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9 pages, 902 KiB  
Article
Flat Top Non-Polarizing Optical Bandpass Filtering in Form of Planar Optical Waveguide
by Jianhua Liu and Ping Jiang
Photonics 2025, 12(7), 724; https://doi.org/10.3390/photonics12070724 - 17 Jul 2025
Viewed by 245
Abstract
To obtain a flat top shaped passband in a conventional thin-film-based optical bandpass filter (OBF), it needs a large number of constitutional layers of thin films, which makes the film deposition systems more complicated and accumulates errors in film growth. A flat top [...] Read more.
To obtain a flat top shaped passband in a conventional thin-film-based optical bandpass filter (OBF), it needs a large number of constitutional layers of thin films, which makes the film deposition systems more complicated and accumulates errors in film growth. A flat top and polarization-independent optical bandpass filter structure is proposed based on experimentally verified polarization independency in the form of a prism-pair coupled planar optical waveguide (POW). The POW is composed of two waveguide stacks, which consists of nine planar thin-film layers. Theoretical simulations show that the flat band top spans about 5 nm with transmittance over 97.8%. The passband is designed to be centered at 632.8 nm, the He-Ne laser wavelength, and the FWHM (full width at half maximum) bandwidth is about 35 nm. Within 0.5° tuning for the incident angle of the light, the passband could be shifted within 50 nm, while its transmittance fluctuates only less than 1% and the passband shape distorts only slightly. This type of OBF is potentially applicable in various fields of optical and laser spectroscopies. Full article
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12 pages, 3225 KiB  
Article
Multiple Slater Determinants and Strong Spin-Fluctuations as Key Ingredients of the Electronic Structure of Electron- and Hole-Doped Pb10−xCux(PO4)6O
by Dimitar Pashov, Swagata Acharya, Stephan Lany, Daniel S. Dessau and Mark van Schilfgaarde
Crystals 2025, 15(7), 621; https://doi.org/10.3390/cryst15070621 - 2 Jul 2025
Viewed by 1053
Abstract
LK-99, with chemical formula Pb10−xCux(PO4)6O, was recently reported to be a room-temperature superconductor. While this claim has met with little support in a flurry of ensuing work, a variety of calculations (mostly based on [...] Read more.
LK-99, with chemical formula Pb10−xCux(PO4)6O, was recently reported to be a room-temperature superconductor. While this claim has met with little support in a flurry of ensuing work, a variety of calculations (mostly based on density-functional theory) have demonstrated that the system possesses some unusual characteristics in the electronic structure, in particular flat bands. We have established previously that within DFT, the system is insulating with many characteristics resembling the classic cuprates, provided the structure is not constrained to the P3(143) symmetry nominally assigned to it. Here we describe the basic electronic structure of LK-99 within self-consistent many-body perturbative approach, quasiparticle self-consistent GW (QSGW) approximation and their diagrammatic extensions. QSGW predicts that pristine LK-99 is indeed a Mott/charge transfer insulator, with a bandgap gap in excess of 3 eV, whether or not constrained to the P3(143) symmetry. When Pb9Cu(PO4)6O is hole-doped, the valence bands modify only slightly, and a hole pocket appears. However, two solutions emerge: a high-moment solution with the Cu local moment aligned parallel to neighbors, and a low-moment solution with Cu aligned antiparallel to its environment. In the electron-doped case the conduction band structure changes significantly: states of mostly Pb character merge with the formerly dispersionless Cu d state, and high-spin and low spin solutions once again appear. Thus we conclude that with suitable doping, the ground state of the system is not adequately described by a band picture, and that strong correlations are likely. Irrespective of whether this system class hosts superconductivity or not, the transition of Pb10(PO4)6O from being a band insulator to Pb9Cu(PO4)6O, a Mott insulator, and multi-determinantal nature of doped Mott physics make this an extremely interesting case-study for strongly correlated many-body physics. Full article
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32 pages, 11250 KiB  
Article
Novel Dielectric Resonator-Based Microstrip Filters with Adjustable Transmission and Equalization Zeros
by David Espinosa-Adams, Sergio Llorente-Romano, Vicente González-Posadas, José Luis Jiménez-Martín and Daniel Segovia-Vargas
Electronics 2025, 14(13), 2557; https://doi.org/10.3390/electronics14132557 - 24 Jun 2025
Viewed by 495
Abstract
This work presents a comprehensive technological study of dielectric resonator-based microstrip filters (DRMFs), encompassing the design, fabrication, and rigorous characterization of the TE01δ mode. Through systematic coupling analysis, we demonstrate filters featuring novel input–output coupling techniques and innovative implementations of [...] Read more.
