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Search Results (1,191)

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Keywords = energy absorbing materials

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24 pages, 9695 KiB  
Article
Dynamic Response and Stress Evolution of RPC Slabs Protected by a Three-Layered Energy-Dissipating System Based on the SPH-FEM Coupled Method
by Dongmin Deng, Hanqing Zhong, Shuisheng Chen and Zhixiang Yu
Buildings 2025, 15(15), 2769; https://doi.org/10.3390/buildings15152769 - 6 Aug 2025
Abstract
Aiming at the lightweight design of a bridge-shed integration structure, this paper presents a three-layered absorbing system in which a part of the sand cushion is replaced by expanded polystyrene (EPS) geofoam and the reinforced concrete (RC) protective slab is arranged above the [...] Read more.
Aiming at the lightweight design of a bridge-shed integration structure, this paper presents a three-layered absorbing system in which a part of the sand cushion is replaced by expanded polystyrene (EPS) geofoam and the reinforced concrete (RC) protective slab is arranged above the sand cushion to enhance the composite system’s safety. A three-dimensional Smoothed Particle Hydrodynamics–Finite Element Method (SPH-FEM) coupled numerical model is developed in LS-DYNA (Livermore Software Technology Corporation, Livermore, CA, USA, version R13.1.1), with its validity rigorously verified. The dynamic response of rockfall impacts on the shed slab with composite cushions of various thicknesses is analyzed by varying the thickness of sand and EPS materials. To optimize the cushion design, a specific energy dissipation ratio (SEDR), defined as the energy dissipation rate per unit mass (η/M), is introduced as a key performance metric. Furthermore, the complicated interactional mechanism between the rockfall and the optimum-thickness composite system is rationally interpreted, and the energy dissipation mechanism of the composite cushion is revealed. Using logistic regression, the ultimate stress state of the reactive powder concrete (RPC) slab is methodically analyzed, accounting for the speed and mass of the rockfall. The results are indicative of the fact that the composite cushion not only has less dead weight but also exhibits superior impact resistance compared to the 90 cm sand cushions; the impact resistance performance index SEDR of the three-layered absorbing system reaches 2.5, showing a remarkable 55% enhancement compared to the sand cushion (SEDR = 1.61). Additionally, both the sand cushion and the RC protective slab effectively dissipate most of the impact energy, while the EPS material experiences relatively little internal energy build-up in comparison. This feature overcomes the traditional vulnerability of EPS subjected to impact loads. One of the highlights of the present investigation is the development of an identification model specifically designed to accurately assess the stress state of RPC slabs under various rockfall impact conditions. Full article
(This article belongs to the Section Building Structures)
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19 pages, 3220 KiB  
Review
Integrated Technology of CO2 Adsorption and Catalysis
by Mengzhao Li and Rui Wang
Catalysts 2025, 15(8), 745; https://doi.org/10.3390/catal15080745 - 5 Aug 2025
Abstract
This paper discusses the integrated technology of CO2 adsorption and catalysis, which combines adsorption and catalytic conversion, simplifies the traditional process, reduces energy consumption, and improves efficiency. The traditional carbon capture technology has the problems of high energy consumption, equipment corrosion, and [...] Read more.
