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22 pages, 2174 KB  
Article
Dynamic CO2 Emission Differences Between E10 and E85 Fuels Based on Speed–Acceleration Mapping
by Piotr Laskowski, Edward Kozłowski, Magdalena Zimakowska-Laskowska, Piotr Wiśniowski, Jonas Matijošius, Stanisław Oszczak, Robertas Keršys, Marcin Krzysztof Wojs and Szymon Dowkontt
Energies 2026, 19(1), 40; https://doi.org/10.3390/en19010040 - 21 Dec 2025
Viewed by 491
Abstract
This study compared CO2 emissions during a WLTP (Worldwide Harmonized Light-Duty Vehicles Test Procedure) test performed on a chassis dynamometer for the same flex-fuel vehicle, fuelled sequentially with E10 gasoline and E85 fuel. Based on the test data, a CO2 emissions [...] Read more.
This study compared CO2 emissions during a WLTP (Worldwide Harmonized Light-Duty Vehicles Test Procedure) test performed on a chassis dynamometer for the same flex-fuel vehicle, fuelled sequentially with E10 gasoline and E85 fuel. Based on the test data, a CO2 emissions map was created, describing its dependence on speed and acceleration. The use of a 3D surface enabled the visualisation of the whole dynamics of emissions as a function of engine load in the WLTP cycle, including the identification of distinct emission peaks in areas of high positive acceleration. Analysis of the emission surface enabled the identification of structural differences between the fuels. For E85, more pronounced emission increases are observed in areas of intense acceleration, a consequence of the higher fuel demand resulting from the lower calorific value of bioethanol. In steady-state and moderate-load driving, CO2 emissions for both fuels are similar. The results confirm that the main differences between E10 and E85 are not simply a shift in emission levels per se, but stem from variations in engine load during the dynamic cycle. Although E85 emits measurable CO2 emissions, its carbon is not of fossil origin, highlighting the importance of biofuels in the context of greenhouse gas emission reduction strategies and the pursuit of climate neutrality. The presented methodology, combining chassis dynamometer tests with analysis of the speed-acceleration emission map, provides a tool for clearly identifying emission zones and can serve as a basis for further optimisation of engine control strategies and assessing the impact of fuel composition on emissions under dynamic conditions. Full article
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21 pages, 2611 KB  
Article
Hydrogen-Rich Gaseous Mixture for Enhanced Combustion in a Flex-Fuel Engine: An Experimental Analysis
by Lucimar Venancio Amaral, Augusto César Teixeira Malaquias, Gabriel Heleno de Paula Araújo, Marcos de Carvalho Torres Filho, Marco André Fraga, Ricardo Belchior Torres, Rita de Cássia de Oliveira Sebastião and Fabricio José Pacheco Pujatti
Hydrogen 2025, 6(4), 99; https://doi.org/10.3390/hydrogen6040099 - 3 Nov 2025
Viewed by 656
Abstract
This experimental study examines the effect of adding a hydrogen-enriched synthetic gaseous mixture (HGM’) on the combustion and fuel conversion efficiency of a single-cylinder research engine (SCRE). The work assesses the viability of using this mixture as a supplemental fuel for flex-fuel engines [...] Read more.
