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37 pages, 6284 KiB  
Systematic Review
Valorization of Medical Waste in Cement-Based Construction Materials: A Systematic Review
by M. Murillo, S. Manzano, Y. F. Silva, C. Burbano-García and G. Araya-Letelier
Buildings 2025, 15(10), 1643; https://doi.org/10.3390/buildings15101643 - 13 May 2025
Viewed by 913
Abstract
Worldwide, the healthcare industry produces massive quantities of medical waste (MW), most of which is incinerated, releasing large quantities of dioxins, mercury, and other pollutants. Despite this, only a limited number of studies have explored the incorporation of MW into construction materials, with [...] Read more.
Worldwide, the healthcare industry produces massive quantities of medical waste (MW), most of which is incinerated, releasing large quantities of dioxins, mercury, and other pollutants. Despite this, only a limited number of studies have explored the incorporation of MW into construction materials, with a special focus on cement-based construction materials (CB-CMs). However, to the best of the authors’ knowledge, no existing review formally structures, summarizes, correlates, and discusses the findings of previous studies on MW in CB-CMs to encourage further research and applications of this promising alternative. Therefore, the added value of this study lies in providing an innovative and critical analysis of existing research on the use of MW in CB-CMs, consolidating and evaluating dispersed findings through a systematic literature review, enhancing understanding of the topic, and identifying knowledge gaps to guide future research. A robust systematic literature review was conducted, encompassing 40 peer-reviewed research articles, retrieved from the Web of Science Core Collection database. The methodology involved a three-stage process: a descriptive analysis of the included articles, the identification and synthesis of key thematic areas, and a critical evaluation of the data to ensure a rigorous and systematic report. The selection criteria prioritized peer-reviewed research articles in English with full text availability published in the last 7 years, explicitly excluding conference papers, book chapters, short reports, and articles not meeting the language or accessibility requirements. The results indicate that the influence of MW in CB-CM varies significantly. For example, while the incorporation of face masks as fiber reinforcement in concrete generally enhances its mechanical and durability properties, the use of gloves is less effective and not always recommended. Finally, it was found that further research is needed in this field due to its novelty. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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17 pages, 7919 KiB  
Article
Recycling Face Mask Fibers in Geopolymer-Based Matrices for Sustainable Building Materials
by Roberto Ercoli, Paola Stabile, Elena Ossoli, Irene Luconi, Alberto Renzulli and Eleonora Paris
Ceramics 2025, 8(2), 54; https://doi.org/10.3390/ceramics8020054 - 12 May 2025
Cited by 1 | Viewed by 938
Abstract
This study investigates the upcycling of disposable face masks, which were produced in vast quantities during the COVID-19 pandemic and are now widely stockpiled in public institutions, destined for landfills after reaching expiration dates. The research focuses on incorporating shredded mask fibers into [...] Read more.
This study investigates the upcycling of disposable face masks, which were produced in vast quantities during the COVID-19 pandemic and are now widely stockpiled in public institutions, destined for landfills after reaching expiration dates. The research focuses on incorporating shredded mask fibers into geopolymer matrices, evaluating the effects on mechanical and thermal properties to develop sustainable, high-performance materials. This approach addresses critical environmental, social, and economic challenges by transforming problematic waste into valuable resources while promoting sustainable building practices, such as developing insulating products for the construction industry. Mechanical testing demonstrated that adding shredded mask fibers (2 mm and 6 mm in size, up to 5 wt.