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Search Results (1,037)

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Keywords = energy-absorbing properties

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25 pages, 13557 KiB  
Article
Mechanical Properties and Energy Absorption Characteristics of a Combined Gradient BCC Lattice Structure: A Numerical Study
by Xiangheng Zhao, Xiaoqiang Wang and Yunmiao Shang
Materials 2025, 18(15), 3652; https://doi.org/10.3390/ma18153652 - 4 Aug 2025
Viewed by 133
Abstract
As a new functional graded lattice structure construction strategy, the relative density gradient strategy has a promising future due to its ease of realization in various lattice structures. This paper proposes a BCC lattice structure combining two different lattice single cells. Based on [...] Read more.
As a new functional graded lattice structure construction strategy, the relative density gradient strategy has a promising future due to its ease of realization in various lattice structures. This paper proposes a BCC lattice structure combining two different lattice single cells. Based on this, the single cells of different structures are assigned different relative density gradients, resulting in 18 combined gradient lattice structures. Based on proving the experimental feasibility of numerical simulation, the mechanical properties and energy absorption characteristics of the combined gradient lattice structure are investigated by numerical simulation. When applied to composite lattice structures, the proposed wave-like gradient design significantly improves mechanical properties. Among the various gradient strategies examined, several have achieved mechanical performance close to that of uniform lattice structures. To some extent, this approach mitigates the common drawback of gradient lattice structures—where the relative density of the weakest layer is consistently lower than the interlayer relative density of uniform lattice structures—resulting in varying degrees of mechanical performance degradation compared to their uniform counterparts. The proposed linearly enhanced gradient strategy (Strategy-LE) possesses higher SEA and CLE values when the lattice structure is subjected to compressive loading, with an improvement of 6.36% in SEA and 61.6% in CLE over the uniform structure. Through the relative density gradient design, the adaptability of the BCC lattice structure in actual complex application scenarios is greatly enhanced, and the energy-absorbing properties of the lattice structure are greatly improved. Full article
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14 pages, 2082 KiB  
Article
Effect of the Growth Period of Tree Leaves and Needles on Their Fuel Properties
by Tadeusz Dziok, Justyna Łaskawska and František Hopan
Energies 2025, 18(15), 4109; https://doi.org/10.3390/en18154109 - 2 Aug 2025
Viewed by 235
Abstract
The main advantage of using biomass for energy generation is the reduction in carbon dioxide emissions. For a fast reduction effect, it is important to use biomass characterised by an annual growth cycle. These may be fallen leaves. The fuel properties of the [...] Read more.
The main advantage of using biomass for energy generation is the reduction in carbon dioxide emissions. For a fast reduction effect, it is important to use biomass characterised by an annual growth cycle. These may be fallen leaves. The fuel properties of the leaves can change during the growth period. These changes can result from both the natural growth process and environmental factors—particulate matter adsorption. The main objective was to determine changes in the characteristics of leaves and needles during the growth period (from May to October). Furthermore, to determine the effect of adsorbed particulate matter, the washing process was carried out. Studies were carried out for three tree species: Norway maple, horse chestnut and European larch. Proximate and ultimate analysis was performed and mercury content was determined. During the growth period, beneficial changes were observed: an increase in carbon content and a decrease in hydrogen and sulphur content. The unfavourable change was a significant increase in ash content, which caused a decrease in calorific value. The increase in ash content was caused by adsorbed particulate matter. They were mostly absorbed by the tissues of the needle and leaves and could not be removed by washing the surface. Full article
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15 pages, 2018 KiB  
Article
Study on Preparation and Properties of Super Absorbent Gels of Homogenous Cotton Straw-Acrylic Acid-Acrylamide by Graft Copolymerization
by Jun Guo, Jing Shi, Lisheng Xu, Xingtao Zhang, Fangkai Han and Minwei Xu
Gels 2025, 11(8), 583; https://doi.org/10.3390/gels11080583 - 28 Jul 2025
Viewed by 218
Abstract
To rationally utilize and develop agricultural waste products, this research involved the synthesis of degradable high water-absorbing resin through the graft copolymerization of cotton straw (CS) with monomers. Among them, acrylic acid (AA) and acrylamide (Am) are used as grafting copolymer monomers, cellulose [...] Read more.
