Search Results (532)

The success of acid stimulation in tight carbonate reservoirs relies on the formation of non-uniform etching on fracture walls. However, existing research on the influence of the fracture surface morphology on non-uniform etching and fracture conductivity predominantly employed non-replicable tensile fracture surfaces. Previous studies were unable to use identical fracture surfaces to conduct single-factor analysis and clarify the impact of roughness. This study utilized digital engraving technology to fabricate multiple artificial carbonate rock samples with a homogeneous lithology and completely consistent fracture surface morphology. Using the Triangular Prism Method (TPM), the initial fracture roughness of the rock samples was decomposed into large-scale waviness and small-scale unevenness. Through controlled injection parameters, single-factor acid etching experiments were conducted. For the first time, the effects of large-scale waviness and small-scale unevenness on acid etching were investigated, along with the influences of the acid injection rate and injection time. The existence of an optimal injection rate and an optimal injection time was clarified. The results demonstrate that the engraved carbonate samples’ surfaces exhibit good consistency with the original natural fracture surfaces. The acid solution acts to shave the “peaks” and deepen the “valleys” of rough fractures. The large-scale waviness characteristics of the initial rough surfaces determine the overall post-etching morphology, leading to poor surface contact within the fracture. This is the primary reason for the high fluid flow capacity of acid-etched fractures under low closure stresses. However, the small-scale unevenness characteristics of the initial rough surfaces determine the formation and the distribution of small protruding support points on the post-etching surface. This is the primary reason for the retention of high conductivity in acid-etched fractures under high closure stresses. An increase in the acid injection rate or acid injection time does not lead to a linear decrease in linear roughness, surface mismatch, or fracture aperture. A critical acid injection rate or critical acid injection time exists. Optimizing the injection rate or time can achieve an ideal etching morphology—the protrusions formed by punctate etching enable the fractures to maintain a certain level of conductivity even under a high closure stress of 55.2 MPa, while channel etching can increase the conductivity under high closure stress by 20–25%, providing a key direction for optimizing acid etching effects. Full article

Cellulose nanofibers/metal-organic framework (CNFs/MOF) composites hold promise for energy storage thanks to high porosity, large specific surface area, and inherent flexibility, but their poor conductivity limits applications to environmental remediation and gas adsorption. Herein, flexible CNFs served as substrates for in situ growth of continuous ZIF-8 nanolayers via interfacial synthesis, with a CNFs/ZIF-8 gel network built to enhance structural integrity and flexibility. A novel strategy first regulated the layered pore structure: ZIF-8 in CNFs/ZIF-8 nanofibers was etched in the acidic environment of aniline in situ polymerization, constructing a hierarchical porous architecture with interconnected micropores and mesopores. CNFs/ZIF-8/PANI gel composite membranes were then fabricated. As self-supporting electrodes for symmetric supercapacitors, the composites showed excellent electrochemical performance: 1350 F/g at 1 A/g for the electrode, and the flexible solid-state device delivered a specific capacitance of 220.9 F/g at 0.5 A/g, along with a capacitance retention rate of 74% after 5000 charge–discharge cycles at 10 A/g. The superior performance stems from synergistic hierarchical pore structure regulation via partial MOF sacrificial templating and gel matrix-mediated rapid ion diffusion, offering a feasible approach for high-performance flexible energy storage devices. Full article

The plasma-catalytic conversion of CO₂ is a promising route toward sustainable fuel and chemical production under mild operating conditions. However, many aspects still need to be better understood to improve performance and better understand the catalyst-plasma synergies. Among them, one aspect concerns understanding whether photons emitted by plasma discharges could induce changes in the catalyst, thereby promoting interaction between plasma species and the catalyst. This question was addressed by investigating the CO₂ splitting reaction in a planar dielectric barrier discharge (pDBD) reactor using titania-based catalysts that simultaneously act as discharge electrodes. Four systems were examined feeding pure CO₂ at different flow rates and applied voltage: bare titanium gauze, anodically formed TiO₂ nanotubes (TiNT), TiNT decorated with Ag–Au nanoparticles (TiNTAgAu), and TiNT supporting Ag–Au nanoparticles coated with polyaniline (TiNTAgAu/PANI). The TiNTAgAu exhibited the highest CO₂ conversion (35% at 10 mL min⁻¹ and 5.45 kV) and the most intense optical emission, even in the absence of external light irradiation, suggesting that the improvement is primarily attributed to plasma–nanoparticle interactions and self-induced localized surface plasmon resonance (si-LSPR) rather than conventional photocatalytic pathways. SEM analyses indicated severe plasma-induced degradation of TiNT and TiNTAgAu surfaces, leading to performance decay over time. In contrast, the TiNTAgAu/PANI catalyst retained structural integrity, with the polymeric coating mitigating plasma etching while maintaining competitive efficiency. There is thus a complex behavior with catalytic performance governed by nanostructure stability, plasmonic enhancement, and the interfacial protection. The results demonstrate how integrating plasmonic nanoparticles and conductive polymers can enable the rational design of durable and efficient plasma-photocatalysts for CO₂ valorization and other plasma-assisted catalytic processes. Full article