%) enhanced the flexural strength of geopolymeric products. The optimal performance was achieved by adding 3 wt.% of 2 mm-length fibers, resulting in a flexural strength of 4.56 ± 0.23 MPa. Regarding compressive strength, the highest value (54.78 ± 2.08 MPa) was recorded in geopolymers containing 1 wt.% of 2 mm fibers. Thermal insulation properties of the materials improved with higher mask content, as evidenced by reductions in thermal conductivity, diffusivity, and specific heat. The lowest thermal conductivity values were observed in geopolymers containing 5 wt.% (0.4346 ± 0.0043 W·m−1·K−1) and 3 wt.% (0.6514 ± 0.0002 W·m−1·K−1) of 2 mm mask fibers. To further enhance thermal insulation, geopolymers with 5 wt.% mask fibers were foamed using H2O2 to obtain highly porous light materials, obtaining a reduction of thermal conductivity (0.3456 and 0.3710 ± 0.0007 W·m−1·K−1). This research highlights the potential of integrating fibrous waste materials into advanced construction technologies, offering solutions for waste reduction and development in the building sector toward sustainability. Full article
(This article belongs to the Special Issue The Production Processes and Applications of Geopolymers, 2nd Edition)
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25 pages, 107543 KiB  
Article
Development of a Color-Changing Face Mask for Fever Detection Applications
by Nareerut Jariyapunya, Sunee Hathaiwaseewong, Nanjaporn Roungpaisan and Mohanapriya Venkataraman
Materials 2025, 18(9), 2042; https://doi.org/10.3390/ma18092042 - 29 Apr 2025
Viewed by 612
Abstract
This study focused on developing a color-changing fabric face mask for fever detection. Reversible Thermochromic Leuco dye (RTL) was applied as an indicator to alert wearers of elevated body temperatures, with the color change occurring at 37.5 °C. Five fabric types Polyethylene (PE), [...] Read more.
This study focused on developing a color-changing fabric face mask for fever detection. Reversible Thermochromic Leuco dye (RTL) was applied as an indicator to alert wearers of elevated body temperatures, with the color change occurring at 37.5 °C. Five fabric types Polyethylene (PE), cotton (CO), a cotton–polyester blend (TC), polyester (PL), and Polyamide (PA) were coated with blue RTL to evaluate their color change responsiveness. The results showed that fabrics with higher thermal conductivity (λ), thermal absorptivity (b), and heat flow (q) exhibited faster color transitions. RTL-coated PE fabric demonstrated the best performance, with a thermal absorptivity of 312.8 Ws0.5m−2K−1 and a heat flow of 2.11 Wm−2, leading to a rapid color-change time of approximately 4.20 s. Although PE fabric had a lower thermal conductivity (57.6 × 10−3 Wm−1K−1) compared to PA fabric 84.56 (10−3 Wm−1K−1), the highest thickness 0.65 mm of PA fabric slowed its color-change reaction to 11.8 s. When selecting fabrics for optimal heat transfer, relying solely on fiber type or thermal conductivity (λ) is insufficient. The fabric’s structural properties, particularly thickness, significantly impact thermal resistance (γ). Experimental results suggest that thermal absorptivity and heat flow are more effective criteria for fabric selection, as they directly correlate with color-change performance. Full article
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13 pages, 3366 KiB  
Article
Improvement in the Damping Behavior of Hierarchical Carbon Fiber-Reinforced Plastic for Park Golf Club Faces
by Seoyeon Bae, Minhyeok Shin, Eunjung Kim, Sungbi Lee, Woong-Ryeol Yu, Cheol-Hee Ahn and Wonjin Na
Polymers 2025, 17(3), 264; https://doi.org/10.3390/polym17030264 - 21 Jan 2025
Viewed by 1157
Abstract
Park golf, introduced to Korea in 2000, has become a popular leisure activity, especially among older people. However, sudden shock between the ball and carbon fiber-reinforced plastic (CFRP) face can increase the risk of injuries, highlighting the need for enhanced damping material. However, [...] Read more.