To rationally utilize and develop agricultural waste products, this research involved the synthesis of degradable high water-absorbing resin through the graft copolymerization of cotton straw (CS) with monomers. Among them, acrylic acid (AA) and acrylamide (Am) are used as grafting copolymer monomers, cellulose in the straw serves as the network framework, and MBA acts as the crosslinking agent. 60Co gamma rays as initiators. Different concentrations of alkaline solution were used to dissolve the cellulose in the straw. Single-factor and orthogonal experiments were conducted to optimize the experimental conditions. various analytical methods such as thermogravimetric analysis (TG), X-ray crystallography (XRD), infrared spectroscopy (IR), and scanning electron microscopy (SEM) were employed to characterize the structure and properties of the product. 60Co gamma rays as initiators, can reduce the pollution caused by chemical initiators and lower energy consumption. Through this research, agricultural waste can be effectively utilized, reducing environmental pollution, lowering industrial energy consumption, and synthesizing degradable and environmentally friendly high-absorbent resins. The product can be applied to agricultural water retention agent, fertilizer controlled release agent and other aspects. Full article
(This article belongs to the Special Issue Cellulose-Based Hydrogels for Advanced Applications)
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19 pages, 2633 KiB  
Article
Influence of Mullite and Halloysite Reinforcement on the Ablation Properties of an Epoxy Composite
by Robert Szczepaniak, Michał Piątkiewicz, Dominik Gryc, Paweł Przybyłek, Grzegorz Woroniak and Joanna Piotrowska-Woroniak
Materials 2025, 18(15), 3530; https://doi.org/10.3390/ma18153530 - 28 Jul 2025
Viewed by 273
Abstract
This paper explores the impact of applying a powder additive in the form of halloysite and mullite on the thermal protection properties of a composite. The authors used CES R70 epoxy resin with CES H72 hardener, modified by varying the amount of powder [...] Read more.
This paper explores the impact of applying a powder additive in the form of halloysite and mullite on the thermal protection properties of a composite. The authors used CES R70 epoxy resin with CES H72 hardener, modified by varying the amount of powder additive. The composite samples were exposed to a mixture of combustible gases at a temperature of approximately 1000 °C. The primary parameters analyzed during this study were the temperature on the rear surface of the sample and the ablative mass loss of the tested material. The temperature increase on the rear surface of the sample, which was exposed to the hot stream of flammable gases, was measured for 120 s. Another key parameter considered in the data analysis was the ablative mass loss. The charred layer of the sample played a crucial role in this process, as it helped block oxygen diffusion from the boundary layer of the original material. This charred layer absorbed thermal energy until it reached a temperature at which it either oxidized or was mechanically removed due to the erosive effects of the heating factor. The incorporation of mullite reduced the rear surface temperature from 58.9 °C to 49.2 °C, and for halloysite, it was reduced the rear surface temperature to 49.8 °C. The ablative weight loss dropped from 57% to 18.9% for mullite and to 39.9% for halloysite. The speed of mass ablation was reduced from 77.9 mg/s to 25.2 mg/s (mullite) and 52.4 mg/s (halloysite), while the layer thickness loss decreased from 7.4 mm to 2.8 mm (mullite) and 4.4 mm (halloysite). This research is innovative in its use of halloysite and mullite as functional additives to enhance the ablative resistance of polymer composites under extreme thermal conditions. This novel approach not only contributes to a deeper understanding of composite behavior at high temperatures but also opens up new avenues for the development of advanced thermal protection systems. Potential applications of these materials include aerospace structures, fire-resistant components, and protective coatings in environments exposed to intense heat and flame. Full article
(This article belongs to the Section Advanced Composites)
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16 pages, 8118 KiB  
Article
The Influence of Long-Term Service on the Mechanical Properties and Energy Dissipation Capacity of Flexible Anti-Collision Rings
by Junhong Zhou, Jia Lu, Wei Jiang, Ang Li, Hancong Shao, Zixiao Huang, Fei Wang and Qiuwei Yang
Coatings 2025, 15(8), 880; https://doi.org/10.3390/coatings15080880 - 27 Jul 2025
Viewed by 287
Abstract
This study investigates the long-term performance of flexible anti-collision rings after 12 years of service on the Xiangshan Port Highway Bridge. Stepwise loading–unloading tests at multiple loading rates (0.8–80 mm/s) were performed on the anti-collision rings, with full-field strain measurement via digital image [...] Read more.
