Gel Formation Processes and Materials for Functional Thin Films

A special issue of Gels (ISSN 2310-2861). This special issue belongs to the section "Gel Processing and Engineering".

Deadline for manuscript submissions: 20 July 2025 | Viewed by 883

Special Issue Editors


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Guest Editor
Faculty of Chemistry and Pharmacy, Sofia University, 1164 Sofia, Bulgaria
Interests: rare earth; lanthanoids; MOFs; sensors; luminescence; thin films; sol-gel; coating; gels

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Guest Editor
Institute of Optical Materials and Technologies, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria
Interests: optical sensors; thin films; nanomaterials
Special Issues, Collections and Topics in MDPI journals

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Guest Editor
Faculty of Chemistry and Pharmacy, Sofia University, Sofia, Bulgaria
Interests: coordination chemistry; rare earth complexes; immobilization matrices; photoluminescence
Special Issues, Collections and Topics in MDPI journals

Special Issue Information

Dear Colleagues,

This Special Issue on “Gel Formation Processes and Materials for Functional Thin Filmsis dedicated to the gels applied for obtaining thin films, which have a variety of applications.

Gels are multi-component soft materials with long mechanical relaxation times that can be deformed with modest stresses. One of the main characteristics of gels is their ability to hold shape. Gelation is the transition of a liquid to a disordered solid via the formation of a network of chemical or physical bonds between the molecules or particles composing the liquid.

Gels are commonly used for a great deal of applications: sustained-release delivery systems, materials responsive to specific molecules (glucose or antigens used as biosensors), diapers, contact lenses, medical electrodes, water–gel explosives, breast implants, paints, coatings, adhesives, recyclable absorbents, bioreactors containing immobilized enzymes, bioassay systems, display devices, actuators, valves, sensors, artificial muscles for robotic devices, chemical memories, optical shutters, molecular separation systems and toys.

Sol–gel processing is a versatile technique that may be employed to create a wide range of materials based on biopolymers, such as glasses, ceramics, and coatings. It is considered an economical and straightforward method. Chemical tailoring of raw materials to produce new functional compositions is more feasible than conventional methods. The sol–gel process entails the chemical transformation of a sol (liquid) into a gel (solid). A polymer solution is formed into a thin film on a substrate using different methods, such dip coating, spin coating, or spray coating. After drying and heating, the coated substrate removes the solvent and promotes crosslinking of the polymer molecules; then, a solid film is formed. By changing the composition of the starting materials and processing conditions, the characteristics of the resulting materials based on polymers can be tailored.

Thin-film coatings have been explored extensively since films are well suited for studying the physical properties of materials and have many scientific, technological, and commercial applications. Among the numerous applications is optical coating, as films are known for their distinctive optical properties that can be applied in electronic devices, data communications, ultra-fast optical data storage, sensor materials, etc. Moreover, films are used as protect coatings with good thermal and electrical properties and high resistance to oxidation. Porous films are used in various fields because of their high surface area. They are used in solar cells and in many surface reactions as catalysis, sensors, and so on.

Since it is impossible to cover all aspects of gel formation processes, we are hoping that this Special Issue will stimulate new research and discoveries in this field.

Dr. Denitsa K. Elenkova
Dr. Katerina Lazarova
Dr. Joana Zaharieva
Guest Editors

Manuscript Submission Information

Manuscripts should be submitted online at www.mdpi.com by registering and logging in to this website. Once you are registered, click here to go to the submission form. Manuscripts can be submitted until the deadline. All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the Editorial Office for announcement on this website.

Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a single-blind peer-review process. A guide for authors and other relevant information for submission of manuscripts is available on the Instructions for Authors page. Gels is an international peer-reviewed open access monthly journal published by MDPI.

Please visit the Instructions for Authors page before submitting a manuscript. The Article Processing Charge (APC) for publication in this open access journal is 2100 CHF (Swiss Francs). Submitted papers should be well formatted and use good English. Authors may use MDPI's English editing service prior to publication or during author revisions.