This experimental study examines the effect of adding a hydrogen-enriched synthetic gaseous mixture (HGM’) on the combustion and fuel conversion efficiency of a single-cylinder research engine (SCRE). The work assesses the viability of using this mixture as a supplemental fuel for flex-fuel engines operating under urban driving cycling conditions. An SCRE, the AVL 5405 model, was employed, operating with ethanol and gasoline as primary fuels through direct injection (DI) and a volumetric compression ratio of 11.5:1. The HGM’ was added in the engine’s intake via fumigation (FS), with volumetric proportions ranging from 5% to 20%. The tests were executed at 1900 rpm and 2500 rpm engine speeds, with indicated mean effective pressures (IMEPs) of 3 and 5 bar. When HGM’s 5% v/v was applied at 2500 rpm, the mean indicated effective pressure of 3 bar was observed. A decrease of 21% and 16.5% in the ISFC was observed when using gasoline and ethanol as primary fuels, respectively. The usage of an HGM’ combined with gasoline or ethanol, proved to be a relevant and economically accessible strategy in the improvement of the conversion efficiency of combustion fuels, once this gaseous mixture could be obtained through the vapor-catalytic reforming of ethanol, giving up the use of turbochargers or lean and ultra-lean burn strategies. These results demonstrated the potential of using HGM’ as an effective alternative to increase the efficiency of flex-fuel engines. Full article
(This article belongs to the Special Issue Hydrogen for a Clean Energy Future)
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25 pages, 1319 KB  
Article
Biofuel Dynamics in Brazil: Ethanol–Gasoline Price Threshold Analysis for Consumer Preference
by Letícia Rezende Mosquéra, Matheus Noschang de Oliveira, Patricia Helena dos Santos Martins, Guilherme Dantas Bispo, Raquel Valadares Borges, André Luiz Marques Serrano, Fabiano Mezadre Pompermayer, Clovis Neumann, Vinícius Pereira Gonçalves and Carlos Alberto Schuch Bork
Energies 2024, 17(21), 5265; https://doi.org/10.3390/en17215265 - 23 Oct 2024
Cited by 4 | Viewed by 4666
Abstract
The global transition towards environmentally friendly energy sources plays a major role in addressing both energy security and climate change. Brazil is at the forefront of this transition due to its rich natural resources and increasing investments in biofuels. Therefore, this investigation examines [...] Read more.
The global transition towards environmentally friendly energy sources plays a major role in addressing both energy security and climate change. Brazil is at the forefront of this transition due to its rich natural resources and increasing investments in biofuels. Therefore, this investigation examines the consumption patterns and interactions between ethanol, primarily sourced from sugarcane, and gasoline within Brazil’s energy framework. Ethanol’s renewability, reduced environmental impact, and superior combustion characteristics position it as a feasible substitute for traditional fossil fuels. Nonetheless, obstacles like competition for land use and inadequate distribution infrastructure impede its widespread acceptance. This study explores the economic interaction between ethanol and gasoline, focusing on pricing dynamics and regional influences. Using consumer preferences and the accessibility of ethanol, this research identifies a range of price ratios within which consumer preferences shift from gasoline to ethanol in various Brazilian regions. The study also classifies Brazilian states into three distinct ranges based on the ethanol-to-gasoline price ratio in 2023 for a granular analysis of the economic dynamics influencing fuel choice. The research identifies states with competitive and dominant ethanol markets by examining the interplay between ethanol market share, fuel prices, and the adoption of flex-fuel vehicles (FFVs) in the country. Lastly, the findings support the importance of regional economic conditions and the influence of price ratios on consumer behavior, highlighting that ethanol’s market share does not always correlate with favorable pricing. Full article
(This article belongs to the Section B: Energy and Environment)
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13 pages, 951 KB  
Article
Understanding Business Models in the Brazilian Context of Electric Mobility: A Proposed Framework
by Márcio Có, Flávia Consoni, Matheus Coelho Carneiro, Guilherme Fernandes, Reginaldo Barbosa Nunes and Clainer Donadel
Urban Sci. 2024, 8(3), 92; https://doi.org/10.3390/urbansci8030092 - 22 Jul 2024
Cited by 3 | Viewed by 2155
Abstract
In the transition to electric mobility (EM), business model innovation plays a crucial role in expanding the use of electric vehicles and increasing acceptance of this technology. The transition pathways differ between countries in the largest economies and those in Latin America. Brazil [...] Read more.
