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51 pages, 4099 KiB  
Review
Artificial Intelligence and Digital Twin Technologies for Intelligent Lithium-Ion Battery Management Systems: A Comprehensive Review of State Estimation, Lifecycle Optimization, and Cloud-Edge Integration
by Seyed Saeed Madani, Yasmin Shabeer, Michael Fowler, Satyam Panchal, Hicham Chaoui, Saad Mekhilef, Shi Xue Dou and Khay See
Batteries 2025, 11(8), 298; https://doi.org/10.3390/batteries11080298 - 5 Aug 2025
Abstract
The rapid growth of electric vehicles (EVs) and new energy systems has put lithium-ion batteries at the center of the clean energy change. Nevertheless, to achieve the best battery performance, safety, and sustainability in many changing circumstances, major innovations are needed in Battery [...] Read more.
The rapid growth of electric vehicles (EVs) and new energy systems has put lithium-ion batteries at the center of the clean energy change. Nevertheless, to achieve the best battery performance, safety, and sustainability in many changing circumstances, major innovations are needed in Battery Management Systems (BMS). This review paper explores how artificial intelligence (AI) and digital twin (DT) technologies can be integrated to enable the intelligent BMS of the future. It investigates how powerful data approaches such as deep learning, ensembles, and models that rely on physics improve the accuracy of predicting state of charge (SOC), state of health (SOH), and remaining useful life (RUL). Additionally, the paper reviews progress in AI features for cooling, fast charging, fault detection, and intelligible AI models. Working together, cloud and edge computing technology with DTs means better diagnostics, predictive support, and improved management for any use of EVs, stored energy, and recycling. The review underlines recent successes in AI-driven material research, renewable battery production, and plans for used systems, along with new problems in cybersecurity, combining data and mass rollout. We spotlight important research themes, existing problems, and future drawbacks following careful analysis of different up-to-date approaches and systems. Uniting physical modeling with AI-based analytics on cloud-edge-DT platforms supports the development of tough, intelligent, and ecologically responsible batteries that line up with future mobility and wider use of renewable energy. Full article
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25 pages, 2661 KiB  
Article
Fuzzy Logic-Based Energy Management Strategy for Hybrid Renewable System with Dual Storage Dedicated to Railway Application
by Ismail Hacini, Sofia Lalouni Belaid, Kassa Idjdarene, Hammoudi Abderazek and Kahina Berabez
Technologies 2025, 13(8), 334; https://doi.org/10.3390/technologies13080334 - 1 Aug 2025
Viewed by 229
Abstract
Railway systems occupy a predominant role in urban transport, providing efficient, high-capacity mobility. Progress in rail transport allows fast traveling, whilst environmental concerns and CO2 emissions are on the rise. The integration of railway systems with renewable energy source (RES)-based stations presents [...] Read more.
Railway systems occupy a predominant role in urban transport, providing efficient, high-capacity mobility. Progress in rail transport allows fast traveling, whilst environmental concerns and CO2 emissions are on the rise. The integration of railway systems with renewable energy source (RES)-based stations presents a promising avenue to improve the sustainability, reliability, and efficiency of urban transport networks. A storage system is needed to both ensure a continuous power supply and meet train demand at the station. Batteries (BTs) offer high energy density, while supercapacitors (SCs) offer both a large number of charge and discharge cycles, and high-power density. This paper proposes a hybrid RES (photovoltaic and wind), combined with batteries and supercapacitors constituting the hybrid energy storage system (HESS). One major drawback of trains is the long charging time required in stations, so they have been fitted with SCs to allow them to charge up quickly. A new fuzzy energy management strategy (F-EMS) is proposed. This supervision strategy optimizes the power flow between renewable energy sources, HESS, and trains. DC bus voltage regulation is involved, maintaining BT and SC charging levels within acceptable ranges. The simulation results, carried out using MATLAB/Simulink, demonstrate the effectiveness of the suggested fuzzy energy management strategy for various production conditions and train demand. Full article
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14 pages, 2351 KiB  
Article
Facile SEI Improvement in the Artificial Graphite/LFP Li-Ion System: Via NaPF6 and KPF6 Electrolyte Additives
by Sepehr Rahbariasl and Yverick Rangom
Energies 2025, 18(15), 4058; https://doi.org/10.3390/en18154058 - 31 Jul 2025
Viewed by 346
Abstract
In this work, graphite anodes and lithium iron phosphate (LFP) cathodes are used to examine the effects of sodium hexafluorophosphate (NaPF6) and potassium hexafluorophosphate (KPF6) electrolyte additives on the formation of the solid electrolyte interphase and the performance of [...] Read more.