Park golf, introduced to Korea in 2000, has become a popular leisure activity, especially among older people. However, sudden shock between the ball and carbon fiber-reinforced plastic (CFRP) face can increase the risk of injuries, highlighting the need for enhanced damping material. However, restitution and damping are critical properties of golf clubs and often exhibit a conflicting relationship; thus, a method is needed to address this challenge. Therefore, this study aimed to develop a CFRP with an enhanced restitution and damping ratio by incorporating carbon nanotubes and graphene oxide nanofillers into the existing CFRP face material. A drop test apparatus was set up to measure the coefficient of restitution, and the damping properties were evaluated using a pencil lead-breaking test. CNTs exhibited high rebound properties due to their stiffness and hardness. In contrast, GO provided a modest increase in rebound while demonstrating a superior damping ratio, attributed to its layered structure and high internal friction. Based on these results, the optimal nanofiller content was determined as GO 0.025 wt%, showing a minor improvement in rebound performance, a 1033% improvement in vibration damping, and an 84% improvement in acoustic damping. Notably, this finding implies the importance of nanomaterial shape and its interaction with the composite matrix. A double-masked user test with a prototype confirmed enhanced comfort and reduced vibration feedback. The low-vibration components developed in this study are expected to be applicable in future research for controlling the damping ratio under impact or vibrations, such as UAM and helicopters. Full article
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15 pages, 13730 KiB  
Article
Influence of Humidity on FFP Masks with Electret Filter Media Under Real-Life Wearing Conditions
by Daniel Stoll and Sergiy Antonyuk
Atmosphere 2025, 16(1), 62; https://doi.org/10.3390/atmos16010062 - 8 Jan 2025
Cited by 2 | Viewed by 1655
Abstract
Most FFP (Filtering Face Piece) masks are made from nonwoven filter media that are electrostatically charged, resulting in the additional electrostatic capture mechanism of particles. The protective effect of these masks is therefore mainly dependent on the electric field surrounding the charged fibers. [...] Read more.
Most FFP (Filtering Face Piece) masks are made from nonwoven filter media that are electrostatically charged, resulting in the additional electrostatic capture mechanism of particles. The protective effect of these masks is therefore mainly dependent on the electric field surrounding the charged fibers. Upon prolonged wear, the mask becomes saturated with exhaled air, resulting in humidification on the wearer’s side. However, speaking, coughing, or sneezing also generate droplets, which can deposit on the mask from the person wearing it, as well as from other people. In order to investigate this influence on the filtration efficiency and the existing electric field, an experimental study was carried out. To imitate human breathing, a test setup was constructed using a Sheffield Head with different types of masks. This was followed by the cyclical humidification and drying of the masks through simulated breathing. By observing these phases in detail using sample sections, it was possible to continuously record the water content in the samples, the relative humidity, and the pressure drop (breathing resistance). The results demonstrate that moisture has an impact on the filtration efficiency of the electret FFP masks when worn under real-life conditions and that the initial condition can be restored with sufficient drying time. Full article
(This article belongs to the Special Issue Electrostatics of Atmospheric Aerosols (2nd Edition))
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20 pages, 8373 KiB  
Article
Performance of Environmentally Friendly Concrete Containing Fly-Ash and Waste Face Mask Fibers
by Adnan Nawaz, Ameer Murad Khan, Amorntep Jirasakjamroonsri, Panumas Saingam, Ali Ejaz, Qudeer Hussain, Hisham Mohamad and Phromphat Thansirichaisree
Sustainability 2024, 16(23), 10385; https://doi.org/10.3390/su162310385 - 27 Nov 2024
Cited by 1 | Viewed by 997
Abstract
This work was carried out to explore the potential use of used face masks in concrete to develop sustainable green concrete. In this experimental study, used face masks were cut up, removing the ear stripes and internal nose steel wire, to prepare elongated [...] Read more.