This work presents a comprehensive technological study of dielectric resonator-based microstrip filters (DRMFs), encompassing the design, fabrication, and rigorous characterization of the TE01δ mode. Through systematic coupling analysis, we demonstrate filters featuring novel input–output coupling techniques and innovative implementations of both transmission zeros (4-2-0 configuration) and equalization zeros (4-0-2 configuration), specifically designed for demanding space and radar receiver applications, while the loaded quality factor (QL) and insertion loss do not match those of dielectric resonator cavity filters (DRCFs), our solution significantly surpasses conventional microstrip filters (MFs), achieving QL> 3000 compared to typical QL≈ 200 for coupled-line MFs in X-band. The fabricated filters exhibit exceptional performance as follows: input reflection (S11) below −18 dB (4-2-0) and −16.5 dB (4-0-2), flat transmission response (S21), and out-of-band rejection exceeding −30 dB. Mechanical tuning enables precise control of input–output coupling, inter-resonator coupling, cross-coupling, and frequency synthesis, while equalization zeros provide tailored group delay characteristics. This study positions DRMFs as a viable intermediate technology for high-performance RF systems, bridging the gap between conventional solutions. Full article
(This article belongs to the Special Issue Advances in Low Power Circuit and System Design and Applications)
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14 pages, 2221 KiB  
Article
Design and Optimization of Broadband Optical Half-Band Filters Based on Cascaded MZIs
by Ke Zeng, Yu Zheng, Shu Liu, Xin Tang, Xinyu Ouyang, Keyi Fan and Chentong Yang
Photonics 2025, 12(6), 618; https://doi.org/10.3390/photonics12060618 - 18 Jun 2025
Viewed by 286
Abstract
In optical communication systems, optical half-band filters are essential for efficient spectral separation, necessitating stringent performance criteria such as a wide spectral range, low insertion loss, and minimal crosstalk. This paper proposes a broadband optical half-band filter based on a cascaded Mach–Zehnder Interferometer [...] Read more.
In optical communication systems, optical half-band filters are essential for efficient spectral separation, necessitating stringent performance criteria such as a wide spectral range, low insertion loss, and minimal crosstalk. This paper proposes a broadband optical half-band filter based on a cascaded Mach–Zehnder Interferometer (MZI) structure, which effectively improves spectral separation by enhancing flatness and sharpness at transition edges through the optimization of delay line length differences and phase compensation values. The results demonstrate that the proposed design achieves an insertion loss below 0.45 dB and inter-band crosstalk under −20.7 dB over a 40 nm bandwidth, with a roll-off of 2.2 dB/nm between 1517 nm and 1528 nm. The findings highlight the technical advantages of cascaded MZI structures in achieving high-precision spectral separation, offering a valuable reference for the development of future high-performance optical communication networks and integrated optical devices. Full article
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10 pages, 6226 KiB  
Article
8-W 2-Stage GaN Doherty Power Amplifier Module on 7 × 7 QFN for the 5G N78 Band
by Sooncheol Bae, Kuhyeon Kwon, Hyeongjin Jeon, Young Chan Choi, Soohyun Bin, Kyungdong Bae, Hyunuk Kang, Woojin Choi, Youngyun Woo and Youngoo Yang
Electronics 2025, 14(12), 2398; https://doi.org/10.3390/electronics14122398 - 12 Jun 2025
Viewed by 462
Abstract
This paper presents a 2-stage GaN Doherty power amplifier module (DPAM) on a compact 7×7 quad flat no-lead (QFN) package, designed for the needs of 5G massive MIMO base transceiver systems. The interstage and input matching networks employ high-quality factor integrated [...] Read more.