In the transition to electric mobility (EM), business model innovation plays a crucial role in expanding the use of electric vehicles and increasing acceptance of this technology. The transition pathways differ between countries in the largest economies and those in Latin America. Brazil presents a unique scenario, benefiting from an early start with biofuels, the production of flex-fuel vehicles, predominantly renewable electric energy generation (>80%), and the absence of a structured national policy aligned with local governments. This study introduces a framework that surveys and categorizes businesses in EM, relating them to sustainable development aspects and regulatory maturity. It builds a solid conceptual foundation, incorporating data from technical and commercial events, as well as interviews with Brazilian specialists for validation. The proposed framework aids in understanding the Brazilian context, identifying regulatory gaps, and developing a common language to advance studies on business model innovation, contributing to electromobility studies in Latin America. Additionally, it can guide the construction of regional and local public policies and help identify more sustainable projects. Full article
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16 pages, 5526 KB  
Review
Scientific Research on Bioethanol in Brazil: History and Prospects for Sustainable Biofuel
by Adriana Grandis, Janaina da Silva Fortirer, Débora Pagliuso and Marcos S. Buckeridge
Sustainability 2024, 16(10), 4167; https://doi.org/10.3390/su16104167 - 16 May 2024
Cited by 22 | Viewed by 9704
Abstract
Despite the recent need for sustainable energy resources, bioenergy gained its spotlight in the 2000s. Sugarcane is a significant crop in terms of sugar and energy capacity, and it can be an alternative energy source to mitigate the effects of climate change. Bioenergy [...] Read more.
Despite the recent need for sustainable energy resources, bioenergy gained its spotlight in the 2000s. Sugarcane is a significant crop in terms of sugar and energy capacity, and it can be an alternative energy source to mitigate the effects of climate change. Bioenergy production from sugarcane in Brazil is one of the most efficient options. This production lends a centrality to biofuels’ importance in confronting climate change effects. The present article reviews the Brazilian history of this crop as a biofuel source, focusing on plants as a biomass. We highlight the historical changes related to scientific, technological, industrial, and environmental advances since the beginning of the 20th century. We describe how creating governmental institutes and disseminating scientific knowledge strengthened public policies that led Brazil to occupy leadership positions in producing, distributing, and using bioenergy throughout the country. The compiled data show the improvements and the new approaches needed to improve ethanol sugarcane use. We performed a bibliometric analysis to evaluate Brazilian science’s contribution to this process compared to other countries. Brazil’s history of science and investment in sugarcane biofuel development for transportation may be divided into two phases: ethanol-only and flex-fuel cars. A third phase is starting, directed to the SAF and ethanol-to-hydrogen era. Full article
(This article belongs to the Special Issue Recycling Biomass for Agriculture and Bioenergy Production)
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31 pages, 17473 KB  
Article
Flow Field Investigation of a Single Engine Valve Using PIV, POD, and LES
by Jana Hoffmann, Niklas Mirsch, Walter Vera-Tudela, Dario Wüthrich, Jorim Rosenberg, Marco Günther, Stefan Pischinger, Daniel A. Weiss and Kai Herrmann
Energies 2023, 16(5), 2402; https://doi.org/10.3390/en16052402 - 2 Mar 2023
Cited by 3 | Viewed by 3430
Abstract
Due to stringent emission regulations, it is of practical significance to understand cycle-to-cycle variations in the combustion of fossil or renewable fuels to reach future emission regulations. The present study aims to conduct a parametric investigation to analyse the influence of the valve [...] Read more.
Due to stringent emission regulations, it is of practical significance to understand cycle-to-cycle variations in the combustion of fossil or renewable fuels to reach future emission regulations. The present study aims to conduct a parametric investigation to analyse the influence of the valve lift and different mass flows of an inlet valve of the test engine “Flex-OeCoS” on the flow structures. To gain a deeper understanding of the flow behaviour, an optical test bench for 2D Particle Image Velocimetry (PIV) and a Large Eddy Simulation (LES) are used. Turbulence phenomena are investigated using Proper Orthogonal Decomposition (POD) with a quadruple decomposition and the Reynolds stress transport equation. The results show good agreement between the PIV and LES. Moreover, the main flow structures are primarily affected by valve lift while being unaffected by mass flow variation. The turbulent kinetic energy within the flow field increases quadratically to the mass flow and to the decreasing valve lift, where large high-energetic flow structures are observed in the vicinity of the jet and small low-energetic structures are homogeneously distributed within the flow field. Furthermore, the convective flux, the turbulent diffusive flux, the rate of change, and the production of specific Reynolds stress are the dominant terms within the specific Reynolds stress transport equation. Full article
(This article belongs to the Special Issue Combustion Engine In-Cylinder Flow)
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11 pages, 2154 KB  
Article
Induction of a Consumption Pattern for Ethanol and Gasoline in Brazil
by Aloisio S. Nascimento Filho, Rafael G. O. dos Santos, João Gabriel A. Calmon, Peterson A. Lobato, Marcelo A. Moret, Thiago B. Murari and Hugo Saba
Sustainability 2022, 14(15), 9047; https://doi.org/10.3390/su14159047 - 23 Jul 2022
Cited by 10 | Viewed by 5166
Abstract
Historically, carbon dioxide emissions from transport have been a globally discussed and analyzed problem. The adoption of flex fuel vehicles designed to run ethanol–gasoline blends is important to mitigate these emissions. The main purpose of this paper is to analyze the impact of [...] Read more.
