Search Results (36)

Fire has been proven to threaten human lives and buildings significantly. Extensive research is being conducted globally to reduce fire risks, particularly in high-rise buildings that incorporate steel for structural support, timber for decorative elements, and cladding for insulation. Traditional passive fireproofing materials, such as concrete coverings, gypsum boards, and cementitious coatings, often lack aesthetic appeal. Intumescent coatings offer a promising solution to this issue. These coatings require a thin layer on the substrate to protect from fire, and the thin layer expands up to many times its original thickness when exposed to fire, forming an insulating char that acts as a barrier between fire and the substrate. This barrier prevents the steel from reaching critical temperature and helps maintain its integrity during a fire incident. Hence, intumescent coatings are a great choice for passive fire protection of load-bearing steel, wooden structures, timber, and cementitious buildings. Although some research articles discuss intumescent coating types, application methods, fabrication processes, cost-effectiveness, bonding performance, toxicity, and various uses, a comprehensive study encompassing all these topics still needs to be conducted. This review paper explores different types of intumescent coatings, their formulation and manufacturing methods, their application processes, and their use on various substrates. It also covers the key intumescent coating materials and their interactions during fire. Challenges and issues, such as fire protection time, char-forming temperature, and toxicity, are discussed. Full article

The prevailing fire-resistant design of steel structures typically relies on the premise of localized heating, whereas the overall temperature increase resulting from the dispersion of hot smoke is frequently oversimplified. These theoretical simplifications may result in considerable structural safety risks. This research utilized the Transient Thermo-Mechanical Coupling Theory and developed a double-layer steel frame finite element model using ABAQUS 2023 software. The simulation of multi-physics field coupling involving smoke convection-radiation heat transfer and nonlinear structure response in fire situations was accomplished by establishing 24 sets of comparative conditions over three distinct premises. Upon comparing the conditions with the greatest displacement values across the three situations, it was concluded that when hot smoke is produced in the initial room, it commences diffusion into adjacent rooms both horizontally and vertically. In comparison to the scenario that disregards the dispersion of hot smoke, the displacement of the components escalated by 342.3%. The dispersion of hot smoke reveals that the displacement of components in the center room of the fire’s origin was 23.1% greater than in the corner room, while the displacement in the second-story room was 115.6% greater than in the first-story room. The use of fireproof coating markedly diminished component displacement in the context of hot smoke dispersion, achieving an 82.8% reduction in displacement among components in identical positions. The enhanced vulnerability model augmented the precision of forecasting the ongoing failure of steel frames by 29.1%. Full article

As building safety standards keep escalating, research on intumescent fireproof coatings has garnered growing attention. Among them, tunnels, with their enclosed configuration and relatively high accident occurrence rate, impose higher demands on the environmental friendliness, durability, and thermal stability of fireproof coatings. At present, intumescent fireproof coatings have been extensively applied in tunnels; however, a comprehensive and in-depth overview of intumescent fireproof coatings and their application in tunnels is still lacking. This paper summarizes the fire prevention mechanism of intumescent fireproof coatings, the intumescent fireproof system, the impact of functional fillers on the fire resistance performance of intumescent fireproof coatings, and the application of intumescent fireproof coatings in tunnels. Additionally, we present the synergistic effect of the combined use of different functional fillers. Finally, some key challenges regarding the use of intumescent fireproof coatings in tunnel environments are put forward, along with prospects and opportunities. Full article

There are a large number of steel components in substations/converter stations whose performance is seriously affected by being exposed to environmental corrosion and fire, endangering the operation of the substation/converter station. The current protective measures for steel components in substations/converter stations primarily involve the application of anti-corrosion and fireproof coatings. However, these coatings can easily peel off, resulting in a significant loss of their protective effectiveness. In response to this challenge, a new type of silicone-modified epoxy resin substrate has been synthesized by chemically grafting silicone resin onto epoxy resin segments, which retains the high adhesion of epoxy resin while enhancing its weather resistance. The use of synthesized nano zinc oxide-modified graphene oxide as a fireproof filler significantly improves the physical barrier effect and corrosion resistance of the coating. Additionally, the innovative addition of new metal anti-corrosion active pigments improves the adhesion and impermeability of the coating. Therefore, a steel structure coating for substations/converter stations with both fire and corrosion prevention functions has been developed. Standard tests conducted by national institutions have shown that the coating meets the performance requirements. Full article

