Search Results (891)

Precise control over the physicochemical and biological properties of colloidal particles is essential for the rational design of functional soft materials. In this work, we report a simple and scalable strategy for generating modular dendron particles (MDPs) through the self-assembly of fully characterized small-molecule Bis-MPA dendrons that act as programmable molecular building blocks for colloidal particle formation. By systematically varying three structural domains—the inner functionality, methylene spacer length, and outer connector—we achieve tunable formation of MDPs ranging from nano- to microscale dimensions. Upon solvent evaporation under mild drying conditions, pre-assembled MDPs act as structure-directing seeds that guide the emergence of hierarchical surface morphologies with spiky, scaly, or spherical protrusions, depending on dendron architecture. Importantly, these assemblies exhibit good biocompatibility toward non-tumoral bronchial epithelial (NL-20) cells while displaying selective cytotoxicity toward Neuro-2a neuroblastoma cells, demonstrating that dendron molecular architecture alone can govern particle size, morphology, and biological response without external drug loading. Collectively, these findings highlight modular Bis-MPA dendrons as versatile building blocks for directing particle size, morphology, and biological response through controlled self-assembly and evaporation-driven structuring. Full article

Surface water–groundwater interactions within oasis–desert ecotones of arid regions play a pivotal role in sustaining regional water security and ecological stability. Taking the Niya River Basin in Xinjiang, Northwest China, as a representative inland watershed, this study systematically elucidates the mechanisms and seasonal dynamics of surface water–groundwater coupling under the combined influences of natural processes and anthropogenic activities. A total of 68 surface water and groundwater samples were collected during the dry, normal, and wet hydrological periods. Integrated hydrochemical characterization, mineral saturation index analysis, and stable isotope (δ²H and δ¹⁸O) mass balance modeling were employed to quantify recharge contributions and unravel hydrogeochemical evolution pathways. Results indicate that the waters in the study area are predominantly brackish to saline, with consistent dominant ionic assemblages (SO₄²⁻ and Na⁺) across all hydrological periods, highlighting evaporite dissolution as the primary control on solute composition. Hydrochemical evolution is jointly regulated by evaporation concentration, water–rock interactions, and cation exchange processes. Surface water chemistry reflects the combined effects of silicate weathering and evaporite dissolution, whereas groundwater chemistry is mainly governed by evaporite dissolution coupled with pronounced cation exchange. Stable isotope signatures reveal substantial secondary evaporation of regional precipitation prior to recharge. Frequent bidirectional recharge between surface water and groundwater was observed, exhibiting distinct seasonal transitions. During the dry period, groundwater provides significant baseflow support to surface water (48.6% in the oasis zone and 54.3% in the desert zone). In the normal period, recharge direction reverses, with surface water becoming the dominant source of groundwater recharge (99.0% in the oasis zone and 76.6% in the desert zone). In the wet period, spatial heterogeneity becomes evident: surface water continues to dominate groundwater recharge in the oasis zone (92.7%), whereas groundwater recharge to surface water prevails in the desert zone (50.5%). This study identifies a seasonally dynamic “discharge–infiltration–zonal regulation” bidirectional recharge pattern in arid inland river systems. The findings advance the mechanistic understanding of hydrological connectivity reconstruction within oasis–desert ecotones and provide a scientific basis for optimized regional water resource allocation and groundwater salinization risk mitigation. Full article

Climate change is increasingly affecting groundwater resources in the Carpathian Basin, while rising temperatures are likely to increase irrigation demand and pressure on aquifers. We assessed climate- and pumping-driven impacts on the Nyírség recharge–discharge system (north-eastern Hungary) by combining shallow groundwater monitoring (1970–2022) with hydroclimate indicators from CHIRPS precipitation and ERA5-Land air temperature and snow depth (1981–2024). Using these datasets, we developed and calibrated a MODFLOW groundwater-flow model for representative wet (2010) and dry (2022) conditions, incorporating permitted abstraction and scenario-based estimates of unregistered pumping. We then ran scenario simulations to evaluate mid-century (2050) conditions and managed aquifer recharge (MAR) options. Precipitation exhibits strong interannual variability, but the region shows marked warming and a pronounced decline in snow storage, implying reduced cold-season buffering and higher evaporative demand. Simulations reproduce the observed post-2010 decline in shallow groundwater, with the largest decreases in higher-elevation recharge areas, whereas increased pumping mainly intensifies localized drawdown near major well fields. Scenario results indicate that climate-driven reductions in recharge dominate basin-scale declines by 2050, while MAR provides primarily local benefits; direct subsurface injection performs best among the tested options. These findings support practical groundwater management by prioritizing measurable and enforceable abstraction (including unregistered withdrawals), demand-side irrigation efficiency and adaptive caps in recharge areas, and targeted subsurface MAR where source water and infrastructure are available. Full article