This study investigates the long-term performance of flexible anti-collision rings after 12 years of service on the Xiangshan Port Highway Bridge. Stepwise loading–unloading tests at multiple loading rates (0.8–80 mm/s) were performed on the anti-collision rings, with full-field strain measurement via digital image correlation (DIC) technology. The results show that: The mechanical response of the anti-collision ring shows significant asymmetric tension–compression, with the tensile peak force being 6.8 times that of compression. A modified Johnson–Cook model was developed to accurately characterize the tension–compression force–displacement behavior across varying strain rates (0.001–0.1 s−1). The DIC full-field strain analysis reveals that the clamping fixture significantly influences the tensile deformation mode of the anti-collision ring by constraining its inner wall movement, thereby altering strain distribution patterns. Despite exhibiting a corrosion gradient from severe underwater degradation to minimal surface weathering, all tested rings demonstrated consistent mechanical performance, verifying the robust protective capability of the rubber coating in marine service conditions. Full article
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14 pages, 838 KiB  
Article
Impact of Water Vapor on the Predictive Modeling of Full-Scale Indirectly Heated Biomass Torrefaction System Throughput Capacity
by Chaitanya Bhatraju, Matthew Russell and Martijn Dekker
Energies 2025, 18(15), 3978; https://doi.org/10.3390/en18153978 - 25 Jul 2025
Viewed by 227
Abstract
Biomass torrefaction must be self-sustaining and continuous to be commercially viable, eliminating dependence on additional fuels while achieving industrial-scale production. This study presents a predictive model of a full-scale continuous biomass torrefaction process that explicitly incorporates the radiation absorption properties of torrefaction gas, [...] Read more.
Biomass torrefaction must be self-sustaining and continuous to be commercially viable, eliminating dependence on additional fuels while achieving industrial-scale production. This study presents a predictive model of a full-scale continuous biomass torrefaction process that explicitly incorporates the radiation absorption properties of torrefaction gas, with a focus on water vapor. Previous research, primarily based on lab-scale batch processes, has not adequately addressed scale-up challenges or the dynamic evolution of torrefaction gas. Industrial insights from Perpetual Next confirm that water vapor significantly impacts reactor performance by absorbing heat and reducing radiative flux to the biomass. Simulations show that neglecting water vapor absorption in reactor design can lead to throughput deviations of 10–20%, affecting process stability and efficiency. Industrial-scale validation demonstrates that the model accurately predicts this effect, ensuring realistic energy demand and throughput expectations. By explicitly incorporating water vapor absorption into the radiation balance, the model provides a validated framework for optimizing reactor design and process scale-up. It demonstrates that failing to consider this effect can lead to operational instability and deviations from the intended torrefaction severity, ultimately affecting industrial-scale performance and self-sustaining operation. Full article
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18 pages, 3257 KiB  
Article
Experimental Study on the Effects of Loading Rates on the Fracture Mechanical Characteristics of Coal Influenced by Long-Term Immersion in Mine Water
by Xiaobin Li, Gan Feng, Mingli Xiao, Guifeng Wang, Jing Bi, Chunyu Gao and Huaizhong Liu
Appl. Sci. 2025, 15(15), 8222; https://doi.org/10.3390/app15158222 - 24 Jul 2025
Viewed by 236
Abstract
Underground pumped storage hydropower stations (UPSH) are of great significance for energy structure adjustment, and coal mine underground reservoirs are an integral part of UPSH. This study investigates the fracture mechanics behavior of coal in mine water immersion environments with varying loading rates [...] Read more.