This paper presents a 2-stage GaN Doherty power amplifier module (DPAM) on a compact 7×7 quad flat no-lead (QFN) package, designed for the needs of 5G massive MIMO base transceiver systems. The interstage and input matching networks employ high-quality factor integrated passive devices (IPDs) to achieve a small form factor. This multi-chip module consists of three GaN-HEMT bare dies used for the driver stage, carrier amplifier, and peaking amplifier. Additionally, two IPD dies are included for the interstage and input matching networks. The external load network is developed using a printed circuit board (PCB). Utilizing a 5G NR signal of 100 MHz bandwidth and a 9.3 dB PAPR within the 3.4–3.8 GHz band, the developed DPAM demonstrated a power gain exceeding 26.8 dB and a power-added efficiency (PAE) greater than 37.8% at a 39 dBm average output power. Full article
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16 pages, 3537 KiB  
Article
A 5–18 GHz Four-Channel Multifunction Chip Using 3D Heterogeneous Integration of GaAs pHEMT and Si-CMOS
by Bai Du, Zhiyu Wang and Faxin Yu
Electronics 2025, 14(12), 2342; https://doi.org/10.3390/electronics14122342 - 7 Jun 2025
Viewed by 509
Abstract
Compact, broadband, multi-channel RF chips with low loss and high integration are required for high-performance phased-array systems. Presented in this paper is a four-channel, multifunction RF chip operating in the 5–18 GHz frequency range that integrates broadband phase shifting, amplitude control, power amplification, [...] Read more.
Compact, broadband, multi-channel RF chips with low loss and high integration are required for high-performance phased-array systems. Presented in this paper is a four-channel, multifunction RF chip operating in the 5–18 GHz frequency range that integrates broadband phase shifting, amplitude control, power amplification, and switching functions. The chip is designed to have flip-chip bonding and stacked gold bumps to enable the compact 3D integration of the GaAs pHEMT and Si-CMOS. To ensure high-density interconnects with minimal parasitic effects, a fan-in redistribution process is implemented. The RF front-end part of this chip, fabricated through a 0.15 µm GaAs pHEMT process, integrates 6-bit digital phase shifters, 6-bit digital attenuators, low-noise amplifiers (LNAs), power amplifiers (PAs), and single-pole double-throw (SPDT) switches. To enhance multi-channel isolation and reduce crosstalk between RF chips and digital circuits, high isolation techniques, including a ground-coupled shield layer in the fan-in process and on-chip shield cavities, are utilized, which achieve isolation levels greater than 41 dB between adjacent RF channels. The measurement results demonstrate a reception gain of 0 dB with ±0.6 dB flatness, an NF below 11 dB, and transmit gain of more than 10 dB, with a VSWR of below 1.6 over the entire 5–18 GHz frequency band. The 6-bit phase shifter achieves a root mean square (RMS) phase error below 2.5° with an amplitude variation of less than 0.8 dB, while the 6-bit attenuator exhibits an RMS attenuation error of below 0.5 dB and a phase variation of less than 7°. The RF and digital chips are heterogeneously integrated using flip-chip and fan-in technology, resulting in a compact chip size of 6.2 × 6.2 × 0.33 mm3. These results validate that this is a compact, high-performance solution for advanced phased-array radar applications. Full article
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11 pages, 14805 KiB  
Article
Dilute Paramagnetism and Non-Trivial Topology in Quasicrystal Approximant Fe4Al13
by Keenan E. Avers, Jarryd A. Horn, Ram Kumar, Shanta R. Saha, Peter Zavalij, Yuanfeng Xu, Bogdan Andrei Bernevig and Johnpierre Paglione
Crystals 2025, 15(5), 485; https://doi.org/10.3390/cryst15050485 - 21 May 2025
Viewed by 532
Abstract
A very fundamental property of both weakly and strongly interacting materials is the nature of their magnetic response. In this work, we detail the growth of crystals of the quasicrystal approximant Fe4Al13 with an Al flux solvent method. We characterize [...] Read more.