Background: Dry Eye Disease (DED) is a multifactorial disorder characterized by tear film instability and ocular surface inflammation. Murine models based on environmental stress are widely used to mimic evaporative DED, although many focus on limited disease features. This study aimed to provide an integrated characterization of ocular surface alterations induced by chronic desiccating stress. Methods: Adult mice were housed in a Controlled-Environmental Chamber (CEC) with low humidity and increased airflow for up to 21 days and sacrificed after 14 or 21 days. Corneal damage was assessed by fluorescein staining. Conjunctival histology was evaluated for epithelial morphology, goblet cell (GC) size, and mucin composition. Complement fractions C3 and C5a were assessed by immunohistochemistry. Expression of inflammatory markers (Major Histocompatibility Complex, Class II, DR, HLA-DR; interleukin-1β, IL-1β; tumor necrosis factor-α, TNF-α) was quantified by Real-Time PCR (RT-PCR) in corneal and conjunctival epithelium. Results: Fluorescein staining revealed progressive corneal epithelial damage over time. Histological analysis demonstrated conjunctival epithelial alterations characterized by a significant reduction in GC size and in neutral mucin-positive GCs, consistent with mucin remodeling of the ocular surface epithelium. Increased epithelial deposition of complement fractions C3 and C5a was observed, while molecular analysis confirmed upregulation of inflammatory markers, including HLA-DR, IL-1β, and TNF-α. Collectively, these findings indicate that the model captures key pathophysiological components of DED. Conclusions: The CEC model reproduces major features of evaporative DED, including epithelial damage, GC remodeling, immune activation, and inflammation. As a non-invasive desiccating stress model, it represents a relevant experimental platform for studying ocular surface inflammation and for preclinical evaluation of therapeutic strategies. Full article

The Loess Plateau has experienced persistent vegetation greening over the past two decades, yet this recovery has occurred under a concurrent intensification of atmospheric evaporative demand and drying. This raises a key land–atmosphere question: which hydroclimatic processes most strongly constrain greening, and where do vegetation responses shift across environmental regimes? To address this issue, we integrated spatiotemporal trend analysis, Geographical Convergent Cross Mapping (GCCM)-based directional attribution, and an interpretable machine-learning framework combining Extreme Gradient Boosting (XGBoost) and SHapley Additive exPlanations (SHAP) to diagnose the dominant controls and threshold-like response patterns of vegetation activity. Using 1 km kernel Normalized Difference Vegetation Index (kNDVI) and eight hydroclimatic variables during 2000–2019, we found that regionally averaged kNDVI increased from 0.099 in 2000 to 0.164 in 2019, with a significant trend of 0.003 year⁻¹, and greening trends covered 65.503% of the Loess Plateau. Over the same period, Vapor Pressure Deficit (VPD) increased from 0.142 to 0.275 kPa (+0.133 kPa), indicating that vegetation recovery did not occur under a more humid atmospheric background. GCCM results consistently showed stronger directional influence from hydroclimatic drivers to kNDVI than the reverse, with evaporation and thermal conditions, especially Tmin, emerging as the dominant constraints, followed by Tmax, VPD, and wind speed, whereas precipitation showed comparatively weaker recoverable influence. The tuned XGBoost model achieved strong out-of-sample performance (R² = 0.9611, RMSE = 0.0188, MAE = 0.0131), and SHAP revealed clear nonlinear thresholds: evaporation and Tmin shifted into persistently positive contribution regimes beyond 302 mm and −17.6 °C, respectively; Tmax became predominantly inhibitory beyond −1.9 °C, and Palmer Drought Severity Index (PDSI) exhibited a multi-stage non-monotonic transition around −0.7. These results provide a coherent evidence chain linking directional influence, relative contribution, and threshold boundaries, offering quantitative support for identifying climate-sensitive zones and restoration risk regimes under continued warming and rising atmospheric dryness. Full article

