Search Results (2,422)

The accurate detection and quantification of electromagnetic radiation in the infrared (IR) and terahertz (THz) regions are critical for modern applications, yet they remain challenging due to the “THz gap” and the limitations of current room-temperature technologies. This paper proposes a novel uncooled IR–THz power sensor based on a hybrid graphene oxide (GO) and polydimethylsiloxane (PDMS) bilayer integrated into a surface plasmon resonance (SPR) architecture in the Kretschmann configuration. The device exploits the broadband optical absorption of GO to efficiently convert incident radiation into heat, while the high thermo-optic coefficient of the PDMS layer translates these thermal variations into measurable refractive index shifts. Finite Element Method (FEM) modeling was employed to optimize the sensor design, predicting a linear angular shift of 0.093 deg/mW. Experimental results confirm the theoretical expectations, demonstrating a high sensitivity of 0.083 deg/mW and an exceptionally low limit of detection and resolution on the order of 15 nW. By eliminating the need for cryogenic cooling or vacuum packaging, this platform offers a compact, low-cost, and high-performance solution for next-generation IR–THz metrology. Full article

A simplified design framework for narrowband terahertz thermal emitters based on a resonant Salisbury-type structure is investigated numerically. The structure consists of a metallic backreflector, a dielectric spacer, and a thin resonant layer with a Lorentz-type dielectric response. Using the transfer matrix method, we show that matching the intrinsic resonance of the resonant layer with an interference resonance of the Salisbury structure enables selective enhancement of a single emissivity peak without requiring time-consuming full-wave optimization at the initial design stage. The influence of spacer thickness, refractive index, and resonance strength on the spectral response is analysed, providing simple guidelines for tuning the emission frequency and suppressing parasitic peaks. A realistic implementation based on a graphene metamaterial layer on a silicon spacer is also investigated using finite-element simulations to demonstrate the applicability of the proposed design concept. The obtained emissivity and thermal emission spectra show that the approach can be used for the efficient design of spectrally selective terahertz thermal emitters in the 10–40 THz range. Full article

Corrosion-protective coatings have progressed from passive barrier systems and chromate-based technologies toward multifunctional materials that integrate barrier durability, interfacial adhesion, active inhibition, electrochemical response, and self-healing capabilities. However, the intellectual framework connecting these technological developments remains fragmented, as most reviews focus on specific material families rather than on the broader evolution of the field. This study examines technological paradigms in corrosion-protective coatings through a citation network analysis of highly cited publications retrieved from Web of Science and processed with CitNetExplorer. The most influential publications were thematically reviewed to identify dominant materials, coating architectures, protection mechanisms, seminal contributions, and bridge articles. Four principal paradigms were identified: smart and self-healing coatings based on nanocontainers, layered double hydroxides, mesoporous silica, halloysite, zeolites, hydroxyapatite reservoirs, and microcapsules; chromate-free sol–gel and silane pretreatments based on organic–inorganic hybrid matrices, organosilanes, rare-earth inhibitors, and oxide nanoparticles; graphene and graphene oxide-based nanocomposite coatings in which two-dimensional fillers enhance tortuosity, reduce water uptake, and reinforce polymer matrices and coating–substrate interfaces; and electroactive coatings based mainly on polyaniline and polypyrrole, where protection is associated with passivation, redox mediation, and dopant-controlled inhibition. The findings indicate that corrosion-protective coatings have evolved through partially overlapping and increasingly integrated paradigms rather than through a single technological trajectory. This citation network analysis clarifies the transition from chromate replacement toward active, nanostructured, electroactive, and self-healing corrosion-protective systems. Full article