A very fundamental property of both weakly and strongly interacting materials is the nature of their magnetic response. In this work, we detail the growth of crystals of the quasicrystal approximant Fe4Al13 with an Al flux solvent method. We characterize our samples using electrical transport and heat capacity, yielding results consistent with a simple non-magnetic metal. However, magnetization measurements portray an extremely unusual response for a dilute paramagnet and do not exhibit the characteristic Curie behavior expected for a weakly interacting material at high temperature. Electronic structure calculations confirm metallic behavior but also indicate that each isolated band near the Fermi energy hosts non-trivial topologies, including strong, weak, and nodal components, with resultant topological surface states distinguishable from bulk states on the (001) surface. With half-filled flat bands apparent in the calculation, but an absence of long-range magnetic order, the unusual quasi-paramagnetic response suggests the dilute paramagnetic behavior in this quasicrystal approximant is surprising and may serve as a test of the fundamental assumptions that are taken for granted for the magnetic response of weakly interacting systems. Full article
(This article belongs to the Section Crystalline Metals and Alloys)
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54 pages, 15241 KiB  
Review
Heterogeneous Photocatalysis for Advanced Water Treatment: Materials, Mechanisms, Reactor Configurations, and Emerging Applications
by Maria Paiu, Doina Lutic, Lidia Favier and Maria Gavrilescu
Appl. Sci. 2025, 15(10), 5681; https://doi.org/10.3390/app15105681 - 19 May 2025
Cited by 2 | Viewed by 1584
Abstract
Heterogeneous photocatalysis has emerged as a versatile and sustainable technology for the degradation of emerging contaminants in water. This review highlights recent advancements in photocatalysts design, including band gap engineering, heterojunction formation, and plasmonic enhancement to enable visible-light activation. Various reactor configurations, such [...] Read more.
Heterogeneous photocatalysis has emerged as a versatile and sustainable technology for the degradation of emerging contaminants in water. This review highlights recent advancements in photocatalysts design, including band gap engineering, heterojunction formation, and plasmonic enhancement to enable visible-light activation. Various reactor configurations, such as slurry, immobilized, annular, flat plate, and membrane-based systems, are examined in terms of their efficiency, scalability, and operational challenges. Hybrid systems combining photocatalysis with membrane filtration, adsorption, Fenton processes, and biological treatments demonstrate improved removal efficiency and broader applicability. Energy performance metrics such as quantum yield and electrical energy per order are discussed as essential tools for evaluating system feasibility. Special attention is given to solar-driven reactors and smart responsive materials, which enhance adaptability and sustainability. Additionally, artificial intelligence and machine learning approaches are explored as accelerators for catalyst discovery and process optimization. Altogether, these advances position photocatalysis as a key component in future water treatment strategies, particularly in decentralized and low-resource contexts. The integration of material innovation, system design, and data-driven optimization underlines the potential of photocatalysis to contribute to global efforts in environmental protection and sustainable development. Full article
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17 pages, 9977 KiB  
Article
Statistical Properties of Correlated Semiclassical Bands in Tight-Binding Small-World Networks
by Natalya Almazova, Giorgos P. Tsironis and Efthimios Kaxiras
Entropy 2025, 27(4), 420; https://doi.org/10.3390/e27040420 - 12 Apr 2025
Viewed by 278
Abstract
Linear tight-binding models with long-range interactions and small-world geometry have a broad energy spectrum in the nearest neighbor coupling limit, while the spectrum becomes narrow in the fully connected limit due to the emergence of flat bands. A transition to a Wigner-like density [...] Read more.
Linear tight-binding models with long-range interactions and small-world geometry have a broad energy spectrum in the nearest neighbor coupling limit, while the spectrum becomes narrow in the fully connected limit due to the emergence of flat bands. A transition to a Wigner-like density of states appears at a low fraction of long-range bonds. Adding nonlinearity to the model introduces correlations among the stationary states, while multiple new states are generated as a result of the nonlinearity. In this work, we study the effect of band correlations on the local density of states for small-world networks as a function of the number of long-range bonds. We find that close to the nearest neighbor limit, the onset of correlations shifts the nonlinear density of states towards the band edge of the spectrum. Close to the opposite limit of the fully connected model, the band collapses in the band center, accompanied by a large increase in the new states induced by the nonlinearity. While in both limits the effect of correlations is to flatten the band, close to the mean field fully connected limit, the states are correlated and generally have distinct localized features. These effects may have implications for the dynamics of electrons in two-dimensional moiré structures and the onset of superconductivity in these systems. Full article
(This article belongs to the Special Issue New Challenges in Contemporary Statistical Physics)
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24 pages, 19392 KiB  
Article
Platinum Compound on Gold–Magnesia Hybrid Structure: A Theoretical Investigation on Adsorption, Hydrolysis, and Interaction with DNA Purine Bases
by Zhenjun Song, Mingyue Liu, Aiguo Zhong, Meiding Yang, Zhicai He, Wenmin Wang and Hongdao Li
Nanomaterials 2024, 14(24), 2027; https://doi.org/10.3390/nano14242027 - 17 Dec 2024
Viewed by 938
Abstract
Cisplatin-based platinum compounds are important clinical chemotherapeutic agents that participate in most tumor chemotherapy regimens. Through density-functional theory calculations, the formation and stability of the inorganic oxide carrier, the mechanisms of the hydrolysis reaction of the activated platinum compound, and its binding mechanism [...] Read more.