This paper discusses the integrated technology of CO2 adsorption and catalysis, which combines adsorption and catalytic conversion, simplifies the traditional process, reduces energy consumption, and improves efficiency. The traditional carbon capture technology has the problems of high energy consumption, equipment corrosion, and absorbent loss, while the integrated technology realizes the adsorption, conversion, and catalyst regeneration of CO2 in a single reaction system, avoiding complex desorption steps. Through micropore confinement and surface electron transfer mechanism, the technology improves the reactant concentration and mass transfer efficiency, reduces the activation energy, and realizes the low-temperature and high-efficiency conversion of CO2. In terms of materials, MOF-based composites, alkali metal modified oxides, and carbon-based hybrid materials show excellent performance, helping to efficiently adsorb and transform CO2. However, the design and engineering of reactors still face challenges, such as the development of new moving bed reactors. This technology provides a new idea for CO2 capture and resource utilization and has important environmental significance and broad application prospects. Full article
(This article belongs to the Special Issue Catalysis Accelerating Energy and Environmental Sustainability)
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19 pages, 2633 KiB  
Article
Influence of Mullite and Halloysite Reinforcement on the Ablation Properties of an Epoxy Composite
by Robert Szczepaniak, Michał Piątkiewicz, Dominik Gryc, Paweł Przybyłek, Grzegorz Woroniak and Joanna Piotrowska-Woroniak
Materials 2025, 18(15), 3530; https://doi.org/10.3390/ma18153530 - 28 Jul 2025
Viewed by 280
Abstract
This paper explores the impact of applying a powder additive in the form of halloysite and mullite on the thermal protection properties of a composite. The authors used CES R70 epoxy resin with CES H72 hardener, modified by varying the amount of powder [...] Read more.
This paper explores the impact of applying a powder additive in the form of halloysite and mullite on the thermal protection properties of a composite. The authors used CES R70 epoxy resin with CES H72 hardener, modified by varying the amount of powder additive. The composite samples were exposed to a mixture of combustible gases at a temperature of approximately 1000 °C. The primary parameters analyzed during this study were the temperature on the rear surface of the sample and the ablative mass loss of the tested material. The temperature increase on the rear surface of the sample, which was exposed to the hot stream of flammable gases, was measured for 120 s. Another key parameter considered in the data analysis was the ablative mass loss. The charred layer of the sample played a crucial role in this process, as it helped block oxygen diffusion from the boundary layer of the original material. This charred layer absorbed thermal energy until it reached a temperature at which it either oxidized or was mechanically removed due to the erosive effects of the heating factor. The incorporation of mullite reduced the rear surface temperature from 58.9 °C to 49.2 °C, and for halloysite, it was reduced the rear surface temperature to 49.8 °C. The ablative weight loss dropped from 57% to 18.9% for mullite and to 39.9% for halloysite. The speed of mass ablation was reduced from 77.9 mg/s to 25.2 mg/s (mullite) and 52.4 mg/s (halloysite), while the layer thickness loss decreased from 7.4 mm to 2.8 mm (mullite) and 4.4 mm (halloysite). This research is innovative in its use of halloysite and mullite as functional additives to enhance the ablative resistance of polymer composites under extreme thermal conditions. This novel approach not only contributes to a deeper understanding of composite behavior at high temperatures but also opens up new avenues for the development of advanced thermal protection systems. Potential applications of these materials include aerospace structures, fire-resistant components, and protective coatings in environments exposed to intense heat and flame. Full article
(This article belongs to the Section Advanced Composites)
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19 pages, 474 KiB  
Review
A Review on the Technologies and Efficiency of Harvesting Energy from Pavements
by Shijing Chen, Luxi Wei, Chan Huang and Yinghong Qin
Energies 2025, 18(15), 3959; https://doi.org/10.3390/en18153959 - 24 Jul 2025
Viewed by 412
Abstract
Dark asphalt surfaces, absorbing about 95% of solar radiation and warming to 60–70 °C during summer, intensify urban heat while providing substantial prospects for energy extraction. This review evaluates four primary technologies—asphalt solar collectors (ASCs, including phase change material (PCM) integration), photovoltaic (PV) [...] Read more.