In this work, graphite anodes and lithium iron phosphate (LFP) cathodes are used to examine the effects of sodium hexafluorophosphate (NaPF6) and potassium hexafluorophosphate (KPF6) electrolyte additives on the formation of the solid electrolyte interphase and the performance of lithium-ion batteries in both half-cell and full-cell designs. The objective is to assess whether these additives may increase cycle performance, decrease irreversible capacity loss, and improve interfacial stability. Compared to the control electrolyte (1.22 M Lithium hexafluorophosphate (LiPF6)), cells with NaPF6 and KPF6 additives produced less SEI products, which decreased irreversible capacity loss and enhanced initial coulombic efficiency. Following the formation of the solid electrolyte interphase, the specific capacity of the control cell was 607 mA·h/g, with 177 mA·h/g irreversible capacity loss. In contrast, irreversible capacity loss was reduced by 38.98% and 37.85% in cells containing KPF6 and NaPF6 additives, respectively. In full cell cycling, a considerable improvement in capacity retention was achieved by adding NaPF6 and KPF6. The electrolyte, including NaPF6, maintained 67.39% greater capacity than the LiPF6 baseline after 20 cycles, whereas the electrolyte with KPF6 demonstrated a 30.43% improvement, indicating the positive impacts of these additions. X-ray photoelectron spectroscopy verified that sodium (Na+) and potassium (K+) ions were present in the SEI of samples containing NaPF6 and KPF6. While K+ did not intercalate in LFP, cyclic voltammetry confirmed that Na+ intercalated into LFP with negligible impact on the energy storage of full cells. These findings demonstrate that NaPF6 and KPF6 are suitable additions for enhancing lithium-ion battery performance in the popular artificial graphite/LFP system. Full article
(This article belongs to the Special Issue Research on Electrolytes Used in Energy Storage Systems)
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15 pages, 2830 KiB  
Article
Predictive Framework for Lithium Plating Risk in Fast-Charging Lithium-Ion Batteries: Linking Kinetics, Thermal Activation, and Energy Loss
by Junais Habeeb Mokkath
Batteries 2025, 11(8), 281; https://doi.org/10.3390/batteries11080281 - 22 Jul 2025
Viewed by 333
Abstract
Fast charging accelerates lithium-ion battery operation but increases the risk of lithium (Li) plating—a process that undermines efficiency, longevity, and safety. Here, we introduce a predictive modeling framework that captures the onset and severity of Li plating under practical fast-charging conditions. By integrating [...] Read more.
Fast charging accelerates lithium-ion battery operation but increases the risk of lithium (Li) plating—a process that undermines efficiency, longevity, and safety. Here, we introduce a predictive modeling framework that captures the onset and severity of Li plating under practical fast-charging conditions. By integrating an empirically parameterized SOC threshold model with time-dependent kinetic simulations and Arrhenius based thermal analysis, we delineate operating regimes prone to irreversible Li accumulation. The framework distinguishes reversible and irreversible plating fractions, quantifies energy losses, and identifies a critical activation energy (0.25 eV) associated with surface-limited deposition. Visualizations in the form of severity maps and voltage-zone risk classifications enable direct application to battery management systems. This approach bridges electrochemical degradation modeling with real-time charge protocol design, offering a practical tool for safe, high-performance battery operation. Full article
(This article belongs to the Section Battery Modelling, Simulation, Management and Application)
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25 pages, 9888 KiB  
Article
An Optimal Multi-Zone Fast-Charging System Architecture for MW-Scale EV Charging Sites
by Sai Bhargava Althurthi and Kaushik Rajashekara
World Electr. Veh. J. 2025, 16(7), 389; https://doi.org/10.3390/wevj16070389 - 10 Jul 2025
Viewed by 276
Abstract
In this paper, a detailed review of electric vehicle (EV) charging station architectures is first presented, and then an optimal architecture suitable for a large MW-scale EV fast-charging station (EVFS) with multiple fast chargers is proposed and evaluated. The study examines various EVFS [...] Read more.