Balancing energy efficiency and wearer thermal comfort in cold environments remains a critical challenge for wearable heating systems. Commercial graphene-film heating pads, consisting of a graphene film sandwiched between cotton-gauze layers, provide a flexible heating platform; however, the effects of temporal power-modulation strategies on physiological responses, subjective thermal perception, and energy use remain insufficiently understood. Using identical heating elements and fixed heating locations, this study evaluated three intermittent heating strategies for electrically heated garments: (i) a descending-step protocol (IP-1), (ii) alternating dual-power heating (IP-2), and (iii) periodic ON/OFF cycling (IP-3). Ten healthy male participants completed five randomized experimental conditions, including continuous heating (CP) and no heating (NH), during 60 min of exposure at −5 °C. Mean skin and torso temperatures, together with subjective thermal sensation, comfort, and preference, were assessed. Compared with IP-3, IP-1 and IP-2 maintained significantly higher mean skin temperatures from 15 to 60 min (p < 0.05), while their subjective responses remained closer to thermal neutrality. CP produced the strongest local warming but resulted in excessive warmth in the directly heated torso regions, whereas IP-3 provided insufficient thermal compensation. IP-1 achieved the most favorable comfort–efficiency balance, maintaining torso warmth and acceptable subjective responses while reducing energy use by approximately 46% relative to CP. These findings indicate that the transition characteristics and continuity of power delivery, rather than heating duration alone, are critical for optimizing thermal comfort and energy efficiency in wearable heating systems. Full article

Graphene was directly synthesized on monocrystalline Si(100) at 500 °C by microwave plasma-enhanced chemical vapor deposition using an increased CH₄/H₂ gas flow ratio. Raman analysis revealed spectral features and intensity ratios consistent with the growth of hydrogenated graphene and revealed changes in defect structure, graphene layer number, and self-doping. Atomic force microscopy measurements showed that the surface morphology and local conductivity strongly depended on the growth conditions. The electrical and photoelectrical characteristics of graphene/Si junctions were correlated with the Raman parameters and surface morphology. For the hydrogenated graphene samples synthesized at 500 °C, the photocurrent, short-circuit current, and open-circuit voltage were found to be competitive with those of pristine graphene reference samples grown at 700 °C. The results demonstrate the potential of low-temperature direct PECVD synthesis for graphene/Si optoelectronic devices. Full article

Graphene-reinforced CrCoNiFeMo high-entropy alloy composite coatings were fabricated on 17-4PH stainless steel by laser cladding for the surface protection of industrial robotic end-effector grippers. The effects of graphene content on microstructure, hardness, wear behavior and corrosion resistance were investigated. Graphene-derived carbon suppressed Laves and σ phases and promoted the in situ formation of M23C6, M7C3 and Co2C carbides, transforming the coating into a carbide-reinforced FCC/BCC composite structure. The average hardness increased from 462 HV0.2 to 676 HV0.2 with increasing graphene content. The 0.4 wt.% graphene coating showed the best wear resistance, with the lowest friction coefficient of 0.42 and minimum wear scar width and depth of 546 μm and 5.72 μm, which was attributed to carbide strengthening and the possible formation of a carbonaceous lubricating tribo-layer. The 0.2 wt.% graphene coating exhibited the best corrosion resistance, with the lowest corrosion current density of 5.81 μA/cm² and the highest impedance response. Excessive graphene caused carbon-rich agglomeration, excessive carbide precipitation and weakened passivation. This work provides a feasible surface strengthening strategy for 17-4PH stainless steel robotic gripper components. Full article

Biosensors are rapidly emerging as a pivotal technology with far-reaching implications in fields such as medical diagnostics, environmental analysis and pharmaceutical research. Among the various biosensing platforms, Graphene Field-Effect Transistor (GFET) biosensors have attracted considerable interest due to their exceptional sensitivity, potential for cost-efficient fabrication, and compatibility with scalable manufacturing processes. This work computationally addresses sensing mechanisms and design strategies associated with GFET-based biosensors, with a focus on the influence of electrolyte gating on device performance, tackling the role of graphene’s quantum capacitance and testing the electrical detection of β2-microglobulin as a case study. Molecular dynamics is used to rationalize the details of the physisorption of a single biomolecule onto the graphene surface, while finite element method simulations are employed to evaluate device sensitivity and figure of merit. Results reveal that incorporating quantum capacitance into the model leads to a Sensitivity-over-FWHM_min figure of merit exceeding 100 L/g being achievable for a β2-microglobulin concentration of 0.001 g/L. These computational outcomes highlight the relevance of quantum-electrostatic effects in GFET biosensor performance and suggest potential routes towards the optimization of graphene-based electronic biodetector engineering. Full article

