Search Results (137)

The results show that the numerical simulation error based on the RPI two-phase boiling heat transfer model is less than 5%, which is in good agreement with the test results. Compared with the original engine, the temperature near the spark plugs’ position of improvement in scheme 2 decreased by 8.4 K, and the maximum temperature difference between the cylinder head intake and exhaust decreased by 14 K. Moreover, the overheating degree of the water jacket wall is the lowest, avoiding the occurrence of film boiling, and the local maximum vaporization rate is less than 50%. The prototype tests also confirmed that the improvement scheme effectively enhanced the heat transfer performance of the water jacket. The inlet flow rate and temperature of the coolant have significant and complex effects on two-phase boiling heat transfer. Both too low a flow rate and too high a temperature will lead to local film boiling, deteriorating heat transfer. Too high a flow rate will blow away bubbles, while too low an inlet temperature will not cause boiling, both of which can only enforce convective heat transfer. Appropriately reducing the flow rate and increasing the temperature can effectively utilize the enhanced heat transfer potential of subcooled boiling, while also save pump power consumption and improving engine fuel economy. The average heat flux density of boiling heat transfer in this paper is 13.9% higher than that of the forced convective heat transfer. When designing a water jacket with boiling heat transfer, attention should be paid to the transport effect of convective motion on bubbles, controlling subcooled boiling in the high-temperature zone and preventing film boiling. Full article

A novel fluorinated diamine monomer, 4,4′-((bicyclo[2.2.1]hept- 5-ene-2,3-diylbis (methylene)) bis(oxy))bis(3- (trifluoromethyl) aniline) (NFDA), featuring a tailored alicyclic norbornane core, flexible ether linkages, and pendant trifluoromethyl groups, was successfully synthesized. This monomer was polymerized with six commercial dianhydrides to produce a series of poly(amic acid) precursors, which were subsequently converted into high-performance polyimide (PI) films via a thermal imidization process. The strategic integration of the alicyclic, ether, and fluorinated motifs within the polymer backbone resulted in materials with an exceptional combination of properties. These PI films display outstanding solubility in a wide range of organic solvents, including low-boiling options like chloroform and tetrahydrofuran, highlighting their superior solution processability. The films are amorphous and exhibit remarkable hydrophobicity, evidenced by high water contact angles (up to 109.4°) and minimal water absorption (as low as 0.26%). Furthermore, they possess excellent optical transparency, with a maximum transmittance of 86.7% in the visible region. The materials also maintain robust thermal stability, with 5% mass loss temperatures exceeding 416 °C, and offer a desirable balance of mechanical strength and flexibility. This unique set of attributes, stemming from a rational molecular design, positions these polyimides as highly promising candidates for next-generation flexible electronics and advanced photovoltaics. Full article

Predicting phase-change heat transfer in two-phase closed thermosyphons (TPCTs) represents a significant challenge owing to the complex interaction of boiling, condensation, and conjugate heat transfer (CHT) mechanisms. This study presents a numerical investigation of a TPCT using the Combined Boiling Model (CBM) within a conjugate heat transfer (CHT) framework. Unlike prior TPCT studies, the CBM integrates an improved RPI-based wall boiling model with sliding bubble dynamics, a laminar film condensation closure, and Lee-type bulk phase change in a single, energy-consistent formulation suited for engineering-scale meshes and time-steps. Building on these extensions, we demonstrate the approach on a vertical TPCT with full CHT and validate it against experiments and a VOF–Lee reference. Simulations for heat loads ranging from 173 to 376 W capture key flow features, including vapour generation, vapour-pocket dynamics, and thin-film condensation, while reducing temperature deviations typically below 3% in the evaporator and adiabatic sections and about 2 to 5% in the condenser. The results confirm that the CBM provides a physically consistent and computationally efficient approach for predicting evaporation–condensation phenomena in TPCTs. Full article