In this paper, a detailed review of electric vehicle (EV) charging station architectures is first presented, and then an optimal architecture suitable for a large MW-scale EV fast-charging station (EVFS) with multiple fast chargers is proposed and evaluated. The study examines various EVFS architectures, including those currently deployed in commercial sites. Most EVFS implementations use either a common AC-bus or a common DC-bus configuration, with DC-bus architectures being slightly more predominant. The paper analyzes the EV charging and battery energy storage system (BESS) requirements for future large-scale EVFSs and identifies key implementation challenges associated with the full adoption of the common DC-bus approach. To overcome these limitations, a novel multi-zone EVFS architecture is proposed that employs an optimal combination of isolated and non-isolated DC-DC converter topologies while maintaining galvanic isolation for EVs. The system efficiency and total power converter capacity requirements of the proposed architecture are evaluated and compared with those of other EVFS models. A major feature of the proposed design is its multi-zone division and zonal isolation capabilities, which are not present in conventional EVFS architectures. These advantages are demonstrated through a scaled-up model consisting of 156 EV fast chargers. The analysis highlights the superior performance of the proposed multi-zone EVFS architecture in terms of efficiency, total power converter requirements, fault tolerance, and reduced grid impacts, making it the best solution for reliable and scalable MW-scale commercial EVFS systems of the future. Full article
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21 pages, 2201 KiB  
Article
Evaluating China’s Electric Vehicle Adoption with PESTLE: Stakeholder Perspectives on Sustainability and Adoption Barriers
by Daniyal Irfan and Xuan Tang
Sustainability 2025, 17(14), 6258; https://doi.org/10.3390/su17146258 - 8 Jul 2025
Viewed by 547
Abstract
The electric vehicle (EV) business model integrates advanced battery technology, dynamic power train architectures, and intelligent energy management systems with ecosystem strategies and digital services. It incorporates environmental sustainability through lifecycle analysis and renewable energy integration. China, with 9.49 million EV sales in [...] Read more.
The electric vehicle (EV) business model integrates advanced battery technology, dynamic power train architectures, and intelligent energy management systems with ecosystem strategies and digital services. It incorporates environmental sustainability through lifecycle analysis and renewable energy integration. China, with 9.49 million EV sales in 2023 (33% market share), faces infrastructure gaps constraining further growth. China is strategically mitigating CO2 emissions while fostering economic expansion, notwithstanding constraints such as suboptimal battery technology advancements, elevated production expenditure, and enduring ecological impacts. This Political, Economic, Social, Technological, Legal, Environmental (PESTLE) assessment, operationalized through a survey of 800 stakeholders and Statistical Package for the Social Sciences IBM SPSS SPSS (Version 28) quantitative analysis (factor loading = 0.73 for Technology; eigenvalue = 4.12), identifies infrastructure gaps as the dominant barrier (72% of stakeholders). Political factors (β = 0.82) emerged as the strongest adoption predictor, outweighing economic subsidies in significance. The adoption of EVs in China presents a significant prospect for reducing CO2 emissions and advancing technology. However, economic barriers, market dynamics, inadequate infrastructure, regulatory uncertainty, and social acceptance issues are addressed in the assessment. The study recommends prioritizing infrastructure investment (e.g., 500 K fast-charging stations by 2027) and policy stability to overcome adoption barriers. This study provides three key advances: (1) quantification of PESTLE factor weights via factor analysis, revealing technological (infrastructure) and political factors as dominant; (2) identification of infrastructure gaps, not subsidies, as the primary adoption barrier; and (3) demonstration of infrastructure’s persistence post-subsidy cuts. These insights redefine EV adoption priorities in China. Full article
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32 pages, 8765 KiB  
Article
Hybrid Efficient Fast Charging Strategy for WPT Systems: Memetic-Optimized Control with Pulsed/Multi-Stage Current Modes and Neural Network SOC Estimation
by Marouane El Ancary, Abdellah Lassioui, Hassan El Fadil, Yassine El Asri, Anwar Hasni, Abdelhafid Yahya and Mohammed Chiheb
World Electr. Veh. J. 2025, 16(7), 379; https://doi.org/10.3390/wevj16070379 - 6 Jul 2025
Viewed by 446
Abstract
This paper presents a hybrid fast charging strategy for static wireless power transfer (WPT) systems that synergistically combines pulsed current and multi-stage current (MCM) modes to enable rapid yet battery-health-conscious electric vehicle (EV) charging, thereby promoting sustainable transportation. The proposed approach employs a [...] Read more.
