Search Results (178)

The facet-dependent catalytic behavior of MgO in non-thermal plasma (NTP)-driven CO₂ decomposition is systematically investigated by combining experimental measurements and density functional theory (DFT) calculations. Three MgO catalysts with dominant exposure of the (100), (110), and (111) facets are synthesized. CO₂ temperature-programmed desorption (CO₂-TPD) shows that CO₂ adsorption capacity follows the order MgO(110) > MgO(111) > MgO(100), consistent with DFT-derived adsorption energies. DFT energy profiles reveal that although MgO(110) binds CO₂ most strongly, it suffers from excessively strong CO adsorption (5.84 eV), inhibiting product desorption. In contrast, MgO(111) offers a favorable CO₂ adsorption energy combined with a remarkably low CO desorption energy (0.71 eV), enabling rapid turnover. Electronic structure analyses demonstrate substantial charge transfer from MgO(111) to CO₂ (up to 1.76 |e|) and pronounced orbital hybridization near the Fermi level, which are further enhanced under plasma conditions. Plasma-catalytic tests at 0.8 W show that MgO(111) achieves the highest CO₂ conversion (60.7%) with excellent selectivity toward CO (95.3%) and O₂ (94.4%), outperforming MgO(110) and MgO(100). Increasing the input power from 0.8 to 2.5 W raises conversion to 78.1% but reduces energy efficiency due to increased gas heating or non-productive pathways. Overall, the (111)-enriched MgO is identified as an efficient and selective catalyst for NTP-based CO₂ splitting, owing to its optimal balance of adsorption strength, facile CO desorption, strong charge transfer, and plasma–catalyst synergy. This work highlights the importance of facet engineering and power optimization for designing oxide-based plasma catalysts toward energy-efficient CO₂ utilization. Full article

Sulfur-containing medium-carbon microalloyed steel blooms are widely used for high-load automotive components, and reducing surface defects is important for improving product yield and lowering downstream processing costs. To address surface defects such as star cracks and microcracks in the continuous casting of these steel blooms, this study redesigned the mold flux on the basis of the steel’s solidification characteristics and crack susceptibility and carried out a twin-strand industrial comparative casting trial. Thermodynamic and thermophysical analyses indicated that the relatively high contents of S, Mn, and Ti/N in the steel promoted the precipitation of MnS and TiN–MnS complex inclusions along grain boundaries, severely weakening grain boundary cohesion. Meanwhile, the high specific heat capacity and low thermal conductivity further intensified thermal stress concentration in the solidifying shell, rendering the steel highly susceptible to cracking. Evaluation of the originally used mold flux (Flux A) revealed that its high melting temperature (1189 °C), long melting time (106 s), high break temperature (1170 °C), and poor crystallization behavior resulted in an excessively thin liquid slag layer (<5 mm) within the mold, making it difficult to provide adequate lubrication and stable heat transfer; these were key external factors inducing surface defects. Accordingly, the optimized mold flux (Flux B) was designed and prepared by increasing the basicity from 0.95 to 1.1, raising the Al₂O₃ content from 9.48% to 11.16%, increasing the F content from 4.93% to 5.58%, and reducing the carbon content from 13.85% to 6.97%. The rheological and crystallization properties of the flux were optimized in a coordinated manner, allowing uniform heat transfer through the crystalline slag layer while maintaining adequate lubrication. Industrial comparative trials demonstrated that Flux B stabilized the liquid slag layer at 8–10 mm, increased slag consumption to 0.56 kg/t, and significantly reduced surface defects such as star cracks and microcracks on blooms. The ultrasonic testing acceptance rate for rolled products increased to 98.6%, thereby meeting stringent quality requirements for the continuous casting of sulfur-containing, medium-carbon, microalloyed steel blooms. Full article

This paper presents a temperature field analysis and a new water-cooling channel design for a 1000 kW, 72-slot/8-pole permanent magnet synchronous motor used in mining applications. To capture temperature rise data related to electromagnetic losses and fluid heat transfer, a multiphysics coupling model was established, and its accuracy was verified through temperature rise experiments on a prototype. To address the issues of poor temperature uniformity and excessive head loss in the original structure, a double-helix return cooling water channel structure was designed, effectively compensating for the heat exchange capacity at the motor ends and reducing fluid resistance. Comparative analysis shows that this structure significantly outperforms traditional cooling water channels in terms of heat dissipation efficiency, temperature uniformity, and pressure loss. Under optimal geometric parameters—10 spiral turns and a flow velocity of 1 m/s—the maximum winding temperature was suppressed to 67.7 °C, with a winding temperature difference of only 2.6 °C, while the pressure drop was maintained at a low level of 9580 Pa. This study provides a theoretical basis and an efficient engineering solution for the design of water-cooling structures in large mining motors. Full article