Historically, carbon dioxide emissions from transport have been a globally discussed and analyzed problem. The adoption of flex fuel vehicles designed to run ethanol–gasoline blends is important to mitigate these emissions. The main purpose of this paper is to analyze the impact of the ethanol–gasoline price ratio on different vehicle models, and discuss the opportunities to increase ethanol consumption from this perspective. Our analysis shows that the use of a unique fuel economy ratio for all flex–fuel vehicles in the country significantly reduces the opportunity of some customers to purchase hydrous ethanol. The paper also discusses possible actions to provide adequate information that may increase the possibility of fuelling vehicles with a high-level ethanol blend. Full article
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19 pages, 40535 KB  
Article
Life Cycle and Exergoenvironmental Analyses of Ethanol: Performance of a Flex-Fuel Spark-Ignition Engine at Wide-Open Throttle Conditions
by Eduardo J. C. Cavalcanti, Daniel R. S. da Silva and Monica Carvalho
Energies 2022, 15(4), 1422; https://doi.org/10.3390/en15041422 - 15 Feb 2022
Cited by 7 | Viewed by 3049
Abstract
The growth in the number of vehicles circulating has led to a proportional increase in polluting gas emissions. Bioenergy can be used to help meet these increasing energy demands and mitigate environmental impacts. This work verified the effect of the content of ethanol [...] Read more.
The growth in the number of vehicles circulating has led to a proportional increase in polluting gas emissions. Bioenergy can be used to help meet these increasing energy demands and mitigate environmental impacts. This work verified the effect of the content of ethanol on the exergy and exergoenvironmental analyses of a spark-ignition engine. Different gasoline–ethanol mixtures were tested along with hydrous ethanol (4.6% water by volume). The thermodynamic data refer to wide-open throttle conditions and variable engine speeds. The life cycle assessment methodology quantified the environmental impacts associated with equipment and fuel using the Eco-indicator 99 method. Pollutants emitted during combustion were measured and included in the environmental assessment (nitrogen oxides, carbon monoxide, and dioxide). Hydrous ethanol at 1500 rpm presented the highest energy efficiency. The effects of the environmental impact rate of pollutant formation and exergy efficiency were significantly higher than the environmental impact rate of fuel. The lowest specific environmental impact of the product (brake power) was 24.39 mPt/MJ, obtained with the fuel blend with 50% ethanol at 2500 rpm. The combined evaluation of the exergoenvironmental factor and the relative difference in environmental impact indicated the optimization priorities and where improvements should be directed. Full article
(This article belongs to the Topic Exergy Analysis and Its Applications)
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19 pages, 2772 KB  
Article
Life Cycle Air Emissions and Social Human Health Impact Assessment of Liquified Natural Gas Maritime Transport
by Saleh Aseel, Hussein Al-Yafei, Murat Kucukvar and Nuri C. Onat
Energies 2021, 14(19), 6208; https://doi.org/10.3390/en14196208 - 29 Sep 2021
Cited by 5 | Viewed by 3350
Abstract
Air pollution, which causes over seven million deaths per year, is the most significant and specifically related to health impacts. Nearly 90% of the urban population worldwide is exposed to pollution not meeting the World Health Organization guidelines for air quality. Many atmospheric [...] Read more.