Underground pumped storage hydropower stations (UPSH) are of great significance for energy structure adjustment, and coal mine underground reservoirs are an integral part of UPSH. This study investigates the fracture mechanics behavior of coal in mine water immersion environments with varying loading rates and layer direction. Three types of samples were analyzed: Crack-arrester, Crack-splitter, and Crack-divider types. The immersion duration extended up to 120 days. The results indicate that, after immersion in mine water for 120 days, the fracture toughness (KIC), fracture modulus (ES), and absorbed energy (UT) of coal decreased by 60.87%, 53.38%, and 63.21%, respectively, compared to the unsaturated coal samples. An immersion period of 30 days significantly weakens the mechanical properties of coal fractures. The KIC, ES, and UT of coal demonstrate a positive correlation with loading rate, primarily influenced by the duration of coal damage. At the same loading rate, the order of fracture toughness among the three coal types is as follows: Crack-divider > Crack-arrester > Crack-splitter. This hierarchy is determined by the properties of the coal matrix and bedding planes, as well as the mechanical structures composed of them. This study holds significant implications for the safe construction and operational design of underground water reservoirs in coal mines. Full article
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20 pages, 2071 KiB  
Article
Thermal Performance and Energy Efficiency Evaluation of Building Envelopes Incorporating Trombe Walls, PCM, and Multi-Alveolar Structures in Tunisian Climate
by Nour Lajimi, Noureddine Boukadida, Chemseddine Maatki, Bilel Hadrich, Walid Hassen, Lioua Kolsi and Habib Ben Aissia
Buildings 2025, 15(14), 2575; https://doi.org/10.3390/buildings15142575 - 21 Jul 2025
Viewed by 272
Abstract
Solar energy is one of the most promising solutions for improving building energy efficiency. Among passive heating systems, the combination of a Trombe wall, phase change materials (PCM), and multi-alveolar structures (MAS) stands out. This configuration enhances the wall’s ability to absorb solar [...] Read more.
Solar energy is one of the most promising solutions for improving building energy efficiency. Among passive heating systems, the combination of a Trombe wall, phase change materials (PCM), and multi-alveolar structures (MAS) stands out. This configuration enhances the wall’s ability to absorb solar heat and distribute it evenly throughout the interior. This study evaluated thermal comfort by examining the effects of phase change materials and multi-alveolar structures combined with a Trombe wall on the thermal behavior of a building and improving the thermal inertia of brick walls. Numerical simulations using Visual FORTRAN were conducted to evaluate the thermal properties of different configurations under the climatic conditions recorded in Hammam Sousse, Tunisia. The results show that the integration of the Trombe wall and PCM has a significant impact on interior temperature stability, energy consumption, and overall thermal comfort. The combined effect of the MAS and PCM with the Trombe wall improved heat gain in winter and spring, reaching a low thermal damping factor of 40% in March, reducing heating power, and optimizing thermal comfort for occupants. Full article
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13 pages, 7300 KiB  
Article
Strain and Layer Modulations of Optical Absorbance and Complex Photoconductivity of Two-Dimensional InSe: A Study Based on GW0+BSE Calculations
by Chuanghua Yang, Yuan Jiang, Wendeng Huang and Feng Pan
Crystals 2025, 15(7), 666; https://doi.org/10.3390/cryst15070666 - 21 Jul 2025
Viewed by 262
Abstract
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and [...] Read more.
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and the Bethe–Salpeter equation, we calculated the quasiparticle electronic structure, optical absorbance, and complex photoconductivity of 2D InSe from a single layer (1L) to three layers (3L). The calculation results show that the energy difference between the direct and indirect band gaps in 1L, 2L, and 3L InSe is so small that strain can readily tune its electronic structure. The 2D optical absorbance results calculated taking into account exciton effects show that light absorption increases rapidly near the band gap. Strain modulation of 1L InSe shows that it transforms from an indirect bandgap semiconductor to a direct bandgap semiconductor in the biaxial compressive strain range of −1.66 to −3.60%. The biaxial compressive strain causes a slight blueshift in the energy positions of the first and second absorption peaks in monolayer InSe while inducing a measurable redshift in the energy positions of the third and fourth absorption peaks. Full article
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18 pages, 4312 KiB  
Article
Influence of Rare Earth Elements on the Radiation-Shielding Behavior of Serpentinite-Based Materials
by Ayşe Didem Kılıç and Demet Yılmaz
Appl. Sci. 2025, 15(14), 7837; https://doi.org/10.3390/app15147837 - 13 Jul 2025
Viewed by 447
Abstract
In this study, the neutron and gamma radiation-shielding properties of serpentinites from the Guleman ophiolite complex were investigated, and results were evaluated in comparison with rare earth element (REE) content. The linear and mass attenuation coefficients (LAC and MAC), half-value layer (HVL), mean [...] Read more.