This work was carried out to explore the potential use of used face masks in concrete to develop sustainable green concrete. In this experimental study, used face masks were cut up, removing the ear stripes and internal nose steel wire, to prepare elongated fibers. These fibers were incorporated in cement fly ash mixtures as an additive to determine the response of M20-grade concrete. The Class F fly ash (FA) was employed as a fractional substitute of cement up to 25% by weight, whereas the addition of face masks occurred at 0%, 0.125%, and 0.25% by volume of concrete. The testing scheme focused on the mechanical and durability characteristics of the cement FA mixtures carried out after 3, 28, and 60 days of curing. The inclusion of FA and face mask fibers reduced the density of concrete specimens. The compressive, splitting tensile, and flexural strengths of mixes were also reduced at an early age; however, the strength characteristics improved at later ages, compared to the control mix. The combination of both materials in concrete mixtures resulted in lower water absorption, lower bulk water sorption, and lower mass loss values against acid attack at later ages. Similarly, the electrical resistance of concrete substantially enhanced by increasing the percentage of both materials. The experimental results demonstrated that processed face masks can be utilized in cement fly ash mixes without significantly compromising the resultant concrete characteristics. Full article
(This article belongs to the Special Issue Sustainable Approaches for Developing Concrete and Mortar)
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15 pages, 13689 KiB  
Article
Impact of Changing Inlet Modes in Ski Face Masks on Adolescent Skiing: A Finite Element Analysis Based on Head Models
by Minxin Huang, Ruiqiu Zhang and Xiaocheng Zhang
Modelling 2024, 5(3), 936-950; https://doi.org/10.3390/modelling5030049 - 14 Aug 2024
Viewed by 1121
Abstract
Due to the material properties of current ski face masks for adolescents, moisture in exhaled air can become trapped within the material fibers and freeze, leading to potential issues such as breathing difficulties and increased risk of facial frostbite after prolonged skiing. This [...] Read more.
Due to the material properties of current ski face masks for adolescents, moisture in exhaled air can become trapped within the material fibers and freeze, leading to potential issues such as breathing difficulties and increased risk of facial frostbite after prolonged skiing. This paper proposes a research approach combining computational fluid dynamics (CFD) and ergonomics to address these issues and enhance the comfort of adolescent skiers. We developed head and face mask models based on the head dimensions of 15–17-year-old males. For enclosed cavities, ensuring the smooth expulsion of exhaled air to prevent re-inhalation is the primary challenge. Through fluid simulation of airflow characteristics within the cavity, we evaluated three different inlet configurations. The results indicate that the location of the air inlets significantly affects the airflow characteristics within the cavity. The side inlet design (type II) showed an average face temperature of 35.35 °C, a 38.5% reduction in average CO2 concentration within the cavity, and a smaller vortex area compared to the other two inlet configurations. Although the difference in airflow velocity within the cavity among the three configurations was minimal, the average exit velocity differed by up to 0.11 m/s. Thus, we conclude that the side inlet configuration offers minimal obstruction to airflow circulation and better thermal insulation when used in the design of fully enclosed helmets. This enhances the safety and comfort of adolescent wearers during physical activities in cold environments. Through this study, we aim to further promote the development of skiing education, enhance the overall quality of adolescents’ skiing, and thus provide them with more opportunities for the future. Full article
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20 pages, 10696 KiB  
Article
Filtering Efficiency and Design Properties of Medical- and Non-Medical-Grade Face Masks: A Multiscale Modeling Approach
by Manoochehr Rasekh, Francesca Pisapia, Sassan Hafizi and David Rees
Appl. Sci. 2024, 14(11), 4796; https://doi.org/10.3390/app14114796 - 1 Jun 2024
Cited by 2 | Viewed by 2197
Abstract
Approved medical face masks have been shown to prevent the spread of respiratory droplets associated with coronavirus transmission in specific settings. The primary goal of this study was to develop a new strategy to assess the filtering and transmissibility properties of medical- and [...] Read more.