Cisplatin-based platinum compounds are important clinical chemotherapeutic agents that participate in most tumor chemotherapy regimens. Through density-functional theory calculations, the formation and stability of the inorganic oxide carrier, the mechanisms of the hydrolysis reaction of the activated platinum compound, and its binding mechanism with DNA bases can be studied. The higher the oxidation state of Pt (II to IV), the more electrons transfer from the magnesia–gold composite material to the platinum compound. After adsorption on the composite carrier, 5d←2p coordination bonds of Pt-N are strengthened. For flat and oblique adsorption modes of cisplatin, there is no significant difference in the density of states of the gold and magnesium oxide film, indicating the maintenance of the heterojunction structural framework. However, there are significant changes in the electronic states of cisplatin itself with different adsorption configurations. In the flat configuration, the band gap width of cisplatin is larger than that of the oblique configuration. The Cl-Pt bond range in the Pt(III) compound shows a clear charge reduction on the magnesia film, indicating the Cl-Pt bond is an active site with the potential for decomposition and hydrolysis. The substitution of chloride ions by water can lead to hydrolysis products, enhancing the polarization of the composite and showing strong charge separation. The hydrolysis of the free platinum compound is endothermic by 0.309 eV, exceeding the small activation energy barrier of 0.399 eV, indicating that hydrolysis of this platinum compound is easily achievable. ADME (absorption, distribution, metabolism, and excretion) prediction parameters indicate that hydrolysis products have good ESOL (Estimated SOLubility) solubility and high gastrointestinal absorption, consistent with Lipinski’s rule. During the coordination reaction process, there are significant changes in the distribution of frontier molecular orbitals, with the HOMO (highest occupied molecular orbital) of the initial state primarily located on the purine base, providing the possibility for electron transfer to the empty orbitals of the platinum compound in the LUMO (lowest unoccupied molecular orbital). The HOMO and HOMO-1 of the transition state and product are mainly distributed on the platinum compound, indicating clear electron transfer and orbital rearrangement. The activation energy barrier for the purine coordination reaction with the hydrolysis products is reduced to 0.61 eV, and the dipole moment gradually decreases to 6.77 Debye during the reaction, indicating a reduction in the system’s charge separation and polarization. This contribution is anticipated to provide a new theoretical clue for developing inorganic oxide carriers of platinum compounds. Full article
(This article belongs to the Section Biology and Medicines)
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10 pages, 5839 KiB  
Communication
Broadband Thermo-Optic Photonic Switch for TE and TM Modes with Adiabatic Design
by Babak Hashemi, Maurizio Casalino, Teresa Crisci, Mohamed Mammeri and Francesco G. Della Corte
Photonics 2024, 11(12), 1177; https://doi.org/10.3390/photonics11121177 - 14 Dec 2024
Cited by 1 | Viewed by 1038
Abstract
Optical power switches are essential components in fiber optic communication systems, requiring minimal losses, a broad operating wavelength range, and high tolerance to fabrication errors for optimal performance. Adiabatic optical power switches inherently meet these criteria and are well suited for manufacturing processes [...] Read more.