This study aimed to elucidate the impact of environmental factors on the efficacy of epigallocatechin gallate (EGCG) in inhibiting acrylamide formation and to clarify the role of the 3-aminopropionamide (3-APA) pathway in this process. Asparagine–glucose and 3-APA model systems were employed for the investigation. The results revealed that EGCG exerted a pronounced, condition-dependent inhibitory effect on acrylamide formation during the Maillard reaction. The maximum inhibition rate of 91% was observed at 180 °C and pH 6.0 without metal ions, while alkaline conditions, excessive heating, and Fe³⁺ markedly weakened the inhibitory capacity of EGCG. In the 3-APA model, a positive correlation (R² = 0.9111) was found between acrylamide generation and EGCG oxidation, and the key o-quinone-derived adduct was identified as an indirect evidence for EGCG oxidation. Collectively, the redox state of EGCG, which is highly susceptible to food processing conditions, may modulate its anti-acrylamide activity. These findings provide valuable mechanistic insights for the rational application of EGCG to mitigate acrylamide contamination in thermally processed foods. Full article

The eddy current braking system (ECBS) is a crucial non-contact technology for high-speed railway. Conventional DC-excited systems face significant challenges such as excessive rail heating and high-capacity power supply requirements. This paper proposes a novel ECBS with AC excitation and auxiliary capacitor to achieve integrated energy recovery and power supply optimization. To evaluate its performance, a rigorous analytical framework is developed. First, a 2D subdomain model is established by incorporating the longitudinal end effect to solve the magnetic field distribution. Subsequently, an equivalent circuit is derived from the subdomain results to investigate steady-state braking characteristics and power flow. Analysis results demonstrate that the proposed system not only generates controllable braking force but also converts a portion of kinetic energy into storable electrical energy, effectively mitigating secondary rail heating. Most significantly, the implementation of an optimal auxiliary capacitor (134 μF) is found to reduce the required inverter capacity compared to inverter-only conditions. These findings provide a theoretical foundation and a practical design tool for developing high-performance, energy-efficient braking systems in high-speed transportation. Full article

Industrial tunnel pasteurizers are widely used for bottled liquid products because they provide a robust and continuous thermal treatment. However, operating conditions are often conservatively selected to ensure microbiological safety, which may result in excessive energy consumption and limited thermal efficiency. This study experimentally investigates the thermal behavior and energy performance of an industrial tunnel pasteurizer used for a sealed bottled herbal-based high-viscosity liquid formulation under both nominal and modified operating conditions. An instrumented bottle was developed to measure temperature evolution at different locations inside the bottle, including the product core. In parallel, the overall heat capacity of the bottle–product system was determined by differential scanning calorimetry, enabling the estimation of the thermal energy absorbed by the bottles. Mass and energy balances were applied to quantify the heat exchanged in each process stage and to estimate phase-specific and overall heat-transfer efficiencies. Under nominal conditions, the pasteurization requirement, defined as a temperature above 72 °C for at least 12 min at the coldest point, was fully satisfied, with the temperature remaining above 72 °C for approximately 22 min near the bottle wall and 17–18 min at the product core. The energy analysis showed that overall process efficiency was limited, indicating room for improvement. Three additional experimental tests were therefore carried out under modified temperature and flow-rate conditions. In all cases, the pasteurization target was maintained. The results demonstrate that the process complies with the prescribed pasteurization target while offering significant opportunities for energy savings through optimization of the operating parameters. Full article