This paper presents a hybrid fast charging strategy for static wireless power transfer (WPT) systems that synergistically combines pulsed current and multi-stage current (MCM) modes to enable rapid yet battery-health-conscious electric vehicle (EV) charging, thereby promoting sustainable transportation. The proposed approach employs a memetic algorithm (MA) to dynamically optimize the charging parameters, achieving an optimal balance between speed and battery longevity while maintaining 90.78% system efficiency at the SAE J2954-standard 85 kHz operating frequency. A neural-network-based state of charge (SOC) estimator provides accurate real-time monitoring, complemented by MA-tuned PI control for enhanced resonance stability and adaptive pulsed current–MCM profiles for the optimal energy transfer. Simulations and experimental validation demonstrate faster charging compared to that using the conventional constant current–constant voltage (CC-CV) methods while effectively preserving the battery’s state of health (SOH)—a critical advantage that reduces the environmental impact of frequent battery replacements and minimizes the carbon footprint associated with raw material extraction and battery manufacturing. By addressing both the technical challenges of high-power WPT systems and the ecological imperative of battery preservation, this research bridges the gap between fast charging requirements and sustainable EV adoption, offering a practical solution that aligns with global decarbonization goals through optimized resource utilization and an extended battery service life. Full article
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12 pages, 2263 KiB  
Article
Fast-Charging Model of Lithium Polymer Cells
by Joris Jaguemont and Fanny Bardé
World Electr. Veh. J. 2025, 16(7), 376; https://doi.org/10.3390/wevj16070376 - 4 Jul 2025
Viewed by 207
Abstract
Lithium-polymer (LiPo) batteries are valued for their high energy density, stable voltage output, low self-discharge, and strong reliability, making them a popular choice for high-performance and portable applications. Despite these advantages, the charging behavior of LiPo batteries—especially during rapid charging—remains an area with [...] Read more.
Lithium-polymer (LiPo) batteries are valued for their high energy density, stable voltage output, low self-discharge, and strong reliability, making them a popular choice for high-performance and portable applications. Despite these advantages, the charging behavior of LiPo batteries—especially during rapid charging—remains an area with limited understanding. This research examines the electro-thermal characteristics of VARTA LiPo batteries when subjected to high charging currents (2C, 3C, and 4C rates). A temperature-sensitive charging model is developed to address safety and efficiency concerns during fast charging. Experimental data indicate that charging at 45 °C yields the best performance, achieving 80% state of charge (SoC) within 25 min. However, charging at temperatures above or below this level (such as 25 °C) reduces efficiency due to increased internal resistance and accelerated battery aging. The model, validated across a range of temperatures (25 °C, 35 °C, 45 °C, and 60 °C), shows that longer constant-current (CC) charging phases at higher temperatures are associated with lower internal resistance. These results highlight the importance of effective thermal management for optimizing both safety and performance in LiPo battery applications. Full article
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22 pages, 6898 KiB  
Article
The Impact of Aluminum Doping on the Performance of MgV2O4 Spinel Cathodes for High-Rate Zinc-Ion Energy Storage
by He Lin, Zhiwen Wang and Yu Zhang
Molecules 2025, 30(13), 2833; https://doi.org/10.3390/molecules30132833 - 1 Jul 2025
Viewed by 387
Abstract
This study explores the development of aluminum-doped MgV2O4 spinel cathodes for aqueous zinc-ion batteries (AZIBs), addressing the challenges of poor Zn2+ ion diffusion and structural instability. Al3+ ions were pre-inserted into the spinel structure using a sol-gel method, [...] Read more.