Approved medical face masks have been shown to prevent the spread of respiratory droplets associated with coronavirus transmission in specific settings. The primary goal of this study was to develop a new strategy to assess the filtering and transmissibility properties of medical- and non-medical-grade face masks. In this study, we designed and assessed the filtering efficiency of particles through six different masks with a diverse set of fabrics, textures (woven and non-woven), fiber diameters, and porosity. The filtering and transmissibility properties of face mask layers individually and in combination have been assessed using mathematical analyses and new experimental data. The latter provided velocity profiles and filtration efficiencies for which the data were shown to be predictable. The filtration efficacy and pressure drop across each fabric have been tested using an aerosol particle spray and scanning electron microscopy. To assess clinical significance, the temperature and humidity of the masks were tested on a group of healthy volunteers spanning various age ranges (9–79 years old), utilizing an embedded temperature sensor disc. Also, a mask filter model was developed using fluid dynamic simulations (Solidworks Flow) to evaluate the aerodynamic dispersion of respiratory droplets. Overall, the FFP2 and FFP3 masks demonstrated the highest filtration efficiencies, each exceeding 90%, a feature of multi-layered masks that is consistent with simulations demonstrating higher filtering efficiencies for small particles (<5 µm). The velocity and temperature simulations of all six masks revealed a low air velocity (~1 m/s) inside the mask and a temperature variation of approximately 3 °C during the breathing cycle. Full article
(This article belongs to the Special Issue Multiscale Modeling of Complex Fluids and Soft Matter)
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12 pages, 3725 KiB  
Perspective
The Fate of Microplastics, Derived from Disposable Masks, in Natural Aquatic Environments
by Wei Zhang, Senyou Chai, Changhui Duan, Xueliang Sun, Qiting Zuo and Lin Gong
Toxics 2024, 12(1), 61; https://doi.org/10.3390/toxics12010061 - 12 Jan 2024
Cited by 4 | Viewed by 2838
Abstract
This paper mainly reviews the fate of microplastics, released from used face masks, in the water environment. Through previous experiments, the amount of fiber microplastics released from used face masks into aqueous environments was not negligible, with the maximum microplastics releasing amount reaching [...] Read more.
This paper mainly reviews the fate of microplastics, released from used face masks, in the water environment. Through previous experiments, the amount of fiber microplastics released from used face masks into aqueous environments was not negligible, with the maximum microplastics releasing amount reaching 10,000 piece·day−1 for each mask. Microplastic derived from these masks often occurred in the shape of polymeric fibers that resulted from the breakage of the chemical bonds in the plastic fibers by the force of water flow. The potential contact forces between microplastics (originating from face masks) with other pollutants, primarily encompass hydrophobic and electrostatic interactions. This critical review paper briefly illustrates the fate of microplastics derived from disposable face masks, further devising effective strategies to mitigate the environmental impact of plastic particle release from the used personal protective equipment. Full article
(This article belongs to the Section Emerging Contaminants)
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17 pages, 4201 KiB  
Article
Optimization of the Centrifugal Spinning Parameters to Prepare Poly(butylene succinate) Nanofibers Mats for Aerosol Filter Applications
by Ayben Pakolpakçıl, Ali Kılıç and Zbigniew Draczynski
Nanomaterials 2023, 13(24), 3150; https://doi.org/10.3390/nano13243150 - 15 Dec 2023
Cited by 5 | Viewed by 2034
Abstract
Air pollution is becoming a serious issue because it negatively impacts the quality of life. One of the first most useful self-defense approaches against air pollution are face masks. Typically made of non-renewable petroleum-based polymers, these masks are harmful to the environment, and [...] Read more.
Air pollution is becoming a serious issue because it negatively impacts the quality of life. One of the first most useful self-defense approaches against air pollution are face masks. Typically made of non-renewable petroleum-based polymers, these masks are harmful to the environment, and they are mostly disposable. Poly(butylene succinate) (PBS) is regarded as one of the most promising materials because of its exceptional processability and regulated biodegradability in a range of applications. In this regard, nanofiber-based face masks are becoming more and more popular because of their small pores, light weight, and excellent filtration capabilities. Centrifugal spinning (CS) provides an alternative method for producing nanofibers from various materials at high speeds and low costs. This current study aimed to investigate the effect of processing parameters on the resultant PBS fiber morphology. Following that, the usability of PBS nonwoven as a filter media was investigated. The effects of solution concentration, rotating speed, and needle size have been examined using a three-factorial Box–Behnken experimental design. The results revealed that PBS concentration had a substantial influence on fiber diameter, with a minimum fiber diameter of 172 nm attained under optimum production conditions compared to the anticipated values of 166 nm. It has been demonstrated that the desired function and the Box–Behnken design are useful instruments for predicting the process parameters involved in the production of PBS nanofibers. PBS filters can achieve an excellent efficiency of more than 98% with a pressure drop of 238 Pa at a flow rate of 85 L/min. The disposable PBS filter media was able to return to nature after use via hydrolysis processes. The speed and cost-effectiveness of the CS process, as well as the environmentally benign characteristics of the PBS polymer, may all contribute considerably to the development of new-age filters. Full article
(This article belongs to the Special Issue Nanomaterials and Textiles)
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18 pages, 4720 KiB  
Article
Potential Use of COVID-19 Surgical Masks and Polyethylene Plastics in Developing Sustainable Concrete
by Suvash Chandra Paul, Md. Ahosun Habib Santo, Sowmik Ahmed Nahid, Asifur Rahman Majumder, Md. Fahim Al Mamun, Md Abdul Basit and Adewumi John Babafemi
J. Compos. Sci. 2023, 7(9), 402; https://doi.org/10.3390/jcs7090402 - 20 Sep 2023
Cited by 6 | Viewed by 2780
Abstract
Managing disposable waste surgical face masks and plastic made from polyethylene (PE) resin is a real challenge. Thus, these are considered a great threat to the environment. Generally, surgical face masks are made of microplastic made of polypropylene materials. Both polypropylene and PE [...] Read more.