This research develops a numerical fire model for a converter transformer utilizing the Fire Dynamics Simulator (FDS). The model’s accuracy was validated through comprehensive evaluations of temperature distribution, radiative heat transfer, and mass burning rate. Additionally, the cooling efficacy of fire-resistant coating and fine water mist with varying droplet sizes was investigated. The results indicate that fireproof coating significantly reduces the surface temperature of the transformer, thereby enhancing its fire resistance. Specifically, temperature reductions of 57.68%, 45.63%, 37.78%, and 36.78% were recorded at different facade heights. Furthermore, the cooling performance of fine water mist is strongly influenced by droplet size, primarily due to thermal buoyancy effects. Larger droplets (400 μm) exhibited the most efficient cooling effect directly beneath the spray, achieving temperature reductions of up to 67%. In contrast, smaller droplets (100 μm) showed diminished cooling performance in certain regions, owing to the compensatory buoyancy of hot air, even resulting in an 11% temperature increase in some cases. During the flame stabilization phase, the mass burning rate stabilized between 0.056 kg/(m²·s) and 0.070 kg/(m²·s), with the inhibitory effect of small particle mist becoming pronounced only after 450 s. These findings offer critical insights for optimizing fire protection strategies for converter transformers, highlighting the significance of cooling mechanisms and material properties. Full article

The adsorption efficiency of Cr(VI) and anionic textile dyes onto MgAl-layered double hydroxides (LDHs) and MgAl-LDH coated on bio-silica (b-SiO₂) nanoparticles (MgAl-LDH@SiO₂) derived from waste rice husks was studied in this work. The material was characterized using field-emission scanning electron microscopy (FE-SEM/EDS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopic (XPS) techniques. The adsorption capacities of MgAl-LDH@SiO₂ were increased by 12.2%, 11.7%, 10.6%, and 10.0% in the processes of Cr(VI), Acid Blue 225 (AB-225), Acid Violet 109 (AV-109), and Acid Green 40 (AG-40) dye removal versus MgAl-LDH. The obtained results indicated the contribution of b-SiO₂ to the development of active surface functionalities of MgAl-LDH. A kinetic study indicated lower intraparticle diffusional transport resistance. Physisorption is the dominant mechanism for dye removal, while surface complexation dominates in the processes of Cr(VI) removal. The disposal of effluent water after five adsorption/desorption cycles was attained using enzymatic decolorization, photocatalytic degradation of the dyes, and chromate reduction, satisfying the prescribed national legislation. Under optimal conditions and using immobilized horseradish peroxidase (HRP), efficient decolorization of effluent solutions containing AB-225 and AV-109 dyes was achieved. Exhausted MgAl-LDH@SiO₂ was processed by dissolution/precipitation of Mg and Al hydroxides, while residual silica was used as a reinforcing filler in polyester composites. The fire-proofing properties of composites with Mg and Al hydroxides were also improved, which provides a closed loop with zero waste generation. The development of wastewater treatment technologies and the production of potentially marketable composites led to the successful achievement of both low environmental impacts and circular economy implementation. Full article

Traditional and modern coatings play a key role in enhancing the fire resistance of ancient Chinese buildings. However, further comparative analysis is needed on the fire properties of the two coatings and their effects on different timber structural components. This study focuses on the main hall of the Shanxi Changzhi Xianqing Temple, a typical traditional column and beam construction built between the Song and Jin periods. Firstly, the combustion characteristics of various timber structural component samples with different surface treatments (traditional “Yi-ma-wu-hui” and modern flame retardants) were analyzed using cone calorimeter. Secondly, the fire development process of the Xianqing Temple building model was analyzed by a fire dynamics simulator (FDS), and the effect mechanism of different surface treatments on the burning process was further studied. The results show that the fire resistance of timber structural components is significantly improved after modern and traditional surface treatments. The traditional method is more effective in delaying the peak heat release rate and reducing the surface temperature during combustion, while the modern surface treatment significantly prolongs the ignition time of the timber structural components. The FDS results confirm that modern and traditional surface treatments significantly improve the fire resistance of the building, delaying the flashover time by about 300 s, with no collapse occurring within 800 s. In addition, the fire resistance of buildings after traditional surface treatment is better compared to traditional methods. The above research results can provide direct data support for the selection and optimization of fireproof coatings and treatment methods for ancient buildings. Full article

This study deals with the design of modern environmentally friendly and non-toxic flame retardants based on expandable graphite 25 K + 180 (EG) modified by cellulose ethers (Lovose TS 20, Tylose MH 300, Klucel H) and nanocellulose (CNC) that are biocompatible with wood and, therefore, are a prerequisite for an effective surfactant for connecting EG to wood. The effectiveness of the formulations and surfactants was verified using a radiant heat source test. The cohesion of the coating to the wood surface and the cohesion of the expanded graphite layer were also assessed. The fire efficiency of the surfactants varied greatly. Still, in combination with EG, they were all able to provide sufficient protection—the total relative mass loss was, in all cases, in the range of 7.38–7.83% (for untreated wood it was 88.67 ± 1.33%), and the maximum relative burning rate decreased tenfold compared to untreated wood, i.e., to 0.04–0.05%·s⁻¹. Good results were achieved using Klucel H + EG and CNC + EG formulations. Compared to Klucel H, CNC provides significantly better cohesion of the expanded layer, but its high price increases the cost of the fireproof coating. Full article