Optical power switches are essential components in fiber optic communication systems, requiring minimal losses, a broad operating wavelength range, and high tolerance to fabrication errors for optimal performance. Adiabatic optical power switches inherently meet these criteria and are well suited for manufacturing processes which support large-scale production at low costs. This paper presents the design and simulation of an adiabatic switch with a flat response in the whole 1525–1625 nm wavelength range (C band and L band) for both TE and TM polarizations. The switch is based on the thermo-optic effect induced by local variations in temperature. The impacts of the design parameters, such as the device length and dissipated heat, are analyzed. The simulation results indicate that the switch achieved high efficiency and low insertion losses, highlighting the potential of adiabatic switches for reliable and scalable integration into advanced optical circuits. Full article
(This article belongs to the Special Issue Photonics: 10th Anniversary)
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9 pages, 3068 KiB  
Article
Nanograting p-n Junctions with Enhanced Charge Confinement
by Avtandil Tavkhelidze, Larisa Jangidze, Givi Skhiladze, Sergo Sikharulidze, Kristine Dzneladze, Rusudan Kvesitadze and Amiran Bibilashvili
Nanomaterials 2024, 14(23), 1889; https://doi.org/10.3390/nano14231889 - 24 Nov 2024
Cited by 2 | Viewed by 1049
Abstract
Recently, geometry-induced quantum effects in a new quasi-1D system, or nanograting (NG) layers, were introduced and investigated. Dramatic changes in band structure and unconventional photoluminescence effects were found in silicon quantum wells with high-energy barriers. Nanograting metal–semiconductor junctions were fabricated and investigated. Here, [...] Read more.
Recently, geometry-induced quantum effects in a new quasi-1D system, or nanograting (NG) layers, were introduced and investigated. Dramatic changes in band structure and unconventional photoluminescence effects were found in silicon quantum wells with high-energy barriers. Nanograting metal–semiconductor junctions were fabricated and investigated. Here, we report the latest results on a special type of p-n junction in which the charge confinement of the NG is enhanced. The reverse bias dark current is increased in contrast to the metal–semiconductor junctions. When such a junction works as a photovoltaic cell, NG significantly increases short-circuit current and conversion efficiency without affecting open-circuit voltage. These effects are explained by the formation of geometry-induced excitons. To distinguish exciton formation from G-doping effects, we fabricated NGs in both n-type and p-type top layers and obtained qualitatively the same results. To further verify the excitonic mechanism, we analyzed photoluminescence spectrums previously obtained from NG and other NG-like periodic structures. The collected experimental results and previous findings are well explained by the formation of geometry-induced excitons and corresponding quasi-flat bands. Geometry-induced quantum effects can be used to significantly increase the conversion efficiency of photovoltaic cells and enhance the characteristics of other optoelectronic devices. Full article
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16 pages, 6518 KiB  
Article
Design and On-Orbit Performance of Ku-Band Phased-Array Synthetic-Aperture Radar Payload System
by Wei Yan, Xiaomin Tan, Jiang Wu, Mingze Yuan, Hongxing Dang and Wujun Chang
Sensors 2024, 24(20), 6741; https://doi.org/10.3390/s24206741 - 20 Oct 2024
Cited by 3 | Viewed by 2194
Abstract
The current emphasis in the advancement of space-based synthetic-aperture radar (SAR) is on lightweight payloads under 100 kg with resolutions surpassing 1 m. This focus is directed toward meeting the launch criteria for multiple satellites on a single rocket and cutting costs. This [...] Read more.
The current emphasis in the advancement of space-based synthetic-aperture radar (SAR) is on lightweight payloads under 100 kg with resolutions surpassing 1 m. This focus is directed toward meeting the launch criteria for multiple satellites on a single rocket and cutting costs. This article discusses the creation and progress of a Ku-band SAR payload for the Taijing-4(03) satellite, launched on 23 January 2024 and accompanied by four other satellites. The SAR payload design was customized to meet the demands of a micro-nano satellite platform, resulting in a lightweight, flat design weighing less than 80 kg, seamlessly integrated with the plate-shaped satellite platform. The article also introduces a beam optimization strategy for the phased array SAR antenna, significantly boosting the SAR system’s performance. The SAR payload provides various operating modes like slide-spot, strip, Scan 1, Scan 2, and others, with a maximum achievable resolution exceeding 1 m. Extensive in-orbit testing of the payload produced numerous high-quality SAR images with potential uses in emergency disaster mitigation, safeguarding ecosystems, monitoring forests, managing crops, tracking sea ice, and more. Full article
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17 pages, 5669 KiB  
Article
Stacking Fault Nucleation in Films of Vertically Oriented Multiwall Carbon Nanotubes by Pyrolysis of Ferrocene and Dimethyl Ferrocene at a Low Vapor Flow Rate
by Ayoub Taallah, Shanling Wang, Omololu Odunmbaku, Lin Zhang, Xilong Guo, Yixin Dai, Wenkang Li, Huanqing Ye, Hansong Wu, Jiaxin Song, Jian Guo, Jiqiu Wen, Yi He and Filippo S. Boi
C 2024, 10(4), 91; https://doi.org/10.3390/c10040091 - 12 Oct 2024
Viewed by 1691
Abstract
Recent observations of superconductivity in low-dimensional systems composed of twisted, untwisted, or rhombohedral graphene have attracted significant attention. One-dimensional moiré superlattices and flat bands have interestingly been identified in collapsed chiral carbon nanotubes (CNTs), opening up new avenues for the tunability of the [...] Read more.