This study explores the development of aluminum-doped MgV2O4 spinel cathodes for aqueous zinc-ion batteries (AZIBs), addressing the challenges of poor Zn2+ ion diffusion and structural instability. Al3+ ions were pre-inserted into the spinel structure using a sol-gel method, which enhanced the material’s structural stability and electrical conductivity. The doping of Al3+ mitigates the electrostatic interactions between Zn2+ ions and the cathode, thereby improving ion diffusion and facilitating efficient charge/discharge processes. While pseudocapacitive behavior plays a dominant role in fast charge storage, the diffusion of Zn2+ within the bulk material remains crucial for long-term performance and stability. Our findings demonstrate that Al-MgV2O4 exhibits enhanced Zn2+ diffusion kinetics and robust structural integrity under high-rate cycling conditions, contributing to its high electrochemical performance. The Al-MgVO cathode retains a capacity of 254.3 mAh g−1 at a high current density of 10 A g−1 after 1000 cycles (93.6% retention), and 186.8 mAh g−1 at 20 A g−1 after 2000 cycles (90.2% retention). These improvements, driven by enhanced bulk diffusion and the stabilization of the crystal framework through Al3+ doping, make it a promising candidate for high-rate energy storage applications. Full article
(This article belongs to the Special Issue Inorganic Chemistry in Asia)
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20 pages, 2583 KiB  
Article
Selective Lithium Plating on Graphite–Silicon Composite Anodes During Fast Charging in Rechargeable Lithium Batteries
by Minkyu Park, Seong-Hyeok Ha, Jiung Jeong and Heon-Cheol Shin
Energies 2025, 18(13), 3423; https://doi.org/10.3390/en18133423 - 29 Jun 2025
Viewed by 381
Abstract
In this study, we systematically analyzed selective lithium plating on graphite (Gr)–silicon (Si) composite anodes for lithium-ion batteries during fast charging, using electrochemical techniques. To achieve this, half-cells were first constructed with single Gr and Si electrodes, and lithium plating on each electrode [...] Read more.
In this study, we systematically analyzed selective lithium plating on graphite (Gr)–silicon (Si) composite anodes for lithium-ion batteries during fast charging, using electrochemical techniques. To achieve this, half-cells were first constructed with single Gr and Si electrodes, and lithium plating on each electrode was examined at different charging rates. It was observed that lithium plating on both electrodes began at a lower state of charge (SoC) as the charge rate increased. Furthermore, at a given charge rate, lithium plating occurred on the Si electrode at a lower SoC than on the Gr electrode. Based on the experimental findings, the lithium plating behavior of Gr and Si as a function of the charge rate was formulated to investigate the plating behavior of hypothetical composite electrodes with varying Gr–Si ratios. The lithium plating behavior observed on the actual composite electrode was consistent with that predicted from the hypothetical composite electrode, which was simulated using the same Gr–Si ratio based on the behaviors of the individual electrodes. By comparing the results from the single and composite electrodes, it is proposed that lithium plating occurs first on Si and then on Gr at low charge rates, whereas, at high charge rates, it proceeds first on Gr and then on Si. We discuss how to extrapolate the preferential plating signals—namely, plating onto Si at low charge rates and onto Gr at high charge rates—that are not directly evident in the signal from the actual composite electrode. Full article
(This article belongs to the Special Issue Advanced Electrochemical Energy Storage Materials)
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31 pages, 11216 KiB  
Article
An Optimal Integral Fast Terminal Synergetic Control Scheme for a Grid-to-Vehicle and Vehicle-to-Grid Battery Electric Vehicle Charger Based on the Black-Winged Kite Algorithm
by Ishak Aris, Yanis Sadou and Abdelbaset Laib
Energies 2025, 18(13), 3397; https://doi.org/10.3390/en18133397 - 27 Jun 2025
Viewed by 448
Abstract
The utilization of electric vehicles (EVs) has grown significantly and continuously in recent years, encouraging the creation of new implementation opportunities. The battery electric vehicle (BEV) charging system can be effectively used during peak load periods, for voltage regulation, and for the improvement [...] Read more.