Dark asphalt surfaces, absorbing about 95% of solar radiation and warming to 60–70 °C during summer, intensify urban heat while providing substantial prospects for energy extraction. This review evaluates four primary technologies—asphalt solar collectors (ASCs, including phase change material (PCM) integration), photovoltaic (PV) systems, vibration-based harvesting, thermoelectric generators (TEGs)—focusing on their principles, efficiencies, and urban applications. ASCs achieve up to 30% efficiency with a 150–300 W/m2 output, reducing pavement temperatures by 0.5–3.2 °C, while PV pavements yield 42–49% efficiency, generating 245 kWh/m2 and lowering temperatures by an average of 6.4 °C. Piezoelectric transducers produce 50.41 mW under traffic loads, and TEGs deliver 0.3–5.0 W with a 23 °C gradient. Applications include powering sensors, streetlights, and de-icing systems, with ASCs extending pavement life by 3 years. Hybrid systems, like PV/T, achieve 37.31% efficiency, enhancing UHI mitigation and emissions reduction. Economically, ASCs offer a 5-year payback period with a USD 3000 net present value, though PV and piezoelectric systems face cost and durability challenges. Environmental benefits include 30–40% heat retention for winter use and 17% increased PV self-use with EV integration. Despite significant potential, high costs and scalability issues hinder adoption. Future research should optimize designs, develop adaptive materials, and validate systems under real-world conditions to advance sustainable urban infrastructure. Full article
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20 pages, 2071 KiB  
Article
Thermal Performance and Energy Efficiency Evaluation of Building Envelopes Incorporating Trombe Walls, PCM, and Multi-Alveolar Structures in Tunisian Climate
by Nour Lajimi, Noureddine Boukadida, Chemseddine Maatki, Bilel Hadrich, Walid Hassen, Lioua Kolsi and Habib Ben Aissia
Buildings 2025, 15(14), 2575; https://doi.org/10.3390/buildings15142575 - 21 Jul 2025
Viewed by 281
Abstract
Solar energy is one of the most promising solutions for improving building energy efficiency. Among passive heating systems, the combination of a Trombe wall, phase change materials (PCM), and multi-alveolar structures (MAS) stands out. This configuration enhances the wall’s ability to absorb solar [...] Read more.
Solar energy is one of the most promising solutions for improving building energy efficiency. Among passive heating systems, the combination of a Trombe wall, phase change materials (PCM), and multi-alveolar structures (MAS) stands out. This configuration enhances the wall’s ability to absorb solar heat and distribute it evenly throughout the interior. This study evaluated thermal comfort by examining the effects of phase change materials and multi-alveolar structures combined with a Trombe wall on the thermal behavior of a building and improving the thermal inertia of brick walls. Numerical simulations using Visual FORTRAN were conducted to evaluate the thermal properties of different configurations under the climatic conditions recorded in Hammam Sousse, Tunisia. The results show that the integration of the Trombe wall and PCM has a significant impact on interior temperature stability, energy consumption, and overall thermal comfort. The combined effect of the MAS and PCM with the Trombe wall improved heat gain in winter and spring, reaching a low thermal damping factor of 40% in March, reducing heating power, and optimizing thermal comfort for occupants. Full article
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13 pages, 7300 KiB  
Article
Strain and Layer Modulations of Optical Absorbance and Complex Photoconductivity of Two-Dimensional InSe: A Study Based on GW0+BSE Calculations
by Chuanghua Yang, Yuan Jiang, Wendeng Huang and Feng Pan
Crystals 2025, 15(7), 666; https://doi.org/10.3390/cryst15070666 - 21 Jul 2025
Viewed by 268
Abstract
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and [...] Read more.