Managing disposable waste surgical face masks and plastic made from polyethylene (PE) resin is a real challenge. Thus, these are considered a great threat to the environment. Generally, surgical face masks are made of microplastic made of polypropylene materials. Both polypropylene and PE are not easily decomposable in the soil. Consequently, the presence of these waste materials can have detrimental effects on terrestrial and aquatic ecosystems, exacerbating the ongoing crisis faced by the animal kingdom and the broader biosphere. Hence, it is imperative to identify alternate and efficient methods for waste management. Given its significant economic importance, the construction industry holds a prominent position among many industries globally. Consequently, waste masks within the construction sector might assume a crucial role in mitigating plastic pollution. Concrete, one of the most widely used construction materials, is being adapted with various waste materials as the partial or complete substitutes for natural constituents, such as cement and aggregates. This study focused on using different percentages of used COVID-19 surgical masks in fiber form and PE as partial replacements of natural coarse aggregates in producing sustainable concrete. Mask fibers were used in concrete production at percentages of 0%, 0.5%, 1%, 1.5%, and 2% of the total volume of concrete. Similarly, PE aggregates replaced the coarse aggregates by volume at 0%, 5%, 10%, and 15% in concrete. The results showed that the strength of concrete reduced as the percentages of mask fiber and PE aggregates increased. However, the strength and crack-bridging capability of mask concrete are still acceptable for some structural and non-structural applications. The results obtained from this research could also help engineers to design sustainable concrete materials with mask fibers. Full article
(This article belongs to the Special Issue Polymer Composites and Fibers, Volume II)
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13 pages, 4058 KiB  
Article
Eflornithine Hydrochloride-Loaded Electrospun Nanofibers as a Potential Face Mask for Hirsutism Application
by Shuruq S. Almuwallad, Dunia A. Alzahrani, Walaa S. Aburayan, Ahmed J. Alfahad, Khulud A. Alsulami, Alhassan H. Aodah, Samar A. Alsudir, Sulaiman S. Alhudaithi and Essam A. Tawfik
Pharmaceutics 2023, 15(9), 2343; https://doi.org/10.3390/pharmaceutics15092343 - 19 Sep 2023
Cited by 2 | Viewed by 2329
Abstract
Hirsutism is a distressing condition that can affect women’s self-esteem due to the excessive amount of hair growth in different body parts, including the face. A temporary managing option is to develop a self-care routine to remove unwanted hair through shaving or waxing. [...] Read more.