Intensive aquaculture induces severe environmental stress and disease susceptibility in Pacific white shrimp (Litopenaeus vannamei). Cannabidiol (CBD) offers significant potential as a bioactive stress-mitigating additive. This study evaluated the effects of dietary CBD supplementation (0, 10, 20, 40, and 80 mg/kg) on the growth, intestinal microecology, and stress tolerance of juvenile L. vannamei over an 8-week feeding trial, followed by a combined chronic ammonia and acute hypoxia challenge. Moderate CBD supplementation (10–40 mg/kg) significantly promoted growth, minimized feed conversion ratios, and enriched muscle eicosapentaenoic (EPA) and docosahexaenoic acids (DHA). Furthermore, CBD restructured the intestinal microbiota by suppressing opportunistic pathogens and enriching beneficial taxa. Under combined stress, moderate CBD prolonged the median lethal time (LT₅₀) by up-regulating hypoxia-inducible factor 1-alpha (hif-1α) and heat shock protein 70 (hsp70) transcription and boosting systemic antioxidant capacity to neutralize lipid peroxidation. Conversely, the highest dose (80 mg/kg) induced metabolic exhaustion and hepatopancreatic toxicity, evidenced by drastically elevated serum transaminases and diminished stress tolerance. Conclusively, dietary CBD exerts a classic biphasic effect in L. vannamei. Inclusion at 10–40 mg/kg safely promotes the best comprehensive effects on growth, immune homeostasis, and environmental resilience within the concentration range tested in this study, whereas excessive administration provokes severe metabolic burden, highlighting the critical need for strict dosage regulation. Full article

Rapid urbanization has intensified the mismatch between urban green space (UGS) and urban spatial vitality (USV), hindering sustainable development. To address this, we developed the Urban Green Space Vitality Adaptation Model (UGSVAM) and analyzed 64 subdistricts in central Nanjing. Specifically, this study asks: Does the mismatch exist? What are its spatiotemporal patterns? What factors drive it? Methodologically, we use the Gini coefficient and Lorenz curve to assess overall UGS-USV adaptation, then construct the Urban Green Space Vitality Density (UGVD) indicator to quantify the match level, classifying units as overloaded, underloaded, or balanced. OLS and GWR reveal global and local influencing mechanisms, while quadrant analysis supports differentiated planning. Results show: (1) UGS-USV adaptation in Nanjing is weak, with Gini coefficients of 0.466 (weekday) and 0.456 (weekend). UGVD exhibits a spatial pattern of a primary overload core in the central city, a secondary core in the southwest, and peripheral decline, with the southeast underloaded. Overloaded units also show notable temporal variation. (2) Globally POI density and intersection density promote UGVD, while excessive transport facilities, air pollution, and high temperatures inhibit it—ecological factors have stronger weekend effects. (3) Locally, the northeast is more sensitive to POI density, the southwest to transport and heat, and the Jiangbei New Area could enhance green space carrying capacity through transport optimization and spatial integration. The UGSVAM integrates spatial diagnosis, mechanism analysis, and planning response, offering a transferable framework for refining green space governance in high-density cities. Full article

Effective thermal management is critical for high-power lithium-ion batteries to mitigate excessive heat generation and ensure operational reliability. Failure to maintain a uniform temperature distribution can lead to accelerated capacity fading and severe safety risks, such as thermal runaway. In this study, a ferrofluid-based magnetohydrodynamic (MHD) microchannel cooling system was numerically investigated to elucidate the influence of magnetic intensity, magnet geometry, and electrical boundary conditions on flow behavior and heat transfer performance for battery cooling applications. A fully coupled multiphysics model incorporating electromagnetic, fluid flow, and heat transfer phenomena was developed and validated against experimental and numerical data from the literature. The results show that increasing the applied voltage enhances current density and Lorentz force almost linearly, leading to significant flow acceleration and improved convective heat transfer. Electrical insulation effectively suppresses current leakage into the channel walls, increasing the average current density by up to 222% and the Lorentz force by more than 300%. Compared with a cylindrical magnet, a rectangular magnet provides a more uniform magnetic field distribution and stronger near-wall Lorentz forcing, resulting in superior cooling performance. Under a 4C discharge condition, the insulated rectangular magnet reduces the maximum battery temperature by approximately 30% and increases the average Nusselt number by up to 103% relative to the non-insulated case. The findings reveal the critical roles of magnetic-field-controlled flow symmetry and near-wall forcing in MHD-driven microchannels, and provide practical design guidelines for battery cooling systems with no moving mechanical parts and active electromagnetic flow control. Full article