Electrocatalytic CO₂ reduction is a promising approach to mitigate rising atmospheric CO₂ levels while converting CO₂ into valuable products such as CH₄. Conversion into other useful substances further expands its potential applications. However, the efficiency of the CO₂ reduction reaction (CO₂RR) is strongly influenced by device geometry and CO₂ mass transfer in the electrolyte. In this work, we present and evaluate microchannel electrocatalytic devices consisting of a porous Cu cathode and a Pt anode, fabricated via metal-assisted chemical etching (MACE). The porous surfaces generated through MACE enhanced reaction activity. To study the impact of the distance between electrodes, several devices with different channel heights were fabricated and tested. The device with the highest CH₄ selectivity had a narrow inter-electrode gap of 50 μm and achieved a Faradaic efficiency of 56 ± 11% at an applied potential of −5 V versus an Ag/AgCl reference electrode. This efficiency was considerably higher than that of the device with larger inter-electrode gaps (300 and 480 μm). This reduced efficiency in the larger channel was attributed to limited CO₂ availability at the cathode surface. Bubble visualization experiments further demonstrated that the electrolyte flow rate had a strong impact on supplied CO₂ bubble morphology and mass transfer. At a flow rate of 0.75 mL/min, smaller CO₂ bubbles were formed, increasing the gas–liquid interfacial area and thereby enhancing CO₂ dissolution into the electrolyte. These results underline the critical role of electrode gap design and bubble dynamics in optimizing microchannel electrocatalytic devices for efficient CO₂RR. Full article

Low gas recovery in the Sebei-2 gas field is linked to residual gas trapping under water encroachment. This study investigates the pore-scale trapping behaviour of residual gas in three types of layer: conventional, low-resistivity, and low-acoustic high-resistivity. High-fidelity pore structures were reconstructed by integrating mercury intrusion porosimetry with thin-section data and microfluidic models were designed using the Quartet Structure Generation Set method and fabricated by wet etching. Visualized displacement experiments were performed under different wettability conditions and water invasion rates, and image analysis was used to quantify the distribution of trapped gas. Results show that the low-resistivity gas layer exhibits the highest residual gas saturation (30.57%), followed by the low-acoustic high-resistivity gas layer (20.20%), while the conventional gas layer has the lowest (15.29%). These values correspond to apparent pore-scale gas recoveries of about 48.95%, 65.01%, and 72.14% for the low-resistivity, low-acoustic high-resistivity and conventional gas layers, respectively. In hydrophilic systems, wetting-film thickening and flow diversion are the main trapping processes, whereas in hydrophobic systems, flow diversion dominates and residual gas decreases markedly. Increasing the water invasion rate reduces trapped gas in the conventional and low-resistivity layers, whereas in the strongly heterogeneous low-acoustic high-resistivity layer, higher invasion intensity strengthens preferential channelling/viscous fingering, leading to a non-monotonic residual gas response. These findings clarify the differentiated pore-scale trapping mechanisms of gas under water encroachment and highlight that mitigating water film-controlled trapping in low-resistivity layers and flow diversion trapping in low-acoustic high-resistivity layers is essential for mobilizing trapped gas, improving dynamic reserves, and ultimately enhancing the economic recovery of water-bearing gas reservoirs similar to the Sebei-2 gas field. Full article

We demonstrate the fabrication of air gaps in a PECVD SiN interlayer through lateral recess by employing two consecutive plasma etch steps on an AlN/SiN/Al₂O₃ stack. This approach enables the preservation of sub-100 nm openings in Al₂O₃, offering a potential optimization for the GaN-HEMT gate stack in RF applications while retaining low gate foot dimensions. A low-power, SF₆-based plasma etch is introduced, and time-dependent etch profiles reveal the formation of a skirt-like profile. The process exhibits excellent selectivity between SiN and Al₂O₃ etch rates. Furthermore, low-power SF₆ plasma produces a small self-bias voltage, and surface fluorine contamination which can subsequently be eliminated by annealing. Full article