Hirsutism is a distressing condition that can affect women’s self-esteem due to the excessive amount of hair growth in different body parts, including the face. A temporary managing option is to develop a self-care routine to remove unwanted hair through shaving or waxing. Laser or electrolysis are alternative methods, but in some cases, the use of medications, such as the topical cream Vaniqa®, can help in reducing the growth of unwanted hair. Electrospun fibers have been used in several drug delivery applications, including skin care products, owing to their biocompatibility, biodegradability, high surface area-to-volume ratio, and dry nature that can release the encapsulated drugs with maximum skin penetration. Therefore, polyvinyl pyrrolidone (PVP) fibers were fabricated in combination with hyaluronic acid to deliver the active compound of Vaniqa®, i.e., Eflornithine hydrochloride (EFH), as a face mask to inhibit excess facial hair growth. The prepared drug-loaded fibers showed a diameter of 490 ± 140 nm, with an encapsulation efficiency of 88 ± 7% and a drug loading capacity of 92 ± 7 μg/mg. The in vitro drug release of EFH-loaded fibers exhibited an initial burst release of 80% in the first 5 min, followed by a complete release after 360 min, owing to the rapid disintegration of the fibrous mat (2 s). The in vitro cytotoxicity indicated a high safety profile of EFH at all tested concentrations (500–15.625 μg/mL) after 24-h exposure to human dermal fibroblast (HFF-1) cells. Therefore, this drug-loaded nanofibrous system can be considered a potentially medicated face mask for the management of hirsutism, along with the moisturizing effect that it possesses. Topical applications of the developed system showed reduced hair growth in mice to a certain extent. Full article
(This article belongs to the Section Pharmaceutical Technology, Manufacturing and Devices)
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16 pages, 12943 KiB  
Article
Development of a Layer Made of Natural Fibers to Improve the Ecological Performance of the Face Mask Type II
by Jerzy Mańkowski, Małgorzata Zimniewska, Weronika Gieparda, Barbara Romanowska, Anna Kicińska-Jakubowska, Jacek Kołodziej, Joanna Foksowicz-Flaczyk, Szymon Rojewski, Krzysztof Bujnowicz, Patrycja Przybylska, Edyta Kwiatkowska, MD Masud Alam, Wanda Różańska, Aleksandra Wawro and Elżbieta Hołderna-Kędzia
Materials 2023, 16(16), 5668; https://doi.org/10.3390/ma16165668 - 17 Aug 2023
Cited by 1 | Viewed by 2402
Abstract
The aim of this study was to develop a natural nonwoven layer made of cottonized bleached flax and cotton fibers which is suitable to replace one of the three polypropylene layers of face mask type II in order to reduce non-biodegradable waste production [...] Read more.
The aim of this study was to develop a natural nonwoven layer made of cottonized bleached flax and cotton fibers which is suitable to replace one of the three polypropylene layers of face mask type II in order to reduce non-biodegradable waste production and limit the negative impact of used masks on the environment. The work focused on the design of a nonwoven structure based on properly blending cotton and flax fibers as well as ensuring the cover factor, which can support the mask’s barrier properties against air dust particles and does not make breathing difficult. Additionally, a biodegradable film was developed to connect the nonwoven layer with the other polypropylene filtering layers. The effectiveness of the biodeterioration of the flax/cotton nonwoven was evaluated based on a test of the susceptibility of materials to the action of soil microorganisms. The flax/cotton nonwoven layer was tested in terms of mechanical, physical, and biophysical properties, and an analysis of the covering of the nonwoven surface with fibers was conducted as well. The results confirmed that the structure of flax/cotton nonwovens is suitable to replace the nondegradable polypropylene layer of the face mask type II to improve its environmental performance. Full article
(This article belongs to the Special Issue Green Textile Materials: Fibers, Processing and Applications)
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18 pages, 5862 KiB  
Article
Preparation of Self-Curling Melt-Blown Fibers with Crimped Masterbatch (CM) and Its Application for Low-Pressure Air Filtration
by Xiaofang Lin, Minggang Lin, Tan Li, Hao Lu, Huan Qi, Ting Chen, Lili Wu and Chuyang Zhang
Polymers 2023, 15(16), 3365; https://doi.org/10.3390/polym15163365 - 10 Aug 2023
Cited by 9 | Viewed by 2250
Abstract
Particulate matter (PM) and airborne viruses pose significant threats to both the environment and public health. As the most viable solution to prevent the inhalation of these pollutants, there is an urgent demand for face masks with excellent filtration efficiency and low-pressure drop. [...] Read more.