Enhancing plant protein structure, functionality, and digestion-associated bioactivity is pivotal to advancing sustainable food applications. In this study, a controlled thermal treatment was applied to Xanthoceras sorbifolium seed meal protein (XSMP) to characterize alterations in structural features, functional performance, and digestion-related bioactivity. Structural analyses showed that moderate heating induced partial unfolding and disaggregation, leading to reduced particle size and improved colloidal stability, with optimal performance observed at 65 °C. Accordingly, foaming capacity and emulsifying activity index reached their highest values under moderate heat pretreatment (71.43% and 27.21 m²/g, respectively). Simulated in vitro gastrointestinal digestion revealed that moderate heat pretreatment enhanced protease accessibility and was associated with increased formation of low-molecular-weight fragments. As a result, digestion products from optimally treated XSMP exhibited significantly enhanced antioxidant activities during the intestinal phase, including higher reducing power, Fe²⁺-chelating capacity (up to 51.21%), and lipid peroxidation inhibition (82.83%). In contrast, insufficient unfolding at lower temperatures or excessive aggregation at higher temperatures reduced the susceptibility to digestive proteases and the associated functional performance. These findings demonstrate that controlled heat treatment provides a simple and eco-friendly strategy to enhance the functional potential of XSMP, supporting its application as a functional protein ingredient. Full article

Adipose tissues (ATs) are dynamic and heterogeneous organs divided into three distinct categories, including white, beige, and brown ATs. Collectively, they contribute to systemic energy homeostasis in various ways. White adipocytes primarily store excess energy, whereas brown and beige adipocytes dissipate energy as heat through non-shivering thermogenesis. Recent advances in multi-omics technologies have transformed our understanding of adipocyte biology, enabling comprehensive interrogation of transcriptional, epigenetic, proteomic, and metabolomic networks that define adipocyte identity and function. Transcriptomic studies reveal distinct gene signatures underlying thermogenic activation and lineage commitment, while epigenomic profiling highlights regulatory elements that orchestrate adipocyte plasticity, particularly the inducible browning of white fat. Proteomic and metabolomic analyses further uncover mitochondrial remodeling, lipid turnover pathways, and metabolite, hormone interactions that regulate thermogenic capacity and metabolic health. Integrating these multi-layered datasets provides systems-level insights into the roles of environmental cues, such as diet and temperature, and endogenous factors, including hormonal signaling, circadian rhythms, and genetic background, in reshaping adipocyte phenotypes and influencing whole-body metabolism. Multi-omics approaches are increasingly identifying potential novel biomarkers and therapeutic targets aiming to enhance the activity of brown and beige adipocyte to combat obesity and metabolic disorders. Overall, these technologies provide a powerful framework for elucidating the complexity of ATs and advancing precision strategies for metabolic disease management and prevention. Full article

Oxidative stress (OS) and sperm DNA fragmentation (SDF) are complementary contributors to male infertility. OS characterizes a compromised seminal redox status, whereas SDF quantifies downstream genomic damage. Human sperm are highly susceptible to redox damage due to lipid-rich membranes and disrupted post-meiotic DNA-repair capacity. Excess reactive oxygen species (ROS) can cause lipid peroxidation, oxidative base lesions, and DNA strand breaks that impair fertilization, embryo development, and pregnancy outcomes. This review explains how OS promotes genomic instability and summarizes the main laboratory assays that assess redox status and SDF in semen. These include direct ROS chemiluminescence assay, oxidation–reduction potential, total antioxidant capacity/ferric reducing antioxidant power, and lipid peroxidation biomarkers, alongside SDF platforms (Sperm Chromatin Structure Assay, terminal deoxynucleotidyl transferase dUTP nick-end labeling, alkaline/neutral Comet, and sperm chromatin dispersion). Additionally, guideline-aligned indications are highlighted to clarify the conditions for testing OS and SDF. OS testing is most relevant in men with leukocytospermia or suspected genital tract infection or inflammation, including dysbiosis; in cases of major modifiable exposures such as smoking or heat; and for early monitoring after treatment. SDF testing is particularly informative in couples with recurrent pregnancy loss and in unexplained infertility with normal semen parameters. Combined OS and SDF testing is recommended in clinical varicocele, repeated in vitro fertilization (IVF) or intracytoplasmic sperm injection (ICSI) failure, poor embryo development, and follow-up after targeted therapy. Management centers on treating infection and inflammation, improving lifestyle and environmental factors, considering varicocelectomy when indicated, using targeted antioxidant therapy in men with documented OS, and selectively applying sperm selection technologies or testicular sperm for ICSI when SDF remains high. Priorities include assay standardization, etiologic attribution of DNA damage, and trials testing OS/SDF-guided pathways with live birth as the primary endpoint. When used selectively and in the appropriate context, OS and SDF testing can help refine diagnosis, improve counseling, and help personalize care of infertile couples. Full article