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and the Bethe–Salpeter equation, we calculated the quasiparticle electronic structure, optical absorbance, and complex photoconductivity of 2D InSe from a single layer (1L) to three layers (3L). The calculation results show that the energy difference between the direct and indirect band gaps in 1L, 2L, and 3L InSe is so small that strain can readily tune its electronic structure. The 2D optical absorbance results calculated taking into account exciton effects show that light absorption increases rapidly near the band gap. Strain modulation of 1L InSe shows that it transforms from an indirect bandgap semiconductor to a direct bandgap semiconductor in the biaxial compressive strain range of −1.66 to −3.60%. The biaxial compressive strain causes a slight blueshift in the energy positions of the first and second absorption peaks in monolayer InSe while inducing a measurable redshift in the energy positions of the third and fourth absorption peaks. Full article
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15 pages, 3980 KiB  
Article
Four-Dimensional-Printed Woven Metamaterials for Vibration Reduction and Energy Absorption in Aircraft Landing Gear
by Xiong Wang, Changliang Lin, Liang Li, Yang Lu, Xizhe Zhu and Wenjie Wang
Materials 2025, 18(14), 3371; https://doi.org/10.3390/ma18143371 - 18 Jul 2025
Viewed by 338
Abstract
Addressing the urgent need for lightweight and reusable energy-absorbing materials in aviation impact resistance, this study introduces an innovative multi-directional braided metamaterial design enabled by 4D printing technology. This approach overcomes the dual challenges of intricate manufacturing processes and the limited functionality inherent [...] Read more.
Addressing the urgent need for lightweight and reusable energy-absorbing materials in aviation impact resistance, this study introduces an innovative multi-directional braided metamaterial design enabled by 4D printing technology. This approach overcomes the dual challenges of intricate manufacturing processes and the limited functionality inherent to traditional textile preforms. Six distinct braided structural units (types 1–6) were devised based on periodic trigonometric functions (Y = A sin(12πX)), and integrated with shape memory polylactic acid (SMP-PLA), thereby achieving a synergistic combination of topological architecture and adaptive response characteristics. Compression tests reveal that reducing strip density to 50–25% (as in types 1–3) markedly enhances energy absorption performance, achieving a maximum specific energy absorption of 3.3 J/g. Three-point bending tests further demonstrate that the yarn amplitude parameter A is inversely correlated with load-bearing capacity; for instance, the type 1 structure (A = 3) withstands a maximum load stress of 8 MPa, representing a 100% increase compared to the type 2 structure (A = 4.5). A multi-branch viscoelastic constitutive model elucidates the temperature-dependent stress relaxation behavior during the glass–rubber phase transition and clarifies the relaxation time conversion mechanism governed by the Williams–Landel–Ferry (WLF) and Arrhenius equations. Experimental results further confirm the shape memory effect, with the type 3 structure fully recovering its original shape within 3 s under thermal stimulation at 80 °C, thus addressing the non-reusability issue of conventional energy-absorbing structures. This work establishes a new paradigm for the design of impact-resistant aviation components, particularly in the context of anti-collision structures and reusable energy absorption systems for eVTOL aircraft. Future research should further investigate the regulation of multi-stimulus response behaviors and microstructural optimization to advance the engineering application of smart textile metamaterials in aviation protection systems. Full article
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18 pages, 4312 KiB  
Article
Influence of Rare Earth Elements on the Radiation-Shielding Behavior of Serpentinite-Based Materials
by Ayşe Didem Kılıç and Demet Yılmaz
Appl. Sci. 2025, 15(14), 7837; https://doi.org/10.3390/app15147837 - 13 Jul 2025
Viewed by 449
Abstract
In this study, the neutron and gamma radiation-shielding properties of serpentinites from the Guleman ophiolite complex were investigated, and results were evaluated in comparison with rare earth element (REE) content. The linear and mass attenuation coefficients (LAC and MAC), half-value layer (HVL), mean [...] Read more.