In the current work, a novel heat pump drying system with precise control of temperature and humidity of drying medium was developed and the impacts of drying temperature and humidity on the drying characteristics of apple slices and energy consumption of drying system were investigated. Experimental results indicated that the temperature and relative humidity (RH) of drying medium have a significant impact on drying efficiency and operating performance. During the first hour of the drying process, the heat pump drying of apple slices exhibited the highest drying rate throughout the entire process at a temperature of 40~50 °C and a relative humidity of 30~60%. And then the apple slices drying was in a falling-rate drying stage. When the relative humidity of the drying medium exceeded 50%, the final moisture content of the material increased significantly and exceeded 20% (dry basis, d.b.). Increased air medium temperature and humidity enhance the dehumidification rate of the evaporator. When the drying temperature was maintained at 40–60 °C, the condensation rate at 60% RH was 3.5–10 times that at 30% RH. The increased dehumidification rate significantly promoted the energy efficiency. The specific moisture extraction rate (SMER) was 2.53 kg/(kW·h) at 60 °C and 60% RH, which is 3.4 times that at 30% RH. It was appropriate to adopt high-temperature and high-humidity conditions in the early drying stage to improve drying energy efficiency. Meanwhile, the relative humidity should be reduced to promote moisture removal from the material in the late drying stage. The obtained results provided theoretical methods for the energy-saving control of heat pump drying for fruits. Full article

In this study, continuous near-real-time measurements of greenhouse gases (GHGs), particularly carbon dioxide (CO₂) and methane (CH₄), and aerosol optical depth (AOD) were conducted at the Socheongcho Ocean Research Station (SORS) from January 2021 to April 2022. Specifically, AOD products retrieved from the Geo-KOMPSAT-2B sensors—Geostationary Environment Monitoring Spectrometer and Geostationary Ocean Color Imager II—were compared and validated against ground-based Aerosol Robotic Network (AERONET) observations. Both satellite products exhibited overall good agreement with AERONET AOD data and showed low bias. The GHG measurements based on cavity ring-down spectroscopy indicated that CO₂ reached its highest seasonal mean in the spring of 2022, while CH₄ attained its maximum during the wet summer of 2022. Temperature, relative humidity, and evaporation were closely associated with AOD variability during the dry summer period, while elevated temperatures may have contributed to enhanced photochemical activity and modulation of CH₄ concentrations. In the cold season, concurrent increases in GHGs and combustion-related pollutants (PM_2.5, CO, and black carbon) were observed, suggesting reduced oxidation capacity under stable atmospheric conditions. Overall, these findings underscore the potential value of integrating satellite and in situ observations to better characterize GHG–aerosol interactions and support emission mitigation strategies in the Northeast Asian marine environment. Full article

Soil salinization represents a critical constraint to sustainable agriculture in arid and semi-arid regions, where salinity threatens soil productivity, water quality, and ecosystem resilience. Soil salinity pattern prediction is complicated by tightly coupled landscape hydro-climatic processes, wherein the central Sabkha acts as a persistent salt sink, episodic inundation and intense evaporation concentrate dissolved salts, and a shallow saline groundwater table interacts with the semi-arid climate to drive surface salinization. Conventional mapping is laborious and lacks the precision needed to capture the spatio-temporal dynamics of soil salinity across landscapes. This study developed an integrated framework uniting multi-temporal Landsat imagery (2000–2025), hypsometric data, climatic indicators, and in situ soil electrical conductivity (ECe) measurements to model soil salinity dynamics using machine learning (ML), over the Sehb El Masjoune (SEM) semi-arid region, Morocco. A total of 233 soil samples were collected in the investigated area in 2022, 2023, 2024, and 2025 to assess the spatial variability to calibrate and validate modeling findings. To this end, three predictive algorithms, i.e., Gradient-Boosted Trees (GBT), Support Vector Regression (SVR), and Random Forest (RF) were assessed. Our findings showed that SVR achieved the highest predictive capability (R² = 0.76; RMSE = 32.91 dS/m), whereas SVR-based salinity maps revealed a distinct spatial organization of salinization processes, characterized by extremely saline soils (≥64 dS/m) concentrated in the central study area (i.e., SEM center) and a progressive decline toward adjacent agricultural lands (0–8 dS/m). Our results demonstrated that from 2000 to 2025, moderately to highly saline areas (≥16 dS/m) expanded by nearly 10%, driven by recurrent droughts and inefficient drainage. Hydroclimatic analysis confirmed that dry years (SPI: Standardized Precipitation Index ≤ −0.5) promoted net salinity build-up through the expansion and persistence of moderate-to-high salinity classes (≥16 dS/m), whereas wet years (SPI ≥ +0.5) favored temporary leaching and partial recovery, mainly within the low-to-moderate range. This integrative remote sensing–ML approach provides a robust and scalable framework for operational soil salinity monitoring, offering valuable insights for sustainable land-use planning in similar Sabkha’s data-scarce agroecosystems. Full article