To advance the engineering application of the fusion decoupling combustion technology previously proposed by our research group, this work focuses on its second stage—the high-temperature syngas combustion stage—and specifically addresses the critical issue of whether high-temperature gasified syngas can achieve direct and stable ignition when mixed with ambient air. For this purpose, a high-temperature syngas combustion experimental system was established, utilizing syngas that simulates the composition of biomass gasification products as the research subject. A systematic investigation was carried out to explore the influence patterns of syngas temperature and key components on the ignition limits, which are characterized by the lower and upper limits of the excess air coefficient (λ_min and λ_max). The results indicate that increasing the syngas temperature significantly broadens the ignition limits: λ_min decreased from 0.73 to 0.59, while λ_max increased simultaneously, primarily due to accelerated reaction kinetics and the contribution of high-temperature sensible heat. An increase in H₂ content significantly expands the ignition range, whereas an increase in CO content narrows the limits, reflecting the opposing roles of these two components in terms of reactivity. Both diluent components, CO₂ and N₂, increase λ_min; however, N₂ exhibits a more pronounced inhibitory effect due to its higher volumetric heat capacity and greater thermal inertia. This study confirms the feasibility of direct ignition between high-temperature gasification syngas and ambient air, providing important experimental evidence for the engineering application of the fusion decoupling combustion process. Full article

Phase change materials (PCMs) have emerged as an innovative solution in thermal energy storage and thermal management systems (TMS) owing to their outstanding latent heat of fusion during the phase change process. This study is especially addressed to the battery TMS based on Organic PCMs for fast charging/discharging applications of lithium-ion batteries (LIBs). These fast processes generate excessive heat during operation, degrade battery performance, decrease energy efficiency, and reduce the lifespan and safety of batteries. Organic PCMs exhibit desirable properties, including high latent heat capacity, good thermal characteristics, low cost, and ease of integration. The major challenge for the successful application of organic PCM comprises its low thermal conductivity, which impacts the heat storage and release rates. PCM-based Paraffin Wax (PW) has been designed by including expanded graphite (EG) as a high thermal conductivity additive in high latent heat of paraffin wax. Experiments focused on the effects of heating methods (microwaves/S-type EG composition and conventional electric oven/S′-type EG composition) of expandable graphite on the thermophysical properties of different PW/EG composites. The crystal and chemical structure of the study samples were analyzed by X-ray diffraction and Fourier-Transform Infrared spectroscopy. The battery module created with PW/EG composites were ample examined using charging/discharging experiments at five different C-rates. The effect of current rates on battery surface temperature is investigated in two cases: with PCM cooling and with air cooling. A 20.43% decrease in battery temperature is found at 5C rate with PCM cooling and a maximum reduction in battery charging time of 43.77%. Full article

Parallel laying of high-voltage cables will generate a zero-sequence current, due to spatial electromagnetic induction, which reduces the cable’s current-carrying capacity, causing heating and corrosion of the grounding points and deteriorating grounding performance. Currently, there is a lack of effective control measures. This article establishes a calculation model for the cable sheath current under the condition of double circuit cable cross interconnection grounding, analyzes the causes of a zero-sequence grounding current in a double circuit cable sheath, and proposes an optimal phase sequence selection method, considering load changes with the goal of maximizing the probability of the cable sheath current, not exceeding the standard. The results show that when the double circuit cable is evenly distributed in the cross interconnection section, the zero-sequence grounding current will be generated on the metal sheath of the cable, causing an excessive total grounding current. By applying the proposed probability-based phase-sequence optimization, the likelihood that both circuits simultaneously satisfy the sheath-current criterion can be significantly improved; for example, under representative layouts and load distributions, the “both-within-limit” probability can reach 53.3% (horizontal layout), 76.2% (horizontal equilateral triangle layout), 90.5% (vertical layout), and 81.6% (vertical equilateral triangle layout). For different working conditions, selecting the optimal load phase sequence combination by maximizing the probability of the sheath current and not exceeding the standard within the current carrying area can help to reduce the cable sheath current. Full article