In this study, the neutron and gamma radiation-shielding properties of serpentinites from the Guleman ophiolite complex were investigated, and results were evaluated in comparison with rare earth element (REE) content. The linear and mass attenuation coefficients (LAC and MAC), half-value layer (HVL), mean free path (MFP), and effective atomic numbers (Zeff) of serpentinite samples were experimentally measured in the energy range of 80.99–383.85 keV. Theoretical MAC values were calculated. Additionally, fast neutron removal cross-sections, as well as thermal and fast neutron macroscopic cross-sections, were theoretically determined. The absorbed equivalent dose rates of serpentinite samples were also measured. The radiation protection efficiency (RPE) for gamma rays and neutrons were determined. It was observed that the presence of rare earth elements within serpentinite structure has a significant impact on thermal neutron cross-sections, while crystalline water content (LOI) plays an influential role in fast neutron cross-sections. Moreover, it has been observed that the concentration of gadolinium exerts a more substantial influence on the macroscopic cross-sections of thermal neutrons than on those of fast neutrons. The research results reveal the mineralogical, geochemical, morphological and radiation-shielding properties of serpentinite rocks contribute significantly to new visions for the use of this naturally occurring rock as a geological repository for nuclear waste or as a wall-covering material in radiotherapy centers and nuclear facilities instead of concrete. Full article
(This article belongs to the Special Issue Advanced Functional Materials and Their Applications)
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16 pages, 2819 KiB  
Article
High-Strain-Rate Deformation Behavior and Damage Mechanisms of Ti/Al Interpenetrating Phase Composites
by Zhou Li, Zhongli Zhang, Jiahao Tian, Junhao Li, Shiqi Xia, Libo Zhou and Long Yu
Processes 2025, 13(7), 2234; https://doi.org/10.3390/pr13072234 - 12 Jul 2025
Viewed by 394
Abstract
Interpenetrating phase composites (IPCs) have demonstrated tremendous potential across various fields, particularly those based on triply periodic minimal surface (TPMS) structures, whose uniquely interwoven lattice architectures have attracted widespread attention. However, current research on the dynamic mechanical properties of such IPC remains limited, [...] Read more.
Interpenetrating phase composites (IPCs) have demonstrated tremendous potential across various fields, particularly those based on triply periodic minimal surface (TPMS) structures, whose uniquely interwoven lattice architectures have attracted widespread attention. However, current research on the dynamic mechanical properties of such IPC remains limited, and their impact resistance and damage mechanisms are yet to be thoroughly understood. In this study, a novel design of two volume fractions of IPCs based on the TPMS IWP configuration is developed using Python-based parametric modeling, with the Ti6Al4V alloy TPMS scaffolds fabricated via selective laser melting (SLM) and the AlSi12 reinforcing phase through infiltration casting. The influence of Ti alloy volume fraction and strain rate on the dynamic mechanical behavior of the Ti/Al IPC is systematically investigated using a split Hopkinson pressure bar (SHPB) experimental setup. Microscopic characterization validates the effectiveness and reliability of the proposed IPC fabrication method. Results show that the increasing Ti alloy volume fraction significantly affects the dynamic mechanical properties of the IPC, and IPCs with different Ti alloy volume fractions exhibit contrasting mechanical behaviors under increasing strain rates, attributed to the dominance of different constituent phases. This study enhances the understanding of the dynamic behavior of TPMS-based IPCs and offers a promising route for the development of high-performance energy-absorbing materials. Full article
(This article belongs to the Section Manufacturing Processes and Systems)
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17 pages, 3260 KiB  
Article
The Implementation and Application of a Saudi Voxel-Based Anthropomorphic Phantom in OpenMC for Radiological Imaging and Dosimetry
by Ali A. A. Alghamdi
Diagnostics 2025, 15(14), 1764; https://doi.org/10.3390/diagnostics15141764 - 12 Jul 2025
Viewed by 437
Abstract
Objectives: This study aimed to implement a high-resolution Saudi voxel-based anthropomorphic phantom in the OpenMC Monte Carlo (MC) simulation framework. The objective was to evaluate its applicability in radiological simulations, including radiographic imaging and effective dose calculations, tailored to the Saudi population. [...] Read more.