Intumescent fireproof coatings protect steel structures and cables by forming a thick, fire-resistant layer under high temperatures. These coatings can deteriorate over time, impacting their fire resistance. Current testing methods are largely lab-based, lacking in-service evaluation platforms. Laser-Induced Breakdown Spectroscopy (LIBS) is emerging as a promising in situ detection technology but is influenced by low air pressure in high-altitude areas. This study investigates how air pressure affects LIBS signals in intumescent coatings on galvanized steel. Using pressures between 35 and 101 kPa, a linear model was developed to correlate laser pulses to ablation depth for characterizing coating thickness. Results show that spectral intensity decreases with lower air pressure. However, a strong linear relationship persists between laser pulses and ablation depth, with a fitting accuracy above 0.9. The coating thickness is identified by the number of laser pulses required to detect the Zn spectral line from the underlying galvanized steel. As air pressure decreases, the ablation depth increases. The study effectively models and corrects for air pressure effects on LIBS data, enabling its application for field detection of fireproof coatings. This advancement enhances the reliability of LIBS technology in assessing the fire performance of these materials, providing a reference for their in situ evaluation and ensuring better fire safety standards for building steel structures and cables. Full article

Metallum Fire-Resistant paint, denoted as MFR henceforth, represents a cutting-edge insulating material with dual functionality as a fireproof solution, presenting substantial advantages in the realm of construction applications. This exposition derives its primary insights from the scholarly contributions documented in publications. The focal point of these investigations includes the assessment of fire hazards associated with polyethylene materials in building structures and the enhancement of mortars in high-temperature environments in tunnels. The purpose of this study is to evaluate the effectiveness of a modified cork-based coating (MFR) compared to traditional coatings in terms of corrosion protection, fire resistance, and thermal insulation properties in construction applications. This evaluation focuses on quantifying the efficacy of MFR by examining key properties, such as adhesion, the reduced thickness required for fire protection, thermal conductivity reduction, and corrosion resistance under extreme environmental conditions. MFR is highly effective in fire prevention for buildings and tunnels, withstanding temperatures over 1000 °C while maintaining structural integrity. A unique aspect of MFR is its use of cork shavings, a typically underutilized byproduct from wine-bottle-stopper production. This innovative not only amplifies MFR’s fire-resistant attributes, but also introduces sustainability and judicious resource utilization into its manufacturing processes. Full article

Jet fires are the second most common fire scenario after spill fires. This type of fire is characteristic of gas and gas–oil fires occurring on oil platforms and gas production and processing plants. The consequences of such fires are characterized by high material damage; this is associated with extensive networks of technological communications, since there is a high density of technological facilities and installations in the territory where these fires occur. At such facilities, there is a large number of steel structures, which under the action of high temperature quickly lose their strength and deform. To protect steel structures in the oil and gas industry, fire protection is used, which consists of different types: boards in the form of flat plates, plasters, and epoxy paints. This paper compares three types of fire protection materials for steel structures under jet fire: board fireproofing, plaster composition, and epoxy coating. When comparing the efficiency in jet fire, cement boards were found to be the best. However, despite the better fire protection efficiency, their low application is expected due to their massiveness and the high cost of such protection and the difficulty of installation. Nevertheless, the development of fire depends on the place of its origin, the size of the initial fire zone, and the stability and massiveness of the metal elements of the vessel structure or the structure of the boards on which the equipment can be placed. Therefore, it is necessary to take these factors into account when selecting fire protection and to apply it depending on the required fire resistance limits of structures, which should be determined depending on the fire development scenarios. Full article