The two-phase flow within a Boiling Water Reactor steam separator is investigated using an interface capturing method. The simulations are focused on resolving the flow around the first pickoff ring which is the highest contributor to steam carryunder phenomenon. Multiple simulations are conducted of varying levels of resolution to evaluate the capabilities of interface capturing technique for this challenging problem. First, high-resolution simulations of the flow using a simplified $30°$ wedge are conducted without a swirling velocity field present in the actual system. In order to understand the flow field generated by the separator swirler, secondary simulations of single-phase flow passing through a swirler model are conducted. Using this information, a coarse simulation of the full $360°$ model was performed, which incorporated the effect of the swirler using a custom inflow boundary condition. Instantaneous carryunder/carryover along with void fraction and film thickness are evaluated at the pickoff ring entrance. Overall, these simulations demonstrate that interface capturing simulations can be an accurate tool for studying full-scale components within nuclear power plants. Full article

Compact and efficient absorption refrigeration systems can effectively utilize waste heat and renewable energy when operated in a boiling-desorption mode, which maximizes the desorption rate. Hydrophobic membranes play a critical role in microchannel membrane-based generators; however, limited research has addressed bubble cross-membrane removal dynamics under boiling-desorption conditions, particularly the influence of membrane hydrophobicity. In this study, a two-phase flow bubble-removal model was developed to accurately represent boiling-desorption behavior. Numerical simulations were performed to investigate the effects of membrane hydrophobicity and heating power on bubble dynamics, wall temperature, venting rate, and channel pressure drop. Results show that bubble venting proceeds through four stages: nucleation and growth, liquid-film rupture with deformation, lateral spreading, and sustained vapor removal. Hydrophobicity effects become most significant from the third stage onwards. Increased hydrophobicity reduces wall temperature, with greater reductions at higher heat fluxes, and enhances venting performance by increasing total vapor removal and reducing removal time. Channel pressure fluctuations comprise high-frequency components from bubble growth and low-frequency components from venting-induced flow interruptions, with relative contributions dependent on hydrophobicity and heat flux. These findings provide new insights into bubble-removal mechanisms and offer guidance for the design and optimization of high-performance microchannel membrane-based generators. Full article

The critical heat flux (CHF) of minichannel heat sinks is crucial, as it helps prevent thermal safety incidents and equipment failure. However, the underlying mechanisms of CHF in minichannels remain poorly understood, and existing CHF prediction models require further refinement. This study systematically investigates the characteristics and influencing factors of critical heat flux (CHF) in rectangular minichannels through combined experimental and theoretical approaches. Experiments were conducted using microchannels with hydraulic diameters ranging from 0.5 to 2.0 mm, with ethanol employed as the working fluid. Key parameters-including mass flux, channel geometry, system pressure, and inlet subcooling-were analyzed to assess their influence on CHF. Results indicate that CHF increases with mass flux; however, the increase rate diminishes under higher mass flux. Larger channel dimensions significantly enhance CHF by delaying liquid film dryout. System pressure further improves CHF by reducing bubble detachment frequency and promoting flow stability. Increased inlet subcooling enhances CHF by delaying the onset of nucleate boiling and improving convective heat transfer. Four classical CHF prediction models were evaluated, revealing significant overprediction-up to 148.69% mean absolute error (MAE)-particularly for channels with hydraulic diameters below 1.0 mm. An ANN deep learning model was developed, achieving a reduced MAE of 8.93%, with 93% of predictions falling within ±15% error. This study offers valuable insights and a robust predictive model for optimizing microchannel heat sink performance in high heat flux applications. Full article