Recent observations of superconductivity in low-dimensional systems composed of twisted, untwisted, or rhombohedral graphene have attracted significant attention. One-dimensional moiré superlattices and flat bands have interestingly been identified in collapsed chiral carbon nanotubes (CNTs), opening up new avenues for the tunability of the electronic properties in these systems. The nucleation of hexagonal moiré superlattices and other types of stacking faults has also been demonstrated in partially collapsed and uncollapsed carbon nano-onions (CNOs). Here, we report a novel investigation on the dynamics of stacking fault nucleation within the multilayered lattices of micrometer-scale vertically oriented films of multiwall CNTs (MWCNTs), resulting from the pyrolysis of molecular precursors consisting of ferrocene or dimethyl ferrocene, at low vapor flow rates of ~5–20 mL/min. Interestingly, local nucleation of moiré-like superlattices (as stacking faults) was found when employing dimethyl ferrocene as the pyrolysis precursor. The morphological and structural properties of these systems were investigated with the aid of scanning and transmission electron microscopies, namely SEM, TEM, and HRTEM, as well as X-ray diffraction (XRD) and Raman point/mapping spectroscopy. Deconvolution analyses of the Raman spectra also demonstrated a local surface oxidation, possibly occurring on defect-rich interfaces, frequently identified within or in proximity of bamboo-like graphitic caps. By employing high-temperature Raman spectroscopy, we demonstrate a post-growth re-graphitization, which may also be visualized as an alternative way of depleting the oxygen content within the MWCNTs’ interfaces through recrystallization. Full article
(This article belongs to the Special Issue Characterization of Disorder in Carbons (2nd Edition))
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25 pages, 11092 KiB  
Article
Design and Polyphase Implementation of Rotationally Invariant 2D FIR Filter Banks Based on Maximally Flat Prototype
by Radu Matei and Doru Florin Chiper
Electronics 2024, 13(14), 2829; https://doi.org/10.3390/electronics13142829 - 18 Jul 2024
Cited by 2 | Viewed by 1077
Abstract
This paper presents a design approach for a class of rotationally invariant 2D filters of finite impulse response (FIR) type, which may form circular filter banks with imposed specifications. The design is conducted analytically in the frequency domain and starts from a maximally [...] Read more.
This paper presents a design approach for a class of rotationally invariant 2D filters of finite impulse response (FIR) type, which may form circular filter banks with imposed specifications. The design is conducted analytically in the frequency domain and starts from a maximally flat low-pass prototype based on a trapezoidal function with specified width and slope. Its trigonometric approximation is derived using the Fourier series expressed analytically, truncated to a number of terms depending on the imposed accuracy. The chosen trapezoidal function leads to significantly smaller ringing oscillations compared to the approximation of an ideal square characteristic. By shifting the LP prototype to various frequencies, the desired filter bank is generated, where the component filters have a specified bandwidth, steepness, and overlap. The 2D circular filter bank results by applying a specific frequency mapping to the factored frequency response of the prototype filter. Thus, the frequency responses of the 2D filter bank components will also result in factored form, which is an advantage in implementation. The circular filter bank is designed in two versions, a uniform and a non-uniform (dyadic) filter bank. The designed filter banks have accurate shapes and relatively low order for the specified parameters. These filter banks are then used in a sub-band image decomposition application. Finally, an efficient implementation of these filters at the system level is proposed based on polyphase decomposition and the block filtering technique with a high degree of parallelism, resulting in a lower computational complexity. Full article
(This article belongs to the Section Circuit and Signal Processing)
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