To address prevalent industrial challenges, including the high cost of fabricating microstructures via photolithography and 3D printing, impurity residues easily generated by conventional physical/chemical pore-forming techniques, and the limited sensitivity of regular capacitive sensors, this paper innovatively proposes an integrated low-temperature in situ gas foaming strategy using ammonium bicarbonate for the fabrication of porous TPU-based ionic gels. Relying on the complete gaseous decomposition property of ammonium bicarbonate upon heating, a three-dimensionally interconnected continuous porous network is spontaneously constructed inside the polymer matrix. Thermoplastic polyurethane (TPU) is selected as the continuous polymer phase, and [EMIM][TFSI] imidazolium ionic liquid is blended as the ion source to synthesize composite ionic gel substrates. A PDMS composite slurry filled with graphene is employed to prepare flexible substrates, followed by low-temperature oxygen plasma surface modification to introduce polar functional groups such as hydroxyl and carboxyl onto electrode surfaces. A standard sandwich-structured ionic pressure sensor with the configuration of “top modified electrode—porous ionic gel dielectric layer—bottom modified electrode” is finally assembled. The porous framework and modified electrodes constitute a dual synergistic enhancement system: the porous structure markedly reduces the equivalent elastic modulus of the gel and improves its compressive deformation capacity; polar-modified electrodes optimize the interfacial compatibility between electrodes and gels, shorten ion migration paths and lower interfacial contact resistance. Systematic calibration of multiple batches of parallel samples reveals that the as-fabricated sensor achieves a high sensitivity of 25.3 kPa⁻¹ across the full measuring range from 0 to 1000 kPa with a linear fitting coefficient R² = 0.992. The loading response time and unloading recovery time of the device are 60 ms and 80 ms respectively, with a performance degradation of less than 3% after 1000 consecutive loading–unloading cycles, featuring low hysteresis error and excellent signal repeatability. Multi-scenario in vivo wearable tests on human subjects verify that the device can precisely capture subtle fluctuations of radial artery pulse and periodic laryngeal deformation during swallowing, distinguish characteristic waveform patterns of various English words according to differences in vocal cord vibration, and accurately detect bending motions when attached to finger joints. The entire fabrication process adopts common chemical raw materials and standard laboratory equipment without expensive micro-nano processing facilities, featuring convenient raw material procurement and high process fault tolerance, which enables large-area coating-based mass production. This work delivers a novel technical route for the low-cost large-scale production of high-performance ionic flexible sensors and bears significant industrialization reference value for applications in wearable medical monitoring, bionic robotic electronic skin, flexible human–machine interactive touch panels and other related fields. Full article

Graphene oxide (GO)-based nanostructured biomaterials have emerged as promising platforms for tissue engineering due to their novel biointeractive properties. In this study, we developed polyamide 6 (PA6) scaffolds by electrospinning using the Nanospider technique. Unlike conventional laboratory-scale electrospinning systems, Nanospider™ employs a wire-based electrode coated with a thin layer of polymer solution, from which nanofibers are continuously generated under a high-voltage electric field, enabling the large-scale fabrication of scaffolds. The scaffolds were then nanostructured with GO to investigate the effect of surface modification on their physicochemical properties, and biological responses. Surface characterization demonstrated that GO incorporation altered the microtexture of PA6 scaffolds, leading to changes in topographical parameters and surface morphology. In vitro studies performed using human stromal HS-5 cells confirmed high cytocompatibility of both GO nanofilms and PA6-GO composites, with preserved metabolic activity and enhanced cell adhesion. Scanning electron microscopy revealed improved spreading, elongated morphology, and increased filopodia formation on GO-modified scaffolds. Gene expression analyses indicated modulation of mechanotransduction- and adhesion-related pathways, including differential regulation of FN1, FAK, and integrin-associated genes, suggesting that GO nanostructuring influences early cell–material interactions through combined effects on surface architecture and chemistry. Ex vivo studies using embryonic tissues derived from chicken embryo Gallus gallus demonstrated effective colonization of connective, cartilage, and bone tissues on GO-modified scaffolds. Collectively, these findings demonstrate that GO nanostructuring of electrospun PA6 scaffolds improves biointerface formation, supports mechanobiological adaptation, and promotes tissue development, highlighting the potential for regenerative medicine. Full article

