestrian level—up to 40% lower compared to open zones—and higher NO2 concentrations, with maximum simulated values exceeding 50 μg/m3. This study demonstrates that the design of pedestrian corridors in complex urban environments like Medellín can unintentionally create pollutant accumulation zones, underscoring the importance of integrating air quality considerations into urban planning. The findings provide actionable insights for policymakers, emphasizing the need for comprehensive modeling and field validation to ensure healthier urban spaces in cities affected by persistent air quality issues. Full article
(This article belongs to the Section Air, Climate Change and Sustainability)
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39 pages, 8119 KiB  
Article
Magmatic Redox Evolution and Porphyry–Skarn Transition in Multiphase Cu-Mo-W-Au Systems of the Eocene Tavşanlı Belt, NW Türkiye
by Hüseyin Kocatürk, Mustafa Kumral, Hüseyin Sendir, Mustafa Kaya, Robert A. Creaser and Amr Abdelnasser
Minerals 2025, 15(8), 792; https://doi.org/10.3390/min15080792 - 28 Jul 2025
Viewed by 273
Abstract
This study explores the magmatic and hydrothermal evolution of porphyry–skarn–transitional Cu-Mo-W-Au systems within the Nilüfer Mineralization Complex (NMC), located in the westernmost segment of the Eocene Tavşanlı Metallogenic Belt, NW Türkiye. Through integration of field data, whole-rock geochemistry, Re–Os molybdenite dating, and amphibole–biotite [...] Read more.
This study explores the magmatic and hydrothermal evolution of porphyry–skarn–transitional Cu-Mo-W-Au systems within the Nilüfer Mineralization Complex (NMC), located in the westernmost segment of the Eocene Tavşanlı Metallogenic Belt, NW Türkiye. Through integration of field data, whole-rock geochemistry, Re–Os molybdenite dating, and amphibole–biotite mineral chemistry, the petrogenetic controls on mineralization across four spatially associated mineralized regions (Kirazgedik, Güneybudaklar, Kozbudaklar, and Delice) were examined. The earliest and thermally most distinct phase is represented by the Kirazgedik porphyry system, characterized by high temperature (~930 °C), oxidized quartz monzodioritic intrusions emplaced at ~2.7 kbar. Rising fO2 and volatile enrichment during magma ascent facilitated structurally focused Cu-Mo mineralization. At Güneybudaklar, Re–Os geochronology yields an age of ~49.9 Ma, linking Mo- and W-rich mineralization to a transitional porphyry–skarn environment developed under moderately oxidized (ΔFMQ + 1.8 to +0.5) and hydrous (up to 7 wt.% H2O) magmatic conditions. Kozbudaklar represents a more reduced, volatile-poor skarn system, leading to Mo-enriched scheelite mineralization typical of late-stage W-skarns. The Delice system, developed at the contact of felsic cupolas and carbonates, records the broadest range of redox and fluid compositions. Mixed oxidized–reduced fluid signatures and intense fluid–rock interaction reflect complex, multistage fluid evolution involving both magmatic and external inputs. Geochemical and mineralogical trends—from increasing silica and Rb to decreasing Sr and V—trace a systematic evolution from mantle-derived to felsic, volatile-rich magmas. Structurally, mineralization is controlled by oblique fault zones that localize magma emplacement and hydrothermal flow. These findings support a unified genetic model in which porphyry and skarn mineralization styles evolved continuously from multiphase magmatic systems during syn-to-post-subduction processes, offering implications for exploration models in the Western Tethyan domain. Full article
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14 pages, 796 KiB  
Article
The Role of Need for Cognition and Its Interaction with Fluid Intelligence in the Prediction of School Grades in Primary School Children
by Anke Hufer-Thamm, Sebastian Bergold and Ricarda Steinmayr
J. Intell. 2025, 13(8), 94; https://doi.org/10.3390/jintelligence13080094 - 28 Jul 2025
Viewed by 170
Abstract
Fluid intelligence and need for cognition are relevant predictors of school grades and might also interact in the prediction of grades. We examined the independent predictive values of fluid intelligence and need for cognition as well as their interaction for math and German [...] Read more.
Fluid intelligence and need for cognition are relevant predictors of school grades and might also interact in the prediction of grades. We examined the independent predictive values of fluid intelligence and need for cognition as well as their interaction for math and German grades and changes therein in a sample of 565 German primary school children (298 girls, 261 boys, 6 with no gender specified; Mage = 8.40, SD = 0.59). Parental education was considered a control variable. Cross-sectional analyses showed that both intelligence and need for cognition were uniquely related to grades. However, in the latent change score analyses, fluid intelligence, but not need for cognition, was related to change in math grades, but not in German grades, and only when parental education was not considered as a control variable. We found no interaction effects between fluid intelligence and need for cognition. The findings imply that the need for cognition might not play a comparably relevant role for school grades in primary school as it has been shown in previous studies focusing on secondary or tertiary education. Full article
(This article belongs to the Section Studies on Cognitive Processes)
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