The utilization of electric vehicles (EVs) has grown significantly and continuously in recent years, encouraging the creation of new implementation opportunities. The battery electric vehicle (BEV) charging system can be effectively used during peak load periods, for voltage regulation, and for the improvement of power system stability within the smart grid. It provides an efficient bidirectional interface for charging the battery from the grid and discharging the battery into the grid. These two operation modes are referred to as grid-to-vehicle (G2V) and vehicle-to-grid (V2G), respectively. The management of power flow in both directions is highly complex and sensitive, which requires employing a robust control scheme. In this paper, an Integral Fast Terminal Synergetic Control Scheme (IFTSC) is designed to control the BEV charger system through accurately tracking the required current and voltage in both G2V and V2G system modes. Moreover, the Black-Winged Kite Algorithm is introduced to select the optimal gains of the proposed IFTS control scheme. The system stability is checked using the Lyapunov stability method. Comprehensive simulations using MATLAB/Simulink are conducted to assess the safety and efficacy of the suggested optimal IFTSC in comparison with IFTSC, optimal integral synergetic, and conventional PID controllers. Furthermore, processor-in-the-loop (PIL) co-simulation is carried out for the studied system using the C2000 launchxl-f28379d digital signal processing (DSP) board to confirm the practicability and effectiveness of the proposed OIFTS. The analysis of the obtained quantitative comparison proves that the proposed optimal IFTSC provides higher control performance under several critical testing scenarios. Full article
(This article belongs to the Section D: Energy Storage and Application)
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35 pages, 14682 KiB  
Article
Fast-Balancing Passive Battery Management System with Remote Monitoring for the Automotive Industry
by Ionuț-Constantin Guran, Adriana Florescu, Nicu Bizon and Lucian Andrei Perișoară
Electronics 2025, 14(13), 2606; https://doi.org/10.3390/electronics14132606 - 27 Jun 2025
Viewed by 353
Abstract
Batteries have become the main power source in today’s automotive systems. This paper proposes the design of a fast-balancing passive battery management system (BMS) with remote monitoring for the automotive domain. This system is designed for four series-connected lithium iron phosphate (LiFePO4) cells, [...] Read more.
Batteries have become the main power source in today’s automotive systems. This paper proposes the design of a fast-balancing passive battery management system (BMS) with remote monitoring for the automotive domain. This system is designed for four series-connected lithium iron phosphate (LiFePO4) cells, which are the preferred choice in the automotive industry. The results show that the proposed BMS can monitor the cell voltages with an error lower than 0.12%, and it can perform the balancing operation successfully with maximum currents of 750 mA during both charging and discharging cycles, not only for LiFePO4 cells, but also for lithium-ion (Li-ion) cells. Furthermore, the cell voltages are sent over the controller area network (CAN) interface for remote monitoring. Full article
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14 pages, 1029 KiB  
Article
Advanced Algorithm for SOC, Internal Resistance, and SOH Co-Estimation of Lithium-Titanate-Oxide Batteries Using Neural Networks
by Riccardo Di Dio, Roberto Di Rienzo, Gianluca Aurilio, Davide Cavaliere and Roberto Saletti
Batteries 2025, 11(6), 235; https://doi.org/10.3390/batteries11060235 - 19 Jun 2025
Viewed by 485
Abstract
Lithium-titanate-oxide batteries can reduce the long charging time of electric vehicles by offering fast charging capabilities. However, high charging currents require an accurate estimation of battery internal state to prevent early aging of the battery and dangerous situations. An accurate algorithm based on [...] Read more.
Lithium-titanate-oxide batteries can reduce the long charging time of electric vehicles by offering fast charging capabilities. However, high charging currents require an accurate estimation of battery internal state to prevent early aging of the battery and dangerous situations. An accurate algorithm based on neural networks for the co-estimation of state of charge, internal resistance, and capacity state of health is proposed in this work. The algorithm is trained with synthetic data generated by an electric vehicle simulation platform running seven different standard driving cycles at various settings. The algorithm is then validated using an additional standard driving cycle, achieving, for state of charge, internal resistance, and capacity state of health, a root mean square error lower than 2%, 80 μΩ, and 2.9%, and a mean absolute percentage error lower than 3.4%, 4.4%, and 3.3%, respectively. The results obtained and the comparison with literature works indicate that the co-estimation algorithm proposed is able to estimate the considered quantities with very good accuracy. Full article
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12 pages, 2114 KiB  
Article
Interface-Sensitive Charge Storage and Activation Behavior of Mn(1,3,5-Benzenetricarboxylic Acid (BTC))-Derived Mn3O4/Carbon Cathodes for Aqueous Zinc-Ion Batteries
by Jieun Lee and Byoungnam Park
Molecules 2025, 30(12), 2566; https://doi.org/10.3390/molecules30122566 - 12 Jun 2025
Viewed by 365
Abstract
In this study, we couple precise interface engineering via alternating current electrophoretic deposition (AC–EPD) with performance-enhancing structural transformation via annealing, enabling the development of high-performance, stable, and tunable Mn-based cathodes for aqueous zinc-ion batteries (ZIBs). Using AC–EPD to fabricate Mn(BTC) (BTC = 1,3,5-benzenetricarboxylic [...] Read more.