The intumescent flame-retardant coatings were prepared using ammonium polyphosphate (APP), pentaerythritol (PER), melamine (MEL), styrene–acrylic emulsion, and iron oxide yellow (FeOOH) as the base material. A cone calorimeter (CCT), smoke density meter (SDA), and scanning electron microscope (SEM) were employed to investigate the smoke suppression and flame retardancy of FeOOH in intumescent fire-retardant coatings. The thermal degradation performance of intumescent fireproofing coatings with varying FeOOH content was investigated through thermogravimetric analysis (TGA). The structure of the carbon slag in the CCT test was analyzed using a scanning electron microscope (SEM). The results of the cone calorimeter (CCT) experiments demonstrated that FeOOH significantly reduced the heat release rate (HRR), total heat release rate (THR), smoke production rate (SPR), and total smoke release rate (TSR) of the coating, while simultaneously increasing the carbon residue rate of the coating. The smoke density analysis (SDA) results demonstrate that adding FeOOH can effectively reduce smoke generation, regardless of whether a pilot flame is used. TGA results demonstrate that FeOOH can enhance the weight of coke residue at elevated temperatures. SEM results indicate that incorporating FeOOH resulted in a more compact coke residue. According to these findings, among all the samples, those containing 2 wt% FeOOH showed low levels of HRR, THR, SPR, and TSR and high levels of SOD, which proves that FeOOH can be used as a smoke inhibitor in flame-retardant coatings. Full article

The hydrocarbon temperature–time curve is widely used instead of the standard curve to describe the temperature in the environment of structural surfaces exposed to fire in oil and gas chemical facilities and tunnels. This paper presents calculations of the ratio of time to reach critical temperatures at different nominal fire curves for steel structures such as bulkheads and columns with different types of fireproofing. The thermophysical properties of the fireproofing materials were obtained by solving the inverse heat conduction problem using computer simulation. It was found that the time interval for reaching critical temperatures in structures with different types of fireproofing in a hydrocarbon fire decreased, on average, by a factor of 1.2–1.7 compared to the results of standard fire tests. For example, for decks and bulkheads with mineral wool fireproofing, the K-factor of the ratio of the time for reaching the critical temperature of steel under the standard curve to the hydrocarbon curve was 1.30–1.62; for plaster, it was 1.56; for cement boards, it was 1.34; for non-combustible coatings, it was 1.38–2.0; and, for epoxy paints, it was 1.71. The recommended values of the K-factor for fire resistance up to 180 min (incl.) were 1.7 and, after 180 min, 1.2. The obtained dependencies would allow fireproofing manufacturers to predict the insulation thickness for expensive hydrocarbon fire experiments if the results of fire tests under standard (cellulosic) conditions are known. Full article

This study examined the effect of ultralow concentrations of three types of graphene oxide (GO) flakes on the fire resistance of water-based intumescent coatings, which are used widely as fire protectants for steel structures. The fire resistance of the coatings was assessed using a small-scale fireproof testing furnace, and their elemental compositions, oxidation states, and char-layer microstructures were analysed using Thermal Gravimetric analyzer (TG), X-ray Diffraction (XRD), Scanning Electron Microscope (SEM)SEM, and X-Ray Photoelectron Spectroscopy (XPS)XPS, and the reaction mechanisms were revealed. The results show that three types of GO with different sizes and thicknesses all have the ability to enhance the fire-resistance performance of intumescent coatings at different extremely low dosages (0.001%–0.002%), with a maximum increase of 20% compared to that of the blank. Compared with small GO flakes, large GO flakes more effectively enhanced the fire resistance of coatings. The mechanism of enhancement of GO is attributed to two factors. On the one hand, although the presence of GO did not affect the type of final product of intumescent coatings, it affected the proportion of products. After adding GO, the production of titanium pyrophosphate increased, leading to an increase in the strength of the char layer. On the other hand, the microstructure of the char layer of the intumescent coating added with GO has been improved, leading to a significant improvement in the fire-resistance performance. When the dosage was greater than 0.002%, GO tended to agglomerate, which diminished its ability to enhance the fire resistance of coatings. Agglomerated GO can also leaded to a deterioration in the crystal structure of titanium pyrophosphate, thereby affecting the strength of the char layer. Full article

The enormous potential of renewable bioresources is expected to play a key role in the development of the EU’s sustainable circular economy. In this context, inexhaustible, biodegradable, non-toxic, and carbon-neutral forest-origin resources are very attractive for the development of novel sustainable products. The main structural component of wood is cellulose, which, in turn, is the feedstock of nanocellulose, one of the most explored nanomaterials. Different applications of nanocellulose have been proposed, including packaging, functional coatings, insulating materials, nanocomposites and nanohybrids manufacturing, among others. However, the intrinsic flammability of nanocellulose restricts its use in some areas where fire risk is a concern. This paper overviews the most recent studies of the fire resistance of nanocellulose-based materials, focusing on thin films, coatings, and aerogels. Along with effectiveness, increased attention to sustainable approaches is considered in developing novel fire-resistant coatings. The great potential of bio-based fire-resistant materials, combined with conventional non-halogenated fire retardants (FRs), has been established. The formulation methods, types of FRs and their action modes, and methods used for analysing fireproof are discussed in the frame of this overview. Full article