Particulate matter (PM) and airborne viruses pose significant threats to both the environment and public health. As the most viable solution to prevent the inhalation of these pollutants, there is an urgent demand for face masks with excellent filtration efficiency and low-pressure drop. In this study, a crimped masterbatch (CM) is added to polypropylene feedstocks to produce curling fibers through melt-blown spinning. These curled fibers exhibit low filtration resistance and effective dust-holding performances when used for air filtration. The effect of adding CM on fiber diameter, pore size, crimp, porosity, roughness, and surface potential was studied. The filtration performance of the materials, including the PM filtration capabilities, recirculation filtration, and loading test performance, were also investigated. The results demonstrate that the degree of fiber crimp can be adjusted by incorporating varying amounts of CM. This curling was caused by the uneven shrinkage that occurred due to variations in thermal contraction between these polymers. The curled fibers created a fluffy structure in the fiber network and modified the distribution of pore sizes within it. Under the same filtration conditions as sodium chloride aerogel, CM–2 (PP:CM 8:2) exhibited similar filtration efficiency (95.54% vs. 94.74%), lower filtration resistance (88.68 Pa vs. 108.88 Pa), higher quality factor (0.035 Pa−1 vs. 0.028 Pa−1) and better dust holding capacity (10.39 g/m2 vs. 9.20 g/m2) compared to CM–0 (PP:CM 10:0). After 30 days of indoor storage, the filtration efficiency of CM–2 remained above 94%. The self-curling melt-blown filtration material developed here could potentially be applied in the field of protective masks. Full article
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16 pages, 4926 KiB  
Article
Pilot-Scale Melt Electrospinning of Polybutylene Succinate Fiber Mats for a Biobased and Biodegradable Face Mask
by Maike-Elisa Ostheller, Naveen Kumar Balakrishnan, Konrad Beukenberg, Robert Groten and Gunnar Seide
Polymers 2023, 15(13), 2936; https://doi.org/10.3390/polym15132936 - 3 Jul 2023
Cited by 10 | Viewed by 2262
Abstract
The COVID-19 pandemic led to a huge demand for disposable facemasks. Billions were manufactured from nonbiodegradable petroleum-derived polymers, and many were discarded in the environment where they contributed to plastic pollution. There is an urgent need for biobased and biodegradable facemasks to avoid [...] Read more.
The COVID-19 pandemic led to a huge demand for disposable facemasks. Billions were manufactured from nonbiodegradable petroleum-derived polymers, and many were discarded in the environment where they contributed to plastic pollution. There is an urgent need for biobased and biodegradable facemasks to avoid environmental harm during future disease outbreaks. Melt electrospinning is a promising alternative technique for the manufacturing of filter layers using sub-microfibers prepared from biobased raw materials such as polybutylene succinate (PBS). However, it is not yet possible to produce sub-micrometer PBS fibers or uniform nonwoven-like samples at the pilot scale, which hinders their investigation as filter layers. Further optimization of pilot-scale PBS melt electrospinning is therefore required. Here, we tested the effect of different parameters such as electric field strength, nozzle-to-collector distance and throughput on the final fiber diameter and sample uniformity during PBS melt electrospinning on a pilot-scale device. We also studied the effect of a climate chamber and an additional infrared heater on the solidification of PBS fibers and their final diameter and uniformity. In addition, a post-processing step, including a hot air stream of 90 °C for 30 s has been studied and successfully lead to a nonwoven-like structure including filaments that weld together without changing their structure. The finest fibers (1.7 µm in diameter) were produced at an applied electric field strength of −40 kV, a nozzle-to-collector distance of 5.5 cm, and a spin pump speed of 2 rpm. Three uniform nonwoven-like samples were tested as filter layers in a medical face mask by measuring their ability to prevent the transfer of bacteria, but the pore size was too large for effective retention. Our results provide insight into the process parameters influencing the suitability of melt-electrospun nonwoven-like samples as biobased and biodegradable filter materials and offer guidance for further process optimization. Full article
(This article belongs to the Special Issue Fabrication and Application of Electrospun Nanofibers II)
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