Objectives: This study aimed to implement a high-resolution Saudi voxel-based anthropomorphic phantom in the OpenMC Monte Carlo (MC) simulation framework. The objective was to evaluate its applicability in radiological simulations, including radiographic imaging and effective dose calculations, tailored to the Saudi population. Methods: A voxel phantom comprising 30 segmented organs/tissues and over 32 million voxels were constructed from full-body computed tomography data and integrated into OpenMC. The implementation involved detailed voxel mapping, material definition using ICRP/ICRU-116 recommendations, and lattice geometry construction. The simulations included X-ray radiography projections using mesh tallies and anterior–posterior effective dose calculations across 20 photon energies (10 keV–1 MeV). The absorbed dose was calculated using OpenMC’s heating tally and converted to an effective dose using tissue weighting factors. Results: The phantom was successfully modeled and visualized in OpenMC, demonstrating accurate anatomical representation. Radiographic projections showed optimal contrast at 70 keV. The effective dose values for 29 organs were calculated and compared with MCNPX, the ICRP-116 reference phantom, and XGBoost-based machine learning (ML) predictions. OpenMC results showed good agreement, with maximum deviations of −35.5% against ICRP-116 at 10 keV. Root mean square error (RMSE) comparisons confirmed reasonable alignment, with OpenMC displaying higher RMSEs relative to other methods due to expanded organ modeling and material definitions. Conclusions: The integration of the Saudi voxel phantom into OpenMC demonstrates its utility for high-resolution dosimetry and radiographic simulations. OpenMC’s Python (version 3.10.14) interface and open-source nature make it a promising tool for radiological research. Future work will focus on combining MC and ML approaches for enhanced predictive dosimetry. Full article
(This article belongs to the Section Medical Imaging and Theranostics)
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20 pages, 5875 KiB  
Article
Crashworthiness of Additively Manufactured Crash Boxes: A Comparative Analysis of Fused Deposition Modeling (FDM) Materials and Structural Configurations
by Ahmed Saber, A. M. Amer, A. I. Shehata, H. A. El-Gamal and A. Abd_Elsalam
Appl. Mech. 2025, 6(3), 52; https://doi.org/10.3390/applmech6030052 - 11 Jul 2025
Viewed by 514
Abstract
Crash boxes play a crucial role in automotive safety by absorbing impact energy during collisions. The advancement of additive manufacturing (AM), particularly Fused Deposition Modeling (FDM), has enabled the fabrication of geometrically complex and lightweight crash boxes. This study presents a comparative evaluation [...] Read more.
Crash boxes play a crucial role in automotive safety by absorbing impact energy during collisions. The advancement of additive manufacturing (AM), particularly Fused Deposition Modeling (FDM), has enabled the fabrication of geometrically complex and lightweight crash boxes. This study presents a comparative evaluation of the crashworthiness performance of five FDM materials, namely, PLA+, PLA-ST, PLA-LW, PLA-CF, and PETG, across four structural configurations: Single-Cell Circle (SCC), Multi-Cell Circle (MCC), Single-Cell Square (SCS), and Multi-Cell Square (MCS). Quasi-static axial compression tests are conducted to assess the specific energy absorption (SEA) and crush force efficiency (CFE) of each material–geometry combination. Among the materials, PLA-CF demonstrates superior performance, with the MCC configuration achieving an SEA of 22.378 ± 0.570 J/g and a CFE of 0.732 ± 0.016. Multi-cell configurations consistently outperformed single-cell designs across all materials. To statistically quantify the influence of material and geometry on crash performance, a two-factor ANOVA was performed, highlighting geometry as the most significant factor across all evaluated metrics. Additionally, a comparative test with aluminum 6063-T5 demonstrates that PLA-CF offers comparable crashworthiness, with advantages in mass reduction, reduced PCF, and enhanced design flexibility inherent in AM. These findings provide valuable guidance for material selection and structural optimization in FDM-based crash boxes. Full article
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18 pages, 3495 KiB  
Article
Next-Generation Light Harvesting: MXene (Ti3C2Tx)-Based Metamaterial Absorbers for a Broad Wavelength Range from 0.3 μm to 18 μm
by Abida Parveen, Deepika Tyagi, Vijay Laxmi, Naeem Ullah, Faisal Ahmad, Ahsan Irshad, Keyu Tao and Zhengbiao Ouyang
Materials 2025, 18(14), 3273; https://doi.org/10.3390/ma18143273 - 11 Jul 2025
Viewed by 422
Abstract
Electromagnetic wave (EMW) absorption materials are crucial for a wide range of applications, yet most existing materials suffer from complex fabrication and narrow absorption bands, particularly under harsh environmental conditions. In this study, we introduce a broadband metamaterial absorber based on Ti3 [...] Read more.