Background: Adhesive indirect restorations have become increasingly common in daily clinical routine in most dental practices. Before etching and adhesive application, a sandblasting procedure is essential to clean and increase the microporosity of the surface. Air abrasion with aluminum oxide particles significantly improves the bond strength. However, this procedure may have some limitations, such as the presence of powder particles. Recently, the Er:YAG laser in QSP mode has been proposed for conditioning build-ups prior to adhesive cementation. The aim of this study was a retrospective analysis of adhesive indirect restoration in which build-up was conditioned or using a traditional sandblaster with alumina powder or using the Er:YAG laser in QSP mode. Methods: 187 posterior indirect adhesive restorations were cemented using two different conditioning techniques: in 96 cases (51.34%) build-up conditioning was performed using an intraoral sandblaster with alumina oxide (Microetcher CD, Kavo, Biberach, Germany); in 91 cases (48.66%) build-up conditioning was performed using the Er:YAG laser (Fotona LighWalker^®, Ljubljana, Slovenia) in QSP modality (1 W, 10 Hz, 100 mJ). The clinical efficacy of the two techniques was evaluated and compared, assessing the occurrence of complications such as debonding, fracture, secondary leakage, and hypersensitivity over time. Results: The frequency of secondary complications was very low in both groups. Only one case of debonding and one case of restoration cracking was observed in the sandblasting group, with none in the laser group (p = 0.329). Secondary caries occurred in both groups. A difference was observed in postoperative hypersensitivity: 6% in the sandblasting group and 1% in the laser group (p = 0.064). The Kaplan–Meier curves of the two conditioning techniques showed comparable survival over time (Log-rank test χ² = 2.4864/p = 0.1148). The mean follow-up was 30 months. Conclusions: The success rates of these restorations are very high if adhesive cementation steps are properly followed. Conditioning the build-up before etching is essential. Among these, the Er:YAG laser in QSP mode seems to provide excellent results in the absence of dust and smear layer. Recurrence rates of complications such as decementation, leakage, and cracking resulted in less than 1%. Furthermore, it is interesting to note that using the laser to condition the build-up appears to reduce the recurrence of post-cementation hypersensitivity. These data require confirmation through prospective clinical trials. Full article

This study investigates the synergistic effects of co-doping with ultralow-concentration nitrogen and trace carbon dioxide on the growth of polycrystalline diamond films via microwave plasma chemical vapor deposition (MPCVD). The films were characterized using scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and photoluminescence spectroscopy. Results indicate that trace nitrogen effectively promotes <111> oriented growth and enhances the deposition rate, whereas excessive nitrogen leads to the formation of defects such as pores and microcracks. The introduction of CO₂ suppresses the formation of nitrogen-vacancy-related defects through a selective etching mechanism. Under co-doping conditions, diamond films with high growth rates, strong <111> texture, and superior thermal conductivity (up to 1863.94 W·m⁻¹·K⁻¹) were successfully synthesized, demonstrating significant potential for thermal management applications in high-power integrated circuits. Full article

Polygonatum sibiricum polysaccharide (PsP), one of the main components of Polygonatumsibiricum used in traditional Chinese food and medicine, has important bioactive functions, but it is difficult to fully utilize PsP because of the degradative effect of digestive gastric juices. This study aimed to innovatively synthesize a new food formulation for PsP, namely, a PsP–hydroxyapatite (HAP) sustained-release system, so as to reduce its degradation. The new food formulation was optimized and evaluated by the response surface method (RSM) and by in vitro experiments. The optimal stirrer temperature, reaction pH, etching pH, and loading time for synthesizing PsP-HAP were 85.62 °C, pH 11.12, pH 8.40, and 5.10 h, respectively, all of which were different from the findings of other similar research studies. The average encapsulation rate of PsP-HAP reached (40.16 ± 1.54)%, and the content of PsP was 8.98%. Additionally, PsP-HAP appeared to be pH-responsive, and its continuous antioxidative effect was first proven by the DPPH assay and then cytologically by a total antioxidative capacity assay. The CCK-8 assay indicated that PSP-HAP did not induce toxicity. This study successfully developed a new food formulation for PsP which appears to have the potential to reduce the degradative effect of digestive gastric juices. Thus, it is possible to achieve full utilization of PsP by using this new sustained-release food formulation. Full article