In this study, we couple precise interface engineering via alternating current electrophoretic deposition (AC–EPD) with performance-enhancing structural transformation via annealing, enabling the development of high-performance, stable, and tunable Mn-based cathodes for aqueous zinc-ion batteries (ZIBs). Using AC–EPD to fabricate Mn(BTC) (BTC = 1,3,5-benzenetricarboxylic acid) cathodes followed by thermal annealing to synthesize MOF-derived Mn3O4 offers a synergistic approach that addresses several key challenges in aqueous ZIB systems. The Mn3O4 cathode prepared via AC–EPD from Mn(BTC) exhibited a remarkable specific capacity of up to 430 mAh/g at a current density of 200 mA/g. Interestingly, the capacity continued to increase progressively with cycling, suggesting dynamic structural or interfacial changes that improved Zn2+ transport and utilization over time. Such capacity enhancement behavior during prolonged cycling at elevated rates has not been observed in previously reported Mn3O4-based ZIB systems. Kinetic analysis further revealed that the charge storage process is predominantly governed by diffusion-controlled mechanisms. This behavior can be attributed to the intrinsic characteristics of the Mn3O4 phase formed from the MOF precursor, where the bulk redox reactions involving Zn2+ insertion require ion migration into the electrode interior. Even though the electrode was processed as an ultrathin film with enhanced electrolyte contact, the charge storage remains limited by solid-state ion diffusion rather than fast surface-driven reactions, reinforcing the diffusion-dominant nature of the system. Full article
(This article belongs to the Special Issue Functional Porous Frameworks: Synthesis, Properties, and Applications)
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34 pages, 5161 KiB  
Article
Robust Adaptive Fractional-Order PID Controller Design for High-Power DC-DC Dual Active Bridge Converter Enhanced Using Multi-Agent Deep Deterministic Policy Gradient Algorithm for Electric Vehicles
by Seyyed Morteza Ghamari, Daryoush Habibi and Asma Aziz
Energies 2025, 18(12), 3046; https://doi.org/10.3390/en18123046 - 9 Jun 2025
Viewed by 740
Abstract
The Dual Active Bridge converter (DABC), known for its bidirectional power transfer capability and high efficiency, plays a crucial role in various applications, particularly in electric vehicles (EVs), where it facilitates energy storage, battery charging, and grid integration. The Dual Active Bridge Converter [...] Read more.
The Dual Active Bridge converter (DABC), known for its bidirectional power transfer capability and high efficiency, plays a crucial role in various applications, particularly in electric vehicles (EVs), where it facilitates energy storage, battery charging, and grid integration. The Dual Active Bridge Converter (DABC), when paired with a high-performance CLLC filter, is well-regarded for its ability to transfer power bidirectionally with high efficiency, making it valuable across a range of energy applications. While these features make the DABC highly efficient, they also complicate controller design due to nonlinear behavior, fast switching, and sensitivity to component variations. We have used a Fractional-order PID (FOPID) controller to benefit from the simple structure of classical PID controllers with lower complexity and improved flexibility because of additional filtering gains adopted in this method. However, for a FOPID controller to operate effectively under real-time conditions, its parameters must adapt continuously to changes in the system. To achieve this adaptability, a Multi-Agent Reinforcement Learning (MARL) approach is adopted, where each gain of the controller is tuned individually using the Deep Deterministic Policy Gradient (DDPG) algorithm. This structure enhances the controller’s ability to respond to external disturbances with greater robustness and adaptability. Meanwhile, finding the best initial gains in the RL structure can decrease the overall efficiency and tracking performance of the controller. To overcome this issue, Grey Wolf Optimization (GWO) algorithm is proposed to identify the most suitable initial gains for each agent, providing faster adaptation and consistent performance during the training process. The complete approach is tested using a Hardware-in-the-Loop (HIL) platform, where results confirm accurate voltage control and resilient dynamic behavior under practical conditions. In addition, the controller’s performance was validated under a battery management scenario where the DAB converter interacts with a nonlinear lithium-ion battery. The controller successfully regulated the State of Charge (SOC) through automated charging and discharging transitions, demonstrating its real-time adaptability for BMS-integrated EV systems. Consequently, the proposed MARL-FOPID controller reported better disturbance-rejection performance in different working cases compared to other conventional methods. Full article
(This article belongs to the Special Issue Power Electronics for Smart Grids: Present and Future Perspectives II)
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