Air pollution, which causes over seven million deaths per year, is the most significant and specifically related to health impacts. Nearly 90% of the urban population worldwide is exposed to pollution not meeting the World Health Organization guidelines for air quality. Many atmospheric carbon oxides, nitrogen oxides, and particulate matter emitting sources, such as inefficient energy and polluting transportation, directly impact health. Natural gas maritime transport from various parts of the world (carbon supplied to consuming areas) has become more critical. Natural gas liquefaction offers a cleaner and more efficient transportation option and also increases its storage capacity. It is expected that natural gas will reduce the human health impact compared with other traditional fuels consumed. This research establishes a life cycle assessment model of air emission and social human health impact related to LNG maritime transport to investigate the impact of each type of fuel used for the numerous maritime carriers. In order to build a model for air emissions and social human health impact assessments based on hypotheses on various unknown criteria, a calculation model is used. The results revealed Conventional-2 fuel type has the lowest human health impact for annual mode calculations, followed by Conventional-1, Q-Max, and finally Q-Flex. The analysis method for the per year demonstrated discrepancies in the relative human health impact due to the variation of the annual LNG demand by each destination and not only per the trip needs. The results show the importance of using a relatively cleaner fuel type such as Conventional-2 in reducing the health impact of LNG maritime transportation. Moreover, it shows differences in the air emissions as well as the human health impact based on the destination’s location and annual LNG demand. Full article
(This article belongs to the Section B1: Energy and Climate Change)
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24 pages, 6789 KB  
Article
Dynamic Probabilistic Risk Assessment Based Response Surface Approach for FLEX and Accident Tolerant Fuels for Medium Break LOCA Spectrum
by Asad Ullah Amin Shah, Robby Christian, Junyung Kim, Jaewhan Kim, Jinkyun Park and Hyun Gook Kang
Energies 2021, 14(9), 2490; https://doi.org/10.3390/en14092490 - 27 Apr 2021
Cited by 22 | Viewed by 3195
Abstract
After the Fukushima Daiichi Accident, the safety features such as accident tolerant fuel (ATF) and diverse and flexible coping strategies (FLEX) for existing nuclear fleets are being investigated by the US Department of Energy under the Light Water Reactor Sustainability Program. This research [...] Read more.
After the Fukushima Daiichi Accident, the safety features such as accident tolerant fuel (ATF) and diverse and flexible coping strategies (FLEX) for existing nuclear fleets are being investigated by the US Department of Energy under the Light Water Reactor Sustainability Program. This research is being conducted to quantify the risk-benefit of these safety features. Dynamic probabilistic risk assessment (DPRA)-based response-surface approach has been presented to quantify the FLEX and ATF benefits by estimating the risk associated with each option. ATFs with multilayered silicon carbide (SiC), iron-chromium-aluminum, and chromium-coated zirconium cladding were considered in this study. While these ATF candidates perform better than the current zirconium cladding (Zr), they may introduce additional failure modes in some operating conditions. The fuel failure analysis modules (FAMs) were developed to investigate ATF performance. The dynamic risk assessments were performed using RAVEN, a DPRA tool, coupled with RELAP5 and FAMs. A cumulative distribution function-based index provided a mean of comparing the benefits of safety enhancements. For medium break loss of coolant accidents, FLEX operational timing window for each fuel type was estimated. Among these ATF candidates, SiC-type ATF was the most beneficial candidate for an increased safety margin than Zr-based fuel and was found to complement FLEX strategies in terms of risk and coping time. Full article
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23 pages, 1569 KB  
Review
The New Neighbor across the Street: An Outlook for Battery Electric Vehicles Adoption in Brazil
by Jorge Enrique Velandia Vargas, Joaquim E. A. Seabra, Carla K. N. Cavaliero, Arnaldo C. S. Walter, Simone P. Souza and Daniela G. Falco
World Electr. Veh. J. 2020, 11(3), 60; https://doi.org/10.3390/wevj11030060 - 11 Sep 2020
Cited by 25 | Viewed by 12930
Abstract
As the automotive industry steers towards electromobility and electric vehicle adoption surges, Brazil and other Latin-American countries remain laggards. The Brazilian scenario exhibits unique features, such as a powerful automotive sector with large investments in internal combustion engine technology and a well-established biofuels [...] Read more.