Superhydrophobic surfaces have gained considerable attention due to their ability to repel water and reduce surface adhesion, and they are now widely applied for self-cleaning, anti-fouling, anti-icing, and corrosion resistance purposes. In this study, either a computer numerical control (CNC) machine or photolithographic techniques were employed to fabricate molds with microwells, followed by soft lithography to obtain a polydimethylsiloxane (PDMS) micropillar array. An etching process was then carried out. It was found that, as etching time increased, the diameters of micropillars decreased, leading to a decrease in the solid fraction of the composite surface and increases in contact angles. When the ratios of spacing to diameter (W/D) and of height to diameter (H/D) both exceeded 1.5, the contact angle was found to exceed 150° and the original PDMS micropillar surface with a contact angle of around 135° became superhydrophobic. A drastic decrease in sliding angle was also observed at this threshold. Changes in contact angles with different W/D values were in good agreement with values calculated using the Cassie–Baxter equation, and the droplet state was verified by a pressure balance model. Meanwhile, the PDMS etching rate when using acetone as the solvent was approximately 6–8 times faster than that when using 1-Methyl-2-pyrrolidone (NMP), a result which is comparable to data in the literature. Full article

The carbonate reservoir of the Shunbei oilfield is characterized by deep burial depth and high temperature. During acid fracturing, the reaction rate between conventional acid systems and the rock is relatively fast, leading to a limited effective acid penetration distance. To extend the acid penetration distance, a combination of solid retarded acid and conventional acid was used in field operations. The effectiveness of the solid retarded acid depends on its acid generation pattern, making it necessary to study the acid generation behavior of the solid retarded acid. This paper establishes a frame for evaluating the solid retarded acid, including tests for solid retarded acid solubility, acid concentration, and acid-etched fracture conductivity. Based on the test results, the acid generation pattern of solid retarded acid was analyzed, its slow-generation performance was evaluated, and an acid generation model was established. Finally, by integrating the acid generation model with the existing acid fracturing model, the effective distance of solid retarded acid was predicted. The study shows that the solubility of acid-generating materials is influenced by both temperature and solid retarded acid concentration. When the concentration of solid retarded acid exceeds 25%, it does not completely dissolve at room temperature, but can fully dissolve after 40 min at 120 °C. The acid concentration is significantly affected by temperature, with an acid concentration of about 1.6 mol/L at room temperature and up to 3.1 mol/L at high temperatures, comparable to a 12% hydrochloric acid concentration. Solid retarded acid exhibits good slow-generation performance, with a comprehensive reaction rate approximately one-third of that of cross-linked acid. When the acid-rock contact time is around 3 h, the acid-etched fracture conductivity of solid retarded acid can remain above 5 D·cm under a closure pressure of 60 MPa. The predicted effective acid penetration distance of solid retarded acid can reach over 150 m, under typical conditions of Shunbei oilfield. The findings of this study can serve as a reference for the design and optimization of solid retarded acid fracturing. Full article

Conventional dental materials with organised crystal structures exhibit limitations in corrosion resistance, bioactivity, and drug delivery capability. In contrast, amorphous nanomaterials offer potential advantages in overcoming these limitations due to their unique structural properties. They are characterised by a non-crystalline, disordered atomic structure and are similar to a solidified liquid at the nanoscale. Among the amorphous nanomaterials used in dentistry, there are five major categories: calcium-, silicon-, magnesium-, zirconia-, and polymer-based systems. This study reviewed these amorphous nanomaterials by investigating their synthesis, properties, applications, limitations, and future directions in dentistry. These amorphous nanomaterials are synthesised primarily through low-temperature methods, including sol–gel processes, rapid precipitation, and electrochemical etching, which prevent atomic arrangements into crystalline structures. The resulting disordered atomic configuration confers exceptional properties, including enhanced solubility, superior drug-loading capacity, high surface reactivity, and controlled biodegradability. These characteristics enable diverse dental applications. Calcium-based amorphous nanomaterials, particularly amorphous calcium phosphate, demonstrate the ability to remineralise tooth enamel. Silicon-based amorphous nanomaterials function as carriers that can release antibacterial agents in response to stimuli. Magnesium-based amorphous nanomaterials are antibacterial and support natural bone regeneration. Zirconia-based amorphous nanomaterials strengthen the mechanical properties of restorative materials. Polymer-based amorphous nanomaterials enable controlled release of medications over extended periods. Despite the advances in these amorphous nanomaterials, there are limitations regarding material stability over time, precise control of degradation rates in the oral environment, and the development of reliable large-scale manufacturing processes. Researchers are creating smart materials that respond to specific oral conditions and developing hybrid systems that combine the strengths of different nanomaterials. In summary, amorphous nanomaterials hold great promise for advancing dental treatments through their unique properties and versatile applications. Clinically, these materials could improve the durability, bioactivity, and targeted drug delivery in dental restorations and therapies, leading to better patient outcomes. Full article