Electromagnetic wave (EMW) absorption materials are crucial for a wide range of applications, yet most existing materials suffer from complex fabrication and narrow absorption bands, particularly under harsh environmental conditions. In this study, we introduce a broadband metamaterial absorber based on Ti3C2O2 MXene, a novel two-dimensional material that uniquely combines high electrical and metallic conductivity with hydrophilicity, biocompatibility, and an extensive surface area. Through advanced finite-difference time-domain (FDTD) simulations, the proposed absorber achieves over 95% absorption from 0.3 µm to 18 µm. Additionally, other MXene variants, including Ti3C2F2 and Ti3C2(OH)2, demonstrate robust absorption above 85%. This absorber not only outperforms previously reported structures in terms of efficiency and spectral coverage but also opens avenues for integration into applications such as infrared sensing, energy harvesting, wearable electronics, and Internet of Things (IoT) systems. Full article
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28 pages, 7820 KiB  
Review
Mechanisms and Performance of Composite Joints Through Adhesive and Interlocking Means—A Review
by Khishigdorj Davaasambuu, Yu Dong, Alokesh Pramanik and Animesh Kumar Basak
J. Compos. Sci. 2025, 9(7), 359; https://doi.org/10.3390/jcs9070359 - 10 Jul 2025
Viewed by 878
Abstract
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their [...] Read more.
Conventional adhesively bonded joints, such as single-lap, curved-lap, wavy-lap, double-lap, stepped-lap, and scarf joints, are widely used for aerospace, automotive, and medical applications. These adhesively bonded joints exhibit different load transfer mechanisms and stress distributions within adhesive layers, which depend primarily on their geometries and mechanical properties of bonded materials. As such, joint geometry and material properties play a critical role in determining the capability of the joints to withstand high loads, resist fatigue, and absorb energy under impact loading. This paper investigates the effects of geometry and material dissimilarity on the performance of both conventional bonded and interlocking joints under tensile loading based on the information available in the literature. In addition, bonding and load transfer mechanisms were analysed in detail. It was found that stress concentration often occurs at free edges of the adhesive layer due to geometric discontinuities, while most of the load is carried by these regions rather than its centre. Sharp corners further intensify resulting stresses, thereby increasing the risk of joint failure. Adhesives typically resist shear loads better than peel loads, and stiffness mismatches between adherents induce an asymmetric stress distribution. Nonetheless, similar materials promote symmetric load sharing. Among conventional joints, scarf joints provide the most uniform load distribution. In interlocking joints such as dovetail, T-slot, gooseneck, and elliptical types, the outward bending of the female component under tension can lead to mechanical failure. Full article
(This article belongs to the Special Issue Mechanical Properties of Composite Materials and Joints)
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14 pages, 2683 KiB  
Article
Study on the Adsorption Behavior of a Cellulose Nanofibril/Tannic Acid/Polyvinyl Alcohol Aerogel for Cu(II), Cd(II), and Pb(II) Heavy Metal Ions
by Xuejin Zhang, Yulong Tian, Huanhuan Chen, Ying Liu, Shuaichuang Han, Minmin Chang, Jingshun Zhuang and Qingzhi Ma
Nanomaterials 2025, 15(14), 1063; https://doi.org/10.3390/nano15141063 - 9 Jul 2025
Viewed by 332
Abstract
Nanocellulose-based composite aerogels have the advantages of high porosity, biodegradability, and biocompatibility, with wide applications in many fields, such as adsorption, separation, energy storage, and heat insulation. In this study, a nanocellulose-based composite aerogel (NCA) was prepared using the one-pot method with cellulose [...] Read more.