Keywords

  • sol–gel method
  • gels
  • thin films
  • deep coating
  • spin coating
  • film applications
  • membranes

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Published Papers (2 papers)

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Research

14 pages, 5970 KiB  
Article
Si3N4 Nanoparticle Reinforced Si3N4 Nanofiber Aerogel for Thermal Insulation and Electromagnetic Wave Transmission
by Zongwei Tong, Xiangjie Yan, Yun Liu, Yali Zhao and Kexun Li
Gels 2025, 11(5), 324; https://doi.org/10.3390/gels11050324 - 26 Apr 2025
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Abstract
Traditional nanoparticle aerogels suffer from inherent brittleness and thermal instability at elevated temperatures. In recent years, ceramic nanofiber aerogels, utilizing flexible nanofibers as structural units, have emerged as mechanically resilient alternatives with ultrahigh porosity (>90%). However, their thermal insulation capabilities are compromised by [...] Read more.
Traditional nanoparticle aerogels suffer from inherent brittleness and thermal instability at elevated temperatures. In recent years, ceramic nanofiber aerogels, utilizing flexible nanofibers as structural units, have emerged as mechanically resilient alternatives with ultrahigh porosity (>90%). However, their thermal insulation capabilities are compromised by micron-scale pores (10–100 μm) and overdependence on ultralow density, which exacerbates mechanical fragility. This study pioneers a gas-phase self-assembly strategy to fabricate Si3N4 nanoparticle reinforced Si3N4 nanofiber aerogels (SNP-R-SNFA) with gradient pore architectures. By leveraging methyltrimethoxysilane/vinyltriethoxysilane composite aerogel (MVa) as a reactive template, we achieved spontaneous growth of Si3N4 nanofiber films (SNP-R-SNF) featuring nanoparticle-fiber interpenetration and porosity gradients. The microstructure formation mechanism of SNP-R-SNF was analyzed using field-emission scanning electron microscopy. Layer assembly and hot-pressing composite technology were employed to prepare the SNP-R-SNFA, which showed low density (0.033 g/cm3), exceptional compression resilience, insensitive frequency dependence of dielectric properties (ε′ = 2.31–2.39, tan δ < 0.08 across 8–18 GHz). Infrared imaging displayed backside 893 °C cooler than front, demonstrating superior insulation performance. This study not only provides material solutions for integrated electromagnetic wave-transparent/thermal insulation applications but more importantly establishes an innovative paradigm for enhancing the mechanical robustness of nanofiber-based aerogels. Full article
(This article belongs to the Special Issue Gel Formation Processes and Materials for Functional Thin Films)
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15 pages, 3901 KiB  
Article
Distributed Flexible Sensors Based on Supercapacitor Gel Materials
by Chenghong Zhang
Gels 2025, 11(2), 139; https://doi.org/10.3390/gels11020139 - 16 Feb 2025
Viewed by 397
Abstract
Gel material sensors are lightweight, have fast response speeds and low driving voltages, and have recently become a popular research topic worldwide in the bionics field. A sensing unit is formed by pressing two kinds of gel materials together: a positioning layer gel [...] Read more.
Gel material sensors are lightweight, have fast response speeds and low driving voltages, and have recently become a popular research topic worldwide in the bionics field. A sensing unit is formed by pressing two kinds of gel materials together: a positioning layer gel based on acrylamide and lithium chloride and a sensing layer gel based on the ionic liquid BMIMBF4. Based on a stress–strain experiment of the sensing layer gel, a constitutive relationship model of its hyperelastic mechanical properties was established, and the elastic modulus and Poisson’s ratio of the sensing layer material were deduced. The capacitive response of the ion‒gel shunt capacitor to loading was observed to prove its ability to act as a pressure sensor. Although the gel thickness differs, the capacitance and load pressure exhibit a linear relationship. The capacitance was measured via cyclic voltammetry using the equivalent plate capacitor model for the positioning layer gel. The capacitance range of the gel sensor of a certain size was obtained via the cyclic voltammetry integral formula, which provided parameters for circuit design. A plate capacitor model of the sensing layer gel and an open four-impedance branch parallel model of the positioning layer gel were established. Two confirmatory experiments were designed for the models: first, the relationship between the sensing layer force and capacitance was measured, and the function curve relationship was established via a black box model; second, the theoretical and measured points of the positioning layer were compared, and the error was analyzed and corrected. Full article
(This article belongs to the Special Issue Gel Formation Processes and Materials for Functional Thin Films)
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