Yttrium oxide (Y₂O₃) films have been widely used as protective layers in plasma etching equipment, but achieving stoichiometric films with high deposition rates remains a challenge. In this study, Y₂O₃ films were fabricated by a medium-frequency reactive magnetron sputtering (MF-RMS) technique. The oxygen flow and target control voltage were regulated through a closed-loop feedback control system, which effectively solved the problem. The microstructure, mechanical, optical, and plasma etching properties were systematically investigated. The results showed that near-stoichiometric films can achieve a relatively high deposition rate. Increasing the deposition temperature induced a structural transition in the Y₂O₃ film from a predominantly cubic phase to a mixture of cubic and monoclinic phases. For Y₂O₃ films deposited at room temperature, increasing the bias voltage increased the deposition rate but reduced hardness and elastic modulus. The Y₂O₃ film deposited at 300 °C in the near-metallic mode exhibited the highest hardness and elastic modulus, reaching 13.3 GPa and 222.0 GPa, respectively. All Y₂O₃ films exhibited excellent transmittance and resistance to plasma etching. This study provides an effective protective strategy for semiconductor etching chambers. Full article

Proton binding (i.e., charging) isotherms of halloysite nanotubes (HNT) were determined from cycled acid-base potentiometric titrations in KCl solution at constant ionic strengths (0.01, 0.10, 1.00 mol dm⁻³). The isotherms measured in the pH cycle from 3 to 11 and back exhibit a pronounced hysteresis with respect to the direction of pH change, which is accurately reproducible when the cycle is repeated. The hysteresis is absent if the cycled titration is performed within a narrow pH range between 5 and 9. These results align with the dissolution rates of alumina and silica, which form the two surfaces of the rolled kaolinite sheet in HNT, and clearly point to reversible partial dissolution-deposition processes in the HNT interior during a titration cycle, outside the above pH range (alumina dissolution below pH ≈ 5 and silica dissolution above pH ≈ 8.5). In the studied titration experiments, these processes produce partially dissolved surface-bound, rather than completely dissolved species (reversible surface etching). Under the applied conditions, reversible surface etching is less pronounced in the acidic part of the titration cycle. Charging isotherms recorded in the decreasing pH titrations at varied ionic strength exhibit a common intersection point very close to zero charge (point of zero charge) around pH ≈ 8.1, characteristic for an amphoteric solid surface. These isotherms were reasonably well fitted by applying the surface protonation model in the HNT interior, which invokes the Stern model of the electric double layer (EDL), by summing the surface charges calculated for alumina and silica as separate components (surfaces). The model surface charge isotherms for alumina surface in the HNT interior exhibit a point of zero charge at pH = 9.0, while the silica surface has a negative charge above pH > 8.5, which is in very good agreement with the values reported in the literature: as for these two surfaces, thus for kaolinite nanoparticles. The best-fit protonation site density for both surfaces is equal to 8.0 nm⁻², while the best-fit intrinsic pK_a for alumina and silica surfaces of HNT are equal to 9.0 and 8.5, respectively. The pH-dependence of electrophoretic mobility, measured by means of electrophoretic light scattering, reveals a more acidic behavior of the outermost silica surface than within the inner HNT phase, which is consistent with the literature result reported for kaolinite. The results reported herein confirm that the inner and outer surfaces of the HNT are oppositely charged below pH < 8.0 and negatively charged above that value, and importantly, they reveal new details about the protonation affinities and EDL parameters at active surfaces of HNT, important for the colloidal stability of HNT suspensions and the functionalization of HNT through the electrostatic binding of active molecules. Full article

This study aimed to investigate adhesive techniques applied to MIH-affected teeth by analyzing the one-year failure rate of restorations performed using total-etch and self-etch adhesive methods. This systematic review was conducted in accordance with the PRISMA 2020 statement. Eligibility criteria were defined using the PICO acronym. In vivo studies published from 2017 onward were evaluated. Two independent reviewers conducted the search on PubMed, Scopus, Cochrane, and Web of Science. The risk of bias was assessed with RoB2 and the Newcastle-Ottawa Scale. Statistical analysis was performed using the Open Meta [Analyst] software based on the absolute risk of failure. Results were presented as a pooled estimate with a 95% confidence interval (CI) and visualized in forest plots. Four RCTs and one retrospective cohort study were selected for the analysis. Data collected included information such as authors, study design, age, restorations, degree of hypomineralization, protocol, and follow-up. The meta-analysis showed no statistically significant differences between the techniques (p = 0.338) on MIH-affected teeth. This meta-analysis supports the use of both adhesive techniques for managing MIH teeth, emphasizing the need for further studies to examine the specific clinical and technical conditions under which each technique might be more advantageous. Full article