Nanocellulose-based composite aerogels have the advantages of high porosity, biodegradability, and biocompatibility, with wide applications in many fields, such as adsorption, separation, energy storage, and heat insulation. In this study, a nanocellulose-based composite aerogel (NCA) was prepared using the one-pot method with cellulose nanofibrils (CNFs), tannic acid (TA), and polyvinyl alcohol (PVA) as raw materials. The adsorption behaviors of Pb2+, Cd2+, and Cu2+ were also studied. FT-IR analysis confirmed that TA successfully solidified on the nanocellulose, while SEM analysis revealed that the prepared NCA exhibited significantly higher porosity compared with the cellulose nanofibril-only aerogel. The results of the adsorption experiment demonstrated that the adsorption behavior of heavy metal ions using the prepared NCA followed pseudo-second-order kinetics. The adsorption isotherms fit well with the Langmuir adsorption model, indicating that the process of aerogels adsorbing heavy metal ions is that of monolayer adsorption. Under conditions of pH 6 and an initial heavy metal ion concentration of 100 mg/L, the maximum adsorption capacity calculated for the prepared NCA was up to 196.850 mg/g, 181.488 mg/g, and 151.515 mg/g for Cu2+, Cd2+, and Pb2+, respectively. Furthermore, the prepared NCA exhibited excellent reusability, with more than 90% efficiency retained after three cycles. NCAs have the potential to become an efficient material for absorbing heavy metal ions in water. Full article
(This article belongs to the Section Nanocomposite Materials)
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19 pages, 3941 KiB  
Article
Efficient Energy Transfer Down-Shifting Material for Dye-Sensitized Solar Cells
by Emeka Harrison Onah, N. L. Lethole and P. Mukumba
Materials 2025, 18(14), 3213; https://doi.org/10.3390/ma18143213 - 8 Jul 2025
Viewed by 281
Abstract
Dye-sensitized solar cells (DSSCs) are promising alternatives for power generation due to their environmental friendliness, cost effectiveness, and strong performance under diffused light. Conversely, their low spectral response in the ultraviolet (UV) region significantly obliterates their overall performance. The so-called luminescent down-shifting (LDS) [...] Read more.
Dye-sensitized solar cells (DSSCs) are promising alternatives for power generation due to their environmental friendliness, cost effectiveness, and strong performance under diffused light. Conversely, their low spectral response in the ultraviolet (UV) region significantly obliterates their overall performance. The so-called luminescent down-shifting (LDS) presents a practical solution by converting high-energy UV photons into visible light that can be efficiently absorbed by sensitizer dyes. Herein, a conventional solid-state technique was applied for the synthesis of an LDS, europium (II)-doped barium orthosilicate (BaSiO3:Eu2+) material. The material exhibited strong UV absorption, with prominent peaks near 400 nm and within the 200–300 nm range, despite a weaker response in the visible region. The estimated optical bandgap was 3.47 eV, making it well-suited for UV absorbers. Analysis of the energy transfer mechanism from the LDS material to the N719 dye sensitizer depicted a strong spectral overlap of 2×1010M1cm1nm4, suggesting efficient energy transfer from the donor to the acceptor. The estimated Förster distance was approximately 6.83 nm, which matches the absorption profile of the dye-sensitizer. Our findings demonstrate the potential of BaSiO3:Eu2+ as an effective LDS material for enhancing UV light absorption and improving DSSC performance through increased spectral utilization and reduced UV-induced degradation. Full article
(This article belongs to the Special Issue Advanced Luminescent Materials and Applications)
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