As the automotive industry steers towards electromobility and electric vehicle adoption surges, Brazil and other Latin-American countries remain laggards. The Brazilian scenario exhibits unique features, such as a powerful automotive sector with large investments in internal combustion engine technology and a well-established biofuels market based on flex-fuel technology. Although energy security, urban air pollution, greenhouse gas emissions mitigation, and technological advantage have been common drivers for the adoption of electric vehicles worldwide, the Brazilian immediate motivations are different, and the biofuels business ecosystem is likely to transform the path for electromobility. High tag price and public charging infrastructure absence have deeply discouraged electric vehicles adoption. A lack of regulation and a national consensus about the role of electric vehicles have been notorious. In fact, only in 2018 did the electricity regulatory agency (ANEEL) issue a resolution permitting the sale of electricity for recharging. The objective of this review was to create an outlook of the Brazilian transportation landscape. We identified relevant players, public charging infrastructure initiatives, market and other barriers, and regulation actions by consulting academic literature, media sources, and reports. We do not claim to predict the evolution of electrification. Instead, we aim to consolidate the information which can be used for decision support or strategy definition among entrepreneurs or policymakers. The main findings here are the necessity of a model for electrification able to create a synergy with biofuels and the urgency of having well-defined policies on what Brazil wants from electromobility. Full article
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23 pages, 14930 KB  
Article
The Flex-OeCoS—a Novel Optically Accessible Test Rig for the Investigation of Advanced Combustion Processes under Engine-Like Conditions
by Bruno Schneider, Christian Schürch, Konstantinos Boulouchos, Stefan Herzig, Marc Hangartner, David Humair, Silas Wüthrich, Christoph Gossweiler and Kai Herrmann
Energies 2020, 13(7), 1794; https://doi.org/10.3390/en13071794 - 8 Apr 2020
Cited by 7 | Viewed by 4274
Abstract
A new test rig has been designed, built and commissioned, and is now jointly pursued to facilitate experimental investigations into advanced combustion processes (i.e., dual fuel, multi-mode) under turbulent conditions at high, engine-like temperature and pressure levels. Based on a standard diesel engine [...] Read more.
A new test rig has been designed, built and commissioned, and is now jointly pursued to facilitate experimental investigations into advanced combustion processes (i.e., dual fuel, multi-mode) under turbulent conditions at high, engine-like temperature and pressure levels. Based on a standard diesel engine block, it offers much improved optical access to the in-cylinder processes due to its separated and rotated arrangement of the compression volume and combustion chamber, respectively. A fully variable pneumatic valve train and the appropriate preconditioning of the intake air allows it to represent a wide range of engine-like in-cylinder conditions regarding pressures, temperatures and turbulence levels. The modular design of the test rig facilitates easy optimizations of the combustion chamber/cylinder head design regarding different experimental requirements. The name of the new test rig, Flex-OeCoS, denotes its Flexibility regarding Optical engine Combustion diagnostics and/or the development of corresponding Sensing devices and applications. Measurements regarding in-cylinder gas pressures, temperatures and the flow field under typical operating conditions are presented to complete the description and assessment of the new test rig. Full article
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29 pages, 932 KB  
Article
Integrated Process Design and Control for Smart Grid Coordinated IGCC Power Plants Using Economic Linear Optimal Control
by Jin Zhang, Sofia Garcia Fracaro and Donald J. Chmielewski
Processes 2020, 8(3), 288; https://doi.org/10.3390/pr8030288 - 3 Mar 2020
Cited by 22 | Viewed by 4025
Abstract
The Integrated Gasification Combined Cycle (IGCC) possesses a number of advantages over traditional power generation plants, including increased efficiency, flex-fuel, and carbon capture. A lesser-known advantage of the IGCC system is the ability to coordinate with the smart grid. The idea is that [...] Read more.