The evaporation of a thin liquid film representative of power-law rheology flowing along an inclined channel wall under the combined influence of gravity and surface tension is investigated using a semi-analytical modelling framework. The evolution of film thickness, heat transfer characteristics, and dry-out behaviour are examined as functions of the power-law exponent, Weber number, and inlet film thickness. The results show that a decrease in the power-law exponent leads to a slower reduction in film thickness, resulting in a significant increase in the dry-out length for a fixed value of consistency. This behaviour is attributed to the large effective viscosity developing near the free surface for shear-thinning fluids, in contrast to the negligible surface viscosity observed for shear-thickening fluids. The local Nusselt number increases gradually along the flow direction, followed by a sharp terminal rise marking the onset of dry-out. The mean Nusselt number decreases with increasing power-law exponent, which is consistent with the dry-out length variation with the power-law exponent. The dry-out length is found to be largely insensitive to surface tension for a fixed normalised inlet film thickness, while exhibiting an approximately linear dependence on the inlet film thickness that is nearly independent of the power-law index. Overall, the study establishes a hierarchy of controlling parameters for evaporating power-law films in inclined micro-channels, demonstrating that inlet film thickness primarily governs the dry-out location, while rheology and surface tension exert secondary influences within the parameter ranges considered. Full article

Agrivoltaic Systems (AV) constitute a viable alternative to mitigate land-use competition by enabling the simultaneous production of agricultural crops and solar photovoltaic energy. However, the heterogeneous shading and microclimatic modifications induced by AV systems can alter solar radiation, crop physiological performance, and, consequently, its biomass. This study evaluated the effects of two static ground-mounted AV systems—semi-transparent (ST) and conventional opaque (CON) panels—on the growth, physiology, soil water variations, and yield of Arugula (Eruca vesicaria) cultivated in southern Italy from August to October 2022; compared with an open-field control (REF). Daily soil temperature and water content were monitored, alongside leaf-level gas exchange measurements at three vegetative stages. Global solar radiation was reduced by 70% under ST and 80% under CON, reducing Photosynthetically Active Radiation (PAR), transpiration, and net photosynthesis, while leaf water use efficiency remained comparable to REF. Sequential harvests showed that although yields were consistently highest in REF, ST 50% and CON 50% exhibited partial recovery in fresh and dry biomass by the third cutting, reflecting the mitigating effect of seasonal temperature declines on shading. Notably, soil water uniformity improved under AV systems, reaching 90% under ST and 94% under CON compared with 85% in REF, due to reduced evaporative losses and enhanced lateral soil water redistribution. Overall, while AV-induced shading limits radiation and yield in short-cycle leafy arugula, microclimate modulation under AV systems can enhance soil water distribution and partially buffer growth under less favorable seasonal conditions. These findings highlight the trade-offs between crop productivity and resource-use efficiency in AV systems and emphasize the importance of tailoring their design to crop type and local climatic conditions, providing valuable guidance for future experimental research and for policymakers aiming to support sustainable agrivoltaic deployment. Full article