To address the challenge of low iron extraction efficiency from boiling furnace pyrite cinder (BPC), a significant secondary iron resource posing environmental risks due to massive stockpiling in China, this study investigated the kinetics and reactivity regulation of an oxalic acid-sulfuric acid hybrid leaching system to overcome the inertness and diffusion barriers of hematite. Single-factor experiments and Response Surface Methodology (RSM) optimization were employed to determine optimal leaching parameters (time, temperature, liquid–solid ratio, H₂SO₄ concentration) under constant stirring (400 r/min) and BPC–oxalic acid ratio (50:1). Shrinking core kinetic modeling, complemented by SEM-EDS/XRD residue characterization, elucidated the dissolution mechanism. Results showed a maximum iron leaching rate of 94.7% at 90 °C, 40 wt% H₂SO₄, an L/S ratio of 5 mL/g, and a time of 7 h. Kinetics transitioned from liquid-film diffusion control (Ea = 76.9 kJ/mol) below 70 °C to mixed interfacial reaction/internal diffusion control (Ea = 32.4 kJ/mol) above 80 °C. Highly concentrated acid conditions (50% H₂SO₄) reduced efficiency by >20% due to oxalate protonation, CaSO₄ pore occlusion, and increased viscosity. RSM confirmed temperature-dominated kinetics and acid concentration-governed thermodynamics, with no synergy under combined high-temperature/high-acidity conditions. This optimized process enables efficient iron recovery from refractory BPC using minimal reagent consumption. Full article

Fuel with a tight lattice structure in the reactor core is an important design direction for high-performance water reactors. Due to the dispersed flow characteristic, research on post-dryout heat transfer is limited. However, a better understanding of post-dryout heat transfer characteristics under accident conditions is significantly important for fuel design and safety analysis. This study experimentally investigates the characteristics of post-dryout dispersed flow heat transfer in a 3-rod tight-lattice bundle with a pitch-to-diameter ratio of 1.2. The working conditions are as follows: system pressure ranging from 6 to 10 MPa, mass flux between 65 to 200 kg/(m²s), and heat flux varying from 75 to 200 kW/m². Circumferentially non-uniform heat transfer is obviously observed. The wall temperature is higher in the narrow gaps between rods, while lower in the vicinity of the subchannel center. The specific mechanisms of the above phenomena are analyzed. Parametric effects on post-dryout heat transfer are discussed and illustrated. Using the experimental data, commonly utilized correlations for transition boiling and film boiling are evaluated. In order to improve the prediction accuracy, new heat transfer correlations for transition boiling and film boiling in the tight-lattice under low mass flux and low heat flux are developed based on the experimental data and mechanistic analysis. Full article

This work—mixing an original experimental approach, as well as numerical simulations—proposes to study film boiling modes around a small nickel sphere. While dealing with a simple looking phenomenon that is found in many industrial processes and has been solved for basic quenching regimes, we focus on describing precisely how vapor formation and film thicknesses, as well as vapor bubble evacuation, affect cooling kinetics. As instrumenting small spheres may lead to experimental inaccuracies, we optically captured, using a high-speed camera, the vapor film thickness at mid height, the vapor bubble volume, and the bubble detachment frequency, along with the heat flux. More precisely, an estimation of the instant sphere temperature, in different conditions, was obtained through cooling time measurement before the end of the film boiling mode, subsequently facilitating heat flux evaluation. We encountered a nearly linear decrease in both the vapor film thickness and vapor bubble volume as the sphere temperature decreased. Notably, the detachment frequency remained constant across the whole temperature range. The estimation of the heat fluxes confirmed the prevalence of conduction as the primary heat transfer mode; a major portion of the energy was spent increasing the liquid temperature. The results were then compared to finite element simulations using an in-house multiphysics solver, including thermic phase changes (liquid to vapor) and their hydrodynamics, and we also captured the interfaces. While presenting a challenge due to the contrast in densities and viscosities between phases, the importance of the small circulations along them, which improve the heat removal in the liquid phase, was highlighted; we also assessed the suitability of the model and the numerical code for the simulation of such quenching cases when subcooling in the vicinity of a saturation temperature. Full article

In this study, polymer films based on the inorganic sorbents Al₂O₃, ZrO₂ and SiO₂-phenyl with repellent N,N-diethyl-3-methylbenzamide were prepared and used as functional textile coatings. The high sorption activity of oxides with respect to N,N-diethyl-3-methylbenzamide (63–239 mg/g) allows for the use of these compounds as repellent carrier materials, and their mixture with polyacrylates allows for the formation of functional coatings–polymer films. Scanning electron microscopy and Fourier transform infrared spectroscopy results revealed that the inorganic sorbents Al₂O₃, ZrO₂ and SiO₂-phenyl were successfully anchored in the polyacrylate structure, and the FTIR spectra confirmed the presence of repellent molecules. The thermal diffusion parameters of N,N-diethyl-3-methylbenzamide were also calculated via thermogravimetric analysis and high-performance liquid chromatography with diode array detection. The highest thermal diffusion rates and concentrations were observed for the material with Al₂O₃ (up to 148.3∙10⁻⁹ mol at 200 °C), and lower values for ZrO₂ and SiO₂-phenyl (up to 15.2∙10⁻⁹ mol and 34.3∙10⁻⁹ mol at 200 °C, respectively). The heat flux parameter J_f was also calculated according to Onsager’s theory and Fourier’s law. The release of repellent from polymeric materials can be achieved by applying less heat than that required to reach the boiling point of N,N-diethyl-3-methylbenzamide. Full article

Microchannel heat exchangers, with their large specific surface area, exhibit high heat/mass transfer efficiency and have a wide range of applications in chemical engineering and energy. To enhance microchannel flow boiling heat transfer, a top-connected microchannel heat exchanger with a Ni/Ag micro/nano composite surface was designed. Using anhydrous ethanol as the working fluid, comparative flow boiling heat transfer experiments were conducted on regular parallel microchannels (RMC), top-connected microchannels (TCMC), and TCMC with a Ni/Ag micro/nano composite surface (TCMC-Ni/Ag). Results show that the TCMC-Ni/Ag’s maximum local heat transfer coefficient reaches 179.84 kW/m²·K, which is 4.1 times that of RMC. Visualization reveals that its strongly hydrophilic micro/nano composite surface increases bubble nucleation density and nucleation frequency. Under medium-low heat flux, the vapor phase converges in the top-connected region while bubbles form on the microchannel surface; under high heat flux, its capillary liquid absorption triggers a thin-liquid-film convective evaporation mode, which is the key mechanism for improved heat transfer performance. Full article

To analyze the progression of Leidenfrost evaporation, traditional experiments were conducted manually to generate a complete evaporation curve. However, physical constraints render Leidenfrost evaporation experiments inherently time-consuming and susceptible to uncertainty. To address these challenges, this study aimed to develop an automated system using webcams for real-time image acquisition and processing, as well as a syringe pump constructed using an Arduino microcontroller, a stepper motor, and 3D-printed components. In the domain of real-time image processing, the radii of levitated droplets were determined using circular detection techniques. By fitting the droplet radii over hundreds of consecutive frames, it was concluded that the shrinking rate of levitated droplet radii remain constant when the radius exceeds 0.6 mm, and the evaporation time is accurately derived. A moving average algorithm was employed to identify the heat transfer area as well as the evaporation time between the boiling droplet and the hot surface, enabling simultaneous calculation of the heat flux. The automated system was then used to perform Leidenfrost experiments under varying experimental parameters, and was compared to manual methods to demonstrate its superior precision in both the film boiling and nucleate boiling regimes. For example, the automated system was utilized to perform a series of experiments as the Weber number increased from 7.01 to 23.18. The detected Leidenfrost temperature rose from 154 °C to 192 °C, while the evaporation time decreased from 85.2 s to 78.9 s. These findings were consistent with previous studies and aligned with physical expectations, reinforcing the reliability of the system and its results. Full article

Understanding the influence of topography on wettability is essential for improving the modeling of superhydrophobic surfaces. Moreover, wetting predictions can foresee corrosion, biological contamination, self-cleaning properties, and all phenomena related to wetting. In this context, this research work reports the experimental corroboration of a novel theoretical model for stochastic surfaces that relates the static contact angle for the heterogeneous wetting of surfaces to the root mean square (RMS) slope of the surface structures, allowing wetting prediction through topography. For this study, hydrophobic and superhydrophobic alumina thin films with gradual roughness were constructed. The films were deposited on glass using the dip-coating technique, textured with boiling water, and functionalized to achieve low surface energy using Dynasylan F-8815. Surface wettability was characterized using the sessile drop technique, and the RMS slope of the alumina surfaces was quantified using the atomic force microscopy (AFM) technique. The model, presented here for the first time, fits the experimental data, allowing wetting prediction for hydrophobic and superhydrophobic surfaces considering static contact angles. As expected, topography plays a fundamental role in achieving superhydrophobicity. Therefore, defining a topographic criterion, as performed here, for obtaining superhydrophobic surfaces is highly relevant to reduce the production costs of these surfaces and also enable new production processes and designs. Full article

The numerical solution of flow and temperature fields in and around a hot metal component being immersed into a cooling fluid offers powerful insights into investigating industrial quenching processes. The calculation requires a simultaneous solution of the Navier Stokes and the according energy equation. Difficulties arise at the boundaries where high heat transfer rates are forced from the solid surface to the fluid due to high metal temperatures. Heat transfer rates are determined based on the similarity theory, but reliable heat transfer equations valid for the high temperature typical of quenching processes are rare. This paper presents a two-fluid VOF (volume-of-fluid method) approach, giving an insight into the transient heat transfer and its oscillations. Unlike our previous publications, this paper uses the lumped heat conduction model to obtain the heat transfer coefficient in the film boiling heat transfer mode. Its application leads to an estimation of an average heat transfer coefficient. Furthermore, the unsteady distribution of the heat transfer coefficient values, shown in our previous paper, is now supplemented with the corresponding flow behavior obtained using the numerical simulation. In our approach, the vapor bubble formation during the film boiling phase is tracked directly (DNS of interface motion, not turbulence), and the unsteady heat transfer coefficient distribution is obeyed. Full article

This study delves into the distinctive selective property exhibited by a non-conjugated cholesterol-based polymer, poly(CEM₁₁-b-EHA₇), in sorting semiconducting single-walled carbon nanotubes (s-SWCNTs) within isooctane. Comprised of 11 repeating units of cholesteryloxycarbonyl-2-hydroxy methacrylate (CEM) and 7 repeating units of 2-ethylhexyl acrylate (EHA), this non-conjugated polymer demonstrates robust supramolecular interactions across the sp² surface structure of carbon nanotubes and graphene. When coupled with the Double Liquid-Phase Extraction (DLPE) technology, the polymer effectively segregates s-SWCNTs into the isooctane phase (nonpolar) while excluding metallic SWCNTs (m-SWCNTs) in the water phase (polar). DLPE proves particularly efficient in partitioning larger-diameter s-SWCNTs (0.85–1.0 nm) compared to those dispersed directly in isooctane by poly(CEM₁₁-b-EHA₇) using direct liquid-phase exfoliation (LPE) techniques for diameters ranging from 0.75 to 0.95 nm. The DLPE method, bolstered by poly(CEM₁₁-b-EHA₇), successfully eliminates impurities from s-SWCNT extraction, including residual metallic catalysts and carbonaceous substances, which constitute up to 20% of raw HiPCO SWCNTs. DLPE emerges as a scalable and straightforward approach for selectively extracting s-SWCNTs in nonpolar, low-boiling-point solvents like alkanes. These dispersions hold promise for fabricating fast-drying s-SWCNT inks, which are ideal for printed and flexible thin-film transistors. Full article