The Integrated Gasification Combined Cycle (IGCC) possesses a number of advantages over traditional power generation plants, including increased efficiency, flex-fuel, and carbon capture. A lesser-known advantage of the IGCC system is the ability to coordinate with the smart grid. The idea is that process modifications can enable dispatch capabilities in the sense of shifting power production away from periods of low electricity price to periods of high price and thus generate greater revenue. The work begins with a demonstration of Economic Model Predictive Control (EMPC) as a strategy to determine the dispatch policy by directly pursuing the objective of maximizing plant revenue. However, the numeric nature of EMPC creates an inherent limitation when it comes to process design. Thus, Economic Linear Optimal Control (ELOC) is proposed as a surrogate for EMPC in the formulation of the integrated design and control problem for IGCC power plants with smart grid coordination. Full article
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21 pages, 5892 KB  
Article
Feedstock-Dependent Phosphate Recovery in a Pilot-Scale Hydrothermal Liquefaction Bio-Crude Production
by Ekaterina Ovsyannikova, Andrea Kruse and Gero C. Becker
Energies 2020, 13(2), 379; https://doi.org/10.3390/en13020379 - 13 Jan 2020
Cited by 44 | Viewed by 5719
Abstract
Microalgae (Spirulina) and primary sewage sludge are considerable feedstocks for future fuel-producing biorefinery. These feedstocks have either a high fuel production potential (algae) or a particularly high appearance as waste (sludge). Both feedstocks bring high loads of nutrients (P, N) that [...] Read more.
Microalgae (Spirulina) and primary sewage sludge are considerable feedstocks for future fuel-producing biorefinery. These feedstocks have either a high fuel production potential (algae) or a particularly high appearance as waste (sludge). Both feedstocks bring high loads of nutrients (P, N) that must be addressed in sound biorefinery concepts that primarily target specific hydrocarbons, such as liquid fuels. Hydrothermal liquefaction (HTL), which produces bio-crude oil that is ready for catalytic upgrading (e.g., for jet fuel), is a useful starting point for such an approach. As technology advances from small-scale batches to pilot-scale continuous operations, the aspect of nutrient recovery must be reconsidered. This research presents a full analysis of relevant nutrient flows between the product phases of HTL for the two aforementioned feedstocks on the basis of pilot-scale data. From a partial experimentally derived mass balance, initial strategies for recovering the most relevant nutrients (P, N) were developed and proofed in laboratory-scale. The experimental and theoretical data from the pilot and laboratory scales are combined to present the proof of concept and provide the first mass balances of an HTL-based biorefinery modular operation for producing fertilizer (struvite) as a value-added product. Full article
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18 pages, 3124 KB  
Article
Global Warming Potential of Biomass-to-Ethanol: Review and Sensitivity Analysis through a Case Study
by Rui Pacheco and Carla Silva
Energies 2019, 12(13), 2535; https://doi.org/10.3390/en12132535 - 1 Jul 2019
Cited by 51 | Viewed by 7643
Abstract
In Europe, ethanol is blended with gasoline fuel in 5 or 10% volume (E5 or E10). In USA the blend is 15% in volume (E15) and there are also pumps that provide E85. In Brazil, the conventional gasoline is E27 and there are [...] Read more.
In Europe, ethanol is blended with gasoline fuel in 5 or 10% volume (E5 or E10). In USA the blend is 15% in volume (E15) and there are also pumps that provide E85. In Brazil, the conventional gasoline is E27 and there are pumps that offer E100, due to the growing market of flex fuel vehicles. Bioethanol production is usually by means of biological conversion of several biomass feedstocks (first generation sugar cane in Brazil, corn in the USA, sugar beet in Europe, or second-generation bagasse of sugarcane or lignocellulosic materials from crop wastes). The environmental sustainability of the bioethanol is usually measured by the global warming potential metric (GWP in CO2eq), 100 years time horizon. Reviewed values could range from 0.31 to 5.55 gCO2eq/LETOH. A biomass-to-ethanol industrial scenario was used to evaluate the impact of methodological choices on CO2eq: conventional versus dynamic Life Cycle Assessment; different impact assessment methods (TRACI, IPCC, ILCD, IMPACT, EDIP, and CML); electricity mix of the geographical region/country for different factory locations; differences in CO2eq factor for CH4 and N2O due to updates in Intergovernmental Panel on Climate Change (IPCC) reports (5 reports so far), different factory operational lifetimes and future improved productivities. Results showed that the electricity mix (factory location) and land use are the factors that have the greatest effect (up to 800% deviation). The use of the CO2 equivalency factors stated in different IPCC reports has the least influence (less than 3%). The consideration of the biogenic emissions (uptake at agricultural stage and release at the fermentation stage) and different allocation methods is also influential, and each can make values vary by 250%. Full article
(This article belongs to the Special Issue Smart Mobility and Energy Transitions)
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