Droughts are one of the most significant hazards that affect human life due to the imbalanced distribution of water across the world. Some parts of the world are usually dry, and meteorological conditions affect these regions rapidly. In water-scarce regions, droughts significantly put at risk socio-economic stability and food security, which may cause a major challenge to sustainable development. Therefore, a precise definition of drought and the identification of early warning signals can help to minimize the negative effects of droughts, especially in terms of agriculture. In this study, drought signals of three major agricultural provinces of Turkey, namely Antalya, Şanlıurfa, and Konya, were investigated. For this purpose, the Standard Precipitation Index (SPI), Standardized Precipitation Evapotranspiration Index (SPEI), Evaporative Demand Drought Index (EDDI), and Vegetation Condition Index (VCI) were computed for each province. A composite score index was proposed for the evaluation of multiple indices together. All datasets were obtained from remote-sensing products to ensure reproducibility. A dataset for the 2003–2023 period was used. The monthly precipitation derived from CHIRPS data and potential evaporation (PEV) data were obtained from the ERA5-Land. Therefore, the SPEI and EDDI values were calculated by using ERA5-Land PEV values but not the evapotranspiration. The Normalized Difference Vegetation Index (NDVI) values for each province were obtained from the MODIS/Terra MOD13A3 v061. The Mann–Kendall test and Sen’s slope were applied to the computed time series to detect the trends. As a result, the dry and wet periods were identified for each province individually. The VCI was found to have an increasing trend for all tested provinces. Overall, from a future perspective, the most vulnerable province in terms of meteorological drought was indicated to be Antalya. Full article

The Prespa Lakes system, shared between Greece, the Republic of North Macedonia, and Albania, forms a significant transboundary, large-scale integrated freshwater ecosystem subject to multiple anthropogenic and natural pressures. This study focuses on the Greek part of the Prespa Lakes system with particular emphasis on the identification of the ecological and hydrological impacts of the contributing stream inflows on the lakes by examining the spatial variability in physicochemical and biological conditions and conducting water balance and isotopic analyses. Based on our results, streams draining into Lesser Prespa Lake exhibited more pronounced hydrological and physicochemical fluctuations than the Agios Germanos River connected to Great Prespa Lake, while ecological status classifications of all studied streams ranged from high to moderate. Furthermore, moderate ecological status conditions (mainly observed at the downstream stations) were closely associated with adjacent anthropogenic pressures, including agricultural drainage, livestock activities, irrigated croplands, and wastewater discharges. In addition, although both lakes were classified as mesotrophic, field data indicated greater transparency loss in Lesser Prespa than in Great Prespa Lake. Regarding the stream influences on Lesser Prespa Lake’s water quality, nutrient loads induced changes in lake concentrations by roughly one month. Total nitrogen showed moderate stream–lake correlations (R = 0.61) and a strong negative correlation for total phosphorus (R = −0.94), suggesting substantial nutrient retention and processes within the lake. Water balance analysis revealed an annual water deficit for both Lesser and Great Prespa, with the latter exhibiting a markedly stronger and systematic long-term decline in water level. In the Lesser Prespa, seasonal fluctuations in water volume were primarily driven by excess rainfall, while stream inflows contributed minimally. Conversely, correlation analysis for Great Prespa identified surface inflow from the Ag. Germanos catchment as the dominant driver of water storage variability, surpassing direct rainfall, with strong correlations in both wet (R = 0.79) and dry (R = 0.88) periods. Isotopic compositions (δ¹⁸O, δ²H) did not differ significantly between the two lakes, indicating common recharge sources and strong evaporative imprints, while stream isotopic signatures highlighted spatial and seasonal variability in hydrological inputs. Seasonal and spatial variations were proved to be strongly influenced by both natural hydrological dynamics and anthropogenic pressures within the basin, while these findings reinforce the importance and the necessity of adopting holistic, cross-border management strategies that maintain the ecological integrity and the long-term sustainability of the Prespa Lakes ecosystem. Full article