In this study, the neutron and gamma radiation-shielding properties of serpentinites from the Guleman ophiolite complex were investigated, and results were evaluated in comparison with rare earth element (REE) content. The linear and mass attenuation coefficients (LAC and MAC), half-value layer (HVL), mean free path (MFP), and effective atomic numbers (Zeff) of serpentinite samples were experimentally measured in the energy range of 80.99–383.85 keV. Theoretical MAC values were calculated. Additionally, fast neutron removal cross-sections, as well as thermal and fast neutron macroscopic cross-sections, were theoretically determined. The absorbed equivalent dose rates of serpentinite samples were also measured. The radiation protection efficiency (RPE) for gamma rays and neutrons were determined. It was observed that the presence of rare earth elements within serpentinite structure has a significant impact on thermal neutron cross-sections, while crystalline water content (LOI) plays an influential role in fast neutron cross-sections. Moreover, it has been observed that the concentration of gadolinium exerts a more substantial influence on the macroscopic cross-sections of thermal neutrons than on those of fast neutrons. The research results reveal the mineralogical, geochemical, morphological and radiation-shielding properties of serpentinite rocks contribute significantly to new visions for the use of this naturally occurring rock as a geological repository for nuclear waste or as a wall-covering material in radiotherapy centers and nuclear facilities instead of concrete. Full article
(This article belongs to the Special Issue Advanced Functional Materials and Their Applications)
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16 pages, 2819 KiB  
Article
High-Strain-Rate Deformation Behavior and Damage Mechanisms of Ti/Al Interpenetrating Phase Composites
by Zhou Li, Zhongli Zhang, Jiahao Tian, Junhao Li, Shiqi Xia, Libo Zhou and Long Yu
Processes 2025, 13(7), 2234; https://doi.org/10.3390/pr13072234 - 12 Jul 2025
Viewed by 391
Abstract
Interpenetrating phase composites (IPCs) have demonstrated tremendous potential across various fields, particularly those based on triply periodic minimal surface (TPMS) structures, whose uniquely interwoven lattice architectures have attracted widespread attention. However, current research on the dynamic mechanical properties of such IPC remains limited, [...] Read more.
Interpenetrating phase composites (IPCs) have demonstrated tremendous potential across various fields, particularly those based on triply periodic minimal surface (TPMS) structures, whose uniquely interwoven lattice architectures have attracted widespread attention. However, current research on the dynamic mechanical properties of such IPC remains limited, and their impact resistance and damage mechanisms are yet to be thoroughly understood. In this study, a novel design of two volume fractions of IPCs based on the TPMS IWP configuration is developed using Python-based parametric modeling, with the Ti6Al4V alloy TPMS scaffolds fabricated via selective laser melting (SLM) and the AlSi12 reinforcing phase through infiltration casting. The influence of Ti alloy volume fraction and strain rate on the dynamic mechanical behavior of the Ti/Al IPC is systematically investigated using a split Hopkinson pressure bar (SHPB) experimental setup. Microscopic characterization validates the effectiveness and reliability of the proposed IPC fabrication method. Results show that the increasing Ti alloy volume fraction significantly affects the dynamic mechanical properties of the IPC, and IPCs with different Ti alloy volume fractions exhibit contrasting mechanical behaviors under increasing strain rates, attributed to the dominance of different constituent phases. This study enhances the understanding of the dynamic behavior of TPMS-based IPCs and offers a promising route for the development of high-performance energy-absorbing materials. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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28 pages, 7820 KiB  
Review
Mechanisms and Performance of Composite Joints Through Adhesive and Interlocking Means—A Review
by Khishigdorj Davaasambuu, Yu Dong, Alokesh Pramanik and Animesh Kumar Basak
J. Compos. Sci. 2025, 9(7), 359; https://doi.org/10.3390/jcs9070359 - 10 Jul 2025
Viewed by 864
Abstract
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their [...] Read more.