Industrial gear contacts operate under mixed-to-boundary lubrication where reliable antiwear protection is essential. This study assesses whether carbon nanomaterials can enhance the performance of zinc dialkyldithiophosphate (ZDDP) under severe conditions. A crossed-cylinder Reichert configuration (2 GPa, 75 °C, 1 m/s) with PAO6 was used to test ZDDP (1 wt%) and its blends with carbon nanotubes (CNT, 0.05 wt%), graphene nanoplatelets (GNP, 0.05 wt%), and few-layer graphene (FLG, 0.05 wt%) at 1, 10 and 60 min. The lubrication regime was boundary. Friction, specific wear rate (k), and tribofilm coverage were quantified. Oils containing only carbon nanoparticles could not sustain the test (seizure within minutes), confirming the necessity of ZDDP. After 60 min, average CoF remained similar across formulations and largely governed by ZDDP. By contrast, wear showed marked differences: relative to ZDDP alone (A), ZDDP + CNT (F) and ZDDP + GNP (G) reduced k by 52% and 48%, respectively, and exhibited higher tribofilm coverage (F = 68%, G = 72% vs. A = 57%). Time-resolved tests revealed that long-duration degradation was mitigated in F and G: from 10 to 60 min, k rose by 72% (F) and 58% (G) versus 159% for A; coverage decreased by only 8% (F) and 3% (G) versus 22% for A. SEM–EDS indicated no major differences in average elemental chemistry among formulations, suggesting an improvement on tribofilm coverage/stability rather than compositional change. Full article

Two-dimensional (2D) material terahertz (THz) detectors offer a promising platform for compact, room-temperature detection, yet their performance is fundamentally constrained by weak absorption in atomically thin layers. Here, we demonstrate a graphene plasmon polariton atomic cavity (PPAC) THz detector in which intrinsic graphene plasmon absorption is enhanced through vertical cavity-assisted field redistribution. By incorporating a metallic back reflector beneath a silicon substrate of designed thickness, a Fabry–Pérot (FP) interference cavity is formed that positions the standing-wave antinode near the graphene plasmonic layer. Electromagnetic simulations reveal that the Fabry–Pérot cavity itself primarily redistributes the vertical electromagnetic field, thereby enhancing the local in-plane driving field responsible for intrinsic graphene plasmon excitation. Experimental measurements at the optimized cavity condition confirm a pronounced increase in plasmon-induced photothermoelectric response, consistent with the predicted absorption enhancement. As a result, the detector exhibits an approximately 30-fold increase in responsivity compared with the corresponding structure without the cavity, while maintaining a fast response time below 130 μs. The detector further enables discrimination of concealed polar and nonpolar liquids through continuous-wave THz imaging at 2.52 THz, achieving a discrimination speed 30-fold faster than that of conventional time-domain spectroscopy. This result highlights the potential of cavity-enhanced intrinsic plasmon absorption for compact, high-sensitivity, and high-speed THz photodetection. Full article

In this study, a water-based epoxy curing agent was prepared using polyamines (mixed amines), and epoxy coatings were formulated by blending this with a polyurethane-toughened water-based epoxy curing agent in specific proportions. By testing the tensile properties of the water-based epoxy coatings, the curing agent ratio was adjusted and the curing process optimised. A layer of water-based epoxy coating was applied to both the rebar electrodes and the rebar surfaces. Through electrochemical testing, coating thickness measurement, and coating continuity testing, the effects of filler type, particle size, and content on coating performance were investigated. On this basis, steel bars coated with a water-based epoxy coating containing 0.3% graphene–polyaniline composite nanomaterials were used as the control group, whilst a water-based epoxy coating incorporating a silane solution served as the primer. Based on the results of the preliminary screening, a water-based epoxy coating containing 1% silane coupling agent and 10% zinc phosphate was selected as the intermediate coat, whilst a water-based epoxy coating containing fly ash microspheres and polystyrene microspheres was selected as the top coat. Through cold bending tests and tensile strain tests on the coated reinforcing bars, the study investigated the effects of zinc phosphate, fly ash microspheres, and polystyrene microspheres on the cold bending performance and deformation combination performance of the water-based epoxy-coated reinforcing bars. By optimising the curing process, the tensile strength of the coating reached 40.11 MPa, with an elongation at break of 19.94%; the corrosion resistance of the zinc phosphate composite coating (corrosion current density: 0.00589 μA/cm²) was comparable to that of the 0.3% graphene/polyaniline coating; and the fly ash microsphere top coat significantly improved the deformation compatibility between the reinforcing bars and the coating. The high-performance, cost-competitive water-based epoxy coating system developed in this study offers a new technical approach to the durability protection of reinforced concrete structures in marine environments. Full article

The frictional behavior and stability of skid shoe systems are critical to the safety and controllability of walking-type incremental launching for long-span steel truss bridges. Therefore, this study investigates friction control mechanisms and multilayer pad stability through two tests: (1) skid shoe tests to evaluate low-friction performance, sliding stiffness, and the stability of stacked pad assemblies, and (2) interface friction tests to examine the frictional behavior of different material combinations intended to provide high-friction restraint. The results show that Modified Graphene-Enhanced (MGE) plates, when combined with grease and stainless steel, reduce the friction coefficient to 0.017–0.074. High-stack pad assemblies (6–16 layers) exhibited a progressive interlayer slip, with cumulative displacements exceeding the allowable limit, leading to instability; anti-slip measures such as shear keys and segmented restraints were recommended. A load-dependent sliding stiffness relationship, y = 57.46 + 0.00886x, was established to characterize the variation in nominal sliding stiffness with vertical load. The findings provide experimental data and engineering recommendations for the design and operation of skid shoe systems in heavy-load incremental launching applications. The proposed criteria and regression model are applicable to the tested pad geometry, interface configuration, and loading conditions investigated in this study. Full article

Two-dimensional black phosphorus (2D BP) has emerged as one of the most promising two-dimensional semiconductors for next-generation micro and nanoelectronics beyond Moore’s Law. It is distinguished by its unique combination of a layer dependent direct bandgap, broadband photoresponse, and pronounced in-plane anisotropy, addressing key intrinsic limitations that have hindered the widespread application of graphene and conventional transition metal dichalcogenides (TMDCs). This review provides a systematic and comprehensive overview of recent advances in the controllable fabrication of 2D BP and its applications in transistors and photodetectors. We first elucidate its crystal lattice structure and fundamental physical properties, then categorize and summarize synthesis strategies based on production scale ranging from small scale methods (e.g., mechanical exfoliation and solution based exfoliation) to large scale methods (e.g., Chemical Vapor Deposition (CVD) and Pulsed Laser Deposition (PLD)), with a particular focus on recent advances in high-speed field-effect transistors and broadband photodetectors. In summary, the key to achieving large-scale controllable synthesis lies in addressing the challenges of high-temperature oxidation of black phosphorus and the uncontrollable diffusion of phosphorus sources. In the future, industrial applications are expected to be realized through CVD based regulation of phosphorus sources, low-temperature growth by PLD, and deep integration with silicon-based processes. Full article

In this study, free vibration analysis of three-layer sandwich panels with cores based on a triply periodic minimum surface (TPMS) and graphene platelet-reinforced composite (GPLRC) faces is performed. Four different geometries including cylindrical, spherical, saddle and flat panels were investigated and the governing equations were solved using higher-order shear deformation theory (HSDT) extracted from Hamilton’s principle. The accuracy and precision of the presented analytical method is verified by comparing the dimensionless natural frequencies with reference studies. Then, the effect of various parameters including panel geometry, core topology type and graphene weight percentage on the vibration response was investigated. The results show that adding graphene to the face layers significantly increases the natural frequencies and improves the overall stiffness of the structure. In addition, the frequencies of the panel may be controlled through different patterns and topologies. Also, double-curved panels, especially spherical geometries, present the highest fundamental natural frequency. The findings of this research could play an important role in the design and performance evaluation of advanced structures with TPMS cores and nanoscale reinforcement. Full article