Gridded meteorological data sources, such as reanalysis datasets, are increasingly used to estimate evapotranspiration, a key variable for surface water-budget analyses at regional and national scales and for assessing plant water requirements for irrigation. This study, conducted over mainland Portugal for the 44-year reference period from 1980 to 2023, first presents a comprehensive comparative analysis of the spatial patterns of potential ($Ep$) and reference ($Eto$) evapotranspiration at a 0.1° spatial resolution using daily data. Estimates derived from two high-resolution datasets (GLEAM and ERA5-Land) are compared with those obtained from the Thornthwaite, Hargreaves–Samani, and Penman–Monteith models. Secondly, trend analyses of $Eto$ magnitudes on a monthly and annual basis in a gridded format were conducted. The resulting spatial distributions of $Ep$ and $Eto$ show higher values in milder and flatter southern Portugal and lower values in the cooler and more mountainous northern regions, in agreement with existing knowledge. The Penman–Monteith model exhibited the highest reliability, while the Thornthwaite model generally underestimated evapotranspiration across the country, and the Hargreaves–Samani model showed underestimation in coastal areas. Trend analysis of $Eto$ indicates an overall increase in atmospheric evaporative demand over the full study period, with a more pronounced rise during the recent 22-year period (2002–2023) compared with the earlier period (1980–2001). These increases are statistically significant in August and October and may reflect a climate shift towards a progressively longer dry season. Understanding how changes in evapotranspiration affect hydrological processes—including surface water availability, river discharge, reservoir performance, and crop requirement—is critical. This study aims to contribute to addressing these emerging challenges. Full article

To effectively prevent and control coal spontaneous combustion, a novel heat-sensitive hydrogel for mine fire prevention and extinguishment was developed using hydroxypropyl methylcellulose (HPMC) and the organic flame-retardant, sodium alginate (SA). The hydrogel was prepared through single-factor variable control and material compounding. First, the optimal formulation of the hydrogel was determined using analytical instruments and techniques, including a viscometer, vacuum drying oven, and the inverted test tube method. Subsequently, its microstructural characteristics were examined using scanning electron microscopy (SEM) and infrared spectroscopy (FTIR). Finally, a fire suppression test platform was established to perform comparative experiments, verifying the hydrogel’s fire prevention, extinguishing, and cooling performance. Experimental results demonstrated that the optimal hydrogel formulation consists of 2.5 wt% HPMC and 0.3 wt% SA. At this ratio, the hydrogel exhibits excellent fluidity and water retention, ensuring prolonged coverage and wetting of coal surfaces. The gel undergoes a sol–gel phase transition at 58 °C, enabling it to fill voids, bind and reinforce coal particles, and reduce exposed surface area. After drying, the hydrogel forms a uniformly smooth surface capable of both coating the coal body and encapsulating individual coal particles. Following the hydrogel treatment, the coal sample retains its original functional groups, indicating that no chemical reactions occur during mixing. Compared with traditional inhibitors, the hydrogel demonstrates superior fire suppression performance, more effectively covering and encapsulating burning coal. It rapidly reduces the temperature to 28 °C by the cooling effect of water evaporation from the hydrogel, and it maintains thermal stability, achieving outstanding fire-extinguishing efficiency. Full article

Irrigation depth plays a critical role in regulating soil water availability and root water uptake in perennial orchards, yet its mechanistic effects remain poorly understood in subtropical red-soil hilly regions characterized by strong evaporative demand and shallow effective soil water storage. Here, a field experiment was conducted in a citrus orchard with three irrigation depths—shallow (25 cm), intermediate (50 cm), and deep (100 cm)—under a uniform irrigation amount. Soil water dynamics, root traits, and root water uptake sources across a 0–200 cm soil profile were investigated using soil moisture monitoring, root morphological analysis, dual stable isotopes (δ²H and δ¹⁸O), and the MixSIAR Bayesian mixing model. Irrigation depth markedly restructured vertical soil moisture patterns, with the 40–120 cm layer identified as the most responsive zone. Intermediate irrigation maintained the highest and most stable soil water content in this layer, whereas shallow irrigation intensified surface drying and deep irrigation failed to improve water availability within the hydraulically active root zone. Root surface area and dry mass were maximized under intermediate irrigation, indicating enhanced root–soil coupling. Isotopic analysis revealed the strongest evaporative fractionation under shallow irrigation, while intermediate irrigation substantially alleviated surface evaporation. MixSIAR results further showed that shallow irrigation progressively increased reliance on surface soil water (up to 93% in November), whereas intermediate irrigation promoted coordinated uptake from shallow, middle, and deep soil layers, with deep soil water contributing up to 30.7% in November. These results demonstrate that irrigation depth exerts a stronger control over root water uptake strategies by stabilizing water availability within the active root zone and reducing non-productive evaporative losses. Optimizing subsurface irrigation depth therefore represents an effective pathway to improve water-use efficiency in citrus orchards of subtropical hilly regions. Full article