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their geometries and mechanical properties of bonded materials. As such, joint geometry and material properties play a critical role in determining the capability of the joints to withstand high loads, resist fatigue, and absorb energy under impact loading. This paper investigates the effects of geometry and material dissimilarity on the performance of both conventional bonded and interlocking joints under tensile loading based on the information available in the literature. In addition, bonding and load transfer mechanisms were analysed in detail. It was found that stress concentration often occurs at free edges of the adhesive layer due to geometric discontinuities, while most of the load is carried by these regions rather than its centre. Sharp corners further intensify resulting stresses, thereby increasing the risk of joint failure. Adhesives typically resist shear loads better than peel loads, and stiffness mismatches between adherents induce an asymmetric stress distribution. Nonetheless, similar materials promote symmetric load sharing. Among conventional joints, scarf joints provide the most uniform load distribution. In interlocking joints such as dovetail, T-slot, gooseneck, and elliptical types, the outward bending of the female component under tension can lead to mechanical failure. Full article
(This article belongs to the Special Issue Mechanical Properties of Composite Materials and Joints)
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23 pages, 1184 KiB  
Article
Time-Resolved Photoacoustic Response of Thin Semiconductors Measured with Minimal Volume Cell: Influence of Photoinduced Charge Carriers
by Slobodanka P. Galovic, Dragana K. Markushev, Dragan D. Markushev, Katarina Lj. Djordjevic, Marica N. Popovic, Edin Suljovrujic and Dragan M. Todorovic
Appl. Sci. 2025, 15(13), 7290; https://doi.org/10.3390/app15137290 - 28 Jun 2025
Viewed by 227
Abstract
When a semiconducting sample is illuminated by an intensity-modulated monochromatic light beam with photon energy exceeding the band gap, part of the absorbed energy is directly converted into heat through photon–lattice interactions. This gives rise to a heat source that closely follows the [...] Read more.
When a semiconducting sample is illuminated by an intensity-modulated monochromatic light beam with photon energy exceeding the band gap, part of the absorbed energy is directly converted into heat through photon–lattice interactions. This gives rise to a heat source that closely follows the temporal profile of the optical excitation, known as the fast heat source. Simultaneously, another portion of the absorbed energy is used to generate electron-hole pairs. These charge carriers diffuse together and recombine via electron–electron and electron–hole interactions, transferring their kinetic energy to the lattice and producing additional heating of the sample. This indirect heating mechanism, associated with carrier recombination, is referred to as the slow heat source. In this study, we develop a model describing surface temperature variations on the non-illuminated side of a thermally thin semiconductor exposed to a rectangular optical pulse, explicitly accounting for the contribution of surface charge carrier recombinations. Using this model, we investigate the influence of surface recombination velocity and the material’s plasma properties on the time-domain temperature response for both plasma-opaque and plasma-transparent samples. Our results demonstrate that charge carrier recombinations can significantly affect the transient photoacoustic signal recorded using a minimum volume cell, highlighting the potential of time-resolved photoacoustic techniques for probing the electronic properties of semiconductors. Full article
(This article belongs to the Special Issue Advances in Photoacoustic and Photothermal Phenomena)
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19 pages, 5775 KiB  
Article
Optimizing Zinc Selenide and Silicon-Based Heterojunction Solar Cells for Enhanced Photovoltaic Performance
by Amina Laouid, Amine Alaoui Belghiti, Ali Abouais, Krzysztof Wisniewski, Mouhaydine Tlemçani, Przemysław Płóciennik, Abdelowahed Hajjaji and Anna Zawadzka
Solar 2025, 5(3), 29; https://doi.org/10.3390/solar5030029 - 25 Jun 2025
Viewed by 337
Abstract
In the purpose of enhancing solar cell efficiency and sustainability, zinc selenide (ZnSe) and silicon (Si) play indispensable roles, offering a compelling combination of stability and transparency while also highlighting their abundant availability. This study utilizes the SCAPS_1D tool to explore diverse heterojunction [...] Read more.
In the purpose of enhancing solar cell efficiency and sustainability, zinc selenide (ZnSe) and silicon (Si) play indispensable roles, offering a compelling combination of stability and transparency while also highlighting their abundant availability. This study utilizes the SCAPS_1D tool to explore diverse heterojunction setups, aiming to solve the nuanced correlation between key parameters and photovoltaic performance, therefore contributing significantly to the advancement of sustainable energy solutions. Exploring the performance analysis of heterojunction solar cell configurations employing ZnSe and Si elements, various configurations including SnO2/ZnSe/p_Si/p+_Si, SnO2/CdS/p_Si/p+_Si, TiO2/ZnSe/p_Si/p+_Si, and TiO2/CdS/p_Si/p+_Si are investigated, delving into parameters such as back surface field thickness (BSF), doping concentration, operating temperature, absorber layer properties, electron transport layer properties, interface defects, series and shunt resistance. Among these configurations, the SnO2/ZnSe/p_Si/p+_Si configuration with a doping concentration of 1019 cm−3 and a BSF thickness of 2 μm, illustrates a remarkable conversion efficiency of 22.82%, a short circuit current density (Jsc) of 40.33 mA/cm2, an open circuit voltage (Voc) of 0.73 V, and a fill factor (FF) of 77.05%. Its environmentally friendly attributes position it as a promising contender for advanced photovoltaic applications. This work emphasizes the critical role of parameter optimization in propelling solar cell technologies toward heightened efficiency and sustainability. Full article
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15 pages, 2266 KiB  
Article
SCAPS-1D Simulation of Various Hole Transport Layers’ Impact on CsPbI2Br Perovskite Solar Cells Under Indoor Low-Light Conditions
by Chih-Hsi Peng and Yi-Cheng Lin
Solids 2025, 6(3), 31; https://doi.org/10.3390/solids6030031 - 21 Jun 2025
Viewed by 723
Abstract
This study presents the first comprehensive theoretical investigation utilizing SCAPS-1D simulation to systematically evaluate eight hole transport materials for CsPbI2Br perovskite solar cells under authentic indoor LED conditions (560 lux, 5700 K color temperature). Unlike previous studies employing simplified illumination assumptions, [...] Read more.
This study presents the first comprehensive theoretical investigation utilizing SCAPS-1D simulation to systematically evaluate eight hole transport materials for CsPbI2Br perovskite solar cells under authentic indoor LED conditions (560 lux, 5700 K color temperature). Unlike previous studies employing simplified illumination assumptions, our work establishes fundamental design principles for indoor photovoltaics through rigorous material property correlations. The investigation explores the influence of layer thickness and defect concentration on performance to identify optimal parameters. Through detailed energy band alignment analysis, we demonstrate that CuI achieves superior performance (PCE: 23.66%) over materials with significantly higher mobility, revealing that optimal band alignment supersedes carrier mobility under low-light conditions. Analysis of HTL and absorber layer thickness, bulk defect concentration, interface defect density, and an HTL-free scenario showed that interface defect concentration and absorber layer parameters have greater influence than HTL thickness. Remarkably, ultra-thin HTL layers (0.04 μm) maintain >99% efficiency, offering substantial cost reduction potential for large-scale manufacturing. Under optimized conditions of a 0.87 μm absorber layer thickness, defect concentration of 1015 cm−3, interface defect concentration of 109 cm−3, and CuI doping concentration of 1017 cm−3, PCE reached 28.57%, while the HTL-free structure achieved 17.6%. This study establishes new theoretical foundations for indoor photovoltaics, demonstrating that material selection criteria differ fundamentally